US6632766B2 - Composite adsorbents for purifying hydrocarbon streams - Google Patents

Composite adsorbents for purifying hydrocarbon streams Download PDF

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Publication number
US6632766B2
US6632766B2 US09/733,693 US73369300A US6632766B2 US 6632766 B2 US6632766 B2 US 6632766B2 US 73369300 A US73369300 A US 73369300A US 6632766 B2 US6632766 B2 US 6632766B2
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United States
Prior art keywords
zeolite
adsorbent
component
alumina
metal
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Expired - Lifetime, expires
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US09/733,693
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English (en)
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US20020147377A1 (en
Inventor
Vladislav I. Kanazirev
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Honeywell UOP LLC
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UOP LLC
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Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Priority to US09/733,693 priority Critical patent/US6632766B2/en
Priority to CA2364052A priority patent/CA2364052C/fr
Priority to DE10159525A priority patent/DE10159525B4/de
Priority to CH02224/01A priority patent/CH695290A5/de
Priority to IT2001MI002575A priority patent/ITMI20012575A1/it
Priority to FR0115873A priority patent/FR2817772B1/fr
Priority to RU2001133532/15A priority patent/RU2264855C2/ru
Priority to KR1020010077393A priority patent/KR100807160B1/ko
Priority to AU97141/01A priority patent/AU778104B2/en
Priority to CNB011431067A priority patent/CN1230247C/zh
Priority to JP2001374409A priority patent/JP4185279B2/ja
Publication of US20020147377A1 publication Critical patent/US20020147377A1/en
Assigned to UOP LLC reassignment UOP LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KANAZIREV, LADISLAV I.
Priority to US10/459,785 priority patent/US7115154B1/en
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Publication of US6632766B2 publication Critical patent/US6632766B2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3007Moulding, shaping or extruding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041Oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • B01J20/183Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016Particle form
    • B01J20/28019Spherical, ellipsoidal or cylindrical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042Shaped bodies; Monolithic structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3035Compressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3078Thermal treatment, e.g. calcining or pyrolizing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3408Regenerating or reactivating of aluminosilicate molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3483Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3491Regenerating or reactivating by pressure treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/046Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by adsorption, i.e. with the use of solids
    • C10G70/047Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by adsorption, i.e. with the use of solids by molecular sieve technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/12Liquefied petroleum gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42Materials comprising a mixture of inorganic materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
US09/733,693 2000-12-08 2000-12-08 Composite adsorbents for purifying hydrocarbon streams Expired - Lifetime US6632766B2 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US09/733,693 US6632766B2 (en) 2000-12-08 2000-12-08 Composite adsorbents for purifying hydrocarbon streams
CA2364052A CA2364052C (fr) 2000-12-08 2001-11-30 Adsorbants composites servant a epurer les courants d'hydrocarbures
DE10159525A DE10159525B4 (de) 2000-12-08 2001-12-05 Adsorbentien für die Reinigung von Kohlenwasserstoffströmen, Verfahren zu deren Herstellung und Verfahren zur Entfernung von Verunreinigungen aus Kohlenwasserstoffströmen
IT2001MI002575A ITMI20012575A1 (it) 2000-12-08 2001-12-06 Materiali adsorbenti compositi per purificare correnti di idrocarburi
CH02224/01A CH695290A5 (de) 2000-12-08 2001-12-06 Adsorbentien fuer die Reinigung von Kohlenwasserstoffstroemen.
RU2001133532/15A RU2264855C2 (ru) 2000-12-08 2001-12-07 Твердый композиционный адсорбент для очистки углеводородных потоков, способ его получения и способ удаления примесей
FR0115873A FR2817772B1 (fr) 2000-12-08 2001-12-07 Adsorbants composites pour la purification des courants d'hydrocarbures
KR1020010077393A KR100807160B1 (ko) 2000-12-08 2001-12-07 탄화수소 스트림 정제용 복합 흡착제
AU97141/01A AU778104B2 (en) 2000-12-08 2001-12-07 Composite adsorbents for purifying hydrocarbon streams
CNB011431067A CN1230247C (zh) 2000-12-08 2001-12-07 用于提纯烃物流的复合吸附剂
JP2001374409A JP4185279B2 (ja) 2000-12-08 2001-12-07 炭化水素ストリーム精製用合成吸着剤
US10/459,785 US7115154B1 (en) 2000-12-08 2003-06-12 Process for purifying hydrogen streams using composite adsorbents

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/733,693 US6632766B2 (en) 2000-12-08 2000-12-08 Composite adsorbents for purifying hydrocarbon streams
DE10159525A DE10159525B4 (de) 2000-12-08 2001-12-05 Adsorbentien für die Reinigung von Kohlenwasserstoffströmen, Verfahren zu deren Herstellung und Verfahren zur Entfernung von Verunreinigungen aus Kohlenwasserstoffströmen

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/459,785 Continuation-In-Part US7115154B1 (en) 2000-12-08 2003-06-12 Process for purifying hydrogen streams using composite adsorbents

Publications (2)

Publication Number Publication Date
US20020147377A1 US20020147377A1 (en) 2002-10-10
US6632766B2 true US6632766B2 (en) 2003-10-14

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US09/733,693 Expired - Lifetime US6632766B2 (en) 2000-12-08 2000-12-08 Composite adsorbents for purifying hydrocarbon streams

Country Status (7)

Country Link
US (1) US6632766B2 (fr)
JP (1) JP4185279B2 (fr)
CN (1) CN1230247C (fr)
CA (1) CA2364052C (fr)
DE (1) DE10159525B4 (fr)
FR (1) FR2817772B1 (fr)
IT (1) ITMI20012575A1 (fr)

Cited By (22)

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Publication number Priority date Publication date Assignee Title
US20050230302A1 (en) * 2004-04-15 2005-10-20 Iain Muir Filtration and plug drain device for containing oil and chemical spills
US20070000383A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Adsorbent and catalyst mixtures
US20070116620A1 (en) * 2005-11-21 2007-05-24 Kanazirev Vladislav I Halide scavengers for high temperature applications
US20110073527A1 (en) * 2009-09-30 2011-03-31 Uop Llc Process for Removing Nitrogen Compounds from a Hydrocarbon Stream
US20110079145A1 (en) * 2009-10-06 2011-04-07 William Dolan Lower Reactivity Adsorbent and Higher Oxygenate Capacity for Removal of Oxygenates from Olefin Streams
US20130036904A1 (en) * 2011-08-10 2013-02-14 Jian Zheng Process for separating gases and adsorbent compositions used therein
US8435328B2 (en) 2011-01-11 2013-05-07 Praxair Technology, Inc. Ten bed pressure swing adsorption process operating in normal and turndown modes
WO2013093219A2 (fr) 2011-12-20 2013-06-27 IFP Energies Nouvelles Procede de purification de charges olefiniques a l'aide d'un adsorbant comprenant une zeolithe de type 12mr
US8491704B2 (en) 2011-01-11 2013-07-23 Praxair Technology, Inc. Six bed pressure swing adsorption process operating in normal and turndown modes
US8496733B2 (en) 2011-01-11 2013-07-30 Praxair Technology, Inc. Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes
US8551217B2 (en) 2011-01-11 2013-10-08 Praxair Technology, Inc. Six bed pressure swing adsorption process operating in normal and turndown modes
US20130341563A1 (en) * 2010-01-15 2013-12-26 Prakash Kumar Composite absorbent for catalyst residues removal from polyolefin solution polymerization mixture
EP2813290A1 (fr) 2013-06-10 2014-12-17 IFP Energies nouvelles Adsorbant à base d'une zéolithe et d'une argile riche en silice et procédé de purification de charges d'hydrocarbures contenant des molécules insaturées
WO2014209813A1 (fr) 2013-06-25 2014-12-31 Exxonmobil Chemical Patents Inc. Atténuation d'inhibition de catalyseur en polymérisation d'oélfines
US10047178B2 (en) 2017-02-07 2018-08-14 Exxonmobil Chemical Patents Inc. Mitigation of catalyst inhibition in olefin polymerization
US10179839B2 (en) 2016-11-18 2019-01-15 Exxonmobil Research And Engineering Company Sulfur terminated organosilica materials and uses thereof
US10183272B2 (en) 2014-12-12 2019-01-22 Exxonmobil Research And Engineering Company Adsorbent for heteroatom species removal and uses thereof
US10207249B2 (en) 2014-12-12 2019-02-19 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
WO2019045878A1 (fr) 2017-08-29 2019-03-07 Exxonmobil Chemical Patents Inc. Dioxyde de carbone en tant qu'agent de désactivation de catalyseur en polymérisation en solution, et produits fabriqués à partir de ce dernier
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
US10351639B2 (en) 2014-12-12 2019-07-16 Exxonmobil Research And Engineering Company Organosilica materials for use as adsorbents for oxygenate removal
US11660567B2 (en) 2017-05-24 2023-05-30 Basf Corporation Gas dehydration with mixed adsorbent/desiccant beds

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DE10322153A1 (de) * 2003-05-16 2004-12-02 Basf Ag Verringerung des Gehalts an sauerstoffhaltigen und/oder stickstoffhaltigen Verbindungen in isobutenhaltigen Stoffströmen
CN1795979B (zh) * 2004-12-23 2010-11-10 韩国电力公社 高强度干式再生用co2吸附剂
US7820591B2 (en) 2005-01-04 2010-10-26 Korea Electric Power Corporation Highly attrition resistant and dry regenerable sorbents for carbon dioxide capture
DE102005009596A1 (de) * 2005-02-28 2006-08-31 Basf Ag Verfahren zur Metathese umfassend die Reinigung der Ausgangsstoffe
TWI389738B (zh) * 2005-09-09 2013-03-21 Taiyo Nippon Sanso Corp Cu-ZSM5沸石成形吸附劑、其活性化方法、溫度變化型吸附裝置以及氣體精製方法
EP1953129A4 (fr) * 2005-11-14 2011-04-20 Mitsui Chemicals Inc Procede de production de propylene contenant du carbone ayant pour origine une biomasse
JP2007203215A (ja) * 2006-02-02 2007-08-16 Sekisui Chem Co Ltd 二酸化炭素の吸着システム及び脱着・回収システム
FR2918297B1 (fr) * 2007-07-06 2011-03-25 Inst Francais Du Petrole Purification d'une coupe olefinique par adsorption sur des cogranules alumine-faujasite.
CN101250080B (zh) * 2008-04-03 2011-02-16 中国石油大学(北京) 一种甲醇生产的烯烃的净化工艺
JP5119122B2 (ja) * 2008-10-20 2013-01-16 三井化学株式会社 粗炭化水素から含酸素化合物を除去する方法および精製炭化水素の製造方法
JP5119121B2 (ja) * 2008-10-20 2013-01-16 三井化学株式会社 粗炭化水素からエーテル類を除去する方法および精製炭化水素の製造方法
CN102307645B (zh) * 2009-02-06 2015-03-18 浦项工科大学校产学协力团 通过钠沸石类沸石选择性分离氢气或氦气的方法及新型钠沸石类沸石
CN101885656B (zh) * 2009-05-13 2013-12-04 中国石油化工股份有限公司 吸附净化烃类物流的方法
AP3601A (en) 2009-12-03 2016-02-24 Red Leaf Resources Inc Methods and systems for removing fines from hydrocarbon-containing fluids
JP5523924B2 (ja) * 2010-04-30 2014-06-18 Jx日鉱日石エネルギー株式会社 固体成型吸着剤及び炭化水素の精製方法
JP6073818B2 (ja) * 2011-03-08 2017-02-01 ダウ グローバル テクノロジーズ エルエルシー エチレン系重合反応中に使用される溶媒を再循環するための方法およびそのためのシステム
DK2736862T3 (en) * 2011-07-28 2016-01-18 Total Res & Technology Feluy PROCEDURE FOR REMOVING CONTAMINANTS FROM AN ETHYLENE CURRENT
CN102921373B (zh) * 2012-11-15 2014-12-03 上海绿强新材料有限公司 一种用于脱除烯烃流中杂质的吸附剂的制备方法
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CN114425296A (zh) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 脱除烯烃中极性化合物的吸附剂及其制备方法和应用
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Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069172A (en) * 1975-03-17 1978-01-17 Toray Industries, Inc. Adsorbent for aromatic hydrocarbon mixture separation
US4376103A (en) * 1981-10-26 1983-03-08 Standard Oil Company (Indiana) Removing sulfur oxides from a gas
US4481104A (en) * 1981-10-26 1984-11-06 Mobil Oil Corporation Use of low acidity high silica to alumina ratio large pore zeolites for distillate production in catalytic cracking
US4686198A (en) 1986-06-23 1987-08-11 Aluminum Company Of America Method for regenerating adsorbent mixture of alumina and zeolite for adsorption of ammonia
US4717483A (en) 1986-06-23 1988-01-05 Aluminum Company Of America Purification of waste stream from tanning process by adsorption on an adsorbent comprising a mixture of alumina and Y zeolite
US4751211A (en) 1986-08-07 1988-06-14 Aluminum Company Of America Composite adsorbent for removing acids from organophosphate functional fluids
US4762537A (en) 1985-11-07 1988-08-09 Aluminum Company Of America Adsorbent for HCl comprising alumina and acid-treated Y zeolite
US4808742A (en) 1986-08-07 1989-02-28 Aluminum Company Of America Method for removing acids from organophosphate functional fluids
US5068483A (en) * 1987-11-23 1991-11-26 Centre National De La Recherche Scientifique Catalysts based on zeolites modified by alkali metal elements in the metallic form, their preparation, and their application to alkylation of alkylaromatic derivatives
US5194244A (en) * 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
JPH0748319A (ja) * 1992-11-20 1995-02-21 Chiyoda Corp ジアルキルカーボネートの製造方法
JPH0959204A (ja) * 1995-08-24 1997-03-04 Mitsui Toatsu Chem Inc アセトン脱水縮合物の製造方法
US5672799A (en) * 1993-06-16 1997-09-30 Eniricerche S.P.A. Process for the preparation of cumene
US6013600A (en) * 1997-05-23 2000-01-11 Laroche Industries Inc. Alumina bodies containing alkali or alkaline earth metal compounds
US6090738A (en) * 1997-03-10 2000-07-18 Indian Petrochemical Corp. Ltd. Process for the preparation of a molecular sieve adsorbent for selectively adsorbing methane from a gaseous mixture
US6423658B1 (en) * 1999-04-29 2002-07-23 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Adsorbent with a high macroporosity, usable in a gas adsorption process, especially a PSA process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048111A (en) * 1975-06-12 1977-09-13 Uop Inc. Method for manufacturing an adsorbent useful for olefin separation
JPS57196720A (en) * 1981-05-28 1982-12-02 Toyo Soda Mfg Co Ltd Molded body of modified zeolite
US4935580A (en) * 1988-06-14 1990-06-19 Uop Process for purification of hydrocarbons using metal exchanged clinoptilolite to remove carbon dioxide
BE1003395A3 (fr) * 1989-10-16 1992-03-17 Fina Research Procede de traitement d'un materiau absorbant usage a base de nickel.
US5779767A (en) * 1997-03-07 1998-07-14 Air Products And Chemicals, Inc. Use of zeolites and alumina in adsorption processes
ZA987966B (en) * 1997-09-30 1999-02-22 Boc Group Inc Removal of carbon dioxide from air

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069172A (en) * 1975-03-17 1978-01-17 Toray Industries, Inc. Adsorbent for aromatic hydrocarbon mixture separation
US4376103A (en) * 1981-10-26 1983-03-08 Standard Oil Company (Indiana) Removing sulfur oxides from a gas
US4481104A (en) * 1981-10-26 1984-11-06 Mobil Oil Corporation Use of low acidity high silica to alumina ratio large pore zeolites for distillate production in catalytic cracking
US4762537A (en) 1985-11-07 1988-08-09 Aluminum Company Of America Adsorbent for HCl comprising alumina and acid-treated Y zeolite
US4686198A (en) 1986-06-23 1987-08-11 Aluminum Company Of America Method for regenerating adsorbent mixture of alumina and zeolite for adsorption of ammonia
US4717483A (en) 1986-06-23 1988-01-05 Aluminum Company Of America Purification of waste stream from tanning process by adsorption on an adsorbent comprising a mixture of alumina and Y zeolite
US4751211A (en) 1986-08-07 1988-06-14 Aluminum Company Of America Composite adsorbent for removing acids from organophosphate functional fluids
US4808742A (en) 1986-08-07 1989-02-28 Aluminum Company Of America Method for removing acids from organophosphate functional fluids
US5068483A (en) * 1987-11-23 1991-11-26 Centre National De La Recherche Scientifique Catalysts based on zeolites modified by alkali metal elements in the metallic form, their preparation, and their application to alkylation of alkylaromatic derivatives
US5194244A (en) * 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
JPH0748319A (ja) * 1992-11-20 1995-02-21 Chiyoda Corp ジアルキルカーボネートの製造方法
US5672799A (en) * 1993-06-16 1997-09-30 Eniricerche S.P.A. Process for the preparation of cumene
JPH0959204A (ja) * 1995-08-24 1997-03-04 Mitsui Toatsu Chem Inc アセトン脱水縮合物の製造方法
US6090738A (en) * 1997-03-10 2000-07-18 Indian Petrochemical Corp. Ltd. Process for the preparation of a molecular sieve adsorbent for selectively adsorbing methane from a gaseous mixture
US6013600A (en) * 1997-05-23 2000-01-11 Laroche Industries Inc. Alumina bodies containing alkali or alkaline earth metal compounds
US6423658B1 (en) * 1999-04-29 2002-07-23 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Adsorbent with a high macroporosity, usable in a gas adsorption process, especially a PSA process

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050230302A1 (en) * 2004-04-15 2005-10-20 Iain Muir Filtration and plug drain device for containing oil and chemical spills
US7014755B2 (en) 2004-04-15 2006-03-21 Iain Muir Filtration and plug drain device for containing oil and chemical spills
US20070000383A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Adsorbent and catalyst mixtures
US7722702B2 (en) 2005-06-30 2010-05-25 Praxair Technology, Inc. Adsorbent and catalyst mixtures
US20070116620A1 (en) * 2005-11-21 2007-05-24 Kanazirev Vladislav I Halide scavengers for high temperature applications
US20110073527A1 (en) * 2009-09-30 2011-03-31 Uop Llc Process for Removing Nitrogen Compounds from a Hydrocarbon Stream
EP3112019A1 (fr) 2009-10-06 2017-01-04 BASF Corporation Adsorbant de réactivité inférieure et haute capacité de composés oxygénés pour l'élimination de composés oxygénés à partir de flux d'oléfines
US20110079145A1 (en) * 2009-10-06 2011-04-07 William Dolan Lower Reactivity Adsorbent and Higher Oxygenate Capacity for Removal of Oxygenates from Olefin Streams
US8147588B2 (en) 2009-10-06 2012-04-03 Basf Corporation Lower reactivity adsorbent and higher oxygenate capacity for removal of oxygenates from olefin streams
WO2011043974A3 (fr) * 2009-10-06 2011-08-25 Basf Corporataion Adsorbant à faible réactivité et capacité d'oxygénat élevée pour l'élimination d'oxygénats à partir de flux d'oléfine
US8753535B2 (en) * 2010-01-15 2014-06-17 Reliance Industries Ltd, Reliance Technology Group Composite absorbent for catalyst residues removal from polyolefin solution polymerization mixture
US20130341563A1 (en) * 2010-01-15 2013-12-26 Prakash Kumar Composite absorbent for catalyst residues removal from polyolefin solution polymerization mixture
US8496733B2 (en) 2011-01-11 2013-07-30 Praxair Technology, Inc. Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes
US8491704B2 (en) 2011-01-11 2013-07-23 Praxair Technology, Inc. Six bed pressure swing adsorption process operating in normal and turndown modes
US8551217B2 (en) 2011-01-11 2013-10-08 Praxair Technology, Inc. Six bed pressure swing adsorption process operating in normal and turndown modes
US8435328B2 (en) 2011-01-11 2013-05-07 Praxair Technology, Inc. Ten bed pressure swing adsorption process operating in normal and turndown modes
US8657924B2 (en) * 2011-08-10 2014-02-25 Praxair Technology, Inc. Process for separating gases and adsorbent compositions used therein
US20130036904A1 (en) * 2011-08-10 2013-02-14 Jian Zheng Process for separating gases and adsorbent compositions used therein
WO2013093219A2 (fr) 2011-12-20 2013-06-27 IFP Energies Nouvelles Procede de purification de charges olefiniques a l'aide d'un adsorbant comprenant une zeolithe de type 12mr
EP2813290A1 (fr) 2013-06-10 2014-12-17 IFP Energies nouvelles Adsorbant à base d'une zéolithe et d'une argile riche en silice et procédé de purification de charges d'hydrocarbures contenant des molécules insaturées
WO2014209813A1 (fr) 2013-06-25 2014-12-31 Exxonmobil Chemical Patents Inc. Atténuation d'inhibition de catalyseur en polymérisation d'oélfines
US9382344B2 (en) 2013-06-25 2016-07-05 Exxonmobil Chemical Patents Inc. Mitigation of catalyst inhibition in olefin polymerization
US10183272B2 (en) 2014-12-12 2019-01-22 Exxonmobil Research And Engineering Company Adsorbent for heteroatom species removal and uses thereof
US10207249B2 (en) 2014-12-12 2019-02-19 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
US10351639B2 (en) 2014-12-12 2019-07-16 Exxonmobil Research And Engineering Company Organosilica materials for use as adsorbents for oxygenate removal
US10179839B2 (en) 2016-11-18 2019-01-15 Exxonmobil Research And Engineering Company Sulfur terminated organosilica materials and uses thereof
US10047178B2 (en) 2017-02-07 2018-08-14 Exxonmobil Chemical Patents Inc. Mitigation of catalyst inhibition in olefin polymerization
US11660567B2 (en) 2017-05-24 2023-05-30 Basf Corporation Gas dehydration with mixed adsorbent/desiccant beds
WO2019045878A1 (fr) 2017-08-29 2019-03-07 Exxonmobil Chemical Patents Inc. Dioxyde de carbone en tant qu'agent de désactivation de catalyseur en polymérisation en solution, et produits fabriqués à partir de ce dernier
US11117983B2 (en) 2017-08-29 2021-09-14 Exxonmobil Chemical Patents Inc. Carbon dioxide as a catalyst quench agent in solution polymerization, and products made therefrom

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DE10159525B4 (de) 2013-06-27
DE10159525A1 (de) 2004-02-19
US20020147377A1 (en) 2002-10-10
CN1230247C (zh) 2005-12-07
JP2002253959A (ja) 2002-09-10
CN1359749A (zh) 2002-07-24
ITMI20012575A1 (it) 2003-06-06
JP4185279B2 (ja) 2008-11-26

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