US6428757B1 - Device for bringing solid bodies in the form of pourable pieces into contact with liquids and possibly gases - Google Patents

Device for bringing solid bodies in the form of pourable pieces into contact with liquids and possibly gases Download PDF

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Publication number
US6428757B1
US6428757B1 US09/297,626 US29762699A US6428757B1 US 6428757 B1 US6428757 B1 US 6428757B1 US 29762699 A US29762699 A US 29762699A US 6428757 B1 US6428757 B1 US 6428757B1
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US
United States
Prior art keywords
rotary grate
housing
solids
screen basket
liquids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US09/297,626
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English (en)
Inventor
Gert Albert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Germany GmbH
Original Assignee
Sasol Germany GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Germany GmbH filed Critical Sasol Germany GmbH
Assigned to RWE-DEA AKTIENGESELLSCHAFT FUR MINERALOEL UND CHEMIE reassignment RWE-DEA AKTIENGESELLSCHAFT FUR MINERALOEL UND CHEMIE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ALBERT, GERT
Assigned to SASOL GERMANY GMBH reassignment SASOL GERMANY GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: RWE-DEA AKTIENGESELLSCHAFT FUER MINERALOEL UND CHEMIE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00—Dissolving
    • B01F21/15—Dissolving comprising constructions for blocking or redispersing undissolved solids, e.g. sieves, separators or guiding constructions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00—Dissolving
    • B01F21/20—Dissolving using flow mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00—Dissolving
    • B01F21/50—Elements used for separating or keeping undissolved material in the mixer
    • B01F21/504—Sieves, i.e. perforated plates or walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71—Feed mechanisms
    • B01F35/717—Feed mechanisms characterised by the means for feeding the components to the mixer
    • B01F35/7179—Feed mechanisms characterised by the means for feeding the components to the mixer using sprayers, nozzles or jets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/002—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor with a moving instrument
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/68—Preparation of metal alcoholates
    • C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle

Definitions

  • the instant invention relates to an apparatus for contacting solids in the form of flowable lumps with liquids and, optionally, gases in order to dissolve said solids using a housing wherein a perforated vat holding the solids is disposed which, as the liquid flows around, forms a spouted bed.
  • DE 32 44 972 C1 (U.S. Pat. No. 4,590,289) discloses an apparatus comprising a reactor housing with a vat holding aluminium particles in the form of needles or chips arranged therein.
  • An aluminium alcoholate/alcohol mixture is set bubbling such that the fine aluminium particles are whirled up in the screen basket whereby the aluminium dissolves in the aluminium alcoholate/alcohol mixture.
  • the problem is solved by providing a rotary grate for holding the solids at least temporarily.
  • the volume turnover can be significantly increased by using said rotary grate. It is now possible to use large lumps, e.g. ingot off-cuts of more than 1 kg, which could not be used up to now.
  • a vertical pipe for placing the solids into the rotary grate, said pipe allowing to charge the solids from the top and to distribute them evenly in the screen reactor space.
  • said vertical pipe is provided with a joint such that the lower pipe outlet can be shifted between edge and center of the rotary grate.
  • the pipe is adjustable by means of a device which is steerable from outside.
  • the basket-like rotary grate is disposed on a central, vertical shaft protruding from the top of the reactor.
  • the protrusion point is sealed and the shaft can be rotated from outside the reactor using a motor.
  • the rotational speed of said rotary grate is adjustable such that the solids placed therein will be dissolved after a single turn of the grate.
  • the edge of said rotary grate is supported by a console mounted on the interior wall of the reactor.
  • the rotary grate remains rotatable and, thus, is easy to manipulate.
  • purifying jets are arranged around the rotary grate such that a cleaning fluid or fluid mixture can be sprayed onto the screen basket, thus preventing clogging of the meshes.
  • said purifying jets are arranged on a pipe which is led through the hollow shaft of the rotary grate into a space between screen basket and rotary grate and therefrom outside.
  • said pipe extends in the space from the outer end of a radial pipe section to an upward-bent pipe section.
  • the instant invention is illustrated in greater detail by the attached drawing showing a reactor for producing an aluminium alcoholate/alcohol mixture, the reactor comprising a screen basket with a rotary grate disposed thereabove.
  • the drawing shows a reactor 1 in a reactor housing 3 .
  • a screen basket 4 dividing the reactor into an upper section 3 b and a lower section 3 c .
  • a connecting line 3 f is provided for equalizing the pressure between lower section 3 c and upper section 3 b of the reactor.
  • Said connecting line 3 f is important for preventing disturbances in the screen basket 4 which may be caused by formation of reaction gas and vapor at the reactor bottom.
  • the screen basket 4 has orifices 4 a and is mounted (not depicted) on the wall 3 d of the reactor housing 3 .
  • Said vat, too, has orifices 5 a .
  • the rotary grate 6 is connected to a hollow shaft 8 led via a bearing 9 with stuffing-box and slide-ring packing to the toothed wheel 10 of a gear 11 .
  • Said toothed wheel 10 of the gear 11 intermeshes with a toothed wheel 12 driven by a motor 13 .
  • a feeding device 14 (not described in greater detail) through which, by means of a hopper 15 , aluminium lumps, preferably ingot off-cuts (even those of more than 1 kilogram in weight), can be filled into the reactor. Said lumps fall through the feeder 14 into a vertical pipe 17 , while passing several slides 16 which are opened and closed by turns. Said pipe 17 is disposed on a bearing 18 allowing to shift the lower outlet 17 a of the pipe 17 from the center of the rotary grate 6 to its edges, as indicated by the bidirectional arrow 19 .
  • the vertical pipe 17 is shifted by means of an adjusting device 20 disposed outside the reactor and connected with the vertical pipe 17 by means of a rod 21 .
  • the pipe 23 which is rotated with the shaft 8 is led to the edge of the interspace and upward.
  • the pipe sections leading to the edge 23 a of the interspace and then upward 23 b are provided with purifying jets 25 directed at the screen basket 4 .
  • Fresh hexanol can be charged to the reactor 1 via line 26 .
  • the fresh hexanol flows through line 27 to the interior 3 a of the reactor.
  • the aluminium particles employed are very coarse, preferably ingot off-cuts.
  • the space between rotary grate 6 and screen basket 4 is 5 to 10 cm.
  • the speed of drive 11 and 13 is adjusted such that the solids charged through the vertical pipe 17 and evenly distributed on the rotary grate 6 will be dissolved after a single turn of the grate. It is important that the aluminium lumps charged through pipe 17 onto the rotary grate 6 form a layer which is for example 10 to 15 cm thick.
  • an aluminium alcoholate/alcohol mixture will collect in the lower part 3 e of the reactor housing 3 .
  • Said mixture can be charged through lines 28 and 30 , via pump 29 , to the vat 5 .
  • the aluminium alcoholate/alcohol mixture is charged at high pressure such that the mixture is set bubbling, thus forming a spouted bed.
  • the bubbling liquid flows through screen basket 4 and rotary grate 6 over the aluminium lumps in the reactor.
  • the aluminum alcoholate/alcohol mixture flows through lines 31 and 27 to the upper part 3 b of the reactor housing 3 .
  • the mixture will immediately stop bubbling as the pump 29 is switched off.
  • the liquid will drop to the lower part 3 e of the reactor such that the aluminium lumps are no longer contacted by liquid. Thus, the reaction is suddenly interrupted.
  • Part of the aluminium alcoholate/alcohol mixture can be discharged via line 32 .

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
  • Dairy Products (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Treating Waste Gases (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
US09/297,626 1996-11-05 1997-10-29 Device for bringing solid bodies in the form of pourable pieces into contact with liquids and possibly gases Expired - Fee Related US6428757B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE19645527A DE19645527A1 (de) 1996-11-05 1996-11-05 Vorrichtung zum Inkontaktbringen von Festkörpern in Form von schüttfähigen Stücken mit Flüssigkeiten und ggf. Gasen
DE19645527 1996-11-05
PCT/DE1997/002564 WO1998019785A1 (de) 1996-11-05 1997-10-29 Vorrichtung zum inkontaktbringen von festkörpern in form von schüttfähigen stücken mit flüssigkeiten und ggf. gasen
ZA983256A ZA983256B (en) 1996-11-05 1998-04-17 Apparatus for contacting solids in the form of flowable lumps with liquids and optionally gases
AU62820/98A AU738527B2 (en) 1996-11-05 1998-04-20 Apparatus for contacting solids in the form of flowable lumps with liquids and optionally gases
CA002235906A CA2235906C (en) 1996-11-05 1998-04-27 Apparatus for contacting solids in the form of flowable lumps with liquids and, optionally, gases

Publications (1)

Publication Number Publication Date
US6428757B1 true US6428757B1 (en) 2002-08-06

Family

ID=31499357

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US09/297,626 Expired - Fee Related US6428757B1 (en) 1996-11-05 1997-10-29 Device for bringing solid bodies in the form of pourable pieces into contact with liquids and possibly gases

Country Status (12)

Country Link
US (1) US6428757B1 (de)
EP (1) EP0946276B1 (de)
JP (1) JP3855173B2 (de)
CN (1) CN1101724C (de)
AT (1) ATE200035T1 (de)
AU (1) AU738527B2 (de)
CA (1) CA2235906C (de)
DE (2) DE19645527A1 (de)
DK (1) DK0946276T3 (de)
ES (1) ES2157605T3 (de)
WO (1) WO1998019785A1 (de)
ZA (1) ZA983256B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006016398B4 (de) 2006-04-07 2008-07-24 Albert, Gert, Dipl.-Ing. Vorrichtung und Verfahren zur Herstellung von Aluminium-, Magnesium- oder Aluminium/Magnesiummischalkoholaten
CN107537419B (zh) * 2016-06-23 2020-02-28 中国石油化工股份有限公司 一种溢流式固液相反应器及固液反应方法
CN107570077A (zh) * 2017-09-25 2018-01-12 天津市弘亚润滑粉制造有限公司 一种搅拌装置
CN114307820B (zh) * 2021-12-30 2022-11-15 深圳市夏盟生物科技有限公司 一种含有脂肪酶的禽畜饲料配方及其加工装置
CN115608181B (zh) * 2022-12-16 2023-03-14 河北爱普制药有限公司 一种混合溶解装置及湿法制粒方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH396902A (de) 1960-07-26 1965-08-15 Stauffer Chemical Co Verfahren zur Herstellung von Metallalkoxyden
US3888973A (en) * 1972-10-24 1975-06-10 Continental Can Co Method of increasing the speed of chemical reaction between liquid and solid reactants using centrifugal force
WO1984000953A1 (fr) 1982-09-04 1984-03-15 Adolf Voss Appareil et procede pour la fabrication d'engrais a partir de lisiers
US4590289A (en) 1982-12-04 1986-05-20 Condea Chemie Gmbh Process and apparatus for producing aluminium alkoxides
JPS61293536A (ja) 1985-06-21 1986-12-24 Kiyokutoo Internatl:Kk 溶解装置
US5479851A (en) * 1994-05-25 1996-01-02 Breville Pty Ltd. Fruit and vegetable juicer
US5766958A (en) * 1995-09-12 1998-06-16 Sullivan; George D. Method for detecting and collecting infectious airborne microorganisms for rapid identification

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4439860C2 (de) * 1994-11-08 1997-04-30 Rwe Dea Ag Vorrichtung zum Inkontaktbringen von Festkörpern in Form von schüttfähigen Stücken mit Flüssigkeiten und gegebenenfalls Gasen

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH396902A (de) 1960-07-26 1965-08-15 Stauffer Chemical Co Verfahren zur Herstellung von Metallalkoxyden
US3888973A (en) * 1972-10-24 1975-06-10 Continental Can Co Method of increasing the speed of chemical reaction between liquid and solid reactants using centrifugal force
WO1984000953A1 (fr) 1982-09-04 1984-03-15 Adolf Voss Appareil et procede pour la fabrication d'engrais a partir de lisiers
US4590289A (en) 1982-12-04 1986-05-20 Condea Chemie Gmbh Process and apparatus for producing aluminium alkoxides
JPS61293536A (ja) 1985-06-21 1986-12-24 Kiyokutoo Internatl:Kk 溶解装置
US5479851A (en) * 1994-05-25 1996-01-02 Breville Pty Ltd. Fruit and vegetable juicer
US5766958A (en) * 1995-09-12 1998-06-16 Sullivan; George D. Method for detecting and collecting infectious airborne microorganisms for rapid identification

Also Published As

Publication number Publication date
EP0946276A1 (de) 1999-10-06
AU738527B2 (en) 2001-09-20
CN1101724C (zh) 2003-02-19
JP3855173B2 (ja) 2006-12-06
CA2235906C (en) 2006-07-04
CA2235906A1 (en) 1999-10-27
DE59703256D1 (de) 2001-05-03
ZA983256B (en) 1998-12-30
JP2001503322A (ja) 2001-03-13
ES2157605T3 (es) 2001-08-16
DK0946276T3 (da) 2001-08-13
ATE200035T1 (de) 2001-04-15
AU6282098A (en) 1999-10-28
WO1998019785A1 (de) 1998-05-14
CN1236332A (zh) 1999-11-24
EP0946276B1 (de) 2001-03-28
DE19645527A1 (de) 1998-05-07

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