US5534155A - Method for purification of cooling agents and/or lubricants used in rolling mills - Google Patents
Method for purification of cooling agents and/or lubricants used in rolling mills Download PDFInfo
- Publication number
- US5534155A US5534155A US07/883,827 US88382792A US5534155A US 5534155 A US5534155 A US 5534155A US 88382792 A US88382792 A US 88382792A US 5534155 A US5534155 A US 5534155A
- Authority
- US
- United States
- Prior art keywords
- rolling
- water
- rolling scale
- oil
- process water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005096 rolling process Methods 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title claims abstract description 57
- 239000002826 coolant Substances 0.000 title claims abstract description 10
- 238000000746 purification Methods 0.000 title abstract description 33
- 239000005068 cooling lubricant Substances 0.000 title description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 73
- 238000005188 flotation Methods 0.000 claims abstract description 40
- 239000002245 particle Substances 0.000 claims abstract description 32
- 239000012141 concentrate Substances 0.000 claims abstract description 15
- 238000004062 sedimentation Methods 0.000 claims abstract description 15
- 239000002699 waste material Substances 0.000 claims abstract description 15
- 238000003723 Smelting Methods 0.000 claims abstract description 9
- 239000004519 grease Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 8
- 230000005484 gravity Effects 0.000 claims abstract description 7
- 238000007885 magnetic separation Methods 0.000 claims abstract description 6
- 239000000725 suspension Substances 0.000 claims description 11
- 239000008235 industrial water Substances 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract description 22
- 238000004519 manufacturing process Methods 0.000 abstract description 12
- 238000000926 separation method Methods 0.000 abstract description 9
- 239000007788 liquid Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 7
- 238000011109 contamination Methods 0.000 abstract description 2
- 238000005461 lubrication Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 47
- 238000009434 installation Methods 0.000 description 18
- 239000011343 solid material Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000006148 magnetic separator Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000009749 continuous casting Methods 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910017344 Fe2 O3 Inorganic materials 0.000 description 1
- 229910017368 Fe3 O4 Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- -1 tenside Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
- C10M175/04—Working-up used lubricants to recover useful products ; Cleaning aqueous emulsion based
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/0009—Settling tanks making use of electricity or magnetism
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/0084—Enhancing liquid-particle separation using the flotation principle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2221/00—Applications of separation devices
- B01D2221/14—Separation devices for workshops, car or semiconductor industry, e.g. for separating chips and other machining residues
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
- Y10S75/962—Treating or using mill scale
Definitions
- the invention deals with a method for purifying cooling liquids used for cooling and/or for lubricating, that are interspersed or loaded with metallic and/or other material impurities, especially for separation of rolling scale and oily or greasy substances from industrial process or efflux water in open cooling circulation cycles or systems in the iron or steel industry, especially in rolling mills.
- This invention deals also with a pertinent purification installation or plant for performing the method.
- cooling and lubricating agents are therefore continuously contaminated with a fine dust or grit from the shaping process.
- lubricants aging products are additionally formed. Since these cooling and lubricating agents consequently are continuously enriched by fines or grit and other contaminations, they must be purified. The process behavior and the useful life of these media are considerably improved not only by a thorough and continuous purification of the cooling agents or lubricants, but the overall results of the machining and the chipless forming technology are optimized.
- An installation for purification of liquids or liquors in rolling mills containing contaminants, residues and/or aging products is known from the DE-OS 36 16 426.
- the contaminated liquids used for cooling and/or lubrication in rolling mills are, to begin with, collected in a collection tank and are plumped from there towards several diaphragm filters which are located in a reverse flushing cycle and are cyclically activated.
- the filter outputs of the diaphragm filters lead to a presetting tank, from which the purified liquid can be drawn off by means of an initial pump and be directed to its intended use, for instance to a rolling mill to be cooled.
- a separate precipitation vessel is provided for purifying the highly contaminated liquid passing through the diaphragm filters during the flushing process.
- Overflow troughs or ducts are provided in the upper region of the precipitation vessel, into which the liquid precleaned by the precipitation can overflow.
- the liquid collected in the overflow troughs is at least partially pumped back by a pump in a regulated manner to the diaphragm filters and serves there, as a reverse flushing means for cleaning or purifying the diaphragms arranged in the filters.
- one aspect of the present invention resides in a method for purifying industrial process water in open cooling circulation cycles, having the following features: the coarse rolling scale is separated from the contaminated process water by means of gravity sedimentation; and the rolling scale particles of average or finer size are removed from the process water prepurified in the above manner preferably by magnetic separation.
- the thus finely clarified process water or effluent is subjected to flotation and separated into fractions containing oil concentrates, water and very fine rolling scale particles containing little oil.
- the individual fractions, such as the clarified process water are reused as cooling agents and the entire rolling scale separated from the process water is smelted as iron sinter.
- the oil-rich concentrates are either discarded or subjected to a waste oil purification.
- the inventive method is performed in a purification installation according to the invention by a precipitation tank for the supply of used and contaminated process water as well as a device for removal of sedimented coarse rolling scale, and a device for the transfer of the preclarified process water into a presetting tank with an additional solid material separator installed therein, this is preferably a magnetic separator for average and fine rolling scale particles, as well as a device for transfer of the finish-clarified process water into a flotation apparatus with forced or positive aeration or cooling, whose fraction outlets are provided with conveyance means for return of the fractionalized products such as process water into the cooling cycle of the rolling mill and for transfer of the separated rolling scale into a smelting or metallurgical plant as well as for transfer of the filtrate containing oil into a waste oil purification apparatus.
- a precipitation tank for the supply of used and contaminated process water as well as a device for removal of sedimented coarse rolling scale
- the essential advantage of the invention lies consequently in that the formation of the rolling scale sludges containing oil and hitherto separated out of the water circulation cycles in rolling mills are completely eliminated. It is well known that these rolling scale sludges, containing from 20 to 30% of oil shares which accumulate in conventional cleaning procedures and which hitherto were dumped, present a considerable load on the environment.
- the clear water obtained from the flotation process is filtered and subsequently sprayed in a cooling tower and collected and returned to the point of use in the rolling mill.
- the fraction outlet of this flotation apparatus for clear process water is in this case possibly connected with the filter, whose filter output is connected to a cooling tower and with a pump collection or header tank arranged thereunder, whose pump is in connection with a cooling water user in the rolling mill through connection lines.
- the repeated filtering of the clear water from the flotation apparatus is indicated if any sort of operational malfunction with solid material penetrations should occur in the flotation cells.
- the rolled scale particles containing little oil separated in the flotation process are ground up and suspended in water.
- the suspension is then separated into fractions in a secondary flotation, containing oil concentrate, water and very fine rolling scale particles.
- Mechanical processing of the scale particles occurs, among other things, in the mill whereby the adhering oil particles are entirely detached or can be more easily separated in a suspension tank located downstream. Detergents such as tenside, surfactant, or the like can be expediently added at that point.
- the thus prepared suspension can be separated in a particularly simple manner by means of subsequent flotation into the three named fractions.
- the concentrate-containing oil emanating from the initial flotation of the process water and the concentrate-containing oil emanating from the finer flotation of the suspension are separated into several material phases especially into the fractions with oil, water and small shares of rolling scales. From a plant technology point of view this is achieved by connecting the fraction outlet of the concentrate containing oil of the first flotation apparatus and/or the second flotation apparatus with a centrifuge, especially with a three-phase separator with outlet apertures for purified water, waste oil as well as solid materials. In this way flowable waste oil in separated from the water purification process, which can be filled into oil barrels and can easily be temporarily stored, before it is transported into a waste oil dressing or purification plant, or can again be used in the rolling mill.
- FIGURE schematically illustrates the present invention.
- the largest quantities of scale accumulate especially in rolling mills with continuous casting installation, where simultaneously large quantities of exposed or open cooling water are used.
- the rolling scale is formed by oxygen in the air combining with iron.
- the scale is composed of the different forms of iron oxide FeO, Fe 2 O 3 and Fe 3 O 4 .
- the iron content amounts to 70 to 75%.
- oxyacetylene cutting and scale oxidation must be added to the scale losses.
- the scale is obtained over a distance from the ingot mold up to the loading arrangements.
- large blooming mill trains in hot rolling mills the scale is obtained in the form of large flat cakes and so-called fish.
- the highly contaminated process water W 1 flowing in the scale channels is, to begin with, supplied according to the invention to a sedimentation tank 1 arranged externally of the rolling mill proper.
- a coarse purification occurs in the sedimentation tank 1 by large scale flat cakes and scale fish as well as large particles of the flame cutting and scale oxidation accumulating on the bottom of the sedimentation tank.
- the coarse rolling scale Z 1 with an average diameter larger than 0.5 mm is separated to the extent of 80% from the process water by the action of gravity.
- the separated coarse rolling scale is decidedly low in oil content. It is from time to time lifted out of the sedimentation tank 1 by a crane installation 18 shown diagrammatically, and is supplied by a conveyor belt 19 to a smelting or metallurgical plant 21.
- the process water which has been coarse clarified in the sedimentation tank 1, flows subsequently through a magnetic separator 3 installed in a downstream pump collection or header tank.
- a magnetic separator 3 installed in a downstream pump collection or header tank.
- the average and fine rolling scale particles Z 2 between 0 and 0.5 mm diameter are separated by means of the magnetic separator 3 from the process water with a separation efficiency of 50 to 80% and are scraped or wiped off the magnetic separator above the water level.
- the mid-size and fine rolling scale particles can still be classified as containing little oil and can therefore together with the coarse rolling scale from the sedimentation tank 1 be supplied by means of the conveyor belt 19 to the smelting plant 21 after being drained in a drainage tank 20.
- the process water contaminated with oil and grease and still interspersed with specific shares of fine rolling scale particles as well as with very fine rolling scale particles is subsequently conveyed out of the collection or header tank 2 by pumps 4 through a line 5 to a flotation apparatus 6 located above the level of the smelter.
- the finish clarified process water in the flotation apparatus 6 is separated into fractions of oil concentrates, water, and scale particles with very little oil.
- the process water and materials it contains flow with positive guidance through the flotation apparatus 6, wherein air is added in as fine a dispersion as possible.
- a bubbly foam is obtained which is continuously drawn off and removed from the upper region of the flotation cell through an adjustable annular space.
- Various reagents can be added for assisting the flotation process, if necessary.
- the thus obtained oil concentrate flows through a line 6.3 into a separator 7.
- the process water clarified in the flotation apparatus 6 is directed through the line 6.1 having a gradient through a gravity filter 8 utilized as a final filter, which is to fulfill its filtering tasks only if the degree of separation cannot be precisely achieved in the flotation apparatus 6, and solid materials pass into the process water which as such has been purified or clarified.
- the clarified process water is directed to a cooling tower installation 9 where the water is sprayed, cooled and collected in the pump collection or header tank 10 located below the cooling tower. During this cooling process the water sprayed throughout the cooling tower is cooled down to the required operational temperature.
- the clarified industrial process water W 2 is again conveyed back from the pump collection tank 10 by the pump 11 and the line 17 to the users in the rolling mill.
- the fine to finest rolling scale with the particle size of between 0.001 mm to 0.5 mm separated to the extent of 90 to 95% in the flotation apparatus from the process water is collected in the underflow 6.2 of the flotation apparatus 6 and from there is supplied to a mill 12.
- the rolling scale containing oil is ground up in the mill and is herein exposed to shear forces among others.
- the product obtained thereby arrives into a suspension tank 13 enriched with water, where the oil phase can again separate from the rolling scale particles.
- the suspension is introduced by means of a positive action pump 14 and a pipeline 15 into a second flotation apparatus 16 for final flotation. In the flotation apparatus 16 the suspension is separated into three fractions by means of a process described in connection with the flotation apparatus 6.
- the oil concentrate accumulating therein is supplied to the separator 7 through a pipeline 16.3 and is divided in the separator, as has been described previously, into waste oil, water and smallest shares of the most fine rolling scale.
- the water clarified in the flotation apparatus 16 is sent by gravity through a pipeline 16.1 to the pump collection tank 2. This quantity of water, which can correspond to the quantity of water lost, is thus returned into the water purification circulation cycle.
- the finest oil-poor rolling scale Z 3 in the; underflow 16.2 of the flotation apparatus 16 is drawn off from there and arrives together with the remaining rolling scale Z 1 from the sedimentation tank 1 and the rolling scale Z 2 from the pump collection tank 2 onto the sinter belt 19 and from there, after it has been drained in the drainage tank 20, into the smelting or metallurgical installation 21.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Physical Water Treatments (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4115819A DE4115819A1 (de) | 1991-05-15 | 1991-05-15 | Verfahren zur aufbereitung von in walzwerksanlagen benutzten kuehl- und/oder schmiermitteln und hierzu eine aufbereitungsanlage |
DE4115819.9 | 1991-05-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
US5534155A true US5534155A (en) | 1996-07-09 |
Family
ID=6431691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/883,827 Expired - Fee Related US5534155A (en) | 1991-05-15 | 1992-05-15 | Method for purification of cooling agents and/or lubricants used in rolling mills |
Country Status (5)
Country | Link |
---|---|
US (1) | US5534155A (de) |
EP (1) | EP0513809B1 (de) |
JP (1) | JP3159777B2 (de) |
AT (1) | ATE159278T1 (de) |
DE (2) | DE4115819A1 (de) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5766450A (en) * | 1996-09-25 | 1998-06-16 | Bethlehem Steel Corporation | Apparatus for magnetically filtering wastewaters containing oil-coated mill scale |
KR19980032674A (ko) * | 1996-10-09 | 1998-07-25 | 플레밍귄터 | 철강산업에 이용하는 냉매 및/또는 윤활제의 정화 및 선별장치 및 그 방법 |
US6274037B1 (en) * | 1998-04-01 | 2001-08-14 | Yamaha Hatsudoki Kabushiki Kaisha | Coolant purification system |
US20040049265A1 (en) * | 1995-04-19 | 2004-03-11 | Schneider (Usa) Inc. | Drug coating with topcoat |
US6705142B1 (en) * | 1999-08-07 | 2004-03-16 | Henkel Kommanditgesellschaft Auf Aktien | Metal shaping process using a novel two phase cooling lubricant system |
US20060088654A1 (en) * | 1995-04-19 | 2006-04-27 | Boston Scientific Scimed, Inc. | Drug release coated stent |
US20120298224A1 (en) * | 2010-01-29 | 2012-11-29 | Toshiba Mitsubishi-Electric Industrial Systems Corporation | Water injection controller, water injection control method, and water injection control program for rolling lines |
RU175470U1 (ru) * | 2016-11-30 | 2017-12-06 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный технологический университет "СТАНКИН" (ФГБОУ ВО "МГТУ "СТАНКИН") | Устройство очистки СОЖ |
CN113399115A (zh) * | 2021-07-29 | 2021-09-17 | 张鸿文 | 一种矿产生产用铁质矿石分离提纯设备 |
IT202100008330A1 (it) * | 2021-04-01 | 2022-10-01 | Danieli Off Mecc | Impianto e procedimento per la rimozione di solidi sospesi, oli e grassi da acque di raffreddamento nel settore siderurgico e metallurgico |
CN115215500A (zh) * | 2022-08-18 | 2022-10-21 | 合肥丰蓝电器有限公司 | 一种液冷机组用的冷却液过滤装置 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007028737A1 (de) * | 2007-06-21 | 2008-12-24 | Ulrich Georg Hammer | Verfahren und Vorrichtung zur Aufbereitung von Walzöl |
EP2113490B1 (de) * | 2008-04-28 | 2012-09-12 | Edgar Bonnaire | Verfahren und Vorrichtung zur mechanischen Auftrennung von Sekundärrohrstoffen aus eisenhaltigen Schlämmen |
DE102011016190A1 (de) * | 2011-04-06 | 2012-10-11 | OKO-tech GmbH & CO. KG | Verfahren und Vorrichtung zum Entmischen und Trennen eines Stoffgemisches |
DE102019200760A1 (de) * | 2019-01-22 | 2020-07-23 | Sms Group Gmbh | Vorrichtung und Verfahren zum Entzundern eines bewegten Werkstücks |
AT522690B1 (de) * | 2019-11-26 | 2021-01-15 | Lubot Schmierstoff Und Prozesstechnik Gmbh | Aufbereitungseinrichtung und Verfahren zum Aufbereiten von mit Feststoffen beladener Prozessflüssigkeit |
DE102020213077A1 (de) * | 2020-10-16 | 2022-04-21 | Sms Group Gmbh | Verfahren zur Aufbereitung eines mit organischen Stoffen und anorganischen Partikeln belasteten Kühlkreislaufwassers |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US388774A (en) * | 1888-08-28 | Egbert b | ||
US3574329A (en) * | 1969-09-29 | 1971-04-13 | David K Beavon | Process for purifying water containing oil and solids |
US4120697A (en) * | 1977-04-15 | 1978-10-17 | Amax Inc. | Segregation-separation of copper from nickel in copper-nickel sulfide concentrates |
US4234420A (en) * | 1979-05-03 | 1980-11-18 | Turbeville Joseph E | Method and apparatus for pollutant spill control |
US4272341A (en) * | 1980-01-09 | 1981-06-09 | Duval Corporation | Process for recovery of metal values from lead-zinc ores, even those having a high carbonate content |
US4995912A (en) * | 1990-01-29 | 1991-02-26 | Nalco Chemical Company | Mill scale de-oiling |
US5047083A (en) * | 1989-06-15 | 1991-09-10 | Nalco Chemical Company | Process for de-oiling mill scale |
US5147554A (en) * | 1990-06-26 | 1992-09-15 | Filterwerk Mann & Hummel Gmbh | Process for treating wastes from the machining of ferromagnetic materials |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB615705A (en) * | 1943-05-28 | 1949-01-11 | American Cyanamid Co | Method and apparatus for clarifying lubricating and cooling liquids |
DE2220132C3 (de) * | 1972-04-25 | 1975-10-09 | Man Waerme- Und Lufttechnik Gmbh, 3300 Braunschweig | Verfahren und Vorrichtung zum Abtrennen von Sinter aus einer Flüssigkeit |
DE2743055A1 (de) * | 1977-09-24 | 1979-03-29 | Schloemann Siemag Ag | Einrichtung zur reinigung von schmier- und/oder kuehlemulsionen |
DE3146809C1 (de) * | 1980-11-15 | 1982-11-04 | Schauenburg Maschinen- und Anlagen-Bau GmbH, 4330 Mülheim | Verfahren und Anlage zur Reduzierung des Ölgehaltes von ölverschmutztem Walzsinter |
DE3223011A1 (de) * | 1981-12-01 | 1983-07-14 | Thyssen Industrie Ag, 4300 Essen | Verfahren und anlage zur reinigung von mit fettigen substanzen, insbesondere oel, verschmutztem walzzunder und zur gewinnung von erdoel aus oelhaltigen mineralien |
SU1456464A1 (ru) * | 1986-11-04 | 1989-02-07 | Всесоюзный Научно-Исследовательский И Проектный Институт По Очистке Технологических Газов, Сточных Вод И Использованию Вторичных Энергоресурсов Предприятий Черной Металлургии "Внипичерметэнергоочистка" | Способ регенерации водоэмульсионной смазочно-охлаждающей жидкости |
-
1991
- 1991-05-15 DE DE4115819A patent/DE4115819A1/de not_active Withdrawn
-
1992
- 1992-05-13 JP JP12075992A patent/JP3159777B2/ja not_active Expired - Fee Related
- 1992-05-15 AT AT92108213T patent/ATE159278T1/de not_active IP Right Cessation
- 1992-05-15 US US07/883,827 patent/US5534155A/en not_active Expired - Fee Related
- 1992-05-15 DE DE59208964T patent/DE59208964D1/de not_active Expired - Fee Related
- 1992-05-15 EP EP92108213A patent/EP0513809B1/de not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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US388774A (en) * | 1888-08-28 | Egbert b | ||
US3574329A (en) * | 1969-09-29 | 1971-04-13 | David K Beavon | Process for purifying water containing oil and solids |
US4120697A (en) * | 1977-04-15 | 1978-10-17 | Amax Inc. | Segregation-separation of copper from nickel in copper-nickel sulfide concentrates |
US4234420A (en) * | 1979-05-03 | 1980-11-18 | Turbeville Joseph E | Method and apparatus for pollutant spill control |
US4272341A (en) * | 1980-01-09 | 1981-06-09 | Duval Corporation | Process for recovery of metal values from lead-zinc ores, even those having a high carbonate content |
US5047083A (en) * | 1989-06-15 | 1991-09-10 | Nalco Chemical Company | Process for de-oiling mill scale |
US4995912A (en) * | 1990-01-29 | 1991-02-26 | Nalco Chemical Company | Mill scale de-oiling |
US5147554A (en) * | 1990-06-26 | 1992-09-15 | Filterwerk Mann & Hummel Gmbh | Process for treating wastes from the machining of ferromagnetic materials |
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US5766450A (en) * | 1996-09-25 | 1998-06-16 | Bethlehem Steel Corporation | Apparatus for magnetically filtering wastewaters containing oil-coated mill scale |
KR19980032674A (ko) * | 1996-10-09 | 1998-07-25 | 플레밍귄터 | 철강산업에 이용하는 냉매 및/또는 윤활제의 정화 및 선별장치 및 그 방법 |
US5938935A (en) * | 1996-10-09 | 1999-08-17 | Sms Schloemann-Siemag Aktiengesellschaft | Method and apparatus for purifying and treating cooling agents and or lubricants used in the metallurgical industry |
CN1127453C (zh) * | 1996-10-09 | 2003-11-12 | Sms舒路曼-斯玛公司 | 用于对冷却剂和/或润滑剂进行净化和处理的方法和设备 |
US6274037B1 (en) * | 1998-04-01 | 2001-08-14 | Yamaha Hatsudoki Kabushiki Kaisha | Coolant purification system |
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Also Published As
Publication number | Publication date |
---|---|
JPH05132678A (ja) | 1993-05-28 |
EP0513809B1 (de) | 1997-10-15 |
ATE159278T1 (de) | 1997-11-15 |
JP3159777B2 (ja) | 2001-04-23 |
EP0513809A3 (en) | 1993-03-17 |
DE59208964D1 (de) | 1997-11-20 |
DE4115819A1 (de) | 1992-11-19 |
EP0513809A2 (de) | 1992-11-19 |
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