US3876579A - Composition to be applied to a surface to increase its wear resistance - Google Patents
Composition to be applied to a surface to increase its wear resistance Download PDFInfo
- Publication number
- US3876579A US3876579A US238183A US23818372A US3876579A US 3876579 A US3876579 A US 3876579A US 238183 A US238183 A US 238183A US 23818372 A US23818372 A US 23818372A US 3876579 A US3876579 A US 3876579A
- Authority
- US
- United States
- Prior art keywords
- particles
- composition
- order
- abrasion resistant
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000002245 particle Substances 0.000 claims abstract description 78
- 239000000945 filler Substances 0.000 claims abstract description 31
- 238000005299 abrasion Methods 0.000 claims abstract description 25
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000005260 corrosion Methods 0.000 claims abstract description 5
- 230000007797 corrosion Effects 0.000 claims abstract description 5
- 230000003628 erosive effect Effects 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 25
- 239000000919 ceramic Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 10
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical group [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000011324 bead Substances 0.000 claims description 7
- 239000013008 thixotropic agent Substances 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 20
- 238000000576 coating method Methods 0.000 abstract description 20
- 229920000642 polymer Polymers 0.000 abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 8
- 239000004576 sand Substances 0.000 description 5
- 239000010425 asbestos Substances 0.000 description 4
- 229910052895 riebeckite Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052580 B4C Inorganic materials 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 2
- 244000309464 bull Species 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- KYBYPDUGGWLXNO-GRVYQHKQSA-N ethane-1,2-diamine;(9z,12z)-octadeca-9,12-dienoic acid Chemical compound NCCN.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O KYBYPDUGGWLXNO-GRVYQHKQSA-N 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/342—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
- B24D3/344—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/18—Cold vulcanisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/12—Spreading-out the material on a substrate, e.g. on the surface of a liquid
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/32—Wheels, pinions, pulleys, castors or rollers, Rims
- B29L2031/324—Rollers or cylinders having an axial length of several times the diameter, e.g. embossing, pressing or printing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
Definitions
- An object of this invention is an abrasive resistant coating for application on practically any surface subject to wear regardless of its location.
- Another object is such a coating using conventional tools and procedures.
- Another object is an abrasive resistant coating which will conform to the surface to which it is applied.
- Another object is a wearing composition which may be installed on the job and yet provides a hard wearing surface for areas of severe wear.
- Another object is a trowelable composition which quickly hardens to provide a surface having high resistance to abrasion.
- Another object is a wear resistant composition which can be applied to irregular surfaces such as those found in cones, elbows. etc.
- Another object is an abrasive resistant coating having a secondary abrasive filler of a hardness on the order of that of the material causing the wear.
- Another object is an abrasive resistant coating which has a fairly long working life in its mixed stage permitting adequate time to trowel it into difficult to reach or large areas. yet which will cure in a relatively short timev
- Another object is an abrasive resistant coating that is more resistant to wear than Ni-Hard iron.
- Another object is an abrasive resistant coating having a resistance to wear approaching that of ceramic tile.
- Another object is an abrasive resistant material that also functions as a corrosion inhibiting coating.
- Another object is an abrasive resistant coating which contains alumina ceramic particles.
- Another object is an abrasive resistant coating containing alumina ceramic particles which is mixed on the job and in which the particles will not settle out while the composition hardens.
- Another object is an abrasive resistant material of the above type that will not settle out in the can.
- FIG. I is a side view. in section, through a typical application in a diagrammatic or schematic representation.
- FIG. 2 is a portion of FIG. 1 on an enlarged scale.
- This invention is directed to an abrasive resistant surfacing for machinery and wearing surfaces on the job. This is accomplished by use of a composition having high alumina ceramic particles and a co-abrasive filler of smaller particles which are about as hard as the material causing the wear.
- the particles and filler are contained in components which may be mixed together on the job to provide a substance that can be applied by troweling or similar methods to the surface to be protected or repaired.
- the abrasive resistant coating when mixed has a paste-like consistency which enables it to be applied and to conform to any shape such as cones, elbows and other curved surfaces.
- the paste-like mixture cures rapidly. permitting the surface to be put back into operation quickly.
- the coating could have a working life of on the order of 30-45 minutes at 68F, which allows ample time to trowel the material onto difficult to reach or large surfaces. It will cure for use in 3-l6 hours at 70F.
- curing time can be reduced by heating metal surfaces to hand warmth or warmer before or after applying the composition. This will reduce the curing or hardening time to. say. approximately l hour.
- a composition of this invention may take many different forms.
- a base or substrate 10 has been shown which may be assumed to be a worn-out part. such as a liner. chute or what-have-you.
- a coating or composition I2 is superimposed on the surface thereof and. as shown in FIG. 2, in a somewhat schematic or diagrammatic manner.
- the coating includes a matrix or base substance or bonding agent 14 containing and holding in place large abrasive resistant particles I6 at suitable intervals with smaller abrasive filler particles I8 in the matrix and interposed between and around the larger beads or chips.
- the matrix material which may be a polymer.
- the matrix itself which may include the resin and a thixotropic agent. when mixed and adhering to the surface. acts as a cushion for the large abrasive resistant particles.
- the co-abrasive or secondary filler particles I8 are of a much smaller size than the primary abrasive resistant particles 16 and these smaller particles fill the voids or interstices between the large abrasive particles.
- the co-abrasive filler 18 protects the polymer matrix I4 from being worn away from the abrasive resistant particles. As a result, the abrasive resistant particles remain in place in the matrix longer providing a longer wearing surface.
- the abrasive resistant particles and co-abrasive filler are maintained in suspension in the polymer matrix during mixing and curing operations by means of a thixotropic agent.
- a co-abrasive filler found to function particularly well in a wearing composition in accordance with this invention may be silicon carbide, 180 mesh size.
- other fillers may be used as long as they are about as hard as the material being handled, in other words, the material causing the wear on the surface being protected.
- the following substances may be used as fillers:
- the cost of the wearing composition used in connection with the method of this invention may be reduced by matching the co-abrasive filler to the material causing wear.
- the co-abrasive filler may be used as the co-abrasive filler.
- the composition of the matrix holding the large abrasive resistant particles in position may vary over a wide range.
- many types of polymers may be used, such as: epoxide polymers; unsaturated polyester (carboxylate-glycol adduct); a polyurethane; a polyimide or polyamide resin or the like.
- a particular polymer found to function particularly well as the matrix is an epoxy resin containing a thixotropic agent which resin is cured by means of a mixed polyamine/polyamide curing agent.
- the thixotropic agent used is a pure CALlDRlA asbestos sold under the designation RG- 144 by Union Carbide Corporation.
- Other agents might be Bentonite, fumed silica, M-P-A by Baker Caster Oil, polyacrylamide and so forth.
- the composition of this invention it has been found desirable to provide the large abrasive resistant particles and the co-abrasive filler in both the resin and curing components of the epoxy resin composition.
- the purpose of doing this is two-fold. First, it provides a mixing ratio between the resin and curing components of approximately 2 to 1 whether the components are measured by weight or volume. Second, it provides thorough wetting of all the abrasive particles and coabrasive filler. A thorough wetting of these materials is difficult to obtain if the materials are provided in only one of the two components.
- a specific example of a suitable composition for use in this invention is:
- the resin may be supplied in one can and the curing agent in another, the two being sold together with the resin can being, for example, a l-gallon container and the curing components being in a onehalf-gallon can.
- a l-gallon container for the resin
- the one-half-gallon can for the curing agent has been found convenient. In such a situation a proportion of the amounts would be emptied from each and thoroughly mixed before application to the surface to be protected. And, if all of the resin and curing agents in the two-can kit are not used at once, the cans may be sealed up and used later.
- Another example of a suitable composition is as follows:
- the above composition is believed to have the advantage of better viscosity control.
- Another example of a suitable composition is as follows:
- Silicon Carbide. I80 X. Simonds This example is believed to have the advantage of longer term shelf stability and would be suitable for uses or applications that require such.
- the large particles and co-abrasive filler are in a ratio of on the order of 4 to I, while the particles (both large particles and co-abrasive filler) and matrix (resin, curing agent, etc.) are in a ratio on the order of 3 to I.
- the wearing composition may be applied or used on any one of a number of parts or surfaces.
- Good examples are feed chutes, buckets. hoppers, feed plates, pipe and elbows. side plates, diverter plates, discharge chutes and skirts, sand slinger, and the feed spout of grinding mills. It might also be used on trunnion liners, pump casing, return idlers, screens, dust collectors and cyclones and the like.
- the above are merely examples and it should be understood that other applications are important, such as the hard surfacing of classifier flights and shoes, the drums of cement trucks, fan blades, the surfacing of pan feeders, cobbler repulp circulators, the buckets and teeth of front end loaders, and so forth.
- the large abrasive resistant particles have been stated as being high alumina ceramic particles, but a number of other particles could be used, such as boron nitride, tungsten carbide, silicon carbide, boron carbide and the like.
- the large particles have been shown as generally round or spherical. But, in certain situations, chips might be used. Round particles may be used for a trowelable mix, but in certain applications, chips might be used. For example, if the composition is to be applied or cast, chips would not be objectionable and they might be less expensive. In certain situations, chips could be used in a trowelable mixture. This is particularly true in a casting system where different beads would be appropriate.
- a trowelable wearing composition for on-the-job application to a surface to provide a wearing surface having more resistance to wear caused by impact, abrasion, erosion or corrosion than NiHard iron including a matrix composed of an uncured curable crosslinkable thermosetting resin, a curing agent for the resin and a thixotropic agent, large abrasion resistant ceramic particles on the order of one-sixteenth inch in their largest dimension, much smaller co-abrasion resistant filler particles on the order of 180 mesh size and of a hardness on the order of that of the material causing the wear dispersed in rather random fashion among the large particles when applied, the ceramic and filler particles being in a ratio on the order of 4 to l by weight, and the particles and matrix being in a ratio on the order of 3 to l by weight.
- composition of claim I further characterized in that the large abrasion resistant particles are metal coated alumina ceramic particles.
- composition of claim 1 further characterized in that the large ceramic particles are essentially spherical beads.
- composition of claim I further characterized in that the co-abrasion resistant filler is silicon carbide.
- thermosetting resin is an epoxy resin
- a curable resin composition for on-the-job application to a surface to provide a wearing surface having more resistance to wear than NiHard iron a unitary system including a container of a certain amount of the uncured resin with large abrasion resistant ceramic particles on the order of one-sixteenth inch in their largest dimension and much smaller co-abrasion resistant filler particles on the order of I mesh size therethrough and of a hardness on the order of that of the material causing the wear, and a separate container with a proportionate amount of a curing agent and with large abrasion resistant ceramic particles on the order of one-sixteenth inch in their largest dimension and much smaller co-abrasion resistant filer particles on the order of I80 mesh size therethrough whereby the contents of both containers are capable of mixing readily by the existence of large and much smaller abrasive particles in each container, the ceramic and filler particles being in a ratio on the order of 4 to I by weight and the particles and resin plus curing agent being in a ratio on the order of 3 to l by weight
- composition of claim 6 further characterized in that the smaller co-abrasion resistant filler particles in that the large abrasion resistant ceramic particles are are Silicon carbide metal coated alumina ceramic particles.
- composition of claim 6 further characterized in that the large ceramic particles are spherical beads.
- the resin is an epoxy resin.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
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Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US238183A US3876579A (en) | 1972-03-27 | 1972-03-27 | Composition to be applied to a surface to increase its wear resistance |
ZA731080A ZA731080B (en) | 1972-03-27 | 1973-02-15 | Method of applying a wearing surface |
CA164,201A CA1010178A (en) | 1972-03-27 | 1973-02-20 | Method of applying a wearing surface |
AU52440/73A AU475569B2 (en) | 1972-03-27 | 1973-02-21 | Method of applying a wearing surface |
DE2311507A DE2311507C3 (de) | 1972-03-27 | 1973-03-08 | Verfahren zum Auftragen eines verschleißschützenden kunstharzgebundenen Überzugs |
SE7303825A SE404018B (sv) | 1972-03-27 | 1973-03-19 | Beleggningsmedel avsett att med slev appliceras pa ort och stelle pa ett underlag for astadkommande av en slitbestendig yta med storre motstandskraft mot av slag, notning, erosion och korrosion fororsakat slitage... |
BE129087A BE797127A (fr) | 1972-03-27 | 1973-03-21 | Procede pour former une surface d'usure |
NL7304013.A NL163552C (nl) | 1972-03-27 | 1973-03-22 | Werkwijze voor het bekleden van een oppervlak met een tegen corrosie bestendige, slijtvaste laag en werkwijze voor het bereiden van voor het bekleden geschikte mengsels. |
FR7310746A FR2178644A5 (es) | 1972-03-27 | 1973-03-26 | |
ES413001A ES413001A1 (es) | 1972-03-27 | 1973-03-26 | Un metodo de instalar un sistema abrasivo resistente para proporcionar una superficie de desgaste. |
JP48034215A JPS527449B2 (es) | 1972-03-27 | 1973-03-27 | |
GB1464473A GB1431676A (en) | 1972-03-27 | 1973-03-27 | Applying an abrasive-resistant coating to a surface |
BR732177A BR7302177D0 (pt) | 1972-03-27 | 1973-03-27 | Processo para instalar um sistema resistente a abrasivos, e composicao para uso no mesmo |
US06/182,031 USRE30691E (en) | 1972-03-27 | 1980-08-28 | Method of applying a wearing surface |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US238183A US3876579A (en) | 1972-03-27 | 1972-03-27 | Composition to be applied to a surface to increase its wear resistance |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US41487473A Division | 1973-11-12 | 1973-11-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3876579A true US3876579A (en) | 1975-04-08 |
Family
ID=22896826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US238183A Expired - Lifetime US3876579A (en) | 1972-03-27 | 1972-03-27 | Composition to be applied to a surface to increase its wear resistance |
Country Status (13)
Country | Link |
---|---|
US (1) | US3876579A (es) |
JP (1) | JPS527449B2 (es) |
AU (1) | AU475569B2 (es) |
BE (1) | BE797127A (es) |
BR (1) | BR7302177D0 (es) |
CA (1) | CA1010178A (es) |
DE (1) | DE2311507C3 (es) |
ES (1) | ES413001A1 (es) |
FR (1) | FR2178644A5 (es) |
GB (1) | GB1431676A (es) |
NL (1) | NL163552C (es) |
SE (1) | SE404018B (es) |
ZA (1) | ZA731080B (es) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3954694A (en) * | 1975-02-03 | 1976-05-04 | Rexnord, Inc. | Wearing composition |
US4042559A (en) * | 1972-03-23 | 1977-08-16 | The Carborundum Company | Abrasion resistant coated abrasive pipe lining sheet |
US4334970A (en) * | 1976-11-05 | 1982-06-15 | The Richardson Company | Radiation curable solvent-free compositions recovery system |
US4356037A (en) * | 1980-05-12 | 1982-10-26 | Novak Robert L | Abrasion resistant coating |
USRE33011E (en) * | 1984-07-19 | 1989-08-08 | Tennis racket frame made of metal oxide fibers and ceramic particles | |
US5753725A (en) * | 1995-03-08 | 1998-05-19 | Sumitomo Electric Industries, Ltd. | Dry friction material and method of preparing the same |
US6435810B1 (en) * | 2000-10-20 | 2002-08-20 | Delphi Technologies, Inc. | Wear resistant fuel pump |
US6436159B1 (en) * | 1999-12-09 | 2002-08-20 | Lilly Industries, Inc. | Abrasion resistant coatings |
US20050176321A1 (en) * | 2003-10-14 | 2005-08-11 | Crette Stephanie A. | Fiber wear layer for flooring and other products |
US20100087577A1 (en) * | 2007-04-20 | 2010-04-08 | Center for Abrasives and Refractories Research and Development C.A.R.R.D. GmbH | Anti abrasion layer |
US20100196696A1 (en) * | 2007-07-11 | 2010-08-05 | Technip France | Method and apparatus for anchoring an elongate subsea structure to a termination and a filler material therefor |
CN104031521A (zh) * | 2013-12-25 | 2014-09-10 | 广西宾阳县荣良新材料科技有限公司 | 一种木材复合涂料 |
CN106277933A (zh) * | 2016-07-29 | 2017-01-04 | 黄河水利委员会黄河水利科学研究院 | 一种高韧性高强度复合树脂砂浆 |
CN108654961A (zh) * | 2018-05-16 | 2018-10-16 | 安徽三环水泵有限责任公司 | 一种渣浆泵过流部件的修补方法 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH634869A5 (en) * | 1978-08-08 | 1983-02-28 | Wissenschaft Und International | Wall and ceiling filling composition (putty) |
JPS5888480U (ja) * | 1981-12-09 | 1983-06-15 | 株式会社アサカ | 放映用カ−ドチエンジヤ |
JPS58131174A (ja) * | 1982-01-29 | 1983-08-04 | Sadashige Tokushu Gouban Kogyo Kk | 耐摩耗性に優れた化粧板材の製造法 |
GB2120263B (en) * | 1982-05-17 | 1985-07-31 | Ciba Geigy Ag | A process for curing acid-curable abrasive compositions |
FI92419C (fi) * | 1990-11-19 | 1994-11-10 | Valmet Paper Machinery Inc | Menetelmä telan pinnoittamiseksi ja telapinnoite |
DE4226789A1 (de) * | 1992-08-13 | 1994-02-17 | Sigri Great Lakes Carbon Gmbh | Faserverstärkte Kunststoffwalze mit äußerer, verschleißfester, füllerhaltiger Kunststoffschicht |
FR2708875B1 (fr) * | 1993-08-12 | 1995-09-29 | Schmitt Ind Sarl | Procédé de traitement d'éléments meublants susceptibles de résister à des contraintes importantes. |
DE19625749C2 (de) * | 1996-06-27 | 1998-12-17 | Polywest Kunststofftechnik | Verfahren zur Herstellung einer nahtlosen Druckform für den rotativen Hochdruck |
DE102008006336B4 (de) * | 2007-01-24 | 2017-12-14 | Ilona Napp | Verfahren zur Oberflächengestaltung von Ausstattungselementen für ein Gebäude und Ausstattungselement für ein Gebäude |
CN109370385A (zh) * | 2018-11-05 | 2019-02-22 | 四川理工学院 | 一种耐磨抗刮伤涂料及其制备方法 |
CN113372794A (zh) * | 2021-06-02 | 2021-09-10 | 清远市进田企业有限公司 | 一种废旧电路板非金属粉在环氧地坪涂料及其制备方法 |
Citations (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2162600A (en) * | 1936-07-27 | 1939-06-13 | Carborumdum Company | Filler for abrasive articles |
US2213332A (en) * | 1935-11-29 | 1940-09-03 | Carborundum Co | Abrasive articles and the method of manufacturing the same |
US2769699A (en) * | 1951-06-02 | 1956-11-06 | Norton Co | Grinding wheels |
US2913858A (en) * | 1957-09-04 | 1959-11-24 | Nat Broach & Mach | Gear honing tool |
US2943926A (en) * | 1958-07-18 | 1960-07-05 | Cincinnati Milling Machine Co | Abrasive wheel composition |
US2943953A (en) * | 1957-07-05 | 1960-07-05 | Frederick K Daniel | Flooring composition and method of making the same |
US2949351A (en) * | 1958-01-02 | 1960-08-16 | Jr Louis E Vigliatura | Heat-resistant abrasive wheels |
US3003798A (en) * | 1957-05-20 | 1961-10-10 | Jersey Prod Res Co | Anchoring reinforcing cables or braids in well packers |
US3033088A (en) * | 1956-08-20 | 1962-05-08 | Shell Oil Co | Composition comprising a coal product, a polyepoxide and abrasive particles and process for treating surfaces therewith |
US3041156A (en) * | 1959-07-22 | 1962-06-26 | Norton Co | Phenolic resin bonded grinding wheels |
US3087803A (en) * | 1960-07-05 | 1963-04-30 | Federal Screw Works | Diamond grinding wheel and compositions therefor |
US3183633A (en) * | 1963-10-24 | 1965-05-18 | Michigan Tool Co | Polyurethane gear finishing tool |
US3205054A (en) * | 1964-01-20 | 1965-09-07 | Bay State Abrasive Products Co | Abrasive coated material |
US3225495A (en) * | 1962-08-16 | 1965-12-28 | Prismo Safety Corp | Process of peening metals with coated glass beads |
US3277052A (en) * | 1962-02-06 | 1966-10-04 | Shell Oil Co | Process for curing polyepoxides and resulting products |
US3360391A (en) * | 1962-08-01 | 1967-12-26 | Dynamit Nobel Ag | Process for the production of corrosion resistant and highly wearresistant coated surface and the coated surface |
US3383191A (en) * | 1965-06-03 | 1968-05-14 | Simonds Abrasive Company | Diamond abrasive article containing hexagonal crystalline boron nitride particles |
US3469959A (en) * | 1966-09-08 | 1969-09-30 | Carborundum Co | Aluminosilicate zeolite in a synthetic resin bonded abrasive article |
US3502453A (en) * | 1968-08-22 | 1970-03-24 | Minnesota Mining & Mfg | Abrasive article containing hollow spherules filled with lubricant |
US3524286A (en) * | 1967-04-12 | 1970-08-18 | Carborundum Co | Resin bonded abrasive wheels containing fibrous and non-fibrous fillers |
-
1972
- 1972-03-27 US US238183A patent/US3876579A/en not_active Expired - Lifetime
-
1973
- 1973-02-15 ZA ZA731080A patent/ZA731080B/xx unknown
- 1973-02-20 CA CA164,201A patent/CA1010178A/en not_active Expired
- 1973-02-21 AU AU52440/73A patent/AU475569B2/en not_active Expired
- 1973-03-08 DE DE2311507A patent/DE2311507C3/de not_active Expired
- 1973-03-19 SE SE7303825A patent/SE404018B/xx unknown
- 1973-03-21 BE BE129087A patent/BE797127A/xx not_active IP Right Cessation
- 1973-03-22 NL NL7304013.A patent/NL163552C/xx not_active IP Right Cessation
- 1973-03-26 FR FR7310746A patent/FR2178644A5/fr not_active Expired
- 1973-03-26 ES ES413001A patent/ES413001A1/es not_active Expired
- 1973-03-27 BR BR732177A patent/BR7302177D0/pt unknown
- 1973-03-27 JP JP48034215A patent/JPS527449B2/ja not_active Expired
- 1973-03-27 GB GB1464473A patent/GB1431676A/en not_active Expired
Patent Citations (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2213332A (en) * | 1935-11-29 | 1940-09-03 | Carborundum Co | Abrasive articles and the method of manufacturing the same |
US2162600A (en) * | 1936-07-27 | 1939-06-13 | Carborumdum Company | Filler for abrasive articles |
US2769699A (en) * | 1951-06-02 | 1956-11-06 | Norton Co | Grinding wheels |
US3033088A (en) * | 1956-08-20 | 1962-05-08 | Shell Oil Co | Composition comprising a coal product, a polyepoxide and abrasive particles and process for treating surfaces therewith |
US3003798A (en) * | 1957-05-20 | 1961-10-10 | Jersey Prod Res Co | Anchoring reinforcing cables or braids in well packers |
US2943953A (en) * | 1957-07-05 | 1960-07-05 | Frederick K Daniel | Flooring composition and method of making the same |
US2913858A (en) * | 1957-09-04 | 1959-11-24 | Nat Broach & Mach | Gear honing tool |
US2949351A (en) * | 1958-01-02 | 1960-08-16 | Jr Louis E Vigliatura | Heat-resistant abrasive wheels |
US2943926A (en) * | 1958-07-18 | 1960-07-05 | Cincinnati Milling Machine Co | Abrasive wheel composition |
US3041156A (en) * | 1959-07-22 | 1962-06-26 | Norton Co | Phenolic resin bonded grinding wheels |
US3087803A (en) * | 1960-07-05 | 1963-04-30 | Federal Screw Works | Diamond grinding wheel and compositions therefor |
US3277052A (en) * | 1962-02-06 | 1966-10-04 | Shell Oil Co | Process for curing polyepoxides and resulting products |
US3360391A (en) * | 1962-08-01 | 1967-12-26 | Dynamit Nobel Ag | Process for the production of corrosion resistant and highly wearresistant coated surface and the coated surface |
US3225495A (en) * | 1962-08-16 | 1965-12-28 | Prismo Safety Corp | Process of peening metals with coated glass beads |
US3183633A (en) * | 1963-10-24 | 1965-05-18 | Michigan Tool Co | Polyurethane gear finishing tool |
US3205054A (en) * | 1964-01-20 | 1965-09-07 | Bay State Abrasive Products Co | Abrasive coated material |
US3383191A (en) * | 1965-06-03 | 1968-05-14 | Simonds Abrasive Company | Diamond abrasive article containing hexagonal crystalline boron nitride particles |
US3469959A (en) * | 1966-09-08 | 1969-09-30 | Carborundum Co | Aluminosilicate zeolite in a synthetic resin bonded abrasive article |
US3524286A (en) * | 1967-04-12 | 1970-08-18 | Carborundum Co | Resin bonded abrasive wheels containing fibrous and non-fibrous fillers |
US3502453A (en) * | 1968-08-22 | 1970-03-24 | Minnesota Mining & Mfg | Abrasive article containing hollow spherules filled with lubricant |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4042559A (en) * | 1972-03-23 | 1977-08-16 | The Carborundum Company | Abrasion resistant coated abrasive pipe lining sheet |
US3954694A (en) * | 1975-02-03 | 1976-05-04 | Rexnord, Inc. | Wearing composition |
US4334970A (en) * | 1976-11-05 | 1982-06-15 | The Richardson Company | Radiation curable solvent-free compositions recovery system |
US4356037A (en) * | 1980-05-12 | 1982-10-26 | Novak Robert L | Abrasion resistant coating |
USRE33011E (en) * | 1984-07-19 | 1989-08-08 | Tennis racket frame made of metal oxide fibers and ceramic particles | |
US5753725A (en) * | 1995-03-08 | 1998-05-19 | Sumitomo Electric Industries, Ltd. | Dry friction material and method of preparing the same |
US6641629B2 (en) * | 1999-12-09 | 2003-11-04 | Eugen Safta | Abrasion resistant coatings |
US6436159B1 (en) * | 1999-12-09 | 2002-08-20 | Lilly Industries, Inc. | Abrasion resistant coatings |
US6435810B1 (en) * | 2000-10-20 | 2002-08-20 | Delphi Technologies, Inc. | Wear resistant fuel pump |
US20050176321A1 (en) * | 2003-10-14 | 2005-08-11 | Crette Stephanie A. | Fiber wear layer for flooring and other products |
US20100087577A1 (en) * | 2007-04-20 | 2010-04-08 | Center for Abrasives and Refractories Research and Development C.A.R.R.D. GmbH | Anti abrasion layer |
US8410209B2 (en) | 2007-04-20 | 2013-04-02 | Center for Abrasives and Refractories Research and Development C.A.R.R.D. GmbH | Anti abrasion layer |
US8449977B1 (en) | 2007-04-20 | 2013-05-28 | Center for Abrasives and Refractories Research and Development C.A.R.R.D. GmbH | Anti abrasion layer |
US20100196696A1 (en) * | 2007-07-11 | 2010-08-05 | Technip France | Method and apparatus for anchoring an elongate subsea structure to a termination and a filler material therefor |
US9212767B2 (en) * | 2007-07-11 | 2015-12-15 | Technip France | Method and apparatus for anchoring an elongate subsea structure to a termination and a filler material therefor |
CN104031521A (zh) * | 2013-12-25 | 2014-09-10 | 广西宾阳县荣良新材料科技有限公司 | 一种木材复合涂料 |
CN106277933A (zh) * | 2016-07-29 | 2017-01-04 | 黄河水利委员会黄河水利科学研究院 | 一种高韧性高强度复合树脂砂浆 |
CN108654961A (zh) * | 2018-05-16 | 2018-10-16 | 安徽三环水泵有限责任公司 | 一种渣浆泵过流部件的修补方法 |
Also Published As
Publication number | Publication date |
---|---|
DE2311507B2 (de) | 1979-06-28 |
AU475569B2 (en) | 1976-08-26 |
GB1431676A (en) | 1976-04-14 |
JPS498530A (es) | 1974-01-25 |
BR7302177D0 (pt) | 1974-07-25 |
NL163552C (nl) | 1980-09-15 |
JPS527449B2 (es) | 1977-03-02 |
NL7304013A (es) | 1973-10-01 |
ZA731080B (en) | 1974-12-24 |
AU5244073A (en) | 1974-08-22 |
DE2311507A1 (de) | 1973-10-04 |
NL163552B (nl) | 1980-04-15 |
CA1010178A (en) | 1977-05-10 |
SE404018B (sv) | 1978-09-18 |
ES413001A1 (es) | 1976-05-16 |
DE2311507C3 (de) | 1980-02-28 |
FR2178644A5 (es) | 1973-11-09 |
BE797127A (fr) | 1973-07-16 |
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Legal Events
Date | Code | Title | Description |
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PS | Patent suit(s) filed | ||
AS | Assignment |
Owner name: WILMINGTON TRUST COMPANY, RODNEY SQUARE NORTH, WIL Free format text: SECURITY INTEREST;ASSIGNOR:REXNORD INC.;REEL/FRAME:004817/0047 Effective date: 19870430 Owner name: WADE, WILLIAM J., RODNEY SQUARE NORTH, WILMINGTON Free format text: SECURITY INTEREST;ASSIGNOR:REXNORD INC.;REEL/FRAME:004817/0047 Effective date: 19870430 |
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Owner name: CHEMREX INC., 1209 ORANGE STREET, WILMINGTON, DELA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:REXNORD, INC.;REEL/FRAME:004938/0252 Effective date: 19880816 |
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Owner name: WILMINGTON TRUST COMPANY AND WADE, WILLIAM J., AS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. AMENDED SECURITY AGREEMENT;ASSIGNOR:CHEMEX INC., A CORP. OF DE;REEL/FRAME:004945/0829 Effective date: 19880816 Owner name: WILMINGTON TRUST COMPANY AND WADE, WILLIAM J., AS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CHEMEX INC., A CORP. OF DE;REEL/FRAME:004945/0829 Effective date: 19880816 |
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Owner name: FEL-PRO INCORPORATED, ILLINOIS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:CHEMREX, INC.;REEL/FRAME:006289/0900 Effective date: 19921020 |
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Owner name: FEL-PRO CHEMICAL PRODUCTS L.P., ILLINOIS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:FEL-PRO INCORPORATED;REEL/FRAME:006490/0722 Effective date: 19921228 |