US3758409A - Cleaning and bleaching liquid composition - Google Patents
Cleaning and bleaching liquid composition Download PDFInfo
- Publication number
- US3758409A US3758409A US00204344A US3758409DA US3758409A US 3758409 A US3758409 A US 3758409A US 00204344 A US00204344 A US 00204344A US 3758409D A US3758409D A US 3758409DA US 3758409 A US3758409 A US 3758409A
- Authority
- US
- United States
- Prior art keywords
- alkali metal
- composition
- hypochlorite
- cleaning
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract description 41
- 238000004061 bleaching Methods 0.000 title abstract description 13
- 238000004140 cleaning Methods 0.000 title abstract description 11
- 239000007788 liquid Substances 0.000 title abstract description 10
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract description 35
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 15
- 239000000460 chlorine Substances 0.000 abstract description 15
- 229910052801 chlorine Inorganic materials 0.000 abstract description 13
- 239000004094 surface-active agent Substances 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract description 8
- 150000001340 alkali metals Chemical class 0.000 abstract description 8
- 239000003599 detergent Substances 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 18
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 12
- 239000011780 sodium chloride Substances 0.000 description 9
- 239000005708 Sodium hypochlorite Substances 0.000 description 8
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 8
- 239000003513 alkali Substances 0.000 description 7
- -1 alkali metal hypochlorite Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 101100168117 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-8 gene Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3953—Inorganic bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
Definitions
- R stands for an alkyl group having 8 to 22 carbon atoms
- n is an integer of 1 to 40
- m is an integer of l or 2
- M is an alkali metal
- an alkali metal hypochlorite and an alkali agent dissolved in water said alkali metal hypochlorite containing less than mol of alkali metal chloride per mol of the hypochlorite and the available chlorine content of the composition being 0.5-13% by weight.
- This invention relates to a cleaning and bleaching liquid composition containing hypochlorite.
- a cleaning and bleaching liquid composition characterized by consisting of a surface active agent represented by a general formula (1) a--o(cnzcmonwnnm-coom (1) (wherein R stands for an alkyl group having 8 to 22 carbon atoms, 11 is an integer of l to 40, M is an integer of 1 or 2 and m is an alkali metal), an alkali metal hypochlorite and an alkali agent as indispensable components, dissolved in water, said alkali metal hypochlorite containing less than A mol of an alkali metal chloride per mol of the hypochlorite and the available chlorine content of the composition being 0.5-13% by weight.
- a surface active agent represented by a general formula (1) a--o(cnzcmonwnnm-coom (1) (wherein R stands for an alkyl group having 8 to 22 carbon atoms, 11 is an integer of l to 40, M is an integer of 1 or 2 and m is an alkali metal), an alkali
- RO(CH CI-hO) S0 Me (wherein R is an alkyl group having 8 to 9 carbon atoms, Me is an alkali metal, and n is an integer of to 40) (Japanese patent publication No. 2,103/ 1968), and a compound represented by a general formula,
- X is a member of the group consisting of --COOMe, --SO Me, OSO Me, or
- Y is a member of the group consisting of COOMe or OSO Me, and Me is an alkali metal) (Japanese patent publication No. 7,976/1970).
- a conventional commercially-available bleaching liquid employs a hypochlorite containing an equimolar amount of an alkali metal chloride, as it is the most economical; however, the alkali metal hypochlorite used in the composition of this invention (usually the sodium or potassium salt) contains either no alkali metal chloride or less than A mol per mol of the alkali metal chloride of the hypochlorite.
- the stability of a hypochlorite solution depends on the strength of the ions contained in it, but in the system containing a surface active agent represented by the Formula 1, the decomposition of the surface active agent due to sodium hypochlorite and the decomposition of sodium hypochlorite has been found to be much more influenced by the presence of sodium chloride, than by sodium sulfate or sodium orthophosphate, even with the same strength of ions.
- the amount of the surface active agent of the Formula 1 used in the composition of this invention is about 0.5 to 20% by weight of the composition.
- the amount of the hypochlorite used is selected so as to make the available chlorine content in the composition to be about 0.5 to 13% by weight. When the content is less than 0.5%, the bleaching effect is unsatisfactory and when it is more than 13%, the composition tends to be unstable.
- alkali metal hydroxides are the most preferable, but carbonates, orthophosphates or metasilicates may be used.
- alkali metal hydroxides such as sodium hydroxide and potassium hydroxide are preferable.
- alkali agents are effective for the stabilization of the surface active agent and act as a buffer for the system.
- the amount of the alkali agent to be used in the composition of this invention is 0.5 to 2.0% by weight, preferably 0.8 to 1.3% by weight of the composition.
- composition of this invention is a transparent liquid detergent that undergoes neither the decomposition of the hypochlorite and the surface active agent nor any turbid precipitation even after storing it for a long time, and it is excellent in its bleaching and cleaning properties.
- Bleaching and cleaning liquor compositions A, B, C, D and E having 6.0% of the available chlorine concentration were prepared according to the above-described composition with different surface active agents, which are shown
- Surface WW6 agent similar as the amount of sodium hypochlorite, separated A CHEW nto two layers, when it was used in compositions similar to those of compositions F to K.
- composition rate 0.7 7.0 8.0 1.3 1.7 after Storing at room te'mperature and a C; 3 Stability otthe Initial stag $.00 g-gg 51g 2g g-gg months, but the composition M had a high viscosity ust iiltl Bltcillf assassinate; if; enen blending and eepeneeee no inyene en leaving Foaming power n 4 g $3; 1 8 i 3 at room temperature.
- the composition L had 5.13% izg pmpfmy lenmeye sk 'providd 3 available chlorine content after storing at room temperaamso asam GWGXB DU ll'la CC.
- a cleaning and bleaching liquid composition conaccor mg 0 e mven are exce en as a W sisting essentially of an aqueous solution of EXAMPLE 2 (A) from about 0.5 to about 20%, by weight of the The compositions Shown in Table 2 were prepared composition, of surface active agent of the formula with a sodium hypochlorite solution (available chlorine, -0(CH OHz0)n(GH )mC00M 12.5%; sodium chloride, 0.8%).
- NnOH 1.0 1.0 1.0 .0 1.0 1.0 Water Balance Each composition was stored at 5 C. for 30 days but 5 wherein it was still transparent and did not show any turbid precipitation.
- the available chlorine concentrations after 15 alkyl havlng 3 to 22 afb011 aloms, storing at 30 C. for 20 days are as follows: 11 is an integer of l to 40,
- Percent in is an integer of 1 or 2, and F 5.60 M is an alkali metal, G 5.08 (B) an alkali metal hypochlorite selected from the H 6.12 group consisting of sodium hypochlorite and potassium hypochlorite, said alkali metal hypochlorite containing less than A mol of alkali metal chloride per mol of the hypochlorite and the available chlo- 6 rine content of the composition being from 0.5 to References Cited 13.0% by g and UNITED STATES PATENTS (C) from about 0.5 to 2.0%, by weight of the compo- 2 302 715 3 1957 Hodel- 8 1( 3 X sition, of alkali agent selected from the group con- 5 ,2 7 11/ 1966 Aig gp r e et al- 2gg 7 H n i 2, 2,8 8 12/1953 Bran on 2 187 H sistlng of hydrox1des, carbonates, orthophosphates 1,834,210 12/1931
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45109106A JPS4926688B1 (enrdf_load_stackoverflow) | 1970-12-09 | 1970-12-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3758409A true US3758409A (en) | 1973-09-11 |
Family
ID=14501713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00204344A Expired - Lifetime US3758409A (en) | 1970-12-09 | 1971-12-02 | Cleaning and bleaching liquid composition |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3758409A (enrdf_load_stackoverflow) |
| JP (1) | JPS4926688B1 (enrdf_load_stackoverflow) |
| AU (1) | AU458559B2 (enrdf_load_stackoverflow) |
| DE (1) | DE2160409C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2117522A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1378649A (enrdf_load_stackoverflow) |
| NL (1) | NL159709B (enrdf_load_stackoverflow) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4029591A (en) * | 1974-09-27 | 1977-06-14 | Lion Fat & Oil Co., Ltd. | Liquid detersive bleaching composition |
| US4071463A (en) * | 1975-09-11 | 1978-01-31 | The Dow Chemical Company | Stable cleaning agents of hypochlorite bleach and detergent |
| US4174289A (en) * | 1977-07-27 | 1979-11-13 | Basf Wyandotte Corporation | Liquid detergent-bleach concentrates having high alkalinity |
| US4235732A (en) * | 1978-02-08 | 1980-11-25 | The Procter & Gamble Company | Liquid bleaching compositions |
| US4281421A (en) * | 1979-03-12 | 1981-08-04 | The Procter & Gamble Company | Passive dosing dispenser with improved hypochlorite cake |
| US4399050A (en) * | 1980-05-13 | 1983-08-16 | Sandoz Products Limited | Bleach composition |
| US4443353A (en) * | 1981-08-15 | 1984-04-17 | Chem-Y Fabriek Van Chemische Producten B.V. | Aqueous bleaching agent with cleaning action |
| US4599186A (en) * | 1984-04-20 | 1986-07-08 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4657692A (en) * | 1984-04-20 | 1987-04-14 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| WO1988005461A1 (en) * | 1987-01-23 | 1988-07-28 | Molony Donald P | Sodium carbonate/sodium hydroxide/sodium hypochlorite composition and process for removing stains |
| US4772414A (en) * | 1986-07-24 | 1988-09-20 | Ppg Industries, Inc. | Bleaching composition |
| US20070072969A1 (en) * | 2005-09-27 | 2007-03-29 | Lee Eun S | Carboxylic ester dispersant and sulfide phosphor paste composition having same |
| US20070157852A1 (en) * | 2005-06-30 | 2007-07-12 | Lee Eun-Sung | Dispersant, paste composition including the dispersant, inorganic device using the paste composition, and display apparatus including the inorganic device |
| CN112745821A (zh) * | 2021-01-06 | 2021-05-04 | 中海石油(中国)有限公司 | 一种海上稠油蒸汽伴注用耐温抗盐驱油剂及其应用 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8723675D0 (en) * | 1987-10-08 | 1987-11-11 | Unilever Plc | Sanitizer |
| US4855075A (en) * | 1988-03-14 | 1989-08-08 | Sandoz Ltd. | Ethoxylates of alkyl and alkenyl catechols |
| DE19926627A1 (de) * | 1999-06-11 | 2000-12-14 | Henkel Kgaa | Bleich- und Desinfektionsmittel |
-
1970
- 1970-12-09 JP JP45109106A patent/JPS4926688B1/ja active Pending
-
1971
- 1971-12-02 US US00204344A patent/US3758409A/en not_active Expired - Lifetime
- 1971-12-06 DE DE2160409A patent/DE2160409C3/de not_active Expired
- 1971-12-07 GB GB5674571A patent/GB1378649A/en not_active Expired
- 1971-12-08 AU AU36628/71A patent/AU458559B2/en not_active Expired
- 1971-12-08 NL NL7116832.A patent/NL159709B/xx unknown
- 1971-12-08 FR FR7144009A patent/FR2117522A5/fr not_active Expired
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4029591A (en) * | 1974-09-27 | 1977-06-14 | Lion Fat & Oil Co., Ltd. | Liquid detersive bleaching composition |
| US4071463A (en) * | 1975-09-11 | 1978-01-31 | The Dow Chemical Company | Stable cleaning agents of hypochlorite bleach and detergent |
| US4174289A (en) * | 1977-07-27 | 1979-11-13 | Basf Wyandotte Corporation | Liquid detergent-bleach concentrates having high alkalinity |
| US4235732A (en) * | 1978-02-08 | 1980-11-25 | The Procter & Gamble Company | Liquid bleaching compositions |
| US4281421A (en) * | 1979-03-12 | 1981-08-04 | The Procter & Gamble Company | Passive dosing dispenser with improved hypochlorite cake |
| US4399050A (en) * | 1980-05-13 | 1983-08-16 | Sandoz Products Limited | Bleach composition |
| US4443353A (en) * | 1981-08-15 | 1984-04-17 | Chem-Y Fabriek Van Chemische Producten B.V. | Aqueous bleaching agent with cleaning action |
| US4657692A (en) * | 1984-04-20 | 1987-04-14 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4599186A (en) * | 1984-04-20 | 1986-07-08 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4772414A (en) * | 1986-07-24 | 1988-09-20 | Ppg Industries, Inc. | Bleaching composition |
| WO1988005461A1 (en) * | 1987-01-23 | 1988-07-28 | Molony Donald P | Sodium carbonate/sodium hydroxide/sodium hypochlorite composition and process for removing stains |
| US20070157852A1 (en) * | 2005-06-30 | 2007-07-12 | Lee Eun-Sung | Dispersant, paste composition including the dispersant, inorganic device using the paste composition, and display apparatus including the inorganic device |
| US7662317B2 (en) * | 2005-06-30 | 2010-02-16 | Samsung Electronics Co., Ltd. | Dispersant, paste composition including the dispersant, inorganic device using the paste composition, and display apparatus including the inorganic device |
| US20070072969A1 (en) * | 2005-09-27 | 2007-03-29 | Lee Eun S | Carboxylic ester dispersant and sulfide phosphor paste composition having same |
| US7560054B2 (en) * | 2005-09-27 | 2009-07-14 | Samsung Electro-Mechanics Co., Ltd. | Carboxylic ester dispersant and sulfide phosphor paste composition having same |
| CN112745821A (zh) * | 2021-01-06 | 2021-05-04 | 中海石油(中国)有限公司 | 一种海上稠油蒸汽伴注用耐温抗盐驱油剂及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2160409B2 (de) | 1977-10-13 |
| NL7116832A (enrdf_load_stackoverflow) | 1972-06-13 |
| AU3662871A (en) | 1973-06-14 |
| GB1378649A (en) | 1974-12-27 |
| JPS4926688B1 (enrdf_load_stackoverflow) | 1974-07-11 |
| NL159709B (nl) | 1979-03-15 |
| DE2160409C3 (de) | 1978-06-08 |
| FR2117522A5 (enrdf_load_stackoverflow) | 1972-07-21 |
| AU458559B2 (en) | 1975-02-27 |
| DE2160409A1 (de) | 1972-06-15 |
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