US3481881A - Soap or detergent rinsing agent - Google Patents
Soap or detergent rinsing agent Download PDFInfo
- Publication number
- US3481881A US3481881A US522371A US3481881DA US3481881A US 3481881 A US3481881 A US 3481881A US 522371 A US522371 A US 522371A US 3481881D A US3481881D A US 3481881DA US 3481881 A US3481881 A US 3481881A
- Authority
- US
- United States
- Prior art keywords
- acid
- ester
- rinsing
- dishes
- sugar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003795 chemical substances by application Substances 0.000 title description 14
- 239000003599 detergent Substances 0.000 title description 2
- 239000000344 soap Substances 0.000 title description 2
- 150000002148 esters Chemical class 0.000 description 20
- 239000006260 foam Substances 0.000 description 14
- 239000002253 acid Substances 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 235000000346 sugar Nutrition 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 238000004851 dishwashing Methods 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- -1 alkyl phenols Chemical class 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005406 washing Methods 0.000 description 9
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 8
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 8
- 238000009736 wetting Methods 0.000 description 8
- 238000005187 foaming Methods 0.000 description 7
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 6
- 229930091371 Fructose Natural products 0.000 description 5
- 239000005715 Fructose Substances 0.000 description 5
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 229930006000 Sucrose Natural products 0.000 description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 5
- 235000013681 dietary sucrose Nutrition 0.000 description 5
- 239000008103 glucose Substances 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 229960004793 sucrose Drugs 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 235000021313 oleic acid Nutrition 0.000 description 4
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 3
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 3
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 3
- 239000008101 lactose Substances 0.000 description 3
- 150000002772 monosaccharides Chemical class 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- NOBRFKNEKOAANG-RJMJUYIDSA-N CCCCCCCCCCCC(O)=O.O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@H](O)[C@@H](O)C(O)O[C@@H]1CO Chemical compound CCCCCCCCCCCC(O)=O.O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@H](O)[C@@H](O)C(O)O[C@@H]1CO NOBRFKNEKOAANG-RJMJUYIDSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- QMXNBMYMWQZNKH-SSPAHAAFSA-N decanoic acid;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal Chemical compound CCCCCCCCCC(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O QMXNBMYMWQZNKH-SSPAHAAFSA-N 0.000 description 2
- 150000002016 disaccharides Chemical class 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 150000001261 hydroxy acids Chemical class 0.000 description 2
- 235000020778 linoleic acid Nutrition 0.000 description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
- 125000005481 linolenic acid group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 2
- 229940066675 ricinoleate Drugs 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000001195 (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid Substances 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
Definitions
- This invention relates to dishwashing compositions. It more particularly relates to special compositions particularly useful in the rinsing of washed dishes.
- washing agent manufacturers have developed compositions and formulations which have little or no foaming or sudsing action under conditions of mechanical dishwashing.
- compositions have been discovered which, when mixed with Water, form an adequate final rinse of accept- 3,481,881 Patented Dec. 2, 1969 able wetting power and leave dishes in relatively good spot-free condition.
- These compositions include' high molecular weight sulfates and sulfonates and non-ionic addition products of alkylene (e.g. ethylene or propylene) oxides to fatty alcohols, alkyl phenols and the like. It has been found, however, that in order to obtain the desired wetting action, such quantities of these materials had to be used as to produce excessive foaming in the dishwasher and subject it to overflowing, flooding and mechanical damage due to suds-clogging.
- alkylene e.g. ethylene or propylene
- this invention comprises in one of its aspects the provision of a wetting agent suitable for use in the final rinse of mechanical dishwashing, comprising at least one ester of a sugar and a higher fatty acid.
- a wetting agent suitable for use in the final rinse of mechanical dishwashing comprising at least one ester of a sugar and a higher fatty acid.
- the esters of this invention are water-soluble and are in no way physiologically objectionable, at least in the small amounts left remaining on the dishes after drying.
- the acid moiety of the esters of this invention include aliphatic carboxylic acids having about 8 to 20 carbon atoms in straight or branched chain. These acid moieties may be unsubstituted alkanoic acids or they may contain olefinic unsaturation therein and/or hydroxy substituents thereon. Preferably fatty carboxylic acids having about 10 to 18 carbon atoms and of the hereinbefore described configuration are used. Both monosaccharide and disaccharide esters are considered to be within the scope of this invention. Where the monosaccharide esters are chosen, it is preferred to employ fatty acids of the above description containing about 10 to 12 carbon atoms.
- Suitable fatty acids within the scope of this invention are caprilic, capric, lauric, palmitic, stearic, oleic, linoleic and linolenic acids and their hydroxy substituted corresponding acids, such as ricinoleic, etc.
- the alcoholic moiety of the esters of this invention comprises a naturally occurring or synthetic sugar.
- These sugars may be monosaccharides or disaccharides, as the case may be.
- Exemplary of the disaccharides which are useful in this invention are lactose, maltose, saccharose, as well as sugar mixtures obtained by the hydrolysis of starch, cellulose and other naturally occurring polysaccharide type material.
- Exemplary of the monosaccharides are glucose, fructose, xylose and other similar substances.
- esters to be used in this invention it is convenient to produce the esters to be used in this invention by straight acid-alcohol esterification or by rechlorisocyanurate, and were then substantially freed from the adherent alkaline liquid by an intermediate rinsing with clean water at 40 C.
- different surface-active agents were employed, as set forth in detail in the table.
- water of 17 German hardness and a temperature of 75 C. was employed.
- the superiority of the agents in accordance with the invention can be clearly of the desired sugar in the presence of dimethyl formamide 10 noted.
- itrie acid 1 Ester from 1 mol of maltose and 1 mol of the fatty acids obtained by saponification from beef tallow. 0. 2 -.do ... ⁇ No foam. Tartaric acid 0. 5
- ester product can be recovered by known suitable chemical engineering purification procedures, such as extraction or distillation, preferably the latter under reduced pressure to minimize or avoid ester decomposition.
- sugar-fatty acid esters produced which are useful in this invention are saccharose monopalmitate, maltose ester of a mixture of fatty acids obtained by saponification of coconut oil, lactose monolaurate, glucose monocaprate, fructose ricinoleate, the esterification product of oleic acid with the hydrolysis product of starch (mostly maltose and glucose) and lactose dicaprate.
- the wetting or rinsing agent sugar-fatty acid esters are generally used in a water solution in the final rinse formulation. It has been found suitable to use concentrations of 0.01 to 0.4 gram per liter, preferably 0.03 to 0.1 gram per liter of the ester in the final rinse bath. The quantity of ester in the final rinse bath should be adjusted to the salt content of the water, with somewhat larger quantities of ester used in combination with high salt content waters.
- the wetting and rinsing agents of this invention can be used with hard or soft water, as the case may be. Where the rinsing water is hard, it is preferred to additionally include in the rinsing bath hydroxy carboxylic acids having about 2 to 5 carbon atoms. Exemplary of these hydroxy acids are tartaric, lactic, citric and glycollic acid. They may be incorporated into the final rinse bath in proportions of about 0.1 to 2 grams per liter, preferably 0.5 to 1 gram per liter, depending upon the degree of hardness of the water being employed.
- the method of rinsing dishes substantially spotless in a mechanical dishwasher operating under conditions of minimal foam which comprises providing in the final rinse water 0.01 to .4 g./l. of a wetting agent consisting essentially of an ester of a sugar and a fatty acid containing about 8 to 20 carbon atoms, and a lower hydroxy carboxylic acid containing about 2 to 5 carbon atoms wherein said hydroxy acid is present in a proportion of about 0.1 to 2 grams per liter.
- a wetting agent consisting essentially of an ester of a sugar and a fatty acid containing about 8 to 20 carbon atoms, and a lower hydroxy carboxylic acid containing about 2 to 5 carbon atoms wherein said hydroxy acid is present in a proportion of about 0.1 to 2 grams per liter.
- a method as claimed in claim -1 wherein said sugar is a member selected from the group consisting of lactose, maltose, saccharose, glucose, fructose, xylose and hydrolysis products of at least one member selected from the group consisting of cellulose and starch.
- fatty acid is a member selected from the group consisting of caprilic, capric, lauric, palmitic, stearic, oleic, linoleic, and linolenic acids.
- ester is a member selected from the group consisting of saccharose monopalmitate, maltose ester of a mixture of saponified coconut oil acids, lactose monolaurate, glucose monocaprate, fructose ricinoleate, sugars derived by hydrolysis of starch oleate, lactose dicaprate and maltose ester of a mixture of saponified beef tallow acids.
- hydroxy carboxylic acid is a member selected from the group consisting of tartaric acid, lactic acid, citric acid and glycolic acid.
- a wetting and rinsing agent consisting essentially of an aqueous solution of 0.01 to 0.4 g./l. of a sugar ester of a fatty acid, wherein said sugar is a member selected from the group consisting of lactose, maltose, saccharose, glucose, fructose, xylose and hydrolysis products of at least one member selected from the group consisting of cellulose and starch, and said fatty acid is selected from the group consisting of caprilic, capric, lauric, palmitic, stearic, oleic, linoleic, and linolenic acids and a lower hydroxy carboxylic acid containing about 2 to 5 carbon atoms.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB80404A DE1263962B (de) | 1965-02-06 | 1965-02-06 | Verwendung von Zuckerestern als Klarspuelmittel fuer die maschinelle Geschirreinigung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3481881A true US3481881A (en) | 1969-12-02 |
Family
ID=6980702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US522371A Expired - Lifetime US3481881A (en) | 1965-02-06 | 1966-01-24 | Soap or detergent rinsing agent |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3481881A (enrdf_load_stackoverflow) |
| AT (1) | AT271682B (enrdf_load_stackoverflow) |
| BE (1) | BE676058A (enrdf_load_stackoverflow) |
| CH (1) | CH466481A (enrdf_load_stackoverflow) |
| DE (1) | DE1263962B (enrdf_load_stackoverflow) |
| DK (1) | DK129587B (enrdf_load_stackoverflow) |
| ES (1) | ES322657A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1069358A (enrdf_load_stackoverflow) |
| NL (1) | NL6600217A (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4967910A (enrdf_load_stackoverflow) * | 1972-10-31 | 1974-07-02 | ||
| US4239552A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents |
| US4897122A (en) * | 1986-08-11 | 1990-01-30 | Schreiber A Charles | Process, composition and apparatus for cleaning venetian blinds |
| US5501742A (en) * | 1993-02-19 | 1996-03-26 | Ecolab Inc. | Method for dispensing solid rinse aids |
| US5602093A (en) * | 1992-10-07 | 1997-02-11 | Henkel Kommanditgesellschaft Auf Aktien | Dishwashing machine rinse aids containing APG, alkyl polyglycol ether and organic carboxylic acid |
| US20110257108A1 (en) * | 2010-04-14 | 2011-10-20 | Utah State University | Synthesis and activity of lactose esters |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0301847A1 (en) * | 1987-07-29 | 1989-02-01 | Microgenics Corporation | Cleaning using cyclodextrin |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1554483A (en) * | 1924-02-05 | 1925-09-22 | Bailey Preston Perkins | Method of cleaning aluminum |
| US2563856A (en) * | 1945-10-12 | 1951-08-14 | Nopco Chem Co | Defoaming agent for pulp and paper stock |
| US2893990A (en) * | 1955-12-12 | 1959-07-07 | Sugar Res Foundation Inc | Process for producing sugar esters |
| US2954347A (en) * | 1955-10-27 | 1960-09-27 | Procter & Gamble | Detergent composition |
| US2970962A (en) * | 1958-02-11 | 1961-02-07 | Sugar Res Foundation Inc | Novel detergent compositions |
| US3024229A (en) * | 1957-07-26 | 1962-03-06 | Bayer Ag | Preparation of ester salts of di and trisaccharides |
| US3231561A (en) * | 1962-01-03 | 1966-01-25 | Economics Lab | Fatty acid sugar esters and fatty acid sugar-boron esters |
-
1965
- 1965-02-06 DE DEB80404A patent/DE1263962B/de active Pending
-
1966
- 1966-01-07 NL NL6600217A patent/NL6600217A/xx unknown
- 1966-01-24 US US522371A patent/US3481881A/en not_active Expired - Lifetime
- 1966-02-04 CH CH158166A patent/CH466481A/de unknown
- 1966-02-04 AT AT101766A patent/AT271682B/de active
- 1966-02-04 GB GB4916/66A patent/GB1069358A/en not_active Expired
- 1966-02-04 BE BE676058D patent/BE676058A/xx unknown
- 1966-02-05 DK DK60266AA patent/DK129587B/da unknown
- 1966-02-05 ES ES0322657A patent/ES322657A1/es not_active Expired
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1554483A (en) * | 1924-02-05 | 1925-09-22 | Bailey Preston Perkins | Method of cleaning aluminum |
| US2563856A (en) * | 1945-10-12 | 1951-08-14 | Nopco Chem Co | Defoaming agent for pulp and paper stock |
| US2954347A (en) * | 1955-10-27 | 1960-09-27 | Procter & Gamble | Detergent composition |
| US2893990A (en) * | 1955-12-12 | 1959-07-07 | Sugar Res Foundation Inc | Process for producing sugar esters |
| US3024229A (en) * | 1957-07-26 | 1962-03-06 | Bayer Ag | Preparation of ester salts of di and trisaccharides |
| US2970962A (en) * | 1958-02-11 | 1961-02-07 | Sugar Res Foundation Inc | Novel detergent compositions |
| US3231561A (en) * | 1962-01-03 | 1966-01-25 | Economics Lab | Fatty acid sugar esters and fatty acid sugar-boron esters |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4967910A (enrdf_load_stackoverflow) * | 1972-10-31 | 1974-07-02 | ||
| US4239552A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents |
| US4897122A (en) * | 1986-08-11 | 1990-01-30 | Schreiber A Charles | Process, composition and apparatus for cleaning venetian blinds |
| US5602093A (en) * | 1992-10-07 | 1997-02-11 | Henkel Kommanditgesellschaft Auf Aktien | Dishwashing machine rinse aids containing APG, alkyl polyglycol ether and organic carboxylic acid |
| US5501742A (en) * | 1993-02-19 | 1996-03-26 | Ecolab Inc. | Method for dispensing solid rinse aids |
| US20110257108A1 (en) * | 2010-04-14 | 2011-10-20 | Utah State University | Synthesis and activity of lactose esters |
Also Published As
| Publication number | Publication date |
|---|---|
| DK129587C (enrdf_load_stackoverflow) | 1975-04-14 |
| BE676058A (enrdf_load_stackoverflow) | 1966-08-04 |
| NL6600217A (enrdf_load_stackoverflow) | 1966-08-08 |
| DE1263962B (de) | 1968-03-21 |
| ES322657A1 (es) | 1967-09-01 |
| DK129587B (da) | 1974-10-28 |
| AT271682B (de) | 1969-06-10 |
| GB1069358A (en) | 1967-05-17 |
| CH466481A (de) | 1968-12-15 |
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