US2071385A - Treatment of textile materials - Google Patents
Treatment of textile materials Download PDFInfo
- Publication number
- US2071385A US2071385A US680151A US68015133A US2071385A US 2071385 A US2071385 A US 2071385A US 680151 A US680151 A US 680151A US 68015133 A US68015133 A US 68015133A US 2071385 A US2071385 A US 2071385A
- Authority
- US
- United States
- Prior art keywords
- dyeing
- dye
- sodium
- dyed
- lbs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 17
- 239000004753 textile Substances 0.000 title description 16
- 239000000975 dye Substances 0.000 description 46
- 238000004043 dyeing Methods 0.000 description 35
- 239000000835 fiber Substances 0.000 description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 8
- 238000009991 scouring Methods 0.000 description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 8
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 8
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 230000035515 penetration Effects 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 4
- 229940005740 hexametaphosphate Drugs 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 230000008707 rearrangement Effects 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 235000019820 disodium diphosphate Nutrition 0.000 description 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- CGIGDMFJXJATDK-UHFFFAOYSA-N indomethacin Chemical compound CC1=C(CC(O)=O)C2=CC(OC)=CC=C2N1C(=O)C1=CC=C(Cl)C=C1 CGIGDMFJXJATDK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- MOLJFAGWUXDJJC-UHFFFAOYSA-M sodium 3-[(2,4-dihydroxyphenyl)diazenyl]-4-hydroxybenzenesulfonate Chemical compound [Na+].Oc1ccc(N=Nc2cc(ccc2O)S([O-])(=O)=O)c(O)c1 MOLJFAGWUXDJJC-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- KIEOKOFEPABQKJ-UHFFFAOYSA-N sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C3/00—Treatment of animal material, e.g. chemical scouring of wool
- D01C3/02—De-gumming silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67366—Phosphates or polyphosphates
Definitions
- the present invention relates to the treatment of textiles and, more particularly, to the dyeing of textiles by the use of dilute solutions of alkalimetal hexametaphosphates.
- the textile fibers employed are or animal or vegetable origin or of artificial preparation.
- the first are wool and silk; oi the second, cotton and linen; of the third, rayon or other forms or artificial silk made by 10 various processes.
- - Textile fibers may be dyed between any of the steps used in the manufacture of the finished fabnic, namely, they maybe dyed in the form or stock, either raw or previously scoured, in the 15 form of partially or fully combed but untwisted fiber, known as sliver or slubbing, in the form of twisted thread or yarn, or finally in the completely woven piece.
- the object to be attained is the dyeing oi the material to an even shade and of the color desired.
- the woven piece is composed of 85 threads or different classes of fibers which have diflerent aflinities for certain dyes, it is sometimes wished to dye the whole equally and evenly, and at others to choose such dyes or dyeing methods as will color the threads of one composition a & certain color and leave the threads of the other material a difierent color or in their original white condition.
- specific colored designs are given to woven cloth by printing locally there- 35 on certain pigments, dyes or the component parts of dyes and then setting the pigments or develop-v ing the dyes of which a certain essential part or parts were locally applied by subjecting the whole piece of cloth to a uniform treatment.
- Penetration or the evenness thereof may be hindered by fats, waxes, oils, or metallic soaps existing either naturally in the fiber or imposed thereon by some process prior to the dyeing operation.
- dye kettle or'the piping thereto may, in many cases, have most serious results in dulling' or otherwise modifying the color produced by the dye.
- certain metallic salts are deliberately added to the dye bath or else precipitated on the material to be dyed, either prior to the dyeing thereof or subsequently thereto, for the purpose of firmly fixing the dye to the fiber or for changing the color produced otherwise by the dye alone,to a more desired one.
- the dyeing vessel had adjacent thereto a smaller vessel open at the top and the two were so interconnected by piping that the dye liquor in the smaller vessel could be forced by a mechanically driven pump, installed in the pipe line leading from the smaller vessel, into the top of the dyeing vessel, through the material to be dyed and re turned from the bottom of the dyeing vessel to the smaller auxiliary container.
- the dye liquor could thus be continuously clr culated through the material to be dyed.
- a small pipe line conveying steam entered the delivery pipe and enabled the circulating dye liquor to be gradually raised to the boiling point.
- the dyeing machine having been prepared as above, the dyeing was started at an approximate temperature of 100 to 110 F. and brought up to the, boiling point during a period or thirty minutes.
- the dye liquor was boiled for twenty minutes.
- fiIteen pounds of sodium sulphate was added and the boiling continued .for twenty minutes more.
- thirty pounds more sodium sulphate was added and the boiling continued for another twenty minutes.
- sixty pounds more sodium sulphate was added and the boiling continued for another twuty minutes.
- the dye bath containing the material to be dyed was brought to the boil, 'boiled three- 70 quarters 01' an hour, 10 pounds formic acid added. boiled one-halt hour, 4% pounds sodium dichromate added half hour.
- the dye Diamond blue black R. B. N., dyes red but the subsequent treatment with dichromate turnsit to a blue, thus intensifying the black shade or the dye that is present in the largest portion.
- any failure of completeness of the chroming would allow the orisinal red color oi. the blue black to remain and give a reddish cast to portions of the dyed material.
- the material dyed without the use oi" sodium hexametaphosphate not only dyed unevenly, but chromed unevenly as well, whereas the slubbing dyed with the addition oi the metaphosphate not only dyed evenly, but chromed more thoroughlyand evenly and showed no traces of spots oi reddish'hue.
- phates may be used, such as the potassium and ammonium salts. These'alkali-metal hexametaamines I 3 by' the elimination of the sludge in one of the examples above.
- the step which which consists in subjecting the textiles' 1o to a dyeing bath containing an alkali metal hexametaphosphate.
- the-step which consists in subjecting the textiles to a dyeing bath containing sodium hexameta- 15 phosphate.
- phates may be used, such as the potassium and ammonium salts. These'alkali-metal hexametaamines I 3 by' the elimination of the sludge in one of the examples above.
- the step which which consists in subjecting the textiles' 1o to a dyeing bath containing an alkali metal hexametaphosphate.
- the-step which consists in subjecting the textiles to a dyeing bath containing sodium hexameta- 15 phosphate.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Animal Husbandry (AREA)
- Coloring (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI45957D DE685124C (de) | 1932-12-07 | 1932-12-07 | Verfahren zum Faerben von Faserstoffen |
US680151A US2071385A (en) | 1932-12-07 | 1933-07-12 | Treatment of textile materials |
FR764974D FR764974A (fr) | 1932-12-07 | 1933-12-04 | Procédé pour teindre des matières fibreuses |
FR775690D FR775690A (fr) | 1932-12-07 | 1934-07-10 | Procédé de traitement de matières textiles, en vue de leur teinture ou de leur dégommage |
GB20233/34A GB445466A (en) | 1932-12-07 | 1934-07-10 | Improvements in or relating to the dyeing or printing of textile materials |
ES0135022A ES135022A1 (es) | 1932-12-07 | 1934-07-11 | Procedimiento para tratar materiales textiles |
NL70094A NL39843C (enrdf_load_stackoverflow) | 1932-12-07 | 1934-07-12 | |
NL78498A NL42632C (enrdf_load_stackoverflow) | 1932-12-07 | 1936-07-10 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI45957D DE685124C (de) | 1932-12-07 | 1932-12-07 | Verfahren zum Faerben von Faserstoffen |
US680151A US2071385A (en) | 1932-12-07 | 1933-07-12 | Treatment of textile materials |
Publications (1)
Publication Number | Publication Date |
---|---|
US2071385A true US2071385A (en) | 1937-02-23 |
Family
ID=25981722
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US680151A Expired - Lifetime US2071385A (en) | 1932-12-07 | 1933-07-12 | Treatment of textile materials |
Country Status (6)
Country | Link |
---|---|
US (1) | US2071385A (enrdf_load_stackoverflow) |
DE (1) | DE685124C (enrdf_load_stackoverflow) |
ES (1) | ES135022A1 (enrdf_load_stackoverflow) |
FR (2) | FR764974A (enrdf_load_stackoverflow) |
GB (1) | GB445466A (enrdf_load_stackoverflow) |
NL (2) | NL39843C (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2749207A (en) * | 1956-06-05 | Hoxchi | ||
US2829129A (en) * | 1953-10-16 | 1958-04-01 | Ici Ltd | Dyestuff-polyphosphate composition |
CN104593877A (zh) * | 2014-12-29 | 2015-05-06 | 无锡蚕魅科技有限公司 | 一种蚕丝的脱胶方法 |
CN104611865A (zh) * | 2014-12-29 | 2015-05-13 | 无锡蚕魅科技有限公司 | 一种蚕丝染色前处理工艺 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2785040A (en) * | 1957-03-12 | Process for dyeing cellulosic materials | ||
DE933144C (de) * | 1951-12-07 | 1955-09-22 | Ciba Geigy | Verfahren zum Faerben oder Bedrucken cellulosehaltiger Materialien und fuer dessen Durchfuehrung geeignete Farbstoffpraeparate |
DE933145C (de) * | 1951-12-14 | 1955-09-22 | Ciba Geigy | Verfahren zum Faerben cellulosehaltiger Materialien |
DE976052C (de) * | 1952-02-22 | 1963-01-31 | Benckiser Gmbh Joh A | Verfahren zum Faerben von Textilien in saurem Medium unter Zusatz von Alkalimetaphosphaten |
DE1138734B (de) * | 1953-04-16 | 1962-10-31 | Hoechst Ag | Verfahren zur Verhinderung des Verkochens beim neutralen oder schwach sauren Faerben von Fasergemischen aus Cellulosefasern und eiweisshaltigen Textilfasern mit substantiven Farbstoffen in hartem, Magnesiumsalze enthaltendem Wasser |
DE1152989B (de) * | 1954-11-06 | 1963-08-22 | Benckiser Gmbh Joh A | Textildruckpaste mit Alginatverdickung und einem Gehalt an polymeren Phosphaten |
-
1932
- 1932-12-07 DE DEI45957D patent/DE685124C/de not_active Expired
-
1933
- 1933-07-12 US US680151A patent/US2071385A/en not_active Expired - Lifetime
- 1933-12-04 FR FR764974D patent/FR764974A/fr not_active Expired
-
1934
- 1934-07-10 GB GB20233/34A patent/GB445466A/en not_active Expired
- 1934-07-10 FR FR775690D patent/FR775690A/fr not_active Expired
- 1934-07-11 ES ES0135022A patent/ES135022A1/es not_active Expired
- 1934-07-12 NL NL70094A patent/NL39843C/xx active
-
1936
- 1936-07-10 NL NL78498A patent/NL42632C/xx active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2749207A (en) * | 1956-06-05 | Hoxchi | ||
US2829129A (en) * | 1953-10-16 | 1958-04-01 | Ici Ltd | Dyestuff-polyphosphate composition |
CN104593877A (zh) * | 2014-12-29 | 2015-05-06 | 无锡蚕魅科技有限公司 | 一种蚕丝的脱胶方法 |
CN104611865A (zh) * | 2014-12-29 | 2015-05-13 | 无锡蚕魅科技有限公司 | 一种蚕丝染色前处理工艺 |
Also Published As
Publication number | Publication date |
---|---|
NL39843C (enrdf_load_stackoverflow) | 1937-01-15 |
NL42632C (enrdf_load_stackoverflow) | 1938-02-15 |
ES135022A1 (es) | 1934-10-01 |
FR775690A (fr) | 1935-01-07 |
FR764974A (fr) | 1934-05-30 |
GB445466A (en) | 1936-04-14 |
DE685124C (de) | 1939-12-12 |
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