US2412125A

US2412125A - Article and treatment of casein fibers

Info

Publication number: US2412125A
Application number: US415631A
Authority: US
Inventors: John E Conrad
Original assignee: Collins & Aikamn Corp
Current assignee: Collins & Aikamn Corp
Priority date: 1941-10-18
Filing date: 1941-10-18
Publication date: 1946-12-03
Anticipated expiration: 1963-12-03

Description

Patented Dec. 3, 1946 r l l ARTICLE AND TREATMENT OF CASEIN FIBERS John E. Conrad. Baia-Cynwyd, Pa., assignor to Collins 8; Altman Corporation, Philadelphia,

Pa., a corporation of Delaware No Drawing. Application October 18, 1 941,

- Serial No. 415,631

11 Claims. (Cl. 8-21) This invention relates to a processof preparing synthetic fibers derived from casein or from other protein substances for dyeing in certain dyebaths so that these synthetic fibers may be blended or otherwise used together with wool and/or mohair fibers in the manufacture of textile fabrics which are to be dyed in the piece to a substantially uniform shade without oblectionably noticeable striations appearing. My improvements are of particular utility in the union dyeing of fabrics,

both pile and fiat, containing cotton or other cellulose fibers as well as wool and/or mohair. By my improvements a novel fiber and fabric are produced.

Throughout this specification the term casein fibers" will for brevity be used, but the term will be understood to include other synthetic protein fibers such as those derived from the soy bean or from zein (corn), as well as those derived from casein.

Synthetic casein fibers are of protein material and accordingly have affinity for many of the same dyes as have wool and mohair, but the initial afilnity oi the synthetic casein fibers for dyestuffs is much stronger than that of the wool and mchair fibers. Consequently. if untreated casein fibers be blended with wool and/or mohair fibers in yarns which are then dyed by short time immersion methods, as in pad dyeing, the casein fibers will dye so much darker than the wool and mohair as to constitute a difference in color. Where the time of immersion is long, as in kettle dyeing, the stronger initial afiinity of the synthetic casein fibers will be partially overtaken but there will nevertheless be a substantial difference in shade between the synthetic casein and the natural wool and/or mohair fibers.

In the manufacture in quantity of textile pile fabrics having a. cotton backing or base portion and wool. or mohair, or blends thereof. with or without other fibers, including casein fibers, in the pile. it is very desirable for reasons of speed and economy oi. production to dye the fabric in the piece in a union dye bath in a continuous operation using pad dyeing methods. A union dye bath which I contemplate is an aqueous bath containing (a) neutral dyeing acid dyestuffs for the wool. casein and mohair fibers, and (bi substantlve dyestuffs intended primarily for the cotton fibers. The wool. casein and mohair fibers also have affinity for thesubstantive dyestuffs so that the shade or color to which they dye is the combined effect of both components of the union dye bath. Application Serial No. 655,592

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When untreated synthetic casein fibers are included in the pile yarn blend together with wool and/or mohair, and the fabric union dyed in a pad dyeing operation, the synthetic casein fibers will ordinarily dye much darker or deeper than the wool and mohair fibers. As indicated hereinbefore, if such a fabric be union kettle dyed, the difference will not be as great due to the often repeated immerslons. but there will neverthe less be a substantial contrast in shade.

A difference in color or shade will also occur ii untreated synthetic casein fibers be blended with wool and/or mohair fibers in fabrics. such as worsted fiat fabrics. having no cotton and the fabrics dye by pad dyeing methods with acid dyestuiis in a substantially neutral bath.

According to my improvements I may produce 9. treated casein fiber which will dye to a shade approximating that of wool or mohair when the two types of fibers are dyed together in a substantially neutral aqueous union bath containing neutral dyeing acid dyestuffs and substantive dyestutfs using either short time immersion methods. as in pad dyeing. or long time repeated immersion methods. as in kettle dyeing. My treated casein fiber will also dye similarly to wool or mohair when the two types are dyed together by either pad or kettle methods in a substantially neutral aqueous bath containing only neutral dyeing acid dyestufi's or when the two types are pad dyed together with vat dyestufls. My treated casein fiber does not. however. dye like wool or mohair when the two are dyed together by either pad or kettle methods in acid dye baths.

The treatment given the casein fiber to accom' pllsh the foregoing eflects does not weaken the fiber nor does it make the fiber stifl or hard or harsh or gummy. In other words. the treated fiber retains substantially its initial strength. flexibility. elasticity and feel.

My method comprises a two bath treatment whereby a water insoluble metallic tannate is incorporated with the casein fiber. The tannate is preferably light colored so as to affect as little as possible the color or shade to which the fiber is dyed. This is important in connection with producing shades currently used for most automobile upholstery pile fabrics.

According to a preferred embodiment of my improvements, the casein fibers are first sublected to an aqueous solution of tennis acid. The excess solution may then be removed and the fibers next immersed in an aqueous solution, preferably of stannous chloride, whereby tin tannaie is incorporated with the fibers. The fibers may then be rinsed and dried. The second bath may if desired be an aqueous solution of any water soluble aluminum salt such as aluminum sulphate or aluminum acetate, whereby aluminum tannate will be incorporated with the fibers. Or the second bath may be an aqueous solution of tartar emetic, whereby antimony tannate will be incorporated with the fibers. A small amount of acetic acid may preferably be used in each bath, the presence of acetic acid being more important in the second bath than in the first. The time of immersion, the temperature of the baths and the concentration of the solutions will be more fully described hereinafter.

It is an object of this invention to prepare synthetic fibers derived from casein or other protein substances for dyeing so that the said synthetic fibers may be blended or otherwise used together with wool and/or mohair and cotton fibers and dyed in a union bath without objectionably noticeable striations appearing.

More specifically. it is an object of this invention to prepare artificial fibers derived from casein for dyeing in a union bath containing neutral dyeing acid dyestuffs and substantive dyestuds,

or for dyeing with neutral acid dyestufls, or with vat dyestuffs using short time immersion methods as in pad dyeing.

Another object is to produce a synthetic casein fiber having a water insoluble metallic tannate incorporated therewith. which when subjected to neutral dyeing acid dyestuffs, or to substantive dyestufls; or to both as in union dyeing, or .to vat dyestufi's in a short time immersion operation will dye to a shade approximating the shade of wool fibers subjected to the same dye bath for the same length time under the same conditions.

Another object is to provide a method of incorporating a water insoluble tannate with the casein fiber.

Another obiect is to produce a unlormly dyed textile fabric including casein, cotton and other cellulose fibers, and wool fibers; said casein fibers having a water insoluble metallic tannate incor- Dorated therewith.

Another object is to incorporate tin tannate, or aluminum tannate, or antimony tannate, with the casein fiber, whereby the fiber will have an afiinity approximating that or wool fibers for neutral dyeing acid dyestuffs. or substantive dyestufls, or both as in union dyeing.

Another object is to treat casein fibers so that they may be blended together with wool and/or mohair fibers in the pile of pile fabrics having a cotton backing, and dyed together therewith in a union bath using short time immersion methods as in continuous pad dyeing, all of the blended fibers in the pile being dyed to nearly the same shade.

These and other objects of invention will be manifest from a consideration of the specification and ot the claims.

According to a preferred embodiment of my invention, the synthetic casein fibers are immersed in one quarter of one percent. aqueous solution of tannic acid at'lfifl F. It is deslrabe but not essential that the solution contain a small quantity of acetic acid. After about five or more minutes of being worked in the solution as by gentle agitation, the stock may be rinsed or nipped or the solution ma be merely permitted to drain oil.

The casein fiber stock is then immersed for five or more minutes in the second bath, which is preferably an aqueous solution, at approxl 4 mately 120 F., cdhtaining stannous in an amount appr ximating three percent. of the weight of the stock. A temperature substantially higher than 120 F. would damage the available casein fibers, and a substantially lower temperature would give markedly inferior-"resist efi'ects for the contemplated dyebaths. Aceticacid in an amount approximating one percent. of th weight of the stock may be contained in the second bath. As'a result of the reaction between the tannic acid and the stannous chloride, tin tannate is incorporated with the fibers.

The metallic salt of the second bath may. if desired, be aluminum sulphate or aluminum acetate. in which case aluminum tannate is in0or porated with the fibers. Or the second bath may be an aqueous solution of tartar emetic, in which case antimony tannate is incorporated with the fibers. Tin tannate, aluminum tannate and antimony tannate' are all light in color-and accordingly will not substantially darken the natural color of the casein fiber so as to interfere with or limit the color or shade which it is desired to ap ply in the subsequent dyeing operation.

In each bath the volume otaqueous solvent should be sufilcient to work the fiber stock therein. The weight of the aqueous solution may conveniently be about fii'teen times the weight of the fiber stock.

Attention is directed to the (act that in the preferred treatment described above the temperature of the tannlc acid bath is approximate ly 160 F. This temperature is Just above the point where the casein fibers swell markedly and at this temperature the fibers will absorb the tannic acid solution more readily than at substantially lower temperatures. Temperatures below 160 F. may be employed if desired, but the time oi immersion should be increased accordinely.

Higher temperatures than I". may also be employed, but temperatures lubstantially in excess oi F. should not be used. as thestrength' oi the casein fil'irs will be impaired. I have obtained satisfactory resist eflects using as a first bath a one-half of one percent. aqueous solution of tannicacid at a .temperature of 180 F., th time of llnmerslombein-gtwo minutes; As indicated, this is a-maxlmum temperature and a two minute immersion-period is minimum, as shorter periods o-i' immersion do not give sumciently strong resist eflects.

The time of immersion in the second bath should, as indicated above, be five minutes or 3 more and the amount 01' stannous chloride in solution should neither greatly exceed nor be greatly less than three percent. of the weight of the fibers being treated, as in either case the shade of the dye would be adversely ailected, and if more is used the fibers may be weakened. My improvements are particularly applicable for pad type union dyeing where the time of immer sion is very short. that is, a matter of seconds. This type of dyeing is widely used in the production of pile fabrics, as is set forth in United States Patent to Drobile et al. No, 2,071,922. A

satisfactory dyebath immersion time in processlllg according to the prior patent is ten seconds. I have found that after a ten second immersion my treated casein fibers will approximate the shade of wool and/or mohair blended therewith. It is to be understood that wool and mohair do not dye identically, but that they dye sufliciently close in shade to permit blending without objectionably noticeable striations in the finished piece. My treated casein fibers may be brought within a shade range which permits blending with wool or mohair to give a like uniiorm appearance to the cloth utter a ten second immersion as set forth. Thi result is accomplished by the treatment illustrated by this preferred embodiment.

A typical treatment -01' a commercial quantity of caseinfibers according to my method is as follows:

500 lbs, of synthetic casein fibers is placed in a suitable container or kettle. The aqueous solution of tannic acid at about 135 F. is drawn from a reservoir, placed in the kettle and then brought to a temperature of 160 F. and held there for approximately ten minutes, during which the fiber stock may be gently agitated. The tannic acid solution is then drained out and pumped back into the reservoir. A light rinse may then be given the casein fibers, after which any excess water or solution may be removed. The fibers are now ready for the second bath. Water and half of the required acetic acid is poured into the kettle, then the solution of stanncus chloride and the remainder of the acetic acid is added and the entire solution brought to 120' I". and held there. The fibers are kept in this solution for approximately five minutes, after which the kettle is drained. the fibers rinsed and then dried. In

this condition the fibers are ready for blending with wool or other fibers or for use alone in the formation of yarns.

A indicated hereinbei'ore, casein fibers treated according to my methods will dye approximately like wool when the two types 0! fibers are dyed to ether, by either pad or kettle methods, in a substantially neutral aqueous medium containing neutral dyeing acid dyestufls or substantive dyestuffs, or both as in union dyeing, or pad dyed with vat dyestufis. .Casein fibers treated according to my method will not, however, dye like wool where the two are immersed together in an acid bath containing acid dyeing acid dyestuffs,

Having descrlbedmy invention, I claim:

1. A process of making blended fabrics containing casein fibers and natural animal fibers of a proximately the same shade which includes treating the casein fibers so as to form a tin tannate on the fibers, blending the treated casein fibers with natural animal fibers'and then pad dyeing the blended fabric to an approximately uniform shade with a substantially neutral dyebath containing neutral dyeing acid colors.

2. A process as set forthin claim 1 further characterized in that the tin tannate is formed by treating the casein fibers with each of two se arate solutions, one of which contains tannic acid and the other of which contains a tin salt.

3. A process of treatin texti es which includes the steps of treating synthetic fibers derived from asein with each of two separate aqueous solutions, one of which contains tannic acid and the other of which contains a tin salt, then drying the treated fibers, blending the treated synthetic fibers with wool and dyeing the blended fibers to approximately the same shade with a substantially neutral dyebath containing neutral dyeing acid colors.

4. A process oi treatingtextiles which includes the steps of treating synthetic fibers derived from casein with each of two separate aqueous solutions, one of which contains tannic acid and the other 01 which contains a tin salt, then drying the fibers, blending the treated synthetic fibers with wool fibers. andpad dyeing the blerided fibers to approximately the same shade with a substantially neutral dyebath containing neutral dyeing acid colors.

5. A process as set forth in claim 4 further characterized in that the temperature of the tannic acid solution is less than 180 F. and the temperature of the tin salt solution approximates 120 F.

6. A process of making blended fabrics containing casein fibers and natural animal fibers of approximately the same shade, which includes treating the casein fibers so as to form a metallic tannate on the fibers, blending the treated casein fibers with natural animal fibers and then pad dyeing the blended fabric to an approximately uniform shade with a substantially neutral dye bath containing neutral dyeing acid colors.

7. An undyed synthetic fiber derived from 1 casein and having a water insoluble/metallic tannate incorporated therewith in an amount which will provide a partial resist for neutral dyeing acid colors to an extent that it will cause said fiber when immersed for a period of ten seconds in a substantially neutral aqueous medium containing neutral dyeing acid colors and then nipped as in pad dyeing to dye to approximately the shade of wool fibers immersed in the same dye bath for the same period of time under the same practical dyeing conditions.

8. In a process of 'preparing syntheticfibers derived from casein so that they will be partially resisted and, will dye approximately like wool in a substantially neutral aqueous medium containing neutral dyeing acid colors in ill-second immersion pad dyeing operations, the steps which consist in treating the fiber with each of two separate aqueous solutions, one solution containing tannic acid and the other being an aqueous solution of stannous chloride, said stannous chloride being present in an amount approximating 3% by weight of the fibers being treated and the temperature of said stannous chloride solution being approximately F. during processing.

9. An undyed textile fabric including cotton, wool, and caseinfibers, said casein fibers con-L, taming a metallic tannate in an amount that the casein fibers are partially resisted to neutral dyeing acid colors in a manner which causes them to dye to approximately the same shade as the natural wool fibers when the fabric is immersed for ten seconds in a substantially neutral dye bath containing neutral dyeing acid dyestuffs and substantive dyestuffs and then nipped as in pad dyeing.

10. An undyed textile fabric including wool and casein fibers, said casein fibers containing a lightcolored metallic tannate in such percentage that the casein fibers are partially resisted to neutral dyeing acid colors in a manner which will cause the fabric, when immersed for ten seconds in a substantially neutral dye bath containing neutral dyeing acid dyestufis and then nipped as in pad dyeing, to dye to an approximately uniform shade.

11. A synthetic fiber derived from casein, said fiber having a water insoluble metallic tannate incorporated therein in such an amount that the fiber will be partially resisted for neutral dyeing acid colors but will dye to a uniform shade in a substantially neutral aqueous dyebath containing neutral dyeing acid colors.

JOHN E. CONRAD.