US398564A - Mordant - Google Patents
Mordant Download PDFInfo
- Publication number
- US398564A US398564A US398564DA US398564A US 398564 A US398564 A US 398564A US 398564D A US398564D A US 398564DA US 398564 A US398564 A US 398564A
- Authority
- US
- United States
- Prior art keywords
- dye
- colors
- trisodium phosphate
- phosphate
- fabrics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000001488 sodium phosphate Substances 0.000 description 26
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 26
- 235000019801 trisodium phosphate Nutrition 0.000 description 24
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 24
- 239000003086 colorant Substances 0.000 description 20
- 239000004744 fabric Substances 0.000 description 18
- 239000000835 fiber Substances 0.000 description 18
- 239000000975 dye Substances 0.000 description 10
- 235000021317 phosphate Nutrition 0.000 description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 101710031640 ARHGAP32 Proteins 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- 208000006558 Dental Calculus Diseases 0.000 description 2
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- QVLTXCYWHPZMCA-UHFFFAOYSA-N PO4-PO4 Chemical compound OP(O)(O)=O.OP(O)(O)=O QVLTXCYWHPZMCA-UHFFFAOYSA-N 0.000 description 2
- 229940081543 Potassium bitartrate Drugs 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000016693 dipotassium tartrate Nutrition 0.000 description 2
- 230000002045 lasting Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000016337 monopotassium tartrate Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 description 2
- KYKNRZGSIGMXFH-UHFFFAOYSA-M potassium;2,3-dihydroxybutanedioate;hydron Chemical compound [K+].OC(=O)C(O)C(O)C([O-])=O KYKNRZGSIGMXFH-UHFFFAOYSA-M 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000004450 types of analysis Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- My invention relates to the fixing of dyecolors upon fibers or fabrics, whether of cotton, silk, wool, jute, flax, or other material;
- v 1 i i and the object of m y invention is to so treat the fibers or fabrics that the colors will be fixed thereon and that no superfi uou coloringmatter will be absorbed by the fibers or fabrics, and in consequence the latter will be free from rust or oxidation of the colors, and the colors will not come off or crock.
- dye-colors may be fixed on fibers or fabrics by subjecting them to the action of trisodium phosphate.
- the trisodium phosphate may be added directly to the dye- 1 bath, or it may be employed in the finishingphate, which has been but rarely used, pracbath, or it may be added to the water or other liquid which is to be used in either of those baths, or the fabrics or fibers may be treated to the action of a solution of the trisodium phosphate before being put in the dye-bath or after they have been dyed and finished.
- the quantity of trisodium phosphate to be used will vary with the character of the material to be. dyed and with the nature of the dye used, and to some extent with other attendant conditions. A one-per-cent.
- the color is more fully precipiis ob tat-ed and a brighter and a fuller color tained from a smaller quantity of dye andthe color is made more fast.
- the use of this trisodium phosphate results in great economy, for where twenty to twenty-five pounds of Glaubers salts have been heretofore used eight ounces of trisodium phosphate will accomplish the purpose. So, again, the same amount of trisodium phosphate will replace two to thre'e pounds of half-refined potassium bita-rtratc.
- alkaline phosphates should be used in dyeing operations as, for instance, in Bowdens British Patent No. 2,7(3i of 1861- in which it was proposed to use phosphate of soda for fixing colors on cotton goods or fab-.
- Trisodium phosphate has materially different and distinctive properties from disodium or other sodium phosphates. Thus compare the analyses:
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
UniTnn STATES PATENT Orricn.
\VILLIAM JOHN IILLIAMS. OF CAMDEN, NElV JERSEY.
MORDANT.
SPECIFICATION forming part of Letters Patent No. 398,564, dated February 26,1889. Application filed August 13, 1888. Serial No. 282,612. (No specimens) To all whom it may concern..-
Be it known that I, WILLIAM JOHN WIL- LIAMS, a subject of the Queen of Great Britain and Ireland, and a resident of Camden, Camden county, New Jersey, have invented a Mode of Fixing Dye-Colors of which the following is a specification.
My invention relates to the fixing of dyecolors upon fibers or fabrics, whether of cotton, silk, wool, jute, flax, or other material;
v 1 i i and the object of m y invention is to so treat the fibers or fabrics that the colors will be fixed thereon and that no superfi uou coloringmatter will be absorbed by the fibers or fabrics, and in consequence the latter will be free from rust or oxidation of the colors, and the colors will not come off or crock.
I have discovered that dye-colors may be fixed on fibers or fabrics by subjecting them to the action of trisodium phosphate.
In carrying out my invention the trisodium phosphate may be added directly to the dye- 1 bath, or it may be employed in the finishingphate, which has been but rarely used, pracbath, or it may be added to the water or other liquid which is to be used in either of those baths, or the fabrics or fibers may be treated to the action of a solution of the trisodium phosphate before being put in the dye-bath or after they have been dyed and finished. The quantity of trisodium phosphate to be used will vary with the character of the material to be. dyed and with the nature of the dye used, and to some extent with other attendant conditions. A one-per-cent. solution gives the desired eifectthat is, it has the property of fixing the colors on the textile fabrics or fibers so as to give a dense and lasting color-and if the phosphate be used in the dye-bath. it will prevent the absorption of any superfluous coloring-matter in the stock, so that the fibers or fabrics will. be free from rust and the colors be prevented from crocking. Moreover, by the employment of trisodium phosphate the use of sodium sulphate (Glaubers salts) or potassium bitartrate (tartar or argol) both in the dyeing and mordanting operations may be entirely dispensed with. Owing to the strong affinity of the trisodium phosphate for the coloring-matter of the dye-stuffs, the color is more fully precipiis ob tat-ed and a brighter and a fuller color tained from a smaller quantity of dye andthe color is made more fast. The use of this trisodium phosphate results in great economy, for where twenty to twenty-five pounds of Glaubers salts have been heretofore used eight ounces of trisodium phosphate will accomplish the purpose. So, again, the same amount of trisodium phosphate will replace two to thre'e pounds of half-refined potassium bita-rtratc.
I employ trisodium phosphate in place of all other phosphates because in it the phosphoric acid is fully neutralized, so that there is no free acid in the compound, nor is any produced in any of the baths in which it may be used.
I am aware that many years ago the suggestion was made that alkaline phosphates should be used in dyeing operations as, for instance, in Bowdens British Patent No. 2,7(3i of 1861- in which it was proposed to use phosphate of soda for fixing colors on cotton goods or fab-.
rics; but the commercial phosphate of soda previous to this time has been disodium phost-ically on account of drawbacks to its use hereinafter mentioned. On the other hand I have obtained highlysuccessful results with trisodi um phosphate, effecting a saving of fifty per cent. and over in the use of dye-stuff and producing a better and more durable and faster color.
Trisodium phosphate has materially different and distinctive properties from disodium or other sodium phosphates. Thus compare the analyses:
Disodiam phosphate. Trisocli um phosphate Phosphoric acid, 19.84 18.68 Soda, 17.32 24.48 ater, 62. 84 56, Sat
or absorb the dye-stuff freely, producin h brighter and clearer colors with a much smaller quantity of dye.
' I claim as my invention The mode herein described of fixing colors and preventing rust and crocking in textile 1 fibers or fabrics, said mode consistingin sub- 5 jecting the fabrics or fibers to the action of trisodium phosphate.
In testimony whereof I have signed my name to this specification in the presence of two subscribing Witnesses.
W'M. JOHN \VILLIAMS.
\Vitnesses:
JOHN W. PREsTWIcH, i LoUIs B. HUMPHREYS.
Publications (1)
Publication Number | Publication Date |
---|---|
US398564A true US398564A (en) | 1889-02-26 |
Family
ID=2467527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US398564D Expired - Lifetime US398564A (en) | Mordant |
Country Status (1)
Country | Link |
---|---|
US (1) | US398564A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4181498A (en) * | 1975-09-23 | 1980-01-01 | Sandoz Ltd. | Dyeing and printing with synthetic thickeners |
WO1984004087A1 (en) * | 1983-04-15 | 1984-10-25 | Ecolochem Inc | Mobile fluid purification unit |
-
0
- US US398564D patent/US398564A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4181498A (en) * | 1975-09-23 | 1980-01-01 | Sandoz Ltd. | Dyeing and printing with synthetic thickeners |
WO1984004087A1 (en) * | 1983-04-15 | 1984-10-25 | Ecolochem Inc | Mobile fluid purification unit |
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