US20210252579A1 - Manufacturing method for hot stamping component having aluminium-silicon alloy coating, and hot stamping component - Google Patents

Manufacturing method for hot stamping component having aluminium-silicon alloy coating, and hot stamping component Download PDF

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US20210252579A1
US20210252579A1 US17/049,547 US201917049547A US2021252579A1 US 20210252579 A1 US20210252579 A1 US 20210252579A1 US 201917049547 A US201917049547 A US 201917049547A US 2021252579 A1 US2021252579 A1 US 2021252579A1
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heating
temperature
holding
graph
aluminum
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Ning Tan
Jiang Fu
Jiyao HONG
Xuehua FANG
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Baoshan Iron and Steel Co Ltd
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Baoshan Iron and Steel Co Ltd
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Assigned to BAOSHAN IRON & STEEL CO., LTD. reassignment BAOSHAN IRON & STEEL CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FANG, Xuehua, FU, JIANG, HONG, Jiyao, TAN, Ning
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00—Tools as parts of machines covered by this subclass
    • B21D37/16—Heating or cooling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62—Quenching devices
    • C21D1/673—Quenching devices for die quenching
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76—Adjusting the composition of the atmosphere
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D11/00—Process control or regulation for heat treatments
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00—Modifying the physical properties of iron or steel by deformation
    • C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/12—Aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon

Definitions

  • the present invention relates to manufacturing technology of hot stamping components, in particular to a manufacturing method of a hot stamping component having an aluminum-silicon alloy coating and a hot stamping component.
  • Chinese patent CN101583486B discloses a method of coated stamping products, including the temperature and time of stamping, wherein the heating rate from room temperature to 700° C. is 4-12° C./s, which aims at ensuring the spot welding performance of stamping components.
  • Chinese patent CN102300707B further discloses a heating method of coated hot stamping components, specifically discloses the heating rate under melting temperature, the holding time under austenitizing temperature, etc.
  • this heating method still could not solve the problem of adhesion to the roller and nodulation by aluminum-silicon coating, which causes problems such as the decrease in service life of heat treatment furnace roller and peeling of coating of hot stamping components.
  • the purpose of the present invention is to provide a manufacturing method of a hot stamping component having an aluminum-silicon alloy coating and a hot stamping component, which can not only effectively solve the problem of adhesion to the roller by aluminum-silicon coating, reduce the nodulation probability of the heat treatment furnace roller and improve the service life of the roller, but can also ensure the integrity of the coating of the hot stamping component and the mechanical properties, welding performance, coating performance and corrosion resistance of the component.
  • a manufacturing method of a hot stamping component having an aluminum-silicon alloy coating comprising the following steps: machining a steel plate coated with an aluminum-silicon alloy coating into a blank having a shape required for a part; conducting heat treatment and hot stamping of the blank; wherein, in the heat treatment of the blank, the blank is put into a heat treatment furnace for austenitizing heat treatment, and the heat treatment process of the blank comprises a first heating and holding stage, a second heating and holding stage, and a third heating and holding stage;
  • the temperature and time of heating and holding lie within a graph ABCD
  • the graph ABCD represents the ranges of temperature and time defined by coordinates of A (750° C., 30 s), B (750° C., 90 s), C (870° C., 90 s) and D (870° C., 30 s);
  • the temperature and time of heating and holding lie within a graph EFGH
  • the graph EFGH represents the ranges of temperature and time defined by coordinates of E (875° C., 60 s), F (875° C., 240 s), G (930° C., 150 s) and H (930° C., 30 s);
  • the temperature and time of heating and holding lie within a graph IJKL
  • the graph IJKL represents the ranges of temperature and time defined by coordinates of I (935° C., 60 s), J (935° C., 240 s), K (955° C., 180 s) and L (955° C., 30 s);
  • the temperature and time of heating and holding lie within a graph A′B′C′D′
  • the graph A′B′C′D′ represents the ranges of temperature and time defined by coordinates of A′ (750° C., 30 s), B′ (750° C., 90 s), C′ (890° C., 90 s) and D′ (890° C., 30 s);
  • the temperature and time of heating and holding lie within a graph E′F′G′H′
  • the graph E′F′G′H′ represents the ranges of temperature and time defined by coordinates of E′ (895° C., 90 s), F′ (895° C., 270 s), G′ (940° C., 210 s) and H′ (940° C., 60 s);
  • the temperature and time of heating and holding lie within a graph I′J′K′L′
  • the graph I′J′K′L′ represents the ranges of temperature and time defined by coordinates of I′ (945° C., 60 s), J′ (945° C., 240 s), K′ (955° C., 180 s) and L′ (955° C., 30 s).
  • the heating and holding time of the second heating and holding stage is zero so that the heat treatment process of the blank comprises two-stages of heating and temperature-holding, consisting of the first heating and holding stage and the third heating and holding stage; compared with the aforementioned three-stage heating and holding, the two-stage heating and holding has the following characteristics: the heating and holding time in the furnace is shortened and the production efficiency is improved, but as the heating temperature is higher, the energy consumption is increased and the requirement for equipment heating capacity is higher;
  • the temperature and time of heating and holding lie within a graph abcd
  • the graph abcd represents the ranges of temperature and time defined by coordinates of a (750° C., 30 s), b (750° C., 90 s), c (870° C., 90 s) and d (870° C., 30 s);
  • the temperature and time of heating and holding lie within a graph ijkl
  • the graph ijkl represents the ranges of temperature and time defined by coordinates of i (935° C., 180 s), j (935° C., 300 s), k (955° C., 270 s) and l (955° C., 150 s);
  • the temperature and time of heating and holding lie within a graph a′b′c′d′
  • the graph a′b′c′d′ represents the ranges of temperature and time defined by coordinates of a′ (750° C., 30 s), b′ (750° C., 90 s), c′ (890° C., 90 s) and d′ (890° C., 30 s);
  • the temperature and time of heating and holding lie within a graph i′j′kT
  • the graph i′j′k′ 1 ′ represents the ranges of temperature and time defined by coordinates of i′ (945° C., 180 s), j′ (945° C., 300 s), k′ (955° C., 270 s) and l′ (955° C., 150 s).
  • the temperature increases stepwise in the order of the first, second, and third heating and holding stages or the temperatures in the first, second, and third heating and holding stages are set to be certain temperatures.
  • the heat treatment process can be as follows: the temperature and time of the first heating and holding stage are 800° C. and 60 s, respectively; and the temperature and time of the second heating and holding stage are 930° C. and 120 s, respectively; and the temperature and time of the third heating and holding stage are 940° C. and 60 s, respectively.
  • the heat treatment process can also be as follows: multiple temperatures, for example 770° C. for 40 s, 820° C. for 30 s and 770° C. for 50 s are set in the first heating and holding stage; and multiple temperatures, for example 900° C. for 60 s and 930° C. for 60 s are set in the second heating and holding stage; and multiple temperatures, for example 935° C. for 60 s and 940° C. for 60 s are set in the third heating and holding stage.
  • the time of the heat treatment process of the blank is not less than 150 s and not more than 600 s. Within this time range, the blank after heat treatment has high surface quality, good coating performance, and good welding performance.
  • a heat treatment furnace is used in the heat treatment process of the blank.
  • the oxygen content in the furnace's atmosphere is not less than 15% and the dew point in the furnace is not higher than ⁇ 5° C.
  • the final hot stamping component has a low hydrogen content and an excellent resistance to delayed cracking.
  • the heat-treated blank is quickly transferred to a mold for stamping, the transfer time is 4-12 seconds, and the blank is in a temperature of not lower than 600° C. before being fed into the mold; the mold is cooled before stamping to ensure that the surface temperature of the mold before stamping is lower than 100° C., and the cooling rate of the blank is greater than 30° C./s.
  • the microstructure of the hot stamping component obtained through the above process is mainly martensite or bainite, and the hot stamping component has excellent mechanical properties and meets the requirements for use.
  • the steel plate coated with an aluminum-silicon alloy coating comprises a substrate and an aluminum-silicon alloy coating on at least one surface of the substrate, and the substrate comprises the following composition in percentage by weight: C: 0.04-0.8%, Si ⁇ 1.2%, Mn: 0.1-5%, P ⁇ 0.3%, S ⁇ 0.1%, Al ⁇ 0.3%, Ti ⁇ 0.5%, B ⁇ 0.1%, Cr ⁇ 3% and the rest being Fe and inevitable impurities.
  • the aluminum-silicon alloy coating comprises the following composition in percentage by weight: Si: 4-14%, Fe: 0-4%, and the balance being Al and inevitable impurities.
  • the average weight of the aluminum-silicon alloy coating is 58-105 g/m 2 on one side; more preferably, the average weight of the aluminum-silicon alloy coating is 72-88 g/m 2 on one side.
  • the final hot stamping component has a uniform appearance and color (no color difference), good coating performance, and good welding performance.
  • the aluminum-silicon alloy coating of the hot stamping component obtained by the manufacturing method of the present invention comprises a surface alloy layer and a diffusion layer, and the ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.08-0.5.
  • the final hot stamping component has uniform appearance and color, good coating performance and good welding performance.
  • the aluminum-silicon alloy coating comprises two layers, the one that is in contact with the substrate is a diffusion layer.
  • Al in the aluminum-silicon alloy coating and Fe of the substrate further diffuse to form the diffusion layer.
  • Al in the aluminum-silicon alloy coating and Fe of the substrate are alloyed to form a surface alloy layer.
  • the ratio of the thickness of the diffusion layer to the total thickness of the aluminum-silicon alloy coating is 0.08-0.5.
  • the hot stamping component according to the present invention has a yield strength of 400-1300 MPa, a tensile strength of 500-2000 MPa, and an elongation of 4% or more.
  • the elongation of the hot stamping component according to the present invention is 4 to 20%.
  • the hot stamping component For the hot stamping component according to the present invention, no coating peels off, the surface roughness meets the requirements, and the ratio of the thickness of the diffusion layer to the thickness of the coating is between 0.08 and 0.5. After electrophoretic coating, the coating film is complete and the coating film adhesion is evaluated as grade 0 or higher.
  • the thickness of the diffusion layer and the thickness of the coating meet the requirements, the ratio of the thickness of the diffusion layer to the thickness of the coating is between 0.08 and 0.5, and the spot welding performance is excellent with all the spot welding range being 2 KA or above.
  • the coating on the hot stamping component according to the present invention can well meet the diffusion of the coating and the austenitization of the substrate, and the melting and adhesion to the roller of the coating can be avoided, thereby obtaining the hot stamping component with good coating performance and substrate performance.
  • the melting point of Al—Si alloy of the aluminum-silicon alloy coating is between 580 and 600° C.
  • the austenitizing temperature of the steel plate is 840° C. or above
  • the aluminum-silicon alloy coating will melt during the heat treatment process, and adhere to the furnace roller.
  • Al in the coating and Fe of the substrate will diffuse to form an Fe—Al alloy which has a strong heat resistance and a high melting temperature, and will not cause adhesion to the furnace roller.
  • the melting of the aluminum-silicon alloy coating, the adhesion of the coating to the heat treatment furnace roller and the nodulation of the furnace roller are avoided as much as possible.
  • the production cycle time by ensuring the coating to reach an appropriate alloying degree, obtaining a suitable thickness of the coating and of the diffusion layer, and the surface quality of the coating, the welding performance and coating performance of the component are guaranteed.
  • the adhesion of the aluminum-silicon alloy coating to the heat treatment furnace roller is reduced, the occurrence rate of nodulation of the heat treatment furnace roller is reduced, and the maintenance cycle and service life of the roller are extended.
  • the heat treatment process of the blank according to the present invention can improve the surface quality of the stamping component and prevent the coating from peeling off during the heat treatment process.
  • the heat treatment process of the blank according to present invention adopts a stepwise heating mode, fully considers the characteristics of the aluminum-silicon alloy coating, and appropriately adjusts the temperature and time according to the thickness of the blank, so that the energy can be effectively used and a good energy saving effect is achieved.
  • FIG. 1 shows a surface of the hot stamping component with an aluminum-silicon alloy coating prepared in Comparative Example 1.
  • FIG. 2 shows a surface of the hot stamping component with an aluminum-silicon alloy coating prepared in Example 1 of the present invention.
  • FIG. 3 is a cross-sectional view of the hot stamping component with an aluminum-silicon alloy coating prepared in Example 1 of the present invention.
  • FIG. 4 is a schematic diagram of the temperature and time ranges of heating and temperature in the first to the third heating and holding stages of the heat treatment process (three-stage heating and holding) of the blank according to the present invention (in the case of the steel plate thickness ⁇ 1.5 mm).
  • FIG. 5 is a schematic diagram of the temperature and time ranges of heating and holding in the first to the third heating and holding stages of the heat treatment process (three-stage heating and holding) of the blank according to the present invention (in the case of the steel plate thickness ⁇ 1.5 mm).
  • FIG. 6 is a schematic diagram of the temperature and time ranges of heating and holding in the first and the third heating and holding stages of the heat treatment process (two-stage heating and holding) of the blank according to the present invention.
  • Table 1 shows the compositions of the substrates of the steel plates in Examples of the present invention
  • Table 2 shows the manufacturing processes and properties of the hot stamping components in Examples of the present invention.
  • a substrate with a thickness of 1.2 mm was subjected to hot dip aluminum plating at 650° C., the composition of the plating bath is 8% of Si and 2.3% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment, and the specific parameters of the heat treatment are shown in Table 2.
  • the appearance of the obtained hot stamping component is shown in FIG. 2 .
  • the cross-sectional microstructure of the aluminum-silicon alloy coating is shown in FIG. 3 .
  • the aluminum-silicon alloy coating comprises a surface alloy layer and a diffusion layer, and the ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.25.
  • a substrate with a thickness of 0.9 mm was subjected to hot dip aluminum plating at 660° C., the composition of the plating bath is 9% of Si and 2.5% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment, and the specific parameters of the heat treatment are shown in Table 2. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.3.
  • a substrate with a thickness of 1.0 mm was subjected to hot dip aluminum plating at 660° C., the composition of the plating bath is 8.5% of Si and 2.5% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.15.
  • a substrate with a thickness of 1.1 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 9.5% of Si and 2.5% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.28.
  • a substrate with a thickness of 1.2 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 8.8% of Si and 2.4% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.35.
  • a substrate with a thickness of 1.5 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 8.8% of Si and 2.4% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.35.
  • a substrate with a thickness of 1.6 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 8.8% of Si and 2.4% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment.
  • the ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.3.
  • a substrate with a thickness of 1.8 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 8.8% of Si and 2.4% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.35.
  • a substrate with a thickness of 2.0 mm was subjected to hot dip aluminum plating at 680° C., the composition of the plating bath is 8.8% of Si and 2.4% of Fe, with the rest being Al and inevitable impurities.
  • the steel plate coated with the aluminum-silicon alloy coating was continuously blanked into a blank with a certain shape. The blank was subjected to a heat treatment. The ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is 0.4.
  • FIG. 1 shows the surface of the hot stamping component in Comparative Example.
  • the aluminum-silicon coating surface melts, which causes the coating to adhere to the roller.
  • FIG. 2 shows the surface of the hot stamping component in Example 1 of the present invention.
  • the aluminum-silicon alloy coating surface shows no sign of melting, and the alloying is sufficient.
  • FIG. 3 is a cross-sectional view of the coating of the hot stamping component in Example 1 of the present invention.
  • the aluminum-silicon alloy coating comprises two layers, i.e. a surface alloy layer and a diffusion layer.
  • the ratio of the thickness of the diffusion layer to the thickness of the aluminum-silicon alloy coating is about 0.25.
  • the substrate mainly consists of martensite.
  • FIG. 4 shows the ranges of the first, the second and the third heating and holding stages when the thickness of the steel plate coated with an aluminum-silicon alloy coating according to the present invention is less than 1.5 mm.
  • the temperature and time of heating and holding in the first heating and holding stage lie within a graph ABCD
  • the temperature and time of heating and holding in the second heating and holding stage lie within a graph EFGH
  • the temperature and time of heating and holding in the third heating and holding stage lie within a graph IJKL.
  • FIG. 5 shows the ranges of the first, the second and the third heating and holding stages when the thickness of the steel plate coated with an aluminum-silicon alloy coating according to the present invention is 1.5 mm or more.
  • the temperature and time of heating and holding in the first heating and holding stage lie within a graph A′B′C′D′
  • the temperature and time of heating and holding in the second heating and holding stage lie within a graph E′F′G′H′
  • the temperature and time of heating and holding in the third heating and holding stage lie within a graph I′J′K′L′.
  • FIG. 6 is a schematic diagram of the temperature and time ranges of heating and holding in the first and the third heating and holding stages of the heat treatment process (two-stage heating and holding) of the blank according to the present invention, the heating and holding time in the second heating and holding stage is zero, which forms a two-stage heating and holding.
  • the temperature and time of heating and holding in the first heating and holding stage lie within a graph abcd
  • the temperature and time of heating and holding in the third heating and holding stage lie within a graph ijkl.
  • the temperature and time of heating and holding in the first heating and holding section lie within a graph a′b′c′d′
  • the temperature and time of heating and holding in the third heating and holding stage lie within a graph i′j′k′l′.

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CN113814654A (zh) * 2021-08-20 2021-12-21 首钢集团有限公司 一种使用含铝镀层热成形板制备热成形零件的方法
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