US20170217132A1 - Interlayer film for laminated glass, and laminated glass - Google Patents

Interlayer film for laminated glass, and laminated glass Download PDF

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Publication number
US20170217132A1
US20170217132A1 US15/123,670 US201515123670A US2017217132A1 US 20170217132 A1 US20170217132 A1 US 20170217132A1 US 201515123670 A US201515123670 A US 201515123670A US 2017217132 A1 US2017217132 A1 US 2017217132A1
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United States
Prior art keywords
layer
laminated glass
interlayer film
equal
polyvinyl acetal
Prior art date
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Abandoned
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US15/123,670
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English (en)
Inventor
Tatsuya Iwamoto
Shougo Yoshida
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Assigned to SEKISUI CHEMICAL CO., LTD. reassignment SEKISUI CHEMICAL CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: IWAMOTO, TATSUYA, YOSHIDA, SHOUGO
Publication of US20170217132A1 publication Critical patent/US20170217132A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10293—Edge features, e.g. inserts or holes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10605—Type of plasticiser
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
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    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
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    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2605/00—Vehicles
    • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
    • C—CHEMISTRY; METALLURGY
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    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
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    • C08K2201/00—Specific properties of additives
    • C08K2201/012—Additives improving oxygen scavenging properties

Definitions

  • the present invention relates to an interlayer film for laminated glass used for laminated glass. Moreover, the present invention relates to laminated glass prepared with the interlayer film for laminated glass.
  • laminated glass Since laminated glass generates only a small amount of scattering glass fragments even when subjected to external impact and broken, laminated glass is excellent in safety. As such, the laminated glass is widely used for automobiles, railway vehicles, aircraft, ships, buildings and the like.
  • the laminated glass is produced by sandwiching an interlayer film for laminated glass between a pair of glass plates.
  • Patent Document 1 discloses an interlayer film having a low tendency to turn yellow, having high transmittance for UV-A rays and visible light, and having low transmittance for UV-B rays.
  • This interlayer film includes a polyvinyl acetal, a plasticizer and an oxanilide-based compound as a UV absorber.
  • Patent Document 1 a technique for allowing a HAS/HALS/NOR-HALS type non-aromatic light stabilizer to be included in the interlayer film is described.
  • Patent Document 2 discloses an interlayer film which is high in ultraviolet ray blocking characteristics and is capable of maintaining the optical quality over a long period of time.
  • This interlayer film includes a polymer layer.
  • the polymer layer includes a tungsten oxide reagent and at least one kind among a molecule having a benzotriazole group and a polyvalent metal salt.
  • Patent Document 3 discloses an interlayer film with which the sound insulating properties in a high frequency area of laminated glass can be heightened over a wide temperature range.
  • This interlayer film is provided with a first layer which contains a polyvinyl acetal resin and a plasticizer, a second layer which is layered on a first surface of the first layer and contains a polyvinyl acetal resin and a plasticizer, and a third layer which is layered on a second surface opposite to the first surface of the first layer and contains a polyvinyl acetal resin and a plasticizer.
  • the content of the hydroxyl group of the polyvinyl acetal resin contained in the first layer is lower than the content of each hydroxyl group of the polyvinyl acetal resins contained in the second and third layers, and the ratio of the thickness of the first layer to the total thickness of the second layer and the third layer is less than or equal to 0.14.
  • Patent Document 3 a technique capable of obtaining laminated glass in which the generation of foaming and the growth of bubbles can be suppressed is described.
  • Patent Document 1 US 2012/0052310 A1
  • Patent Document 2 US 2009/0035583 A1
  • Patent Document 3 WO 2012/043816 A1
  • a gap is sometimes generated.
  • this gap is easily generated when light, heat and the like are given to the sheet of laminated glass.
  • This gap is a recess portion formed by the omission of the interlayer film at the end part of the sheet of laminated glass.
  • This gap is different from a foamed product generated due to the foaming as described in Patent Document 3.
  • the yellow index (YI) value measured at the end part of the sheet of laminated glass is sometimes increased.
  • An object of the present invention is to provide an interlayer film for laminated glass making a gap difficult to be generated at an end part of the sheet of laminated glass and enabling an increase in the YI value measured at the end part of the sheet of laminated glass to be suppressed.
  • an interlayer film for laminated glass having a one-layer structure or a two or more-layer structure, being provided with only a first layer containing a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus, the first layer having a glass transition temperature of higher than or equal to 32° C.; or being provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and being provided with a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer or not provided with a third layer containing a polyvinyl acetal resin and a plasticizer on a second surface side opposite to the first surface side of the first layer
  • the interlayer film is an interlayer film for laminated glass having a two or more-layer structure, wherein the interlayer film is provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and is provided with a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer or is not provided with a third layer containing a polyvinyl acetal resin and a plasticizer on a second surface side opposite to the first surface side of the first layer, at least one layer among the first layer, the second layer and the third layer contains a hindered amine light stabilizer, at least one layer among the first layer, the second layer and the third layer contains an oxidation inhibitor containing phosphorus and the
  • the interlayer film is an interlayer film for laminated glass having a three or more-layer structure, wherein the interlayer film is provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and is provided with a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, at least one layer among the first layer, the second layer and the third layer contains a hindered amine light stabilizer, at least one layer among the first layer, the second layer and the third layer contains an oxidation inhibitor containing phosphorus and the glass transition temperature of at least one layer among the second layer and the third layer is higher than or equal to 32° C.
  • the interlayer film is an interlayer film for laminated glass having a three or more-layer structure, and the glass transition temperatures of both the second layer and the third layer are higher than or equal to 32° C.
  • the interlayer film is an interlayer film for laminated glass having a two or more-layer structure or a three or more-layer structure, and the glass transition temperature of the first layer is lower than or equal to 30° C.
  • the first layer contains a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus.
  • the interlayer film is an interlayer film for laminated glass having a one-layer structure and is provided with only a first layer containing a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus, and the glass transition temperature of the first layer is higher than or equal to 32° C.
  • the content of the plasticizer contained in the first layer relative to 100 parts by weight of the polyvinyl acetal resin contained in the first layer is greater than the content of the plasticizer contained in the second layer relative to 100 parts by weight of the polyvinyl acetal resin contained in the second layer.
  • the polyvinyl acetal resin contained in the first layer is obtained by acetalizing a polyvinyl alcohol with an average polymerization degree of greater than or equal to 1500.
  • the acetylation degree of the polyvinyl acetal resin contained in the first layer is greater than or equal to 0.1% by mole and less than or equal to 25% by mole, and the content of the hydroxyl group of the polyvinyl acetal resin contained in the first layer is greater than or equal to 20% by mole and less than 30% by mole.
  • the interlayer film allows an oxidation inhibitor including a phenol skeleton to be further included in the interlayer film as a whole.
  • the first layer contains a phenol-based oxidation inhibitor.
  • the molecular weight of the oxidation inhibitor including a phenol skeleton is greater than or equal to 250.
  • the interlayer film for laminated glass is used for obtaining laminated glass of an automobile.
  • laminated glass including a first laminated glass member, a second laminated glass member and an interlayer film for laminated glass described above, wherein the interlayer film for laminated glass is arranged between the first laminated glass member and the second laminated glass member.
  • the interlayer film for laminated glass according to the present invention has a one-layer structure or a two or more-layer structure, wherein the interlayer film is provided with only a first layer containing a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus and the glass transition temperature of the first layer is higher than or equal to 32° C.; or the interlayer film is provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and is provided with a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer or is not provided with a third layer containing a polyvinyl acetal resin and a plasticizer on a second surface side opposite to the first surface side of the
  • the interlayer film for laminated glass according to the present invention allows the polyvinyl acetal resin, the plasticizer, the hindered amine light stabilizer and the oxidation inhibitor containing phosphorus to be included in the interlayer film as a whole, a gap is made difficult to be generated at an end part of the sheet of laminated glass prepared with the interlayer film for laminated glass according to the present invention and an increase in the YI value measured at the end part of the sheet of laminated glass can be suppressed.
  • the interlayer film for laminated glass allowing the glass transition temperature of a first layer to be higher than or equal to 32° C. in the case where the interlayer film is provided with only the first layer, and moreover, allowing the glass transition temperature of at least one layer among a second layer and a third layer to be higher than or equal to 32° C. in the case where the interlayer film is provided with a first layer and the second layer and is provided or not provided with the third layer also make a gap difficult to be generated at an end part of the sheet of laminated glass and enable an increase in the YI value measured at the end part of the sheet of laminated glass to be suppressed.
  • FIG. 1 is a partially cut-away sectional view schematically showing an interlayer film for laminated glass in accordance with one embodiment of the present invention.
  • FIG. 2 is a partially cut-away sectional view schematically showing an interlayer film for laminated glass in accordance with another embodiment of the present invention.
  • FIG. 3 is a partially cut-away sectional view schematically showing an example of laminated glass prepared with the interlayer film for laminated glass shown in FIG. 1 .
  • FIG. 1 shows an interlayer film for laminated glass in accordance with one embodiment of the present invention schematically represented as a partially cut-away sectional view.
  • An interlayer film 1 shown in FIG. 1 is a multi-layered interlayer film having a two or more-layer structure.
  • the interlayer film 1 has a two or more-layered structure.
  • the interlayer film 1 is used for obtaining laminated glass.
  • the interlayer film 1 is an interlayer film for laminated glass.
  • the interlayer film 1 is provided with a first layer 2 , a second layer 3 arranged on a first surface 2 a side of the first layer 2 , and a third layer 4 arranged on a second surface 2 b side opposite to the first surface 2 a of the first layer 2 .
  • the second layer 3 is layered on the first surface 2 a of the first layer 2 .
  • the third layer 4 is layered on the second surface 2 b of the first layer 2 .
  • the first layer 2 is an intermediate layer.
  • the second layer 3 and the third layer 4 are protective layers and are surface layers in the present embodiment.
  • the first layer 2 is arranged between the second layer 3 and the third layer 4 to be sandwiched. Accordingly, the interlayer film 1 has a multilayer structure in which the second layer 3 , the first layer 2 and the third layer 4 are layered in this order.
  • a surface 3 a at a side opposite to the first layer 2 side of the second layer 3 be a surface on which a laminated glass member is layered. It is preferred that a surface 4 a at a side opposite to the first layer 2 side of the third layer 4 be a surface on which a laminated glass member is layered.
  • first layer 2 and the second layer 3 and between the first layer 2 and the third layer 4 may be arranged between the first layer 2 and the second layer 3 and between the first layer 2 and the third layer 4 , respectively. It is preferred that each of the second layer 3 and the third layer 4 be directly layered on the first layer 2 .
  • another layer include a layer containing a thermoplastic resin such as a polyvinyl acetal resin and a layer containing polyethylene terephthalate.
  • the interlayer film 1 allows a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus to be included in the interlayer film 1 as a whole.
  • the interlayer film 1 includes these ingredients and allows these respective ingredients to be included in at least one layer. That is, a polyvinyl acetal resin is contained in at least one layer among the first layer 2 , the second layer 3 and the third layer 4 , a plasticizer is contained therein, a hindered amine light stabilizer is contained therein, and an oxidation inhibitor containing phosphorus is contained therein.
  • the glass transition temperature of at least one layer among the second layer 3 and the third layer 4 is higher than or equal to 32° C.
  • FIG. 2 shows an interlayer film for laminated glass in accordance with another embodiment of the present invention schematically represented as a partially cut-away sectional view.
  • An interlayer film 31 shown in FIG. 2 is a single-layered interlayer film having a one-layer structure.
  • the interlayer film 31 is a first layer.
  • the interlayer film 31 is used for obtaining laminated glass.
  • the interlayer film 31 is an interlayer film for laminated glass.
  • the interlayer film 31 includes a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus.
  • the glass transition temperature of the interlayer film 31 (first layer) is higher than or equal to 32° C.
  • the interlayer films 1 and 31 are provided with the above-described configuration, a gap is made difficult to be generated at an end part of the sheet of laminated glass prepared with the interlayer films 1 and 31 and an increase in the YI value measured at the end part of the sheet of laminated glass can be suppressed.
  • the interlayer film 1 even when a sheet of laminated glass prepared with the interlayer film 1 is irradiated with light for a long period of time and the sheet of laminated glass is allowed to stand at a high temperature for a long period of time, it is possible to make a gap difficult to be generated at an end part of the sheet of laminated glass.
  • the gap is a recess portion formed by the omission of the interlayer film toward the inside thereof at the end part of the sheet of laminated glass.
  • the interlayer film is inwardly retracted, and the recess portion is formed.
  • the interlayer film may be a single-layered interlayer film composed only of the first layer, and may be a multi-layered interlayer film for laminated glass including the first layer.
  • the interlayer film may be an interlayer film provided with at least the first layer and the second layer (this interlayer film is provided or not provided with the third layer).
  • the interlayer film may be provided with the first layer, the second layer and the third layer.
  • the second layer 3 and the third layer 4 each are layered on both faces of the first layer 2 , respectively.
  • the second layer needs only to be arranged on the first surface side of the first layer.
  • the second layer is arranged on the first surface side of the first layer, and the third layer does not need to be arranged on the second surface side of the first layer.
  • the second layer is arranged on the first surface side of the first layer, and it is preferred that the third layer be arranged on the second surface side of the first layer.
  • a gap is further made difficult to be generated at an end part of the sheet of laminated glass and an increase in the YI value measured at the end part of the sheet of laminated glass can be further suppressed.
  • the adhesivity to a laminated glass member and the like can be adjusted. In this connection, in the case where the third layer is absent, the adhesivity of an outer surface of the second layer of the interlayer film to a laminated glass member can be adjusted.
  • the interlayer film is provided with only a first layer containing a polyvinyl acetal resin, a plasticizer, a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus and the glass transition temperature of the first layer is higher than or equal to 32° C.; or (Configuration 2) the interlayer film is provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and is provided with a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer or is not provided with a third layer containing a polyvinyl acetal resin and a plasticizer on a second surface side opposite to the first surface side of the first layer, at least one layer among the first layer, the second layer and the
  • the configuration 2 includes the following configuration 2-1 and the following configuration 2-2, and it is preferred that the configuration 2 be the following configuration 2-1 or the following configuration 2-2.
  • the interlayer film satisfies the requirement for the foregoing configuration 1, the following configuration 2-1 or the following configuration 2-2.
  • (Configuration 2-1) Being provided with a first layer containing a polyvinyl acetal resin and a plasticizer and a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, and not being provided with a third layer containing a polyvinyl acetal resin and a plasticizer on a second surface side opposite to the first surface side of the first layer, allowing at least one layer among the first layer and the second layer to contain a hindered amine light stabilizer, allowing at least one layer among the first layer and the second layer to contain an oxidation inhibitor containing phosphorus and allowing the glass transition temperature of the second layer to be higher than or equal to 32° C.
  • the interlayer film has a two or more-layer structure.
  • (Configuration 2-2) Being provided with a first layer containing a polyvinyl acetal resin and a plasticizer, a second layer being arranged on a first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer and a third layer being arranged on a second surface side opposite to the first surface side of the first layer and containing a polyvinyl acetal resin and a plasticizer, allowing at least one layer among the first layer, the second layer and the third layer to contain a hindered amine light stabilizer, allowing at least one layer among the first layer, the second layer and the third layer to contain an oxidation inhibitor containing phosphorus and allowing the glass transition temperature of at least one layer among the second layer and the third layer to be higher than or equal to 32° C.
  • the interlayer film has a three or more-layer structure.
  • the interlayer film may satisfy the requirement for the configuration 1 and may satisfy the requirement for the configuration 2. It is preferred that the interlayer film satisfy the requirement for the configuration 2.
  • the interlayer film may satisfy the requirement for the configuration 2-1 and may satisfy the requirement for the configuration 2-2. It is preferred that the interlayer film satisfy the requirement for the configuration 2-2.
  • the interlayer film for laminated glass allowing the polyvinyl acetal resin, the plasticizer, the hindered amine light stabilizer and the oxidation inhibitor containing phosphorus to be included in the interlayer film as a whole makes a gap difficult to be generated at an end part of the sheet of laminated glass and enables an increase in the YI value measured at the end part of the sheet of laminated glass to be suppressed. Furthermore, Y) allowing the glass transition temperature of a first layer to be higher than or equal to 32° C.
  • the interlayer film in the case where the interlayer film is provided with only the first layer, and moreover, allowing the glass transition temperature of at least one layer among a second layer and a third layer to be higher than or equal to 32° C. in the case where the interlayer film is provided with a first layer and the second layer and is provided or not provided with the third layer also make a gap difficult to be generated at an end part of the sheet of laminated glass and enable an increase in the YI value measured at the end part of the sheet of laminated glass to be suppressed.
  • the glass transition temperature of the third layer be higher than or equal to 32° C., and accordingly, it is preferred that the glass transition temperatures of both the second layer and the third layer be higher than or equal to 32° C. It is preferred that the interlayer film be provided with the second layer as a surface layer of the interlayer film. It is preferred that the interlayer film be provided with the third layer as a surface layer of the interlayer film.
  • the glass transition temperature of the second layer is preferably higher than or equal to 32° C., more preferably higher than or equal to 33° C. and further preferably higher than or equal to 35° C.
  • the glass transition temperature of the third layer is preferably higher than or equal to 32° C., more preferably higher than or equal to 33° C. and further preferably higher than or equal to 35° C.
  • the upper limit of the glass transition temperature of each of the second layer and the third layer is not particularly limited. From the viewpoint of further heightening the sound insulating properties of the interlayer film, the glass transition temperature of each of the second layer and the third layer may be lower than or equal to 60° C.
  • the first layer contain a polyvinyl acetal resin and it is preferred that the first layer contain a plasticizer.
  • the second layer contain a polyvinyl acetal resin and it is preferred that the second layer contain a plasticizer.
  • the third layer contain a polyvinyl acetal resin and it is preferred that the third layer contain a plasticizer.
  • the third layer by allowing the third layer to contain a polyvinyl acetal resin and a plasticizer, a gap becomes further difficult to be generated at the end part of the sheet of laminated glass, and an increase in the YI value measured at the end part of the sheet of laminated glass can be further suppressed.
  • each of the first layer and the second layer contain a polyvinyl acetal resin and a plasticizer. It is preferred that each of the first layer, the second layer and the third layer contain a polyvinyl acetal resin and a plasticizer.
  • the first layer does not contain a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus
  • the second layer may contain a hindered amine light stabilizer and an oxidation inhibitor containing phosphorus
  • the second layer may contain a hindered amine light stabilizer and the third layer may contain an oxidation inhibitor containing phosphorus
  • the second layer may contain an oxidation inhibitor containing phosphorus
  • the third layer may contain a hindered amine light stabilizer.
  • the details of the first layer including a single-layered interlayer film
  • the second layer and the third layer which constitute the interlayer film for laminated glass according to the present invention, and the details of each ingredient contained in the first layer, the second layer and the third layer will be described.
  • the first layer (including a single-layered interlayer film) contain a polyvinyl acetal resin (hereinafter, sometimes described as a polyvinyl acetal resin (1)). It is preferred that the second layer contain a polyvinyl acetal resin (hereinafter, sometimes described as a polyvinyl acetal resin (2)). It is preferred that the third layer contain a polyvinyl acetal resin (hereinafter, sometimes described as a polyvinyl acetal resin (3)).
  • the polyvinyl acetal resin (1), the polyvinyl acetal resin (2) and the polyvinyl acetal resin (3) may be the same as or different from one another.
  • One kind of each of the polyvinyl acetal resin (1), the polyvinyl acetal resin (2) and the polyvinyl acetal resin (3) may be used alone, and two or more kinds thereof may be used in combination.
  • the polyvinyl acetal resin can be produced by acetalizing polyvinyl alcohol with an aldehyde.
  • the polyvinyl alcohol can be obtained by saponifying polyvinyl acetate.
  • the saponification degree of the polyvinyl alcohol generally lies within the range of 70 to 99.9% by mole.
  • the average polymerization degree of the polyvinyl alcohol is preferably greater than or equal to 200, more preferably greater than or equal to 500, still more preferably greater than or equal to 1500, further preferably greater than or equal to 1600, especially preferably greater than or equal to 2600, most preferably greater than or equal to 2700, preferably less than or equal to 5000, more preferably less than or equal to 4000 and further preferably less than or equal to 3500.
  • the average polymerization degree is greater than or equal to the above lower limit, the penetration resistance of laminated glass is further enhanced.
  • the average polymerization degree is less than or equal to the above upper limit, formation of an interlayer film is facilitated.
  • the average polymerization degree of the polyvinyl alcohol is greater than or equal to 1500, it is possible to prevent the appearance of a sheet of laminated glass from being deteriorated by poor degassing.
  • the average polymerization degree of the polyvinyl alcohol is determined by a method in accordance with JIS K6726 “Testing methods for polyvinyl alcohol”.
  • the number of carbon atoms of the acetal group contained in the polyvinyl acetal resin is not particularly limited.
  • the aldehyde used at the time of producing the polyvinyl acetal resin is not particularly limited. It is preferred that the number of carbon atoms of the acetal group in the polyvinyl acetal resin lie within the range of 3 to 5, and it is preferred that the number of carbon atoms of the acetal group be 3 or 4. When the number of carbon atoms of the acetal group in the polyvinyl acetal resin is greater than or equal to 3, the glass transition temperature of the interlayer film is sufficiently lowered.
  • the aldehyde is not particularly limited. In general, an aldehyde with 1 to 10 carbon atoms is suitably used as the above-mentioned aldehyde.
  • Examples of the aldehyde with 1 to 10 carbon atoms include formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, isobutyraldehyde, n-valeraldehyde, 2-ethylbutyraldehyde, n-hexylaldehyde, n-octylaldehyde, n-nonylaldehyde, n-decylaldehyde, and benzaldehyde.
  • propionaldehyde, n-butyraldehyde, isobutyraldehyde, n-hexylaldehyde or n-valeraldehyde is preferred
  • propionaldehyde, n-butyraldehyde or isobutyraldehyde is more preferred
  • n-butyraldehyde is further preferred.
  • One kind of the aldehyde may be used alone, and two or more kinds thereof may be used in combination.
  • the content of the hydroxyl group (the amount of hydroxyl groups) of the polyvinyl acetal resin (1) is preferably greater than or equal to 17% by mole, more preferably greater than or equal to 20% by mole, further preferably greater than or equal to 22% by mole, preferably less than or equal to 30% by mole, more preferably less than 27% by mole and further preferably less than or equal to 25% by mole.
  • the adhesive force of the interlayer film is further heightened.
  • the content of the hydroxyl group of the polyvinyl acetal resin (1) is greater than or equal to 20% by mole, the resin is high in reaction efficiency and is excellent in productivity, and moreover, when less than 27% by mole, the sound insulating properties of laminated glass are further heightened.
  • the content of the hydroxyl group is less than or equal to the above upper limit, the flexibility of the interlayer film is enhanced and the handling of the interlayer film is facilitated.
  • the content of the hydroxyl group of each of the polyvinyl acetal resin (2) and the polyvinyl acetal resin (3) is preferably greater than or equal to 25% by mole, more preferably greater than or equal to 28% by mole, preferably less than or equal to 35% by mole and more preferably less than or equal to 32% by mole.
  • the adhesive force of the interlayer film is further heightened.
  • the flexibility of the interlayer film is enhanced and the handling of the interlayer film is facilitated.
  • the content of the hydroxyl group of the polyvinyl acetal resin is a mole fraction, represented in percentage, obtained by dividing the amount of ethylene groups to which the hydroxyl group is bonded by the total amount of ethylene groups in the main chain.
  • the amount of ethylene groups to which the hydroxyl group is bonded can be measured in accordance with JIS K6726 “Testing methods for polyvinyl alcohol” to be determined.
  • the acetylation degree (the amount of acetyl groups) of the polyvinyl acetal resin (1) is preferably greater than or equal to 0.01% by mole, more preferably greater than or equal to 0.1% by mole, still more preferably greater than or equal to 7% by mole, further preferably greater than or equal to 9% by mole, preferably less than or equal to 30% by mole, more preferably less than or equal to 25% by mole and further preferably less than or equal to 15% by mole.
  • the acetylation degree is greater than or equal to the above lower limit, the compatibility between the polyvinyl acetal resin and a plasticizer is heightened.
  • the acetylation degree is less than or equal to the above upper limit, with regard to the interlayer film and laminated glass, the moisture resistance thereof is enhanced.
  • the acetylation degree of the polyvinyl acetal resin (1) is greater than or equal to 0.1% by mole and less than or equal to 25% by mole, the laminated glass is excellent in penetration resistance.
  • the acetylation degree of each of the polyvinyl acetal resin (2) and the polyvinyl acetal resin (3) is preferably greater than or equal to 0.01% by mole, more preferably greater than or equal to 0.5% by mole, preferably less than or equal to 10% by mole and more preferably less than or equal to 2% by mole.
  • the acetylation degree is greater than or equal to the above lower limit, the compatibility between the polyvinyl acetal resin and a plasticizer is heightened.
  • the acetylation degree is less than or equal to the above upper limit, with regard to the interlayer film and laminated glass, the moisture resistance thereof is enhanced.
  • the acetylation degree is a mole fraction, represented in percentage, obtained by dividing a value obtained by subtracting the amount of ethylene groups to which the acetal group is bonded and the amount of ethylene groups to which the hydroxyl group is bonded from the total amount of ethylene groups in the main chain by the total amount of ethylene groups in the main chain.
  • the amount of ethylene groups to which the acetal group is bonded can be measured in accordance with JIS K6728 “Testing methods for polyvinyl butyral”.
  • the acetalization degree of the polyvinyl acetal resin (1) is preferably greater than or equal to 47% by mole, more preferably greater than or equal to 60% by mole, preferably less than or equal to 80% by mole and more preferably less than or equal to 70% by mole.
  • the acetalization degree is greater than or equal to the above lower limit, the compatibility between the polyvinyl acetal resin and a plasticizer is heightened.
  • the acetalization degree is less than or equal to the above upper limit, the reaction time required for producing the polyvinyl acetal resin is shortened.
  • the acetalization degree of each of the polyvinyl acetal resin (2) and the polyvinyl acetal resin (3) is preferably greater than or equal to 55% by mole, more preferably greater than or equal to 67% by mole, preferably less than or equal to 75% by mole and more preferably less than or equal to 71% by mole.
  • the acetalization degree is greater than or equal to the above lower limit, the compatibility between the polyvinyl acetal resin and a plasticizer is heightened.
  • the acetalization degree is less than or equal to the above upper limit, the reaction time required for producing the polyvinyl acetal resin is shortened.
  • the acetalization degree is a value expressing the mole fraction determined by dividing the amount of ethylene groups to which the acetal group is bonded by the total amount of ethylene groups in the main chain in terms of percentage.
  • the acetalization degree can be calculated by a method in accordance with JIS K6728 “Testing methods for polyvinyl butyral”.
  • the content of the hydroxyl group (the amount of hydroxyl groups), the acetalization degree (the butyralization degree) and the acetylation degree be calculated from the results measured by a method in accordance with JIS K6728 “Testing methods for polyvinyl butyral”.
  • a method in accordance with ASTM D1396-92 and JIS K6728 may be used.
  • the content of the hydroxyl group (the amount of hydroxyl groups), the acetalization degree (the butyralization degree) and the acetylation degree can be calculated from the results measured by a method in accordance with JIS K6728 “Testing methods for polyvinyl butyral”.
  • the polyvinyl acetal resin (1) be a polyvinyl acetal resin (A) with an acetylation degree (a) less than or equal to 8% by mole and an acetalization degree (a) greater than or equal to 70% by mole or a polyvinyl acetal resin (B) with an acetylation degree (b) greater than 8% by mole.
  • the polyvinyl acetal resin (1) may be the polyvinyl acetal resin (A) and may be the polyvinyl acetal resin (B).
  • the acetylation degree (a) of the polyvinyl acetal resin (A) is less than or equal to 8% by mole, preferably less than or equal to 7.5% by mole, more preferably less than or equal to 7% by mole, further preferably less than or equal to 6.5% by mole, especially preferably less than or equal to 5% by mole, preferably greater than or equal to 0.1% by mole, more preferably greater than or equal to 0.5% by mole, further preferably greater than or equal to 0.8% by mole and especially preferably greater than or equal to 1% by mole.
  • the acetylation degree (a) is less than or equal to the above upper limit and greater than or equal to the above lower limit, the transfer of a plasticizer can be easily controlled and the sound insulating properties of laminated glass are further heightened.
  • the acetalization degree (a) of the polyvinyl acetal resin (A) is greater than or equal to 70% by mole, preferably greater than or equal to 70.5% by mole, more preferably greater than or equal to 71% by mole, further preferably greater than or equal to 71.5% by mole, especially preferably greater than or equal to 72% by mole, preferably less than or equal to 85% by mole, more preferably less than or equal to 83% by mole, further preferably less than or equal to 81% by mole and especially preferably less than or equal to 79% by mole.
  • the acetalization degree (a) is greater than or equal to the above lower limit, the sound insulating properties of laminated glass are further heightened.
  • the reaction time required for producing the polyvinyl acetal resin (A) can be shortened.
  • the content (a) of the hydroxyl group of the polyvinyl acetal resin (A) is preferably greater than or equal to 18% by mole, more preferably greater than or equal to 19% by mole, further preferably greater than or equal to 20% by mole, especially preferably greater than or equal to 21% by mole, preferably less than or equal to 31% by mole, more preferably less than or equal to 30% by mole, further preferably less than or equal to 29% by mole and especially preferably less than or equal to 28% by mole.
  • the adhesive force of the first layer is further heightened.
  • the sound insulating properties of laminated glass are further heightened.
  • the acetylation degree (b) of the polyvinyl acetal resin (B) is greater than 8% by mole, preferably greater than or equal to 9% by mole, more preferably greater than or equal to 9.5% by mole, further preferably greater than or equal to 10% by mole, especially preferably greater than or equal to 10.5% by mole, preferably less than or equal to 30% by mole, more preferably less than or equal to 28% by mole, further preferably less than or equal to 26% by mole and especially preferably less than or equal to 24% by mole.
  • the acetylation degree (b) is greater than or equal to the above lower limit, the sound insulating properties of laminated glass are further heightened.
  • the reaction time required for producing the polyvinyl acetal resin (B) can be shortened.
  • the acetalization degree (b) of the polyvinyl acetal resin (B) is preferably greater than or equal to 50% by mole, more preferably greater than or equal to 53% by mole, further preferably greater than or equal to 55% by mole, especially preferably greater than or equal to 60% by mole, preferably less than or equal to 80% by mole, more preferably less than or equal to 78% by mole, further preferably less than or equal to 76% by mole and especially preferably less than or equal to 74% by mole.
  • the acetalization degree (b) is greater than or equal to the above lower limit, the sound insulating properties of laminated glass are further heightened.
  • the reaction time required for producing the polyvinyl acetal resin (B) can be shortened.
  • the content (b) of the hydroxyl group of the polyvinyl acetal resin (B) is preferably greater than or equal to 18% by mole, more preferably greater than or equal to 19% by mole, further preferably greater than or equal to 20% by mole, especially preferably greater than or equal to 21% by mole, preferably less than or equal to 31% by mole, more preferably less than or equal to 30% by mole, further preferably less than or equal to 29% by mole and especially preferably less than or equal to 28% by mole.
  • the adhesive force of the first layer is further heightened.
  • the sound insulating properties of laminated glass are further heightened.
  • each of the polyvinyl acetal resin (A) and the polyvinyl acetal resin (B) be a polyvinyl butyral resin.
  • the first layer (including a single-layered interlayer film) contain a plasticizer (hereinafter, sometimes described as a plasticizer (1)). It is preferred that the second layer contain a plasticizer (hereinafter, sometimes described as a plasticizer (2)). It is preferred that the third layer contain a plasticizer (hereinafter, sometimes described as a plasticizer (3)).
  • a plasticizer hereinafter, sometimes described as a plasticizer (1).
  • the plasticizer (2) and the plasticizer (3) may be the same as or different from one another. One kind of the plasticizer may be used alone, and two or more kinds thereof may be used in combination.
  • plasticizer examples include organic ester plasticizers such as a monobasic organic acid ester and a polybasic organic acid ester, organic phosphate plasticizers such as an organic phosphate plasticizer and an organic phosphite plasticizer. Of these, organic ester plasticizers are preferred. It is preferred that the plasticizer be a liquid plasticizer.
  • Examples of the monobasic organic acid ester include a glycol ester obtained by the reaction of a glycol with a monobasic organic acid.
  • Examples of the glycol include triethylene glycol, tetraethylene glycol, and tripropylene glycol.
  • Examples of the monobasic organic acid include butyric acid, isobutyric acid, caproic acid, 2-ethylbutyric acid, hepthylic acid, n-octylic acid, 2-ethylhexanoic acid, n-nonylic acid, and decylic acid.
  • polybasic organic acid ester examples include an ester compound of a polybasic organic acid and an alcohol having a linear or branched structure of 4 to 8 carbon atoms.
  • polybasic organic acid examples include adipic acid, sebacic acid, and azelaic acid.
  • organic ester plasticizer examples include triethylene glycol di-2-ethylpropanoate, triethylene glycol di-2-ethylbutyrate, triethylene glycol di-2-ethylhexanoate, triethylene glycol dicaprylate, triethylene glycol di-n-octanoate, triethylene glycol di-n-heptanoate, tetraethylene glycol di-n-heptanoate, dibutyl sebacate, dioctyl azelate, dibutyl carbitol adipate, ethylene glycol di-2-ethylbutyrate, 1,3-propylene glycol di-2-ethylbutyrate, 1,4-butylene glycol di-2-ethylbutyrate, diethylene glycol di-2-ethylbutyrate, diethylene glycol di-2-ethylhexanoate, dipropylene glycol di-2-ethylbutyrate, triethylene glycol di-2-ethy
  • organic phosphate plasticizer examples include tributoxyethyl phosphate, isodecyl phenyl phosphate, and triisopropyl phosphate.
  • the plasticizer be a diester plasticizer represented by the following formula (1).
  • R1 and R2 each represent an organic group with 2 to 10 carbon atoms
  • R3 represents an ethylene group, an isopropylene group or an n-propylene group
  • p represents an integer of 3 to 10. It is preferred that R1 and R2 in the foregoing formula (1) each be an organic group with 5 to 10 carbon atoms, and it is more preferred that R1 and R2 each be an organic group with 6 to 10 carbon atoms.
  • the plasticizer include triethylene glycol di-2-ethylhexanoate (3GO), triethylene glycol di-2-ethylbutyrate (3GH) or triethylene glycol di-2-ethylpropanoate, it is more preferred that the plasticizer include triethylene glycol di-2-ethylhexanoate or triethylene glycol di-2-ethylbutyrate, and it is further preferred that the plasticizer include triethylene glycol di-2-ethylhexanoate.
  • 3GO triethylene glycol di-2-ethylhexanoate
  • 3GH triethylene glycol di-2-ethylbutyrate
  • the plasticizer include triethylene glycol di-2-ethylhexanoate.
  • the content of the plasticizer (1) relative to 100 parts by weight of the polyvinyl acetal resin (1) is preferably greater than or equal to 40 parts by weight, more preferably greater than or equal to 55 parts by weight, preferably less than or equal to 90 parts by weight and more preferably less than or equal to 85 parts by weight.
  • the content (1) is greater than or equal to the above lower limit, the flexibility of the interlayer film is enhanced and the handling of the interlayer film is facilitated.
  • the content (1) is less than or equal to the above upper limit, the transparency of the interlayer film is further enhanced.
  • Each of the content of the plasticizer (2) relative to 100 parts by weight of the polyvinyl acetal resin (2) (hereinafter, sometimes described as the content (2)) and the content of the plasticizer (3) relative to 100 parts by weight of the polyvinyl acetal resin (3) (hereinafter, sometimes described as the content (3)) is preferably greater than or equal to 30 parts by weight, more preferably greater than or equal to 35 parts by weight, preferably less than or equal to 44 parts by weight and more preferably less than or equal to 42 parts by weight.
  • the flexibility of the interlayer film is enhanced and the handling of the interlayer film is facilitated.
  • the penetration resistance of laminated glass is further enhanced.
  • the content (1) be greater than the content (2) and it is preferred that the content (1) be greater than the content (3).
  • each of the absolute value of the difference between the content (1) and the content (2) and the absolute value of the difference between the content (1) and the content (3) is preferably greater than or equal to 10 parts by weight and more preferably greater than or equal to 20 parts by weight.
  • Each of the absolute value of the difference between the content (1) and the content (2) and the absolute value of the difference between the content (1) and the content (3) is preferably less than or equal to 50 parts by weight.
  • the interlayer film includes a hindered amine light stabilizer in the interlayer film as a whole. It is preferred that the first layer contain a hindered amine light stabilizer. It is preferred that the second layer contain a hindered amine light stabilizer. It is preferred that the third layer contain a hindered amine light stabilizer. It is preferred that, among the first layer, the second layer and the third layer, the first layer contain a hindered amine light stabilizer. One kind of the hindered amine light stabilizer may be used alone, and two or more kinds thereof may be used in combination.
  • the hindered amine light stabilizer examples include a hindered amine light stabilizer having an alkyl group, an alkoxy group or a hydrogen atom bonded to the nitrogen atom of a piperidine structure. From the viewpoints of further making a gap difficult to be generated at an end part of the sheet of laminated glass and further suppressing an increase in the YI value measured at the end part of the sheet of laminated glass, a hindered amine light stabilizer having an alkyl group or an alkoxy group bonded to the nitrogen atom of a piperidine structure is preferred.
  • the hindered amine light stabilizer be a hindered amine light stabilizer having an alkyl group bonded to the nitrogen atom of a piperidine structure, and it is also preferred that the hindered amine light stabilizer be a hindered amine light stabilizer having an alkoxy group bonded to the nitrogen atom of a piperidine structure.
  • Examples of the hindered amine light stabilizer having an alkyl group bonded to the nitrogen atom of a piperidine structure include TINUVIN 765, TINUVIN 622SF, and ADK STAB LA-52.
  • Examples of the hindered amine light stabilizer having an alkoxy group bonded to the nitrogen atom of a piperidine structure include TINUVIN XT-850FF, TINUVIN XT-855FF, and ADK STAB LA-81.
  • Examples of the hindered amine light stabilizer having a hydrogen atom bonded to the nitrogen atom of a piperidine structure include TINUVIN 770DF, and Hostavin N24.
  • the molecular weight of the hindered amine light stabilizer is preferably less than or equal to 2000, more preferably less than or equal to 1000 and further preferably less than or equal to 700.
  • the content of the hindered amine light stabilizer is preferably greater than or equal to 0.01% by weight, more preferably greater than or equal to 0.05% by weight, preferably less than or equal to 0.5% by weight and more preferably less than or equal to 0.3% by weight.
  • the content of the hindered amine light stabilizer is preferably greater than or equal to 0.01% by weight, more preferably greater than or equal to 0.05% by weight, preferably less than or equal to 0.5% by weight and more preferably less than or equal to 0.3% by weight.
  • the content of the hindered amine light stabilizer is greater than or equal to the above lower limit and less than or equal to the above upper limit, a gap becomes further difficult to be generated at the end part of the sheet of laminated glass, and an increase in the YI value measured at the end part of the sheet of laminated glass can be further suppressed.
  • the first layer contain an oxidation inhibitor, it is preferred that the first layer contain an oxidation inhibitor containing phosphorus, and it is preferred that the first layer contain an oxidation inhibitor including a phenol skeleton.
  • the second layer contain an oxidation inhibitor, it is preferred that the second layer contain an oxidation inhibitor containing phosphorus, and it is preferred that the second layer contain an oxidation inhibitor including a phenol skeleton.
  • the third layer contain an oxidation inhibitor, it is preferred that the third layer contain an oxidation inhibitor containing phosphorus, and it is preferred that the third layer contain an oxidation inhibitor including a phenol skeleton.
  • the interlayer film includes an oxidation inhibitor containing phosphorus in the interlayer film as a whole.
  • the interlayer film include an oxidation inhibitor including a phenol skeleton in the interlayer film as a whole.
  • One kind of the oxidation inhibitor may be used alone, and two or more kinds thereof may be used in combination.
  • the first layer contain an oxidation inhibitor containing phosphorus, and furthermore, it is preferred that the first layer contain an oxidation inhibitor including a phenol skeleton.
  • oxidation inhibitor examples include an oxidation inhibitor including a phenol skeleton, an oxidation inhibitor containing sulfur, and an oxidation inhibitor containing phosphorus.
  • the oxidation inhibitor be an oxidation inhibitor including a phenol skeleton or an oxidation inhibitor containing phosphorus, and it is more preferred that the oxidation inhibitor be an oxidation inhibitor including a phenol skeleton.
  • Examples of the oxidation inhibitor including a phenol skeleton include 2,6-di-t-butyl-p-cresol (BHT), butylated hydroxyanisole (BHA), 2,6-di-t-butyl-4-ethylphenol, stearyl ⁇ -(3,5-di-t-butyl-4-hydroxyphenyl)propionate, 2,2′-methylenebis-(4-methyl-6-butylphenol), 2,2′-methylenebis-(4-ethyl-6-t-butylphenol), 4,4′-butylidene-bis-(3-methyl-6-t-butylphenol), 1,1,3-tris-(2-methyl-hydroxy-5-t-butylphenyl)butane, tetrakis[methylene-3-(3′,5′-butyl-4-hydroxyphenyl)propionate]methane, 1,3,3-tris-(2-methyl-4-hydroxy-5-t-butylphenol)butane,
  • Examples of the oxidation inhibitor containing phosphorus include tridecyl phosphite, tris(tridecyl) phosphite, triphenyl phosphite, trinonylphenyl phosphite, bis(tridecyl)pentaerithritol diphosphite, bis(decyl)pentaerithritol diphosphite, tris(2,4-di-t-butylphenyl) phosphite, bis(2,4-di-t-butyl-6-methylphenyl)ethyl ester phosphorous acid, tris(2,4-di-t-butylphenyl) phosphite, and 2,2′-methylenebis(4,6-di-t-butyl-1-phenyloxy)(2-ethylhexyloxy)phosphorus.
  • the molecular weight of the oxidation inhibitor is preferably greater than or equal to 200, more preferably greater than or equal to 300, further preferably greater than or equal to 500 and preferably less than or equal to 1500.
  • the content of the oxidation inhibitor is preferably greater than or equal to 0.1% by weight, preferably less than or equal to 2% by weight and more preferably less than or equal to 1.8% by weight.
  • the content of the oxidation inhibitor is preferably greater than or equal to 0.1% by weight, preferably less than or equal to 2% by weight and more preferably less than or equal to 1.8% by weight.
  • the content of the oxidation inhibitor is greater than or equal to the above lower limit and less than or equal to the above upper limit, a gap becomes further difficult to be generated at the end part of the sheet of laminated glass, and an increase in the YI value measured at the end part of the sheet of laminated glass can be further suppressed.
  • the interlayer film include at least one kind of the first metal atom selected from the group consisting of an alkali metal, zinc and aluminum.
  • the interlayer film does not include or includes an alkaline earth metal.
  • the first metal atom and the alkaline earth metal each be contained in the first layer.
  • the first metal atom and the alkaline earth metal each be contained in the second layer.
  • the first metal atom and the alkaline earth metal each be contained in the third layer.
  • the first metal atom and the alkaline earth metal each may be in the state of being a metal salt (hereinafter, sometimes described as a metal salt (M)) to be blended.
  • the metal salt (M) contain at least one kind of metal selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr and Ba. It is preferred that the interlayer film include at least one kind of metal among K and Mg.
  • the metal salt (M) be an alkali metal salt of an organic acid with 2 to 16 carbon atoms or an alkaline earth metal salt of an organic acid with 2 to 16 carbon atoms, and it is further preferred that the metal salt (M) be a magnesium carboxylate with 2 to 16 carbon atoms or a potassium carboxylate with 2 to 16 carbon atoms.
  • magnesium carboxylate with 2 to 16 carbon atoms and the potassium carboxylate with 2 to 16 carbon atoms are not particularly limited, examples thereof include magnesium acetate, potassium acetate, magnesium propionate, potassium propionate, magnesium 2-ethylbutanoate, potassium 2-ethylbutanoate, magnesium 2-ethylhexanoate, and potassium 2-ethylhexanoate.
  • each of the content of the first metal atom in the interlayer film, the content of the alkali metal in the first layer, the content of the first metal atom in the second layer and the content of the second metal atom in the third layer is preferably greater than or equal to 5 ppm, more preferably greater than or equal to 10 ppm, further preferably greater than or equal to 20 ppm, preferably less than or equal to 300 ppm, more preferably less than or equal to 250 ppm and further preferably less than or equal to 200 ppm.
  • the adhesivity between a laminated glass member and the interlayer film or the adhesivity between respective layers in the interlayer film can be further well controlled, and an increase in the YI value measured at the end part of the sheet of laminated glass is further suppressed.
  • each of the content of the alkali metal in the interlayer film, the content of the alkali metal in the first layer, the content of the alkali metal in the second layer and the content of the alkali metal in the third layer is preferably greater than or equal to 5 ppm, more preferably greater than or equal to 10 ppm, further preferably greater than or equal to 20 ppm, preferably less than or equal to 300 ppm, more preferably less than or equal to 250 ppm, further preferably less than or equal to 200 ppm and especially preferably less than or equal to 150 ppm.
  • the adhesivity between a laminated glass member and the interlayer film or the adhesivity between respective layers in the interlayer film can be further well controlled, and an increase in the YI value measured at the end part of the sheet of laminated glass is further suppressed.
  • Each of the first layer, the second layer and the third layer may contain additives such as an ultraviolet ray shielding agent, a flame retardant, an antistatic agent, a pigment, a dye, an adhesive force regulating agent, a moisture-resistance improving agent, a fluorescent brightening agent, and an infrared ray absorber, as necessary.
  • additives such as an ultraviolet ray shielding agent, a flame retardant, an antistatic agent, a pigment, a dye, an adhesive force regulating agent, a moisture-resistance improving agent, a fluorescent brightening agent, and an infrared ray absorber, as necessary.
  • additives such as an ultraviolet ray shielding agent, a flame retardant, an antistatic agent, a pigment, a dye, an adhesive force regulating agent, a moisture-resistance improving agent, a fluorescent brightening agent, and an infrared ray absorber, as necessary.
  • One kind of these additives may be used alone, and two or more kinds thereof may be used
  • the glass transition temperature of the first layer is preferably lower than or equal to 30° C. and more preferably lower than or equal to 20° C.
  • the glass transition temperature of the first layer is preferably higher than or equal to ⁇ 15° C.
  • the thickness of the interlayer film for laminated glass according to the present invention is not particularly limited. From the viewpoint of the practical aspect and the viewpoint of sufficiently heightening the heat shielding properties, the thickness of the interlayer film is preferably greater than or equal to 0.1 mm, more preferably greater than or equal to 0.25 mm, preferably less than or equal to 3 mm and more preferably less than or equal to 1.5 mm. When the thickness of the interlayer film is greater than or equal to the above lower limit, the penetration resistance of laminated glass is enhanced. When the thickness of the interlayer film is lower than or equal to the above upper limit, the transparency of the interlayer film is further enhanced.
  • the thickness of the interlayer film is defined as T.
  • the thickness of the first layer is preferably greater than or equal to 0.0625T, more preferably greater than or equal to 0.1T, preferably less than or equal to 0.375T and more preferably less than or equal to 0.25T.
  • the thickness of each of the second layer and the third layer is preferably greater than or equal to 0.625T, more preferably greater than or equal to 0.75T, preferably less than or equal to 0.9375T and more preferably less than or equal to 0.9T.
  • the thickness of each of the second layer and the third layer is greater than or equal to the above lower limit and less than or equal to the above upper limit, it is possible to suppress the bleed-out of the plasticizer.
  • the total thickness of the second layer and the third layer is preferably greater than or equal to 0.625T, more preferably greater than or equal to 0.75T, preferably less than or equal to 0.9375T and more preferably less than or equal to 0.9T.
  • the total thickness of the second layer and the third layer is greater than or equal to the above lower limit and less than or equal to the above upper limit, it is possible to suppress the bleed-out of the plasticizer.
  • the production method of the interlayer film for laminated glass according to the present invention is not particularly limited.
  • examples of the production method of the interlayer film for laminated glass according to the present invention include a method of allowing a resin composition to be extruded using an extruder.
  • examples of the production method of the interlayer film for laminated glass according to the present invention include a method of separately forming respective resin compositions used for constituting respective layers into respective layers, and then, for example, allowing the respective obtained layers to be layered, a method of allowing respective resin compositions used for constituting respective layers to be coextruded using an extruder and allowing the respective layers to be layered, and the like.
  • a production method of extrusion-molding is preferred because the method is suitable for continuous production.
  • respective polyvinyl acetal resins contained in the second layer and the third layer be the same as each other, it is more preferred that respective polyvinyl acetal resins contained in the second layer and the third layer be the same as each other and respective plasticizers contained therein be the same as each other, and it is further preferred that the second layer and the third layer be formed from the same resin composition as each other.
  • FIG. 3 shows an example of laminated glass prepared with an interlayer film for laminated glass in accordance with one embodiment of the present invention schematically represented as a sectional view.
  • Laminated glass 11 shown in FIG. 3 is provided with a first laminated glass member 21 , a second laminated glass member 22 and an interlayer film 1 .
  • the interlayer film 1 is arranged between the first laminated glass member 21 and the second laminated glass member 22 to be sandwiched.
  • the first laminated glass member 21 is layered on a first surface 1 a of the interlayer film 1 .
  • the second laminated glass member 22 is layered on a second surface 1 b opposite to the first surface 1 a of the interlayer film 1 .
  • the first laminated glass member 21 is layered on an outer surface 3 a of a second layer 3 of the interlayer film 1 .
  • the second laminated glass member 22 is layered on an outer surface 4 a of a third layer 4 of the interlayer film 1 .
  • the laminated glass according to the present invention is provided with a first laminated glass member, a second laminated glass member and an interlayer film arranged between the first laminated glass member and the second laminated glass member, and the interlayer film is the interlayer film for laminated glass according to the present invention.
  • the laminated glass member examples include a glass plate, and a PET (polyethylene terephthalate) film.
  • laminated glass laminated glass in which an interlayer film is sandwiched between a glass plate and a PET film or the like, as well as laminated glass in which an interlayer film is sandwiched between two glass plates, is included.
  • the laminated glass is a laminate provided with a glass plate, and it is preferred that at least one glass plate be used. It is preferred that each of the first laminated glass member and the second laminated glass member be a glass plate or a PET (polyethylene terephthalate) film and the interlayer film include at least one glass plate as the first laminated glass member or the second laminated glass member. It is especially preferred that both of the first laminated glass member and the second laminated glass member be glass plates.
  • the glass plate examples include a sheet of inorganic glass and a sheet of organic glass.
  • the inorganic glass examples include float plate glass, heat ray-absorbing plate glass, heat ray-reflecting plate glass, polished plate glass, figured glass, and wired plate glass.
  • the organic glass is synthetic resin glass substituted for inorganic glass.
  • examples of the organic glass include a polycarbonate plate, and a poly(meth)acrylic resin plate.
  • the poly(meth)acrylic resin plate examples include a polymethyl (meth)acrylate plate.
  • the thickness of the laminated glass member is preferably greater than or equal to 1 mm, preferably less than or equal to 5 mm and more preferably less than or equal to 3 mm. Moreover, in the case where the laminated glass member is a glass plate, the thickness of the glass plate is preferably greater than or equal to 1 mm, preferably less than or equal to 5 mm and more preferably less than or equal to 3 mm. In the case where the laminated glass member is a PET film, the thickness of the PET film is preferably greater than or equal to 0.03 mm and preferably less than or equal to 0.5 mm.
  • the production method of the laminated glass is not particularly limited.
  • an interlayer film is sandwiched between the first laminated glass member and the second laminated glass member, and the air remaining between the first laminated glass member and the interlayer film and between the second laminated glass member and the interlayer film is removed by allowing the members to pass through a pressing roll or by putting the members into a rubber bag and allowing the contents to be sucked under reduced pressure.
  • the members are preliminarily bonded together at about 70 to 110° C. to obtain a laminate.
  • the members are press-bonded together at about 120 to 150° C. and under a pressure of 1 to 1.5 MPa. In this way, laminated glass can be obtained.
  • the interlayer film and the laminated glass can be used for automobiles, railway vehicles, aircraft, ships, buildings and the like.
  • the interlayer film and the laminated glass can also be used for applications other than these applications. It is preferred that the interlayer film and the laminated glass be an interlayer film and laminated glass for vehicles or for building, and it is more preferred that the interlayer film and the laminated glass be an interlayer film and laminated glass for vehicles.
  • the interlayer film and the laminated glass can be used for a windshield, side glass, rear glass or roof glass of an automobile and the like.
  • the interlayer film and the laminated glass are suitably used for automobiles.
  • the interlayer film is used for obtaining laminated glass of an automobile.
  • the butyralization degree (the acetalization degree), the acetylation degree and the content of the hydroxyl group were measured by a method in accordance with JIS K6728 “Testing methods for polyvinyl butyral”.
  • JIS K6728 “Testing methods for polyvinyl butyral”.
  • hindered amine light stabilizers were used in examples and comparative examples.
  • TINUVIN 765 available from BASF Japan Ltd., N—C (alkyl group) type, the molecular weight of 509
  • TINUVIN 622SF available from BASF Japan Ltd., N—C (alkyl group) type, the molecular weight of 1000 or more
  • ADK STAB LA-81 (available from ADEKA CORPORATION, N—OR (alkoxy group) type, the molecular weight of 678)
  • TINUVIN XT-855FF available from BASF Japan Ltd., N—OR (alkoxy group) type
  • TINUVIN 770DF available from BASF Japan Ltd., N—H (hydrogen atom) type, the molecular weight of 481)
  • HOSTAVIN N-24 available from Clariant Japan K.K., N—H (hydrogen atom) type, the molecular weight of 632)
  • IRGANOX 1010 (available from BASF Japan Ltd., an oxidation inhibitor including a phenol skeleton, the molecular weight of 1178)
  • IRGANOX 245 (available from BASF Japan Ltd., an oxidation inhibitor including a phenol skeleton, the molecular weight of 587)
  • ADK STAB AO-40 (available from ADEKA CORPORATION, an oxidation inhibitor including a phenol skeleton, the molecular weight of 383)
  • ADK STAB 3050 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 503)
  • ADK STAB TPP (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 310)
  • ADK STAB C (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 346)
  • ADK STAB 1500 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 1038)
  • ADK STAB 135 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 374)
  • ADK STAB PEP-36 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 633)
  • SUMIRIZER GP available from Sumitomo Chemical Co., Ltd., an oxidation inhibitor containing phosphorus and including a phenol skeleton, the molecular weight of 661)
  • a polyvinyl acetal resin (a polyvinyl butyral (PVB) resin, the average polymerization degree of polyvinyl alcohol (PVA) of 2300, the content of the hydroxyl group of 23.2% by mole, the acetylation degree of 12.5% by mole, the acetalization degree of 64.3% by mole), 60 parts by weight of triethylene glycol di-2-ethylhexanoate (3GO), which is a plasticizer, 0.2 part by weight of TINUVIN 770DF (available from BASF Japan Ltd., N—H (hydrogen atom) type, the molecular weight of 481), 0.2 part by weight of BHT (2,6-di-t-butyl-p-cresol, the molecular weight of 220) and 0.2 part by weight of ADK STAB 3050 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 503) were mixed to obtain Composition X for
  • a polyvinyl acetal resin (a polyvinyl butyral (PVB) resin, the average polymerization degree of the polyvinyl alcohol (PVA) of 1700, the content of the hydroxyl group of 34.5% by mole, the acetylation degree of 0.8% by mole, the acetalization degree of 64.8% by mole), 31.5 parts by weight of triethylene glycol di-2-ethylhexanoate (3GO), which is a plasticizer, and a magnesium-containing compound in an amount that the content thereof in the interlayer film becomes 60 ppm were mixed to obtain Composition Y for forming a second layer and a third layer.
  • an interlayer film (800 ⁇ m in thickness) having a layered structure with a stack of a second layer (350 ⁇ m in thickness)/a first layer (100 ⁇ m in thickness)/a third layer (350 ⁇ m in thickness) was prepared.
  • the interlayer film (multilayer) obtained was cut into a size of 8 cm in longitudinal length ⁇ 8 cm in transversal length.
  • the interlayer film was sandwiched between two sheets of clear glass (8 cm in longitudinal length ⁇ 8 cm in transversal length ⁇ 2.5 mm in thickness), held in place for 30 minutes at 90° C. and pressed under vacuum with a vacuum laminator to obtain a laminate.
  • interlayer film portions protruded from the sheet of glass were cut away to obtain a sheet of laminated glass.
  • An interlayer film and a sheet of laminated glass were prepared in the same manner as that in Example 1 except that the kind of the ingredient contained in the first layer, the second layer and the third layer and the content of the ingredient were set to those listed in the following Tables 1 to 5.
  • a polyvinyl acetal resin (a polyvinyl butyral (PVB) resin, the average polymerization degree of polyvinyl alcohol (PVA) of 1700, the content of the hydroxyl group of 30.7% by mole, the acetylation degree of 0.8% by mole, the acetalization degree of 68.5% by mole), 30 parts by weight of triethylene glycol di-2-ethylhexanoate (3GO), which is a plasticizer, 0.2 part by weight of TINUVIN 770DF (available from BASF Japan Ltd., N—H (hydrogen atom) type, the molecular weight of 481), 0.2 part by weight of BHT (2,6-di-t-butyl-p-cresol, the molecular weight of 220), 0.2 part by weight of ADK STAB 3050 (available from ADEKA CORPORATION, an oxidation inhibitor containing phosphorus, the molecular weight of 503) and magnesium in an amount that the content of
  • PVB poly
  • a sheet of laminated glass was prepared in the same manner as that in Example 1 except that the obtained interlayer film was used.
  • An interlayer film and a sheet of laminated glass were prepared in the same manner as that in Example 31 except that the kind of the ingredient contained in the interlayer film and the content of the ingredient were set to those listed in the following Table 6.
  • Kneaded products having respective compositions of the first layer in examples and comparative examples were prepared.
  • the kneaded product obtained was press-molded with a press molding machine to obtain a resin film A with an average thickness of 0.35 mm.
  • the resin film A obtained was allowed to stand for 2 hours under the condition of 25° C. and a relative humidity of 30%. After allowed to stand for 2 hours, the viscoelasticity thereof was measured by means of the “ARES-G2” available from TA Instruments Japan Inc.
  • a parallel plate with a diameter of 8 mm was used as a jig. The measurement was performed under the condition in which the temperature is decreased from 100° C. to ⁇ 10° C. at a temperature decreasing rate of 3° C./minute and under the condition of a frequency of 1 Hz and a strain of 1%.
  • the peak temperature of the loss tangent was defined as the glass transition temperature Tg (° C.).
  • Kneaded products having respective compositions of the second layer and third layer in examples and comparative examples were prepared.
  • the kneaded product obtained was press-molded with a press molding machine to obtain a resin film A with an average thickness of 0.35 mm.
  • the resin film A obtained was allowed to stand for 2 hours under the condition of 25° C. and a relative humidity of 30%. After allowed to stand for 2 hours, the viscoelasticity thereof was measured by means of the “ARES-G2” available from TA Instruments Japan Inc.
  • a parallel plate with a diameter of 8 mm was used. The measurement was performed under the condition in which the temperature is decreased from 100° C. to ⁇ 10° C. at a temperature decreasing rate of 3° C./minute and under the condition of a frequency of 1 Hz and a strain of 1%.
  • the peak temperature of the loss tangent was defined as the glass transition temperature Tg
  • the glass transition temperature Tg was measured by the following method. After the multi-layered interlayer film obtained was stored for 1 month under the of a temperature of 23° C. and a humidity of 30%, respective layers (the first layer, the second layer and the third layer) were peeled off from one another to be isolated from one another. Each layer as an object to be measured, which was press-molded with a press molding machine and has an average thickness of 0.35 mm, was allowed to stand for 2 hours under the condition of 25° C. and a relative humidity of 30%, and was measured for the viscoelasticity using the “ARES-G2” available from TA Instruments Japan Inc.
  • a parallel plate with a diameter of 8 mm was used as a jig, and the measurement was performed under the condition in which the temperature is decreased from 100° C. to ⁇ 10° C. at a temperature decreasing rate of 3° C./minute and under the condition of a frequency of 1 Hz and a strain of 1%.
  • the peak temperature of the loss tangent was defined as the glass transition temperature Tg (° C.). In any of the foregoing methods, the same glass transition temperature Tg was obtained.
  • a sheet of laminated glass was irradiated with ultraviolet rays (quartz glass mercury lamp (750 W)) for 2000 hours in accordance with JIS R3205 using an ultraviolet-ray irradiation device (“HLG-2S” available from Suga Test Instruments Co., Ltd.). After the test, the end part of the sheet of laminated glass was observed to evaluate the state of a gap generated at the end part of the sheet of laminated glass. The state of the gap was judged according to the following criteria.
  • ⁇ At the end part of the sheet of laminated glass, there is no gap or the gap is generated only within a distance of shorter than or equal to 1 mm from the end part in the inwardly facing direction orthogonal to the end side including the end part.
  • the gap extends by a distance of longer than 1 mm from the end part in the inwardly facing direction orthogonal to the end side including the end part.
  • the sheet of laminated glass obtained was measured for the YI value (the yellowness index, the yellow index) by a transmission method in accordance with JIS K7105 using a spectrophotometer (“U-4100” available from Hitachi High-Technologies Corporation).
  • the end part of the sheet of laminated glass was measured for the initial YI value.
  • the sheet of laminated glass was heated for 4 weeks at 100° C. After the heating, the end part of the sheet of laminated glass was measured for the YI value after heating.
  • the measurement area of the Y value was defined as an area within a distance of 5 mm from the end part in the inwardly facing direction orthogonal to the end side including the end part.
  • the absolute value of the difference between the initial YI value and the YI value after heating was defined as the ⁇ YI to be determined.
  • the ⁇ YI value was judged according to the following criteria.
  • the ⁇ YI value is less than or equal to 20.
  • the ⁇ YI value is greater than 20.
  • the laminated glass was excited by means of a vibration generator for a damping test (“Vibration exciter G21-005D” available from SHINKEN CO., LTD.) to obtain vibration characteristics, the vibration characteristics were amplified by a mechanical impedance measuring apparatus (“XG-81” available from RION Co., Ltd.), and the vibration spectrum was analyzed by an FFT spectrum analyzer (“FFT analyzer HP3582A” available from Yokogawa Electric Corporation).
  • the glass transition temperature of the second layer and third layer is higher than or equal to 32° C.
  • the kind of the polyvinyl acetal resin was changed so that the glass transition temperature of the second layer and third layer becomes lower than 32° C. to obtain respective interlayer films, and the respective interlayer films were used to prepare sheets of laminated glass.
  • the sheets of laminated glass thus prepared as compared to sheets of laminated glass prepared with interlayer films in Examples 1 to 30, there is a tendency that a gap becomes easy to be generated at an end part of the sheet of laminated glass, and there is a tendency for the YI value measured at the end part of the sheet of laminated glass to be increased.
  • the glass transition temperature of the first layer is higher than or equal to 32° C.
  • the kind of the polyvinyl acetal resin was changed so that the glass transition temperature of the second layer and third layer becomes lower than 32° C. to obtain respective interlayer films, and the respective interlayer films were used to prepare sheets of laminated glass.
  • the sheets of laminated glass thus prepared as compared to sheets of laminated glass prepared with interlayer films in Examples 31 to 34, there is a tendency that a gap becomes easy to be generated at an end part of the sheet of laminated glass, and there is a tendency for the YI value measured at the end part of the sheet of laminated glass to be increased.

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  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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US11453205B2 (en) 2016-02-05 2022-09-27 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
US11338555B2 (en) 2017-03-31 2022-05-24 Sekisui Chemical Co., Ltd. Laminated glass
US11225060B2 (en) 2017-04-28 2022-01-18 Sekisui Chemical Co., Ltd. Laminated glass
US11420425B2 (en) 2017-04-28 2022-08-23 Sekisui Chemical Co., Ltd. Laminated glass
US11376819B2 (en) 2017-06-07 2022-07-05 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
US11590736B2 (en) 2017-06-07 2023-02-28 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
US11590735B2 (en) 2017-06-07 2023-02-28 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
US11001039B2 (en) 2017-06-15 2021-05-11 Skc Co., Ltd. Resin film for laminated glass, and laminated glass and preparation thereof
US10562277B2 (en) 2017-06-15 2020-02-18 Skc Co., Ltd. Resin film for laminated glass, and laminated glass and preparation thereof
US11440295B2 (en) 2017-09-27 2022-09-13 Sekisui Chemical Co., Ltd. Laminated glass
US11458705B2 (en) 2017-09-27 2022-10-04 Sekisui Chemical Co., Ltd. Laminated glass
WO2019246218A1 (en) 2018-06-22 2019-12-26 Kuraray America, Inc. Reduction of edge yellowing of polyvinylacetal laminates
WO2021237205A1 (en) 2020-05-22 2021-11-25 Kuraray America, Inc. Interlayer and laminate with controlled debonding zone treatments for enhanced performance
WO2022132417A1 (en) 2020-12-16 2022-06-23 Kuraray Europe Gmbh Laminated structures with adhesive polymeric interlayer comprising cohesive debonding zones for enhanced performance
WO2022132418A2 (en) 2020-12-16 2022-06-23 Kuraray Europe Gmbh Laminated structures with composite adhesive polymeric interlayer comprising cohesive debonding zones for enhanced performance
WO2023096879A1 (en) 2021-11-23 2023-06-01 Kuraray Europe Gbmh Interlayer and laminate with controlled debonding zone treatments

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BR112016021517A2 (pt) 2017-08-15
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US20170072665A1 (en) 2017-03-16
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