US20150175795A1 - Polymer mixtures with optimized toughness/stiffness ratio and optical properties - Google Patents

Polymer mixtures with optimized toughness/stiffness ratio and optical properties Download PDF

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Publication number
US20150175795A1
US20150175795A1 US14/420,218 US201314420218A US2015175795A1 US 20150175795 A1 US20150175795 A1 US 20150175795A1 US 201314420218 A US201314420218 A US 201314420218A US 2015175795 A1 US2015175795 A1 US 2015175795A1
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US
United States
Prior art keywords
weight
graft
styrene
polymer
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US14/420,218
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English (en)
Inventor
Norbert Niessner
Michael Ishaque
Philipp Böckmann
Rolf Minkwitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Styrolution Europe GmbH
Original Assignee
Styrolution Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styrolution Europe GmbH filed Critical Styrolution Europe GmbH
Publication of US20150175795A1 publication Critical patent/US20150175795A1/en
Assigned to STYROLUTION EUROPE GMBH reassignment STYROLUTION EUROPE GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NIESSNER, NORBERT, MINKWITZ, ROLF, ISHAQUE, MICHAEL, BOECKMANN, PHILIPP
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
US14/420,218 2012-08-08 2013-08-06 Polymer mixtures with optimized toughness/stiffness ratio and optical properties Pending US20150175795A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12179673.4 2012-08-08
EP12179673 2012-08-08
PCT/EP2013/066440 WO2014023714A1 (de) 2012-08-08 2013-08-06 Polymermischungen mit optimiertem zähigkeits-/steifigkeits-verhältnis und optischen eigenschaften

Publications (1)

Publication Number Publication Date
US20150175795A1 true US20150175795A1 (en) 2015-06-25

Family

ID=48916087

Family Applications (2)

Application Number Title Priority Date Filing Date
US14/615,811 Active US9644090B2 (en) 2012-08-08 2013-08-06 Polymer mixtures with optimized toughness/stiffness ratio and optical properties
US14/420,218 Pending US20150175795A1 (en) 2012-08-08 2013-08-06 Polymer mixtures with optimized toughness/stiffness ratio and optical properties

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US14/615,811 Active US9644090B2 (en) 2012-08-08 2013-08-06 Polymer mixtures with optimized toughness/stiffness ratio and optical properties

Country Status (6)

Country Link
US (2) US9644090B2 (ko)
EP (1) EP2882806B1 (ko)
KR (1) KR102065805B1 (ko)
CN (1) CN104684991A (ko)
MX (1) MX2015001638A (ko)
WO (1) WO2014023714A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10858510B2 (en) * 2016-08-17 2020-12-08 Ineos Styrolution Group Gmbh Transparent graft copolymers based on acrylate soft phases
EP3395377A1 (en) * 2017-04-28 2018-10-31 Borealis AG Soft polypropylene composition with improved properties
WO2020020834A1 (en) * 2018-07-24 2020-01-30 Ineos Styrolution Group Gmbh Polyacrylate graft rubber copolymer and thermoplastic molding composition
EP4127059A1 (de) 2020-03-24 2023-02-08 INEOS Styrolution Group GmbH Asa-polymerzusammensetzung mit optimierter uv-stabilität sowie gutem zähigkeits-steifigkeits-verhältnis

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1260135B (de) 1965-01-05 1968-02-01 Basf Ag Schlagfeste thermoplastische Formmassen
DE2311129A1 (de) 1973-03-07 1974-09-12 Basf Ag Witterungsbestaendige thermoplastische formmassen
DE2826925A1 (de) 1978-06-20 1980-01-17 Basf Ag Witterungsbestaendige, schlagzaehe thermoplastische massen mit guter einfaerbbarkeit
DE3227555A1 (de) 1982-07-23 1984-01-26 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
DE3149358A1 (de) 1981-12-12 1983-06-16 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
US4876313A (en) 1986-08-29 1989-10-24 Rohm And Haas Company Grafted core-shell polymer compositions using polyfunctional compounds
DE4006643A1 (de) 1990-03-03 1991-09-05 Basf Ag Teilchenfoermiges pfropfpolymerisat mit verbesserter haftung zwischen pfropfgrundlage und pfropfhuelle
DE4131729A1 (de) 1991-09-24 1993-03-25 Basf Ag Pfropfkautschuk-mischung und seine verwendung zur herstellung von formmassen
DE4132497A1 (de) 1991-09-30 1993-04-01 Basf Ag Mehrschaliges pfropfcopolymerisat
EP0669367A1 (de) 1994-02-24 1995-08-30 Ciba-Geigy Ag Phenolische Stabilisatormischungen
EP0698637A3 (en) 1994-08-22 1996-07-10 Ciba Geigy Ag Polyurethanes stabilized with selected UV absorbers of 5-substituted benzotriazole
DE4443966A1 (de) * 1994-12-09 1996-06-13 Basf Ag Thermoplastische Formmassen
KR100260375B1 (ko) * 1997-12-16 2000-07-01 성재갑 내후성 수지 조성물 및 그 제조 방법
US6476128B1 (en) 2001-03-30 2002-11-05 General Electric Company Low-gloss blends containing poly(meth)acrylate rubber-based graft copolymer and process for making thereof
US20060270803A1 (en) 2005-05-26 2006-11-30 Sandeep Dhawan Impact-modified molding composition and method

Also Published As

Publication number Publication date
US20150274953A1 (en) 2015-10-01
KR20150040922A (ko) 2015-04-15
US9644090B2 (en) 2017-05-09
EP2882806A1 (de) 2015-06-17
CN104684991A (zh) 2015-06-03
EP2882806B1 (de) 2017-05-31
WO2014023714A1 (de) 2014-02-13
MX2015001638A (es) 2015-05-12
KR102065805B1 (ko) 2020-01-13

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