US20150044438A1 - Planar composite material - Google Patents

Planar composite material Download PDF

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Publication number
US20150044438A1
US20150044438A1 US14/383,368 US201314383368A US2015044438A1 US 20150044438 A1 US20150044438 A1 US 20150044438A1 US 201314383368 A US201314383368 A US 201314383368A US 2015044438 A1 US2015044438 A1 US 2015044438A1
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United States
Prior art keywords
fibers
layer
fiber
composite material
thermoplastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/383,368
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English (en)
Inventor
Burak Baser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Quadrant Plastic Composites AG
Original Assignee
Quadrant Plastic Composites AG
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Publication date
Application filed by Quadrant Plastic Composites AG filed Critical Quadrant Plastic Composites AG
Assigned to QUADRANT PLASTIC COMPOSITES AG reassignment QUADRANT PLASTIC COMPOSITES AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BASER, BURAK
Publication of US20150044438A1 publication Critical patent/US20150044438A1/en
Abandoned legal-status Critical Current

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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/10Fibres of continuous length
    • B32B2305/20Fibres of continuous length in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/706Anisotropic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/738Thermoformability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/10Trains
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/18Aircraft
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree

Definitions

  • the invention relates to a planar composite material having at least one layer A made of unidirectional reinforcing fiber rovings and at least one layer B made of a thermoplastic fiber nonwoven or a thermoplastic oriented fiber layer which can optionally contain reinforcing fibers, wherein the layers A and B are needled to each other.
  • Thermoplastics are increasingly being used for producing components, particularly components for automobiles, due to their low weight. To provide them with a sufficient rigidity and strength they are usually compounded with reinforcing fibers.
  • planar semifinished products are produced from glass mat reinforced thermoplastics (GMT semifinished products) by merging endless glass fiber mats and thermoplastic molten sheets and consolidating on a double band press.
  • GMT semifinished products glass mat reinforced thermoplastics
  • this procedure requires a high energy expense because the relatively viscous melt has to be pressed into the mat at pressures far above 1 bar.
  • the fiber reinforcement is nondirectional, while in the automotive field reinforcement in one or several preferred directions is particularly desired.
  • thermoplastically moldable composite material comprising a fiber nonwoven layer made of thermoplastic fibers and optionally reinforcing fibers and a woven or oriented layer made of reinforcing fibers which are preferably needled to each other.
  • Oriented fiber layers are prefabricated fiber structures in which several layers of unidirectional fiber rovings are tightly and firmly knitted to each other by means of stitching threads.
  • EP-A 323 571 relates to a fiber reinforced, thermoplastically moldable semifinished product which contains a planar fiber structure that is fixed by needling, consisting of:
  • the textile planar part of EP-A 323 571 preferably contains glass fibers, but other fibers such as carbon fibers and fibers made of aromatic polyamides or other thermoplastics are also mentioned. However, it is not specified whether these thermoplastic fibers may be present in layer A or in layer B or in both layers.
  • the textile planar part is subjected in a second, separate process step to impregnating with a thermoplastic melt and pressing to a solid semifinished product so that in the subsequent third step the semifinished products can be processed to thermoplastic components.
  • EP-A 323 571 mandatorily requires that the areal weight of the layer(s) A shall not be greater than 300 g/m 2 .
  • GB 2 237 583 describes a process for producing a prepreg wherein thermoplastic binding fibers are continuously scattered onto unidirectional reinforcing fibers and consolidated with the same and thereby pressed to a profile part or a planar semifinished product. There is no mention of needling.
  • the subject of the invention is a planar composite material comprising
  • the composite materials of the present invention preferably comprise the layer sequence A-B, but in principle also other layer sequences, for example A-B-A or A-B-A-B, are possible.
  • the fiber mat with randomly oriented fibers B consists of a thermoplastic fiber nonwoven, e.g. a needle nonwoven or a non-needled carding or airlay nonwovens having areal weights of 100 to 2000 g/m 2 , preferably 200 to 1,200 g/m 2 , and particularly 300 to 1,000 g/m 2 .
  • the thermoplastic fiber nonwoven consists preferably of 100% thermoplastic fibers, but it can also contain up to 70 wt.-%, particularly 30 to 70 wt.-% reinforcing fibers. Both the thermoplastic fibers and the reinforcing fibers preferably have a length of 20 to 100 mm.
  • thermoplastic fibers of the randomly oriented fiber layer B any spinnable thermoplastic can be used, but the thermoplastics preferably comprise polypropylene having a MFI (230° C., 2.16 kp) of 25 to 150 g/10 min, particularly unmodified, i.e. polypropylene without carboxyl groups, and also polyamides such as polyamide-6 and polyamide-6,6, but furthermore also linear polyesters, polysulfones, polyketones and polyetherimides.
  • the thermoplastic fibers are intended as “binding fibers”, i.e. they should be thermoplastically moldable into a matrix in the course of subsequent processing of the composite material of the present invention.
  • Preferred reinforcing fibers are glass fibers and carbon fibers, but furthermore also natural fibers and basalt fibers as well as fibers of higher melting thermoplastics such as aramide are suitable.
  • high melting is to be understood in relation to the thermoplastic fibers that are provided as binding fibers, i.e. for the formation of a polymer matrix.
  • the melting or softening point of the reinforcing fibers in the randomly oriented fiber layer B shall be significantly higher, for example at least 50° C. higher, than that of the thermoplastic fibers.
  • the composite material can contain a relatively thin fiber layer C made of nondirectional reinforcing fibers having an areal weight of 50 to 500 g/m 2 , preferably of 100 to 300 g/m 2 on the side of layer B which is facing away from layer A, thus resulting in a layer sequence A-B-C.
  • This layer C provides an additional reinforcement of the composite material, which becomes important when a fiber nonwoven having a relatively low areal weight is used. Glass fibers or carbon fibers are particularly useful as nondirectional fibers.
  • the fiber mat with randomly oriented fibers B consists of a thermoplastic oriented fiber layer with endless thermoplastic fibers which optionally can also contain endless reinforcing fibers.
  • Preferred thermoplastic fibers are polypropylene fibers with a titer of 600 to 2,400 dtex, which can be finished with generally known stabilizers and adhesion promoters.
  • the composite material prefferably comprises exclusively layers A and B, and optionally C, but no further layers of other type.
  • the composite material of the present invention preferably contains 30 to 80 wt.-%, particularly 50 to 70 wt.-% UD fibers. Its areal weight is preferably more than 400 to 4,000 g/m 2 , particularly 1,000 to 1,000 g/m 2 . In the non-consolidated state the thickness is preferably 5 to 15 mm.
  • the reinforcing fiber rovings are, for example, glass, carbon, aramide or basalt fibers with a titer of preferably 100 to 4,800 tex, particularly 200 to 3,000 tex. Particularly preferred are carbon fibers.
  • Composite materials on this basis have a particularly high rigidity in the longitudinal direction and a very good flexibility.
  • the areal weight of the layer A is more than 300 to 2,000 g/m 2 , preferably 350 to 2,000 g/m 2 .
  • Components that are produced from composite materials with relatively heavy UD fibers exhibit better strengths than those produced with light UD fibers as described, for example, in EP-A 323 571.
  • such heavier composite materials particularly if they have only two layers A-B, can be better handled than lighter ones.
  • Particularly preferred composite materials contain carbon fibers as the UD fibers, and the fiber nonwoven layer contains a polyamide, particularly polyamide-6, as the thermoplastic, and also 30 to 70 wt.-% carbon fibers.
  • a polyamide particularly polyamide-6
  • Such composite materials have a good temperature resistance.
  • FIG. 1 An implementation of the method for producing composite materials according to the first embodiment is shown in FIG. 1 as a perspective view.
  • a fiber nonwoven layer is produced according to the carding or airlay method and needled to form a needle nonwoven 2 .
  • the UD fibers 6 are initially laid out next to each other on a circulating endless band ( 4 ), preferably as closely to each other as possible, thereby forming a layer A.
  • the prefabricated needle nonwoven 2 is then continuously laid out to form a layer B, and the two layers A, B are then needled to each other in a needling device 8 .
  • the composite material shall contain further layers A or B, respectively, the corresponding webs can be additionally fed and needled.
  • the composite material shall additionally contain a thin layer C
  • the randomly oriented fibers 10 of the layer C are arranged as endless mats onto the fiber nonwoven of the upper layer B or scattered thereon as chopped fibers. All the three layers are then needled to each other. This is schematically shown in FIG. 1 .
  • FIG. 2 shows in a perspective view a further implementation of the method for producing composite materials according to the second embodiment.
  • the UD fibers 6 of layer A are initially laid out on a circulating endless band 4 , then the thermoplastic fibers 12 and optionally also reinforcing fibers from traversing feeders 14 are laid out thereon by formation of an oriented fiber layer 16 corresponding to layer B, and the layers A, B are subsequently needled to each other in a needling device 8 . This is schematically shown in FIG. 2 .
  • the composite materials of the present invention can be cut into thin plates. These pre-cut parts can then be directly processed into three-dimensional components by pressing them in a mold at temperatures above the softening point of the thermoplastic of the randomly oriented fiber layer B.
  • a semifinished product can be produced by continuously consolidating the planar composite material web e.g. on a double band press at temperatures above the softening point of the thermoplastic of the randomly oriented fiber layer B and at pressures of 0.5 to 5 bar. Pressing on laminating devices is also possible.
  • the consolidated semifinished product preferably has a thickness of 0.3 to 5.0 mm, particularly 1.0 to 3.0 mm.
  • pre-cut parts made of the composite materials for specific reinforcement of fiber composite molded parts by inserting these into a mold together with e.g. GMT or NMT semifinished products (i.e. semifinished products on the basis of glass mat reinforced or natural fiber mat reinforced thermoplastics) and needling together with the same.
  • GMT Greenwich Mean Time
  • NMT semifinished products i.e. semifinished products on the basis of glass mat reinforced or natural fiber mat reinforced thermoplastics
  • the finished parts which are produced from the composite materials of the present invention are very lightweight and highly rigid. They can be used as automobile parts, for sporting goods, for railway wagon construction and for aircraft construction.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
US14/383,368 2012-03-09 2013-03-11 Planar composite material Abandoned US20150044438A1 (en)

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EP12158958.4A EP2636783A1 (de) 2012-03-09 2012-03-09 Flächiger Verbundwerkstoff
EP12158958.4 2012-03-09
PCT/EP2013/054844 WO2013132095A1 (de) 2012-03-09 2013-03-11 Flächiger verbundwerkstoff

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RU2670896C1 (ru) * 2018-01-26 2018-10-25 Общество с ограниченной ответственностью Научно-производственное предприятие "Прикладные перспективные технологии АпАТэК" (ООО НПП "АпАТэК") Способ получения армированного термопластичного композиционного материала и армированный термопластичный композиционный материал
US10167583B2 (en) * 2014-09-12 2019-01-01 Airbus Operations Gmbh Honeycomb structure made of a non-woven made of recycled carbon fibers
US10265885B2 (en) 2014-01-09 2019-04-23 Php Fibers Gmbh Fiber composite and method for its manufacture
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US20130209724A1 (en) * 2010-11-03 2013-08-15 Sgl Carbon Se Pile layer with carbon-fiber encompassing bundles
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US10265885B2 (en) 2014-01-09 2019-04-23 Php Fibers Gmbh Fiber composite and method for its manufacture
US10167583B2 (en) * 2014-09-12 2019-01-01 Airbus Operations Gmbh Honeycomb structure made of a non-woven made of recycled carbon fibers
US11584835B2 (en) 2016-09-14 2023-02-21 Mitsubishi Chemical Corporation Laminated substrate and method for manufacturing the same
US11633939B2 (en) * 2017-04-03 2023-04-25 Quadrant Plastic Composites, AG Method for producing a planar composite component and composite component produced thereby
KR20200088448A (ko) * 2017-11-24 2020-07-22 자에르텍스 게엠베하 운트 코. 카게 일방향으로 놓여진 부직포 및 이의 용도
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RU2670896C1 (ru) * 2018-01-26 2018-10-25 Общество с ограниченной ответственностью Научно-производственное предприятие "Прикладные перспективные технологии АпАТэК" (ООО НПП "АпАТэК") Способ получения армированного термопластичного композиционного материала и армированный термопластичный композиционный материал

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JP7201579B2 (ja) 2023-01-10
US10974481B2 (en) 2021-04-13
CN104160081B (zh) 2018-04-10
JP2020056149A (ja) 2020-04-09
JP2018080442A (ja) 2018-05-24
EP2636783A1 (de) 2013-09-11
US20180272654A1 (en) 2018-09-27
WO2013132095A1 (de) 2013-09-12
JP2015515553A (ja) 2015-05-28
EP2791409B1 (de) 2015-12-09
EP2791409A1 (de) 2014-10-22

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