US20130270212A1 - Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance - Google Patents

Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance Download PDF

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Publication number
US20130270212A1
US20130270212A1 US13/804,672 US201313804672A US2013270212A1 US 20130270212 A1 US20130270212 A1 US 20130270212A1 US 201313804672 A US201313804672 A US 201313804672A US 2013270212 A1 US2013270212 A1 US 2013270212A1
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US
United States
Prior art keywords
plastic bottle
pef
polymer materials
plastic
bio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/804,672
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English (en)
Inventor
Dimitris Ioannis Collias
Patti Jean Kellett
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US13/804,672 priority Critical patent/US20130270212A1/en
Assigned to THE PROCTER & GAMBLE COMPANY reassignment THE PROCTER & GAMBLE COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COLLIAS, DIMITRIS IOANNIS, KELLETT, PATTI JEAN
Priority to MX2014012417A priority patent/MX361965B/es
Priority to EP13718723.3A priority patent/EP2838933B1/fr
Priority to JP2015507067A priority patent/JP6170135B2/ja
Priority to CN201380020381.3A priority patent/CN104271633A/zh
Priority to PCT/US2013/036298 priority patent/WO2013158477A1/fr
Priority to BR112014025607-1A priority patent/BR112014025607B1/pt
Publication of US20130270212A1 publication Critical patent/US20130270212A1/en
Priority to US14/987,838 priority patent/US20160113376A1/en
Priority to US16/025,072 priority patent/US20180317626A1/en
Abandoned legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/002—Methods
    • B29B7/007—Methods for continuous mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/80—Component parts, details or accessories; Auxiliary operations
    • B29B7/88—Adding charges, i.e. additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B32B1/02—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/40—Details of walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/12—Means for the attachment of smaller articles
    • B65D23/14—Means for the attachment of smaller articles of tags, labels, cards, coupons, decorations or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/02—Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/0055—Containers or packages provided with a flexible bag or a deformable membrane or diaphragm for expelling the contents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/38—Details of the container body
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/40—Closure caps
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/02—Scent flasks, e.g. with evaporator
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397—Single layer [continuous layer]

Definitions

  • the present invention relates to plastic bottles containing perfume compositions.
  • the plastic bottles comprise poly(ethylene 2,5-furandicarboxylate) (PEF) and have improved crazing resistance, which reduces the likelihood of cracking of the bottles and increases their lifetime.
  • PEF poly(ethylene 2,5-furandicarboxylate)
  • Plastic bottles containing perfume compositions have been proposed as an alternative to glass bottles. Plastic bottles would give manufacturers increased freedom in developing unique shapes and lowering manufacturing costs.
  • PET Poly(ethylene terephthalate)
  • limonene and other perfume raw materials can diffuse into PET and lower its crazing initiation stress.
  • these perfumes can cause crazing of PET in areas where the tensile stresses, due to the presence of the perfumes, exceed the crazing initiation stress.
  • crazing is more predominant in amorphous areas rather than crystalline and stretched areas, where the PET molecules are more aligned and diffusivity of the perfumes is lower. This crazing of PET can progress into cracking (particularly at higher strains) and cause integrity problems in perfume bottles, and thus reduce their lifetime.
  • a plastic bottle for containing a perfume composition comprises PEF.
  • the plastic bottle further comprises a delivery device and a valve.
  • the plastic bottle further comprises a label, and the label comprises PEF.
  • the plastic bottle further comprises a cap, and the cap comprises PEF.
  • the plastic bottle comprises from about 10 wt % to 100 wt % bio-based content.
  • the plastic bottle comprises a blend of PEF and one or more other polymer materials, wherein the other polymer materials are selected from the group consisting of PET; polyester; polyamide (PA); polycarbonate (PC); polyoxymethylene (POM); polyacrylonitrile (PAN); polyolefin; polyethylene (PE); polypropylene (PP); fluoropolymer; poly(butylene succinate) (PBS); virgin, recycled, and regrind versions of the other polymer materials; bio-based and petroleum-based versions of the other polymer materials; and mixtures thereof.
  • the plastic bottle comprises multiple layers of other polymer materials.
  • the plastic bottle comprises multiple layers of other polymer materials,
  • plastic refers to any synthetic or organic material that can be molded or shaped, generally when heated, and then hardened into a desired form including, but not limited to, polymer, resin, and cellulose derivative.
  • other polymer materials refers to polymer materials other than PEF.
  • other polymer materials are PET; polyester; polyamide (PA); polycarbonate (PC); polyoxymethylene (POM); polyacrylonitrile (PAN); polyolefin; polyethylene (PE); polypropylene (PP); fluoropolymer; poly(butylene succinate) (PBS); virgin, recycled and regrind versions of the other polymer materials; bio-based and petroleum-based versions of the other polymer materials; and mixtures thereof.
  • bio-based material refers to a renewable material.
  • renewable material refers to a material that is produced from a renewable resource.
  • renewable resource refers to a resource that is produced via a natural process at a rate comparable to its rate of consumption (e.g., within a 100 year time frame).
  • the resource can be replenished naturally, or via agricultural techniques.
  • Non limiting examples of renewable resources include plants (e.g., sugar cane, beets, corn, potatoes, citrus fruit, woody plants, lignocellulose, hemicellulose, cellulosic waste), animals, fish, bacteria, fungi, and forestry products. These resources can be naturally occurring, hybrids, or genetically engineered organisms. Natural resources, such as crude oil, coal, natural gas, and peat, which take longer than 100 years to form, are not considered renewable resources. Because at least part of the material of the invention is derived from a renewable resource, which can sequester carbon dioxide, use of the material can reduce global warming potential and fossil fuel consumption.
  • bio-based content refers to the amount of carbon from a renewable resource in a material as a percent of the weight (mass) of the total organic carbon in the material, as determined by ASTM D6866-10 Method B.
  • fossil-based material refers to a material that is produced from fossil material, such as petroleum, natural gas, coal, etc.
  • plastic bottles made with PEF have better crazing and cracking resistance to perfumes than PET or other polymer materials.
  • the better crazing and cracking properties of PEF vs. PET with respect to perfumes may be due to the higher polarity of the oxygen-containing aromatic furan ring compared to the analogous all-hydrocarbon aromatic ring of terephthalic acid, and to the higher crystallinity of PEF than PET. These differences between PEF and PET may alter the interactions between PEF and perfumes so as to reduce or even eliminate the crazing in a PEF bottle.
  • PEF is produced by a condensation reaction of furan-1,4-dicarboxylic acid (FDCA) and ethylene glycol (EG; also called monoethylene glycol or MEG), analogous to the condensation reaction between EG and terephthalic acid used to make PET.
  • FDCA can be prepared from sugar by the acid dehydration to form hydroxymethylfurfural (HMF) or its derivatives. These derivatives can then be oxidized to FDCA.
  • Ethylene glycol can be derived conventionally from petroleum resources leading to a partially-renewable PEF (75% of carbons renewably sourced) or ethylene glycol can also be sourced from sugar from plants to give a fully renewable PEF (100% of carbons renewably sourced).
  • Sugar-sourced EG can be made by fermenting the sugar to give ethanol, dehydrating the ethanol to give bio-ethylene, oxidizing the bio-ethylene to give bio-ethylene oxide, and hydrolyzing the bio-ethylene oxide to give bio-EG.
  • Non-limiting examples of other polymer materials useful in the present invention are PET; polyester; polyamide (PA); polycarbonate (PC); polyoxymethylene (POM); polyacrylonitrile (PAN); polyolefin; polyethylene (PE); polypropylene (PP); fluoropolymer; poly(butylene succinate) (PBS); virgin, recycled, and regrind versions of the other polymer materials; bio-based and petroleum-based versions of the other polymer materials; and mixtures thereof.
  • the bio-based versions of the other polymer materials can be either partially or fully bio-based polymers.
  • the recycled or regrind versions of the other polymer materials are either collected from a consumer recycling plant, typically called PCR, or an industrial recycling source, typically called PIR.
  • the plastic bottle comprises a monolayer PEF.
  • Monolayer PEF is more resistant than PET to perfumes, such as limonene, and other perfume raw materials (prms).
  • monolayer PEF is able to meet the perfume loss specification across the necessary shelf lifetime for the plastic bottle, whereas PET alone cannot.
  • the plastic bottle comprises multiple layers of other polymer materials. The multiple layers will produce further improvements to crazing resistance and increase the bottle lifetime.
  • the plastic bottle comprises multiple layers of other polymer materials, wherein one or more layers comprise PEF.
  • the plastic bottle comprises multiple layers of other polymer materials, wherein the inside layer comprises PEF. This ensures higher crazing resistance in the areas under tensile stress.
  • the plastic bottle comprises multiple layers of other polymer materials, wherein one or more layers comprise PEF, and wherein the other layers comprise the other polymer materials.
  • the plastic bottle comprises multiple layers of polymer materials, wherein at least one of the polymer materials is a barrier material.
  • Typical barrier materials retard the transmission of chemicals through them, such as, by way of example and not limitation, water vapor or oxygen.
  • barrier materials are poly(ethylene 2,6-naphthalate) (PEN); PA; liquid crystalline polymers (LCP); ethylene vinyl alcohol (EVOH); or mixtures thereof.
  • the barrier material is a polymer material coated with a barrier coating.
  • barrier coatings are SiO 2 ; SiO x ; Al 2 O 3 ; AlO x ; glass-like coating; diamond-like coating; metallic coating; carbon coating; or mixtures thereof.
  • the plastic bottle is coated with a barrier coating either externally or internally or both.
  • the plastic bottle comprises a blend of PEF and one or more of the other polymer materials. In another embodiment, the plastic bottle comprises a blend of PEF and one or more barrier materials. In yet another embodiment, the plastic bottle comprises up to about 25 wt % recycled PET. In yet another embodiment, the plastic bottle comprises a blend of PEF and recycled PET with recycled PET being up to about 25 wt % of the plastic bottle weight. In even yet another embodiment, the plastic bottle comprises recycled PET is contained in a separate layer within the plastic bottle. In one embodiment, the plastic bottle of the present invention comprises recycled PEF. In another embodiment, the plastic bottle of the present invention comprises regrind PEF.
  • PEF may be enhanced by blending various compounds that can scavenge various molecules, such as oxygen, moisture, etc.
  • a non-limiting example of such a compound is farnesene, which can be used to scavenge oxygen.
  • the plastic bottle comprises PEF blended with farnesene.
  • the plastic bottle is substantially clear.
  • the plastic bottle comprises one or more pigments or dyes.
  • the pigments are incorporated into the bottle via a colorant masterbatch.
  • a “colorant masterbatch” refers to a mixture in which pigments are dispersed at high concentration in a carrier material. The colorant masterbatch is used to impart color to the final product.
  • the carrier material is a bio-based plastic or a petroleum-based plastic, while in alternative embodiments, the carrier is a bio-based oil or a petroleum-based oil.
  • the carrier may also be a bio-based wax or a petroleum-based wax.
  • the colorant masterbatch can be derived wholly or partly from a petroleum resource, wholly or partly from a renewable resource, or wholly or partly from a recycled resource.
  • the carrier material are bio-based or petroleum-based polyethylene (e.g., linear low-density polyethylene (LLDPE), low-density polyethylene (LDPE), high-density polyethylene (HDPE)), bio-based oil (e.g., olive oil, rapeseed oil, peanut oil, soybean oil, or hydrogenated plant-derived oils), bio-based wax (e.g.), petroleum-based oil, petroleum-based wax (e.g.), recycled oil, bio-based or petroleum-based PET, bio-based or petroleum-based polypropylene, or a mixture thereof.
  • bio-based or petroleum-based polyethylene e.g., linear low-density polyethylene (LLDPE), low-density polyethylene (LDPE), high-density polyethylene (HDPE)
  • bio-based oil e.g., olive oil,
  • the pigment within the carrier material can include, by way of example and not limitation, an inorganic pigment, an organic pigment or dye, a polymeric resin, or a mixture thereof.
  • pigments are titanium dioxide (e.g., rutile or anatase), copper phthalocyanine, antimony oxide, zinc oxide, calcium carbonate, fumed silica, phthalocyamine (e.g., phthalocyamine blue), ultramarine blue, cobalt blue, monoazo pigments, diazo pigments, acid dye, base dye, quinacridone, and a mixture thereof.
  • the colorant masterbatch can further include one or more additives, which can either be derived from a renewable resource or a non-renewable resource.
  • additives are slip agents, UV absorbers, nucleating agents, UV stabilizers, heat stabilizers, clarifying agents, fillers, brighteners, process aids, perfumes, flavors, or a mixture thereof.
  • the plastic bottle further comprises a delivery device and a valve.
  • the delivery device can be any known delivery device including, but not limited to, a button actuator and a porous sintered dome.
  • the valve controls the flow of the perfume composition.
  • any known valve can be used that is capable of sealing the perfume composition within the plastic bottle and of being easily opened and closed to control the release of the perfume composition to the delivery device.
  • Both the delivery device and valve can be made of any material including, but not limited to, metal, plastic, or glass. PEF may be used to produce a plastic valve that can be glued or welded to the plastic bottle instead of a typical metal valve.
  • the plastic bottle further comprises a label. In another embodiment, the plastic bottle further comprises a label, wherein the label comporises PEF. In another embodiment, the plastic bottle further comprises a cap. In another embodiment, the plastic bottle further comprises a cap, wherein the cap comporises PEF.
  • color can be imparted to the label, cap, delivery system, and valve of the present invention in any of the aspects by using direct compounding (i.e., in-line compounding).
  • direct compounding i.e., in-line compounding
  • a twin screw compounder is placed at the beginning of the injection molding, blow molding, or film line and additives, such as pigments, are blended into the resin just before article formation.
  • Additional materials may be incorporated into the plastic bottle, label, cap, delivery system, and valve of the present invention in any of the aspects to improve the strength or other physical characteristics of the plastic.
  • additional materials are inorganic salt (e.g. calcium carbonate, calcium sulfate, talc, clay, and nanoclay), aluminum hydroxide, CaSiO 3 , glass fibers, glass spheres, crystalline silicas (e.g., quartz, novacite, and crystallobite), magnesium hydroxide, mica, sodium sulfate, lithopone, magnesium carbonate, iron oxide, or mixtures thereof.
  • the plastic bottle, cap, and label are made from up to 50 wt % recycled PEF in a blend with PEF or other polymer materials. In another embodiment, the plastic bottle, cap, and label is made from up to 50 wt % recycled PEF in a multiple layer structure. In another embodiment, up to 100 wt % of the plastic bottle, cap, and label are made from recycled PEF.
  • PEF bottles can be recycled along with PET. Alternatively, a separate recycling stream can be set up for PEF only. It is desirable for plastic bottles for perfume compositions to be recyclable, particularly in North America and other developed countries, where substantial recycling infrastructure exists. For example, several States in the U.S. (e.g. California and Oregon) require consumer goods companies to make their bottles recyclable.
  • the bottles of the present invention can be produced using blow molding.
  • Blow molding is a manufacturing process by which hollow plastic parts are formed from thermoplastic materials.
  • the blow molding process begins with melting down the thermoplastic material and forming it into a parison or preform.
  • the parison is a tube-like piece of plastic with a hole in one end through which compressed air can pass.
  • Pressurized gas usually air, is used to expand the parison or the hot preform and press it against a mold cavity. The pressure is held until the plastic cools. After the plastic has cooled and hardened the mold opens up and the part is ejected.
  • extrusion blow molding EBM
  • injection blow molding IBM
  • injection stretch blow molding ISBM
  • EBM extrusion blow molding
  • a molten tube of plastic is extruded into a mold cavity and inflated with compressed air.
  • One end of the cylinder is pinched closed. After the plastic part has cooled, it is removed from the mold.
  • These containers can be single layer or multilayer.
  • Injection blow molding involves three steps: injection, blowing, and ejection.
  • the preform mold forms the external shape of the resulting container and is clamped around a mandrel (the core rod), which forms the internal shape of the preform.
  • the preform consists of a fully formed bottle/jar neck with a thick tube of polymer attached, which will form the body.
  • the preform mold opens and the core rod is rotated and clamped into the hollow, chilled blow mold.
  • the core rod opens and allows compressed air into the preform, which inflates it to the finished article shape.
  • Injection blow molding is useful for the formation of article components that have embedded bio-based polymer. Injection blow molding can be used to produce containers that include blends of bio-based polymers.
  • Injection stretch blow molding is a method for producing a plastic bottle from a preform or parison that is stretched in both the hoop direction and the axial direction, when the preform is blown into its desired container shape.
  • a plastic is first molded into a “preform” using the injection molding process. These preforms are produced with the necks of the containers, including threads. The preforms are packaged, and after cooling, fed into a reheat stretch blow molding machine. The preforms are heated above their glass transition temperature, then blown using high pressure air into bottles using metal blow molds. Typically, the preform is stretched with a core rod as part of the process. Injection stretch blow molding can be used to produce bottles of the present invention.
  • the label of the invention can be formed using film extrusion.
  • film extrusion thermoplastic material is melted and formed into a continuous profile.
  • multilayer films are coextruded.
  • Film extrusion and coextrusion can be performed by any method known to one skilled in the art.
  • the film layers may be formed from a variety of materials, including PEF, PET, PP and PE.
  • the label comprises virgin PEF.
  • the label comprises recycled PEF.
  • the label comprises regrind PEF.
  • the label comprises other polymer material.
  • the labels of the present invention may be applied using a pressure sensitive adhesive or using a shrink label.
  • the cap of the present invention can be formed using injection molding or thermoforming. Injection molding can be used to make single layer caps or multilayer caps.
  • the cap may be formed from a variety of materials, including PEF, PET, PP and PE.
  • the cap is thermoformed and comprises virgin PEF.
  • the cap comprises recycled PEF.
  • the cap comprises regrind PEF.
  • the cap is thermoformed and comprises virgin PET.
  • the cap comprises recycled PET.
  • the cap comprises regrind PET.
  • the cap comprises other polymer material.
  • the perfume composition of the present invention may comprise a perfume and a solvent.
  • the perfume may be manufactured synthetically or extracted from plant or animal sources.
  • the solvent may be ethanol, mixture of water and ethanol, fractionated coconut oil, or liquid waxes. In one embodiment, the solvent is ethanol or mixture of water and ethanol. In another embodiment, the solvent is ethanol.
  • the perfume composition of the present invention may comprise perfume of any type, such as, by way of example and not limitation, perfume extract, empowering de perfume (ESdP), eau de perfume (EdP), eau de toilette (EdT), eau de cologne (EdC), perfume mist, and splash (EdS).
  • the perfume composition of the present invention may comprise any combination of top, middle, and base fragrance notes.
  • the perfume composition of the present invention can comprise individual components or mixtures from various “Fragrance Families” of the fragrance wheel described by Michael Edwards in Fragrances of the World 2013® 29th Edition, Sydney. In the fragrance wheel, the four standard families are Floral, Oriental, Woody and Fresh which are in turn divided into sub-groups (e.g.
  • perfume compositions can comprise components or mixtures from families and sub-groups including single floral, floral bouquet, oriental, wood, leather, chypre, fougère, bright floral, green, aquatic, oceanic, ozonic, citrus, fruity, or Geneva.
  • the perfume composition of the present invention can comprise components or mixtures from various natural sources, such as, by way of example and not limitation, bark, flowers, blossoms, fruits, leaves, twigs, resins, roots, rhizomes, bulbs, seeds, woods, ambergris, castoreum, civet, hyraceum, honeycomb, deer musk, lichens, seaweed, synthetic sources, or mixtures thereof.
  • natural sources such as, by way of example and not limitation, bark, flowers, blossoms, fruits, leaves, twigs, resins, roots, rhizomes, bulbs, seeds, woods, ambergris, castoreum, civet, hyraceum, honeycomb, deer musk, lichens, seaweed, synthetic sources, or mixtures thereof.
  • the perfume composition of the present invention may comprise components selected from the group consisting of monoterpenes, sesquiterpenes, diterpenes, their derivatives, and mixtures thereof.
  • monoterpenes and their derivatives are menthol, vanillin, citral alcohol, rose alcohol, and limonene.
  • sesquiterpenes and their derivatives are ⁇ - and ⁇ -santalol, patcoulol, and norpatchoulenol.
  • a non-limiting example of diterpenes and their derivatives is sclareol.
  • Other perfume compositions of the present invention may comprise perfumes described in U.S. Pat. No. 5,919,752, incorporated herein by reference.
  • WVTR Water Vapor Transmission Rate
  • ORR Oxygen Transmission Rate
  • Environmental Stress Crack Resistance is determined by placing ASTM Izod bars (ASTM D256-10) or Izod-size parts cut out of the panels of the bottles, under strain (0.25%, 0.5%, and 1%), in headspace or direct contact with product (for 1 month at 25° C. or 40° C.), followed by optical/SEM/TEM characterization. Creep Resistance is determined by placing ASTM Type V dogbones (ASTM D638-10), under stress (1390 psi), in headspace or direct product contact (for 1 week at 25° C. or 40° C.) and measuring dimensional change along the gauge length.
  • the bio-based content of a material is measured using the ASTM D6866 method, which allows the determination of the bio-based content of materials using radiocarbon analysis by accelerator mass spectrometry, liquid scintillation counting, and isotope mass spectrometry.
  • ASTM D6866 method allows the determination of the bio-based content of materials using radiocarbon analysis by accelerator mass spectrometry, liquid scintillation counting, and isotope mass spectrometry.
  • the application of ASTM D6866 to derive a “bio-based content” is built on the same concepts as radiocarbon dating, but without use of the age equations.
  • the analysis is performed by deriving a ratio of the amount of radiocarbon ( 14 C) in an unknown sample to that of a modern reference standard. The ratio is reported as a percentage with the units “pMC” (percent modern carbon). If the material being analyzed is a mixture of present day radiocarbon and fossil carbon (containing no radiocarbon), then the pMC value obtained correlates directly to the amount of biomass material present in the sample.
  • the modern reference standard used in radiocarbon dating is a NIST (National Institute of Standards and Technology) standard with a known radiocarbon content equivalent approximately to the year AD 1950.
  • the year AD 1950 was chosen because it represented a time prior to thermo-nuclear weapons testing, which introduced large amounts of excess radiocarbon into the atmosphere with each explosion (termed “bomb carbon”).
  • the AD 1950 reference represents 100 pMC.
  • “Bomb carbon” in the atmosphere reached almost twice normal levels in 1963 at the peak of testing and prior to the treaty halting the testing. Its distribution within the atmosphere has been approximated since its appearance, showing values that are greater than 100 pMC for plants and animals living since AD 1950.
  • the distribution of bomb carbon has gradually decreased over time, with today's value being near 107.5 pMC. As a result, a fresh biomass material, such as corn, could result in a radiocarbon signature near 107.5 pMC.
  • Petroleum-based carbon does not have the signature radiocarbon ratio of atmospheric carbon dioxide.
  • compounds derived entirely from renewable resources have at least about 95 percent modern carbon (pMC), preferably at least about 99 pMC, for example, about 100 pMC.
  • a bio-based content result is derived by assigning 100% equal to 107.5 pMC and 0% equal to 0 pMC. In this regard, a sample measuring 99 pMC will give an equivalent bio-based content result of 93%.
  • PEF contains eight carbon atoms in its monomeric unit. If PEF is totally derived from a renewable resource, then it theoretically has a bio-based content of 100%, because all of the carbon atoms are derived from a renewable resource. If only the aromatic portion of the monomeric unit of PEF is derived from a renewable resource, then it theoretically has a bio-based content of 75%.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Packages (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wrappers (AREA)
  • Fats And Perfumes (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
US13/804,672 2012-04-16 2013-03-14 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance Abandoned US20130270212A1 (en)

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US13/804,672 US20130270212A1 (en) 2012-04-16 2013-03-14 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance
BR112014025607-1A BR112014025607B1 (pt) 2012-04-16 2013-04-12 frascos plásticos para composições de perfume tendo resistência aprimorada ao fendilhamento
CN201380020381.3A CN104271633A (zh) 2012-04-16 2013-04-12 用于香料组合物的具有改善的抗龟裂性的塑料瓶
EP13718723.3A EP2838933B1 (fr) 2012-04-16 2013-04-12 Bouteilles en plastique pour compositions de parfum ayant une résistance au faïençage améliorée
JP2015507067A JP6170135B2 (ja) 2012-04-16 2013-04-12 改善されたヒビ耐性を有する香料組成物用プラスチックボトル
MX2014012417A MX361965B (es) 2012-04-16 2013-04-12 Frascos de plastico para composiciones de perfume que tienen resistencia mejorada al resquebrajamiento.
PCT/US2013/036298 WO2013158477A1 (fr) 2012-04-16 2013-04-12 Bouteilles en plastique pour compositions de parfum ayant une résistance au faïençage améliorée
US14/987,838 US20160113376A1 (en) 2012-04-16 2016-01-05 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance
US16/025,072 US20180317626A1 (en) 2012-04-16 2018-07-02 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance

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US13/804,672 Abandoned US20130270212A1 (en) 2012-04-16 2013-03-14 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance
US14/987,838 Abandoned US20160113376A1 (en) 2012-04-16 2016-01-05 Plastic Bottles For Perfume Compositions Having Improved Crazing Resistance
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CN104011134A (zh) 2014-08-27
WO2013158582A3 (fr) 2014-05-30
EP2763908A2 (fr) 2014-08-13
WO2013158582A2 (fr) 2013-10-24
MX361965B (es) 2018-12-19
BR112014025607B1 (pt) 2021-01-05
CN104271633A (zh) 2015-01-07
EP2763908B1 (fr) 2015-11-18
EP2838933B1 (fr) 2018-07-04
US20160113376A1 (en) 2016-04-28
MX2014012417A (es) 2015-01-19
MX354728B (es) 2018-03-16
JP2015516341A (ja) 2015-06-11
CN104011134B (zh) 2016-02-03
MX2014011548A (es) 2014-11-14
JP6170135B2 (ja) 2017-07-26
EP2838933A1 (fr) 2015-02-25
US9622563B2 (en) 2017-04-18
JP6317261B2 (ja) 2018-04-25
US20180317626A1 (en) 2018-11-08
WO2013158477A1 (fr) 2013-10-24
JP2015500187A (ja) 2015-01-05
US20130270295A1 (en) 2013-10-17

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