US20100186288A1 - Method for production of emulsion fuel and apparatus for production of the fuel - Google Patents

Method for production of emulsion fuel and apparatus for production of the fuel Download PDF

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Publication number
US20100186288A1
US20100186288A1 US12/439,436 US43943607A US2010186288A1 US 20100186288 A1 US20100186288 A1 US 20100186288A1 US 43943607 A US43943607 A US 43943607A US 2010186288 A1 US2010186288 A1 US 2010186288A1
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United States
Prior art keywords
water
finely
emulsion fuel
oil
combustible oil
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Abandoned
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US12/439,436
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English (en)
Inventor
Saburo Ishiguro
Tomihisa Naito
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Nanomizer Inc
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Nanomizer Inc
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Assigned to NANOMIZER INC. reassignment NANOMIZER INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ISHIGURO, SABURO, NAITO, TOMIHISA
Publication of US20100186288A1 publication Critical patent/US20100186288A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K5/00Feeding or distributing other fuel to combustion apparatus
    • F23K5/02Liquid fuel
    • F23K5/08Preparation of fuel
    • F23K5/10Mixing with other fluids
    • F23K5/12Preparing emulsions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase

Definitions

  • combustion with high efficiency which could not be attained by the conventional emulsion fuel, may be realized by reducing an average particle diameter of respective particles in the emulsion fuel into 1,000 nm or less.
  • Embodiments of present invention have been made based on the above-mentioned findings, and relates to a method and an apparatus for production of an emulsion fuel having the following constructions.
  • a method for production of an emulsion fuel comprising, while adding 10.0 to 150.0 parts by volume of a water with respect to 100 parts by volume of a combustible oil (more preferably, 25.0 to 120.0 parts by volume of a water with respect to 100 parts by volume of a combustible oil), finely-dividing and mixing the water and the combustible oil by a finely-dividing and mixing means, to thereby form an emulsion fuel in which an average diameter of the water or the combustible oil is 1,000 nm or less.
  • the combustible oil is one kind or two or more kinds selected from: petroleum such as a heavy oil, a light oil, a lamp oil, and a volatile oil; an industrial waste oil; and cooking oils such as a tempura oil, a soybean oil, a sesame oil.
  • An apparatus for production of an emulsion fuel including: a water-combustible oil primary mixing means for primarily mixing a water and a combustible oil, while adding 10.0 to 150.0 parts by volume of the water with respect to 100 parts by volume of the combustible oil (more preferably, 25.0 to 120.0 parts by volume of the water with respect to 100 parts by volume of the combustible oil); and a finely-dividing and mixing means for finely-dividing and mixing a water-combustible oil-based primary mixture liquid obtained by the primary mixing means into a fine particle state, to thereby form an emulsion fuel in which an average diameter of the water or the combustible oil is 1,000 nm or less.
  • An emulsion fuel wherein 10.0 to 150.0 parts by volume of a water is mixed with respect to 100 parts by volume of a combustible oil (more preferably, 25.0 to 120.0 parts by volume of a water with respect to 100 parts by volume of a combustible oil) by the finely-dividing and mixing means, and an average diameter of the combustible oil is 1,000 nm or less.
  • An operation method for an internal combustion engine comprising: while adding 25.0 to 40.0 parts by volume of a water with respect to 100 parts by volume of a combustible oil, finely-dividing and mixing the water and the combustible oil by a finely-dividing and mixing means, to thereby form an emulsion fuel in which an average diameter of the water or the combustible oil is 1,000 nm or less; and spraying the obtained emulsion fuel into a reciprocating engine, to thereby operate the internal combustion engine.
  • An operation method for an internal combustion engine comprising: while adding 25.0 to 40.0 parts by volume of a water with respect to 100 parts by volume of a combustible oil, finely-dividing and mixing the water and the combustible oil by a finely-dividing and mixing means, to thereby form an emulsion fuel in which an average diameter of the water or the combustible oil is 200 to 700 nm; and spraying the obtained emulsion fuel into a reciprocating engine, to thereby operate the internal combustion engine.
  • An emulsion fuel for operating a reciprocating engine wherein 25.0 to 40.0 parts by volume of a water is mixed with respect to 100 parts by volume of a combustible oil by the finely-dividing and mixing means, and an average diameter of a water or a combustible oil in the emulsion fuel is 200 to 700 nm.
  • FIG. 1 is a set of graphs illustrating fuel test results of a power engine which uses an emulsion fuel according to an embodiment of the present invention and another fuel.
  • FIG. 2 is a set of graphs illustrating fuel test results of the power engine which uses the emulsion fuel according to another embodiment of the present invention and the other fuel.
  • FIG. 3 is a set of graphs illustrating fuel test results of the power engine which uses the emulsion fuel according to yet another embodiment of the present invention and the other fuel.
  • FIG. 4 is a set of graphs illustrating fuel test results of the power engine which uses the emulsion fuel according to still another embodiment of the present invention and the other fuel.
  • an oil and a water are mixed together under ultra fine states to produce an emulsion fuel, thereby being capable of contributing to improve fuel consumption and to make combustion exhaust gas clean.
  • a finely-dividing and mixing means used for producing the emulsion fuel of the present invention for example, there may be given an apparatus, which pressurizes a primary mixture liquid including a water and a combustible oil that finely divides and mixes through a cavitation effect due to turbulence generated at one or two or more of orifices.
  • the finely-dividing and mixing means there may be given an apparatus, which pressurizes a primary mixture liquid including a water and a combustible oil to cause to flow within a pump at a flow rate of 50 m/s or more; accelerates the primary mixture liquid to pass into holes of a wall member having multiple holes each having a diameter of 500 ⁇ m or less formed therein; and finely divides and mixes through a cavitation effect due to turbulence generated between flows of the liquid.
  • a preferred method for the production of an emulsion fuel includes using: a water-combustible oil primary mixing means for primarily mixing a water and a combustible oil, while adding 10.0 to 150.0 parts by volume of the water (more preferably, 25.0 to 120.0 parts by volume of the water) with respect to 100 parts by volume of the combustible oil; and a finely-dividing and mixing means for finely-dividing and mixing the water-combustible oil-based primary mixture liquid obtained by the primary mixing means into a fine particle state, to thereby form an emulsion fuel in which an average diameter of the water or the combustible oil is 1,000 nm or less.
  • the mixture liquid is introduced into a NanomizerTM apparatus for finely-dividing and mixing a primary mixture liquid dispersed within a liquid sample, and the primary mixture liquid including the water and the combustible oil is finely-divided and mixed, thereby forming an emulsion fuel of a mixture including a ultra fine diameter particles of the water and the combustible oil.
  • the NanomizerTM apparatus is manufactured by Yoshida Kikai Co., Ltd. Of Japan.
  • the water-combustible oil mixture liquid is caused to pass through orifice holes of 200 ⁇ m or less of the NanomizerTM apparatus with a high pressure for several stages.
  • the turbulence is generated when the mixture liquid passes through the narrow orifices, and a strong nano level agitation effect is generated owing to the turbulence effect.
  • the water (or oil) is finely divided into a nano level (for example, average diameter of water is 200 to 700 nm), and the resultants are dispersed within the oil (to form W/O type emulsion) thereby attaining stabilization.
  • a nano level for example, average diameter of water is 200 to 700 nm
  • the reduction method for the water is not particularly limited, but a method using electrolysis is industrially preferred.
  • a method using a chemical, or a method using an ore such as tourmarine there may be given a method using a chemical, or a method using an ore such as tourmarine.
  • the reduction potential of the water is preferably ⁇ 100 my or less, and ⁇ 300 my or less is preferred, if possible.
  • the water and the oil are difficult to mixed with each other because a surface tension of the water is large. If the reduction potential is lowered, the surface tension decreases, resulting in easier mixing together.
  • the obtained emulsion fuel is a W/O type emulsion, and average diameter of the water in the emulsion was 300 to 500 nm.
  • the thus obtained emulsion fuel of the present invention was set to be Sample 2.
  • the mixture liquid produced in the same way as in Sample 2 was caused to pass through NanomizerTM apparatus with 8 MP to obtain an emulsion fuel of the present invention, which was set to be Sample 3.
  • Sample 1 is a A heavy oil as a comparative example
  • Sample 4 is a light oil as a comparative example
  • Samples 5 and 6 each are obtained by the same processing as in Samples 2 and 3, and are emulsion fuels of the present invention in which the light oil is used in place of the A heavy oil.
  • Example 5 and Sample 6 were caused to pass through NanomizerTM apparatus with pressures of 3 MP and 8 MP, respectively, to be finely-divided and mixed).
  • Sample 2 A heavy oil 73.5%, reduced water 24.5%, activator 2%, processed by NanomizerTM apparatus with 3 MP (emulsion fuel)
  • Sample 3 A heavy oil 73.5%, reduced water 24.5%, activator 2% processed by NanomizerTM apparatus with 8 MP (emulsion fuel)
  • Sample 5 light oil 73.5%, reduced water 24.5%, activator 2%, processed by NanomizerTM apparatus with 3 MP (emulsion fuel)
  • Sample 6 light oil 73.5%, reduced water 24.5%, activator 2%, processed by NanomizerTM apparatus with 8 MP (emulsion fuel)
  • Table 1 is test results of a case in which the number of rotation of the engine is 1,000 rpm
  • Table 2 is test results of a case in which the number of rotation of the engine is 1,400 to 2,200 rpm
  • Table 3 is test results of a case in which the number of rotation of the engine is 2,700 rpm.
  • FIG. 1 is a set of graphs showing engine test results in which Sample 1 (comparative example fuel) and Sample 2 (emulsion fuel of the present invention) were used
  • FIG. 2 is a set of graphs showing engine test results in which Sample 1 (comparative example fuel) and Sample 3 (emulsion fuel of the present invention) were used
  • FIG. 3 is a set of graphs showing engine test results in which Sample 4 (comparative example fuel) and Sample 5 (emulsion fuel of the present invention) were used
  • FIG. 4 is a set of graphs showing engine test results in which Sample 4 (comparative example fuel) and Sample 6 (emulsion fuel of the present invention) were used.
  • a diesel generator of 13ES-type manufactured by Denyo Co., Ltd. was used to successively measure the concentrations of nitrogen oxides and oxygen within an exhaust gas together with a power generation amount per unit heavy oil, whereby the power generation efficiency of the emulsion fuel of the present invention was measured.
  • an emulsion fuel having a composition including 75 wt % of a Special A heavy oil, 24.7 wt % of a water, and 0.3 wt % of an emulsifier was produced and used.
  • the emulsion fuel of the present invention and sole A heavy oil are used as the fuels to successively operate the above-mentioned diesel generator, NOx concentration within the exhaust gas and the power generation amount were measured. The concentrations of NOx and O 2 within the exhaust gas were measured successively at an exit smoke-flue of the generator.
  • the measurement results of the exhaust gas which was generated by the use of the emulsion fuel of the present invention, are shown in Table 4, and the measurement results of the exhaust gas when the Special A heavy oil was solely used as fuel are shown in Table 5.
  • an average NOx concentration within the exhaust gas was 193 ppm.
  • the average value of the NOx concentration was 369 ppm.
  • results of power generation of this example are shown in Table 6.
  • the power generation amount per unit heavy oil of the diesel generator was 3.33 KWH/Kg when the emulsion fuel of the present invention was used, and was 2.73 KWH/Kg when the sole heavy oil was used as fuel.
  • the power generation amount was increased by about 22%, whereby it was shown that the power generation efficiency of the emulsion fuel of the present invention was improved.
  • the consumption amount (use amount) of the combustible oil for obtaining an output and torque exerted by solely using a combustible oil was reduced by about 25% by using the emulsion fuel of the present invention.
  • the emulsion fuel of the present invention in which 24.5% of the water was added to the A-heavy oil or the light oil, exhibited almost the same characteristics as 100% A-heavy oil or 100% light oil up to 2,200 rpm. This is astonishingly excellent performance.
  • the emulsion fuel of the present invention is used for a ship, for instance, it is considered to be good to use a light oil in a harbor, and then to switch to use the emulsion fuel outside the harbor.
  • the mixture liquid including a water and a combustible oil is, for example, subjected to a pressure to cause to pass through one or a plurality of small holes, thereby producing the emulsion fuel by finely-diving and mixing the mixture through the cavitation effect due to the turbulence generated when passing through orifices.
  • the emulsion fuel containing about 25% of the finely-divided and mixed water does not cause engine trouble, if being burned within the engine, and exhibits substantially the same output and torque with the A-heavy oil or the light oil.
  • the fuel consumption amount is also the same even though 25% of the water is contained therein (by simple calculation, 25% of energy saving is attained).
  • the generation of soot and dioxin are reduced into 1 ⁇ 2 to 1 ⁇ 5 (theoretically no generation), and NO x was also reduced into about 1 ⁇ 2 to 1 ⁇ 3.
  • the emulsion fuel of the present invention has a further energy saving effect as a fuel for combustion furnace, and attains 25% to 35% energy saving.
  • the waste oil may also be used as a raw material.
  • the emulsion fuel (water-oil-based emulsion-type water-mixed fuel) is obtained by adding 0.5% to 5% of the emulsifier to the water and oil, and by agitating and mixing the mixture into emulsion, and generally contains particles having an average diameter of several ⁇ m to several tens ⁇ m. Even if the emulsion fuel is produced using a particularly excellent emulsifier, the average particle diameter was about several ⁇ m (about 1 ⁇ m to 3 ⁇ m), which is a so-called water-mixed fuel of an emulsified-state liquid (emulsion fuel).
  • the emulsion fuel of the emulsified-state liquid has a tendency of separating with elapse of time, and, even if the separation does not occur, has a nature in which the viscosity thereof becomes higher (dilatancy) with the elapse of time, which is opposite to thixotropy, thereby causing an accident such as clogging of a pipe or a nozzle.
  • the emulsion fuel obtained by the present invention constitutes an emulsion fuel in which the oil and the water are mixed under a ultra fine particle state (i.e., nano level), and the average particle diameter constituting the water or the combustible oil is 1,000 nm, preferably 200 nm to 700 nm.
  • the stability thereof is extremely excellent, and has high combustion efficiency, whereby the emulsion fuel of the present invention may be used for all the purposes such as for an engine, a combustion furnace, an incinerator, a boiler, and a generator.
  • the emulsion fuel of the present invention is used for an engine fuel for a vehicle and a ship, 15% to 25% of energy saving may be achieved. Further, soot and dioxin may be reduced into 1 ⁇ 2 to 1 ⁇ 5, and NO x may be reduced about 1 ⁇ 2 to 1 ⁇ 3, thereby attaining low pollution and excellent stability. As a result, it becomes possible to produce the fine particle mixture liquid at a gas station, and to refuel the liquid into a fuel tank of the vehicle as currently carried out. Moreover, the emulsion fuel of the present invention may be applied for the boiler, the generator, the combustion furnace and the incinerator, and utilization of the waste oil is possible. Such a result was obtained that, if the emulsion fuel of the present invention is used for the combustion furnace, the energy saving effect may be increased by 30% to 40%.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Feeding And Controlling Fuel (AREA)
US12/439,436 2006-09-01 2007-08-31 Method for production of emulsion fuel and apparatus for production of the fuel Abandoned US20100186288A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2006-238131 2006-09-01
JP2006238131 2006-09-01
PCT/JP2007/067451 WO2008029898A1 (fr) 2006-09-01 2007-08-31 Procédé de production de carburant en émulsion et appareil de production du carburant

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US (1) US20100186288A1 (de)
EP (1) EP2068080A1 (de)
KR (1) KR20090049085A (de)
CN (1) CN101535718B (de)
RU (1) RU2440403C2 (de)
SG (1) SG174732A1 (de)
WO (1) WO2008029898A1 (de)

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WO2012135515A2 (en) 2011-03-29 2012-10-04 Fuelina, Inc. Hybrid fuel and method of making the same
US10308885B2 (en) 2014-12-03 2019-06-04 Drexel University Direct incorporation of natural gas into hydrocarbon liquid fuels

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KZ22398A4 (ru) * 2009-02-10 2010-03-15 Tovarischestvo S Ogranichennoj Способ получения водотопливной эмульсии и композиционного многокомпонентного топлива
CN102893087B (zh) * 2010-01-07 2015-09-30 株式会社Kcs 使用燃料和有机化合物水溶液的高温燃烧方法及装置
MX2016011721A (es) * 2014-03-28 2017-04-25 Royal Corp Co Ltd Proceso y dispositivo para producir aceite de hidrocarburo combustible.
RU2596625C2 (ru) * 2014-11-06 2016-09-10 Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" Способ повышения удельной эффективности жидких углеводородных топлив и устройство для осуществления способа
CN106582458A (zh) * 2015-10-16 2017-04-26 世能华奇(北京)科技发展有限公司 一种混合柴油的制造方法、由该方法制造的混合柴油及其制造装置
KR102155265B1 (ko) * 2019-03-13 2020-09-11 김영욱 물을 포함하는 석탄연소용 연료조성물
JP7265250B2 (ja) * 2019-04-22 2023-04-26 真二 長谷川 加水燃料製造方法及び加水燃料製造装置

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Publication number Priority date Publication date Assignee Title
WO2012135515A2 (en) 2011-03-29 2012-10-04 Fuelina, Inc. Hybrid fuel and method of making the same
EP2865735A1 (de) 2011-03-29 2015-04-29 Fuelina, Inc. Hybridkraftstoff und Verfahren zur Herstellung davon
US9493709B2 (en) 2011-03-29 2016-11-15 Fuelina Technologies, Llc Hybrid fuel and method of making the same
EP3354711A1 (de) 2011-03-29 2018-08-01 Fuelina Technologies, LLC Hybridkraftstoff und verfahren zur herstellung davon
US10308885B2 (en) 2014-12-03 2019-06-04 Drexel University Direct incorporation of natural gas into hydrocarbon liquid fuels

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WO2008029898A1 (fr) 2008-03-13
CN101535718B (zh) 2012-02-29
RU2009111851A (ru) 2010-10-10
EP2068080A1 (de) 2009-06-10
SG174732A1 (en) 2011-10-28
CN101535718A (zh) 2009-09-16
RU2440403C2 (ru) 2012-01-20
KR20090049085A (ko) 2009-05-15

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