US20100129008A1 - Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom - Google Patents

Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom Download PDF

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Publication number
US20100129008A1
US20100129008A1 US12/587,915 US58791509A US2010129008A1 US 20100129008 A1 US20100129008 A1 US 20100129008A1 US 58791509 A US58791509 A US 58791509A US 2010129008 A1 US2010129008 A1 US 2010129008A1
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US
United States
Prior art keywords
layer
bag
sub
flowable material
evoh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/587,915
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English (en)
Inventor
David Bellmore
Karen Berger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scholle IPN Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US12/587,915 priority Critical patent/US20100129008A1/en
Assigned to SCHOLLE CORPORATION reassignment SCHOLLE CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BELLMORE, DAVID, BERGER, KAREN
Publication of US20100129008A1 publication Critical patent/US20100129008A1/en
Assigned to BANK OF AMERICA, N.A. reassignment BANK OF AMERICA, N.A. SECURITY AGREEMENT Assignors: SCHOLLE CORPORATION
Assigned to SCHOLLE IPN CORPORATION reassignment SCHOLLE IPN CORPORATION RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: BANK OF AMERICA, N.A.
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • B65D31/02Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/16Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00Thermoplastic elastomer material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/31Heat sealable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/744Non-slip, anti-slip
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/46Bags

Definitions

  • the disclosure relates in general to bags, and more particularly, to a laminate for a bag for flowable material having an oriented polypropylene.
  • bags for flowable material such as liquids and syrups (among others).
  • wines are packaged in such bags which are then inserted into boxes (commonly termed bag-in-box wine packaging).
  • bag-in-box wine packaging A constant struggle with such packaging is to limit bag cracking that typically occurs during shipping and transport. Additionally, with certain products, it is necessary to limit the quantity of oxygen that is transmitted through the bag (typically quite significant for wine products).
  • One structure that is utilized comprises a three layer laminate comprising an EVOH cap layer, a BON core layer and a PE sealant layer. While this structure has been utilized, there is a need to provide a structure that has a material which has less susceptibility to flex cracking and which has a lower oxygen transmission rate.
  • the disclosure is directed to a bag for a flowable material comprising a plurality of walls coupled together by way of a plurality of seals to define a substantially fluid tight cavity.
  • the plurality of walls each comprising a laminate structure comprising a sealant layer comprising a polyethylene material; a core layer comprising an oriented polypropylene material; and a cap layer comprising an EVOH material.
  • At least one of the layers further includes a metallized vapor deposited layer thereon.
  • the metallized vapor deposited layer is deposited on a side of the core layer.
  • the metallized vapor deposited layer comprises aluminum.
  • the metallized vapor deposited layer comprises one of the group consisting of: metals, PVDC, aluminum oxide and silicon oxide.
  • the sealant layer further comprises: 1.8 mil thick 0.920 g/cc octene LLDPE (1.0 g/10 min MI).
  • the core layer further comprises 0.70 mil thick oriented polypropylene material.
  • the core layer further includes a treatment applied thereto, wherein the treatment is selected from the group consisting of: plain, corona, plasma and chemical.
  • the cap layer may comprise a multi-sub-layer EVOH based layer.
  • the base of the EVOH layer comprises a propylene sub-layer.
  • the EVOH layer includes a plurality of polyethylene sub-layers sandwiched around an EVOH sub-layer.
  • the EVOH layer comprises a plurality of sub-layers including, at least one vinyl acetate sub-layer, a plurality of polyethylene sub-layers and an EVOH sub-layer surrounded by the plurality of polyethylene sub-layers.
  • the EVOH layer comprises five sub-layers, including, in order, a first linear low density polyethylene sub-layer, a second linear low density polyethylene sub-layer, a third linear low density polyethylene sub-layer, an EVOH sub-layer, and a forth linear low density polyethylene sub-layer.
  • the first linear low density sub-layer comprises a 0.55 mil 50% 12% VA (0.40 g/10 min MI)/50% 0.920 g/cc octene LLDPE (1.0 g/10 min MI) with anti-block, anti-oxidant, and slip additives.
  • the second linear low density sub-layers comprise a 0.20 mil 100% 0.924 g/cc anhydride modified LLDPE (2.2 g/10 min MI).
  • the third linear low density sub-layer comprises a 0.30 mil 29 mol % ethylene EVOH (3.8 g/10 Min MI).
  • the EVOH sub-layer comprises a 0.20 mil 100% 0.924 g/cc anhydride modified LLDPE (2.2 g/10 min MI).
  • the fourth linear low density sub-layer comprises a 0.55 mil 100% 0.920 g/cc octane LLDPE (1.0 g/10 min MI) with anti-block, anti-oxidant, and slip additives.
  • FIG. 1 of the drawings is a top plan view of a bag having the laminate construction of the present invention.
  • FIG. 2 of the drawings is a cross-sectional view of the laminate construction of the present invention.
  • a bag 12 having a laminate structure 10 is shown.
  • the bag comprises a conventional bag for flowable material (such as syrup, wine, fine powders, and the like).
  • a pillow type bag is shown which includes a plurality of walls 20 , 22 and a plurality of seals, such as seal 24 which joins the walls to each other to define cavity 25 .
  • a spout, such as spout 26 is disposed on one of the walls to provide fluid communication to the cavity.
  • Typical sizes for such pillow type containers often range between 1 liter and 20 liters. Of course, this is not deemed as limiting the bag to a particular size, but, rather, is provided as exemplary of conventional sizes of such containers.
  • the laminate structure 10 can be used in association with other bag constructions, such as gusseted bags or bags that are formed from a number of different constructions with a number of different seals formed in any one of a number of different formats.
  • the laminate is shown in an exemplary embodiment with the understanding that there is no limitation as to the configuration and structure of the bag with which the laminate is utilized.
  • the laminate structure comprises a sealant layer 30 , a core layer 32 and a cap layer 34 .
  • the three layers are laminated together. In one embodiment, it is contemplated that the three layers are adhered to each other.
  • a two component solventless polyurethane adhesive system 41 , 43 can be utilized between the layers.
  • the three layers may be thermally bonded together. Indeed, the particular manner in which the three layers are coupled together to form a laminate can be another mechanism altogether without departing from the scope of the invention.
  • the sealant layer (which comprises the product contact layer) comprises a polyethylene material.
  • the material comprises a 1.8 mil thick 0.920 g/cc octene LLDPE (1.0 g/10 min MI) with anti-block, anti-oxidant and slip additives.
  • a propylene based sealant layer can be utilized (homopolymer, impact copolymer, random copolymer or elastomer/plastomer). In certain embodiments, such a propylene based sealant layer can aid adhesion during thermal lamination processes.
  • the core layer 32 comprises an oriented polypropylene film (OPP).
  • OPP oriented polypropylene film
  • this layer may be metalized such that the structure may include a 2.1 minimum optical density aluminum layer.
  • One manner of applying such a metallized layer comprises the use of metal vapor deposition on the film.
  • other configurations of oriented polypropylene films are likewise contemplated for use.
  • the cap layer 34 comprises a EVOH material.
  • a five sub-layer co-extruded EVOH based layer is contemplated.
  • the five sub-layers 51 - 55 comprise: (1) 0.55 mil 50% 12% VA (0.40 g/10 min MI)/50% 0.920 g/cc octene LLDPE (1.0 g/10 min MI) with anti-block, anti-oxidant, and slip additives; (2) 0.20 mil 100% 0.924 g/cc anhydride modified LLDPE (2.2 g/10 min MI); (3) 0.30 mil 29 mol % ethylene EVOH (3.8 g/10 Min MI); (4) 0.20 mil 100% 0.924 g/cc anhydride modified LLDPE (2.2 g/10 min MI); and (5) 0.55 mil 100% 0.920 g/cc octane LLDPE (1.0 g/10 min MI) with anti-block, anti-oxidant, and slip additives.
  • a propylene based cap layer can be utilized (homopolymer, impact copolymer, random copolymer or elastomer/plastomer).
  • a propylene based cap layer can aid adhesion during thermal lamination. More specifically, this would be applicable to just OPP (not MOPP) and the propylene based material would be added to layer 55 ( FIG. 2 ).
  • the present disclosed embodiment has over a three-fold increase in flex crack resistance and over a two-fold improvement in oxygen transmission rate.
  • the OPP material has a lower modulus than the prior used BON, the thickness of this layer can be increased without affecting the bag modulus.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Bag Frames (AREA)
  • Wrappers (AREA)
  • Packages (AREA)
US12/587,915 2008-07-15 2009-10-15 Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom Abandoned US20100129008A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/587,915 US20100129008A1 (en) 2008-07-15 2009-10-15 Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13493308P 2008-07-15 2008-07-15
PCT/US2009/004103 WO2010008557A2 (fr) 2008-07-15 2009-07-15 Stratifié destiné à la fabrication d’un sac conçu pour contenir des matières liquides, à base de polymère orienté, et sac produit à partir de celui-ci
US12/587,915 US20100129008A1 (en) 2008-07-15 2009-10-15 Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/004103 Continuation WO2010008557A2 (fr) 2008-07-15 2009-07-15 Stratifié destiné à la fabrication d’un sac conçu pour contenir des matières liquides, à base de polymère orienté, et sac produit à partir de celui-ci

Publications (1)

Publication Number Publication Date
US20100129008A1 true US20100129008A1 (en) 2010-05-27

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US12/587,915 Abandoned US20100129008A1 (en) 2008-07-15 2009-10-15 Laminate for a bag for flowable material having an oriented polypropylene, and a bag made therefrom

Country Status (7)

Country Link
US (1) US20100129008A1 (fr)
EP (1) EP2323913A4 (fr)
AU (1) AU2009271582B2 (fr)
BR (1) BRPI0911001A2 (fr)
CA (1) CA2730779C (fr)
NZ (1) NZ590589A (fr)
WO (1) WO2010008557A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101046627B1 (ko) 2011-03-08 2011-07-05 윤태훈 전자기기 포장용 실딩 필름 제조방법
US10526190B2 (en) 2015-04-17 2020-01-07 Ds Smith Plastics Limited Multilayer film used with flexible packaging

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2023592B1 (en) * 2019-07-30 2021-02-23 Scholle Ipn Ip Bv Container assembly and method for preparing such a container assembly

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US3607519A (en) * 1967-08-07 1971-09-21 Tee Pak Inc Lamination of plastic packaging films
US4309466A (en) * 1979-12-17 1982-01-05 Champion International Corporation Flexible laminated packaging material comprising metallized intermediate layer
US4604322A (en) * 1985-08-06 1986-08-05 Hercules Incorporated Metallizable polypropylene film
US4855183A (en) * 1986-11-17 1989-08-08 W. R. Grace & Co.-Conn. Multiple-layer, cook-in film
US5223346A (en) * 1991-10-23 1993-06-29 Mobil Oil Corporation Hdpe/polypropylene film laminates
US5480945A (en) * 1988-08-23 1996-01-02 Viskase Corporation Amorphous nylon copolymer and copolyamide films and blends
US5874155A (en) * 1995-06-07 1999-02-23 American National Can Company Easy-opening flexible packaging laminates and packaging materials made therefrom
US6165574A (en) * 1997-04-04 2000-12-26 Tetra Laval Holdings & Finance S.A. Packaging laminate including a moisture-sensitive gas barrier layer, a method of producing the packaging laminate, as well as packaging containers
US20030024950A1 (en) * 2000-03-01 2003-02-06 Michinori Yoneyama Inner bag for bag-in-box
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US20040213944A1 (en) * 1998-06-12 2004-10-28 Mientus Bernard S. Multilayered thermoplastic film and sign cutting method using the same
US20050003125A1 (en) * 2003-07-01 2005-01-06 Barber Victor Jason Thermoplastic structures for the storing and transporting of organoleptic sensitive products
US20060291756A1 (en) * 2002-02-27 2006-12-28 Thomas Toby R Web materials with active agent for use in forming reclosable packages
WO2007133383A1 (fr) * 2006-05-09 2007-11-22 Dow Global Technologies Inc. Film polymère adhésif multicouche

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JP3094303B2 (ja) * 1990-10-08 2000-10-03 出光石油化学株式会社 多層シート類及び易開封性容器
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US3607519A (en) * 1967-08-07 1971-09-21 Tee Pak Inc Lamination of plastic packaging films
US4309466A (en) * 1979-12-17 1982-01-05 Champion International Corporation Flexible laminated packaging material comprising metallized intermediate layer
US4604322A (en) * 1985-08-06 1986-08-05 Hercules Incorporated Metallizable polypropylene film
US4855183A (en) * 1986-11-17 1989-08-08 W. R. Grace & Co.-Conn. Multiple-layer, cook-in film
US5480945A (en) * 1988-08-23 1996-01-02 Viskase Corporation Amorphous nylon copolymer and copolyamide films and blends
US5223346A (en) * 1991-10-23 1993-06-29 Mobil Oil Corporation Hdpe/polypropylene film laminates
US5874155A (en) * 1995-06-07 1999-02-23 American National Can Company Easy-opening flexible packaging laminates and packaging materials made therefrom
US6165574A (en) * 1997-04-04 2000-12-26 Tetra Laval Holdings & Finance S.A. Packaging laminate including a moisture-sensitive gas barrier layer, a method of producing the packaging laminate, as well as packaging containers
US20030207054A1 (en) * 1998-05-29 2003-11-06 Tetra Laval Holdings & Finance S.A. Packaging laminates based on cardboard and paper
US20040213944A1 (en) * 1998-06-12 2004-10-28 Mientus Bernard S. Multilayered thermoplastic film and sign cutting method using the same
US20030024950A1 (en) * 2000-03-01 2003-02-06 Michinori Yoneyama Inner bag for bag-in-box
US20030087057A1 (en) * 2000-08-29 2003-05-08 Blemberg Robert J. Encapsulated barrier for flexible films and a method of making the same
US20060291756A1 (en) * 2002-02-27 2006-12-28 Thomas Toby R Web materials with active agent for use in forming reclosable packages
US20050003125A1 (en) * 2003-07-01 2005-01-06 Barber Victor Jason Thermoplastic structures for the storing and transporting of organoleptic sensitive products
WO2007133383A1 (fr) * 2006-05-09 2007-11-22 Dow Global Technologies Inc. Film polymère adhésif multicouche

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101046627B1 (ko) 2011-03-08 2011-07-05 윤태훈 전자기기 포장용 실딩 필름 제조방법
US10526190B2 (en) 2015-04-17 2020-01-07 Ds Smith Plastics Limited Multilayer film used with flexible packaging

Also Published As

Publication number Publication date
EP2323913A4 (fr) 2017-04-19
CA2730779A1 (fr) 2010-01-21
NZ590589A (en) 2013-06-28
WO2010008557A2 (fr) 2010-01-21
AU2009271582B2 (en) 2015-02-05
AU2009271582A1 (en) 2010-01-21
EP2323913A2 (fr) 2011-05-25
CA2730779C (fr) 2015-11-24
BRPI0911001A2 (pt) 2015-10-06
WO2010008557A3 (fr) 2010-04-22

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