US20090235573A1 - Methods of making hybrid fuel and fuel additives - Google Patents

Methods of making hybrid fuel and fuel additives Download PDF

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Publication number
US20090235573A1
US20090235573A1 US12/211,110 US21111008A US2009235573A1 US 20090235573 A1 US20090235573 A1 US 20090235573A1 US 21111008 A US21111008 A US 21111008A US 2009235573 A1 US2009235573 A1 US 2009235573A1
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US
United States
Prior art keywords
fuel
oil
oleic acid
hybrid fuel
hybrid
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Abandoned
Application number
US12/211,110
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English (en)
Inventor
Sui Xin Zhang
On Shun Wong
Zhaofeng Zhang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CORPORATE ENVIROABILITY HK Co Ltd
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CORPORATE ENVIROABILITY HK Co Ltd
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Assigned to CORPORATE ENVIROABILITY (HK) COMPANY LIMITED reassignment CORPORATE ENVIROABILITY (HK) COMPANY LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WONG, ON SHUN ANSON, ZHANG, SUI XIN, ZHANG, ZHAOFENG
Publication of US20090235573A1 publication Critical patent/US20090235573A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Definitions

  • the present invention generally relates to a liquid fuel. More particularly, the present invention relates to an environmental protection and energy saving hybrid fuel and fuel additive containing seawater, inexpensively recycled animal oil, vegetable oil and alcohol, in order to utilize renewable energy effectively to make nano-bio chemical fuel. The present invention further relates to a method of making the hybrid fuel and fuel additive.
  • the present invention aims to solve the problems discussed above, and provides a hybrid fuel and fuel additive made from cheap seawater, recycled animal oil and vegetable oil and alcohol mixed with gasoline and diesel, of which the prices increase day by day.
  • the hybrid fuel meets the requirements of energy efficiency and emission reduction, saves or partially replaces the petrochemical energy and greatly reduces the release of pollutant such as CO 2 (carbon dioxide), NO X (nitrogen oxide) and PM (particles and suspended dust particles), thus reduces the negative impact, such as green house effects, caused by the petrochemical fuel.
  • the present invention provides a hybrid fuel and fuel additive comprising seawater, animal oil, vegetable oil and alcohol.
  • the hybrid fuel or additive contains the following components by percentage weights:
  • the hybrid fuel or additive preferably contains the following components by percentage weights:
  • the surfactant comprises one or more components selected from a group consisting of fatty acid, fatty acid methyl ester, sodium alkylbenzene sulfonate, triethanolamine, SPAN 80 and aqueous ammonia.
  • the fatty acid comprises vegetable oleic acid, animal oleic acid or any combination thereof.
  • the vegetable oleic acid is made by acidizing coconut oil, rapeseed oil, palm oil, algae oil or Jatropha curcas oil.
  • the animal oleic acid is made by acidizing lard, butter or mutton oil.
  • the solubilizer is made by mixing ethanol and methanol at weight ratio of 1:1.
  • the vegetable oleic acid and the animal oleic acid are made by acidizing recycled animal oil and vegetable oil respectively.
  • the hybrid fuel and fuel additive comprise particles of microemulsion with a diameter of 100 nm ⁇ 500 nm.
  • the combustion promoter comprises one or more components selected from a group consisting of gasoline, diesel, cerium-containing nano rare earth, oil soluble nano ferrocene, calcium naphthenate, ferric naphthenate and cerium-containing rare earth naphthenate.
  • the present invention further provides a method of making the hybrid fuel and fuel additive, comprising:
  • the hybrid fuel and fuel additive of the present invention can be used as fuels for vehicles, power plants, industries and households, and can also be used as fuel additive separately.
  • the contribution of the present invention lies in its conformity to the need of new energy development in the world.
  • the present invention creates a new environmental protection and energy saving composite fuel.
  • the composite fuel can partially replace gasoline, diesel and other fuels, and can save 5% to 30% of the petrochemical energy and 65% of the diesel fuel.
  • the use of the composite fuel can achieve a 30% to 65% reduction in vehicle emission and cut the pollution of CO 2 , NO x , PM, etc.
  • the present invention can also be used as fuels for power plants, industries (boiler, etc.) and households, or used as fuel additive.
  • the hybrid fuel and fuel additive in present invention is a composite fuel which can be used directly as a fuel and can also be used as additive to gasoline, diesel or other fuels.
  • the embodiment provides an example of preparing the hybrid fuel and fuel additive, which is a micro-emulsified bio-diesel hybrid fuel.
  • the embodiment provides another example of preparing the hybrid fuel and fuel additive, which is a micro-emulsified bio-gasoline hybrid fuel.
  • the surfactant emulsion of the hybrid fuel and fuel additive has a good dispersant effect and can be dispersed thoroughly in the fuel to be burned.
  • the combustion promoter is capable of catalyzing and improving the combustion. Since the microemulsion included in the hybrid fuel and fuel additive contains seawater, animal oil and vegetable oil, a micro-explosion phenomenon within emulsified oil can be induced due to water contained therein during combustion, which prevents accumulated carbon residue and jam, and promotes clean combustion.
  • the hybrid fuel and fuel additive of the present invention can be used as fuels for vehicles, power plants, industries and households. It can be used separately as a fuel, and can also be used as an additive to gasoline or diesel. When using as an additive, add the additive to the oil tank first then fill the tank with gasoline or diesel.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
US12/211,110 2008-03-20 2008-09-16 Methods of making hybrid fuel and fuel additives Abandoned US20090235573A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2008100863496A CN101250447B (zh) 2008-03-20 2008-03-20 环保节能的含海水的乳化生物汽油或柴油的混合燃料
CN200810086349.6 2008-03-20

Publications (1)

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US20090235573A1 true US20090235573A1 (en) 2009-09-24

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Country Status (2)

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US (1) US20090235573A1 (zh)
CN (1) CN101250447B (zh)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127477A (zh) * 2010-01-13 2011-07-20 咸阳天成石化节能科技有限公司 一种石油化工助剂及其制备方法
US20120066962A1 (en) * 2009-01-30 2012-03-22 Susumu Inazawa Emulsifier for water-in-oil emulsion fuel
CN102743987A (zh) * 2012-07-31 2012-10-24 林益煌 纳米高效能燃油的制造方法
US9167668B1 (en) * 2014-09-02 2015-10-20 The Southern Company Systems and methods for commissioning lighting fixtures
CN106336917A (zh) * 2016-08-25 2017-01-18 桂林九马新动力科技有限公司 一种节能汽油及其制备方法
CN114806654A (zh) * 2022-05-06 2022-07-29 张士宁 一种低温燃烧净化剂

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260554B (zh) * 2010-05-27 2014-08-27 浙江中赢节能环保科技有限公司 微乳化生物柴油及其制备工艺
CN103113943B (zh) * 2013-01-24 2015-09-02 九峰能源科技（上海）有限公司 用于驱动内燃机或能量生产设备的乳化燃料
CN104178359A (zh) * 2014-07-22 2014-12-03 郭俊旺 一种动植物油脂微乳液的反应制备方法
CN104357101B (zh) * 2014-11-06 2016-10-26 金景达(北京)环保动力科技有限公司 一种高效稳定生物柴油复合燃料
CN108659896A (zh) * 2017-04-01 2018-10-16 深圳华联世纪生物工程股份有限公司 一种提高生物醇基燃料热值配方及新方法
CN109868166B (zh) * 2019-03-12 2020-11-03 南京科技职业学院 一种复合柴油添加剂

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4451265A (en) * 1981-04-21 1984-05-29 The United States Of America As Represented By The Secretary Of Agriculture Diesel fuel-aqueous alcohol microemulsions
US4526586A (en) * 1982-09-24 1985-07-02 The United States Of America As Represented By The Secretary Of Agriculture Microemulsions from vegetable oil and aqueous alcohol with 1-butanol surfactant as alternative fuel for diesel engines

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5087267A (en) * 1989-04-04 1992-02-11 Atsushi Nasu Fuel additives
KR100491936B1 (ko) * 2002-10-14 2005-05-30 박길원 연료유첨가조성물의 제조방법

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4451265A (en) * 1981-04-21 1984-05-29 The United States Of America As Represented By The Secretary Of Agriculture Diesel fuel-aqueous alcohol microemulsions
US4526586A (en) * 1982-09-24 1985-07-02 The United States Of America As Represented By The Secretary Of Agriculture Microemulsions from vegetable oil and aqueous alcohol with 1-butanol surfactant as alternative fuel for diesel engines

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120066962A1 (en) * 2009-01-30 2012-03-22 Susumu Inazawa Emulsifier for water-in-oil emulsion fuel
US20140075826A1 (en) * 2009-01-30 2014-03-20 Susumu Inazawa Emulsifier for water-in-oil emulsion fuel
US8882860B2 (en) * 2009-01-30 2014-11-11 Susumu Inazawa Emulsifier for water-in-oil emulsion fuel
CN102127477A (zh) * 2010-01-13 2011-07-20 咸阳天成石化节能科技有限公司 一种石油化工助剂及其制备方法
CN102743987A (zh) * 2012-07-31 2012-10-24 林益煌 纳米高效能燃油的制造方法
US9167668B1 (en) * 2014-09-02 2015-10-20 The Southern Company Systems and methods for commissioning lighting fixtures
CN106336917A (zh) * 2016-08-25 2017-01-18 桂林九马新动力科技有限公司 一种节能汽油及其制备方法
CN114806654A (zh) * 2022-05-06 2022-07-29 张士宁 一种低温燃烧净化剂

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Publication number Publication date
CN101250447A (zh) 2008-08-27
CN101250447B (zh) 2012-07-04

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Owner name: CORPORATE ENVIROABILITY (HK) COMPANY LIMITED, CHIN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ZHANG, SUI XIN;WONG, ON SHUN ANSON;ZHANG, ZHAOFENG;REEL/FRAME:021546/0250

Effective date: 20080801

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION