CN108659896A - 一种提高生物醇基燃料热值配方及新方法 - Google Patents

一种提高生物醇基燃料热值配方及新方法 Download PDF

Info

Publication number
CN108659896A
CN108659896A CN201710223761.7A CN201710223761A CN108659896A CN 108659896 A CN108659896 A CN 108659896A CN 201710223761 A CN201710223761 A CN 201710223761A CN 108659896 A CN108659896 A CN 108659896A
Authority
CN
China
Prior art keywords
raw material
accounts
biological alcohol
oil
based fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710223761.7A
Other languages
English (en)
Inventor
罗卫城
张强
刘香亭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Original Assignee
Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Hualian Century Bioengineering Ltd By Share Ltd filed Critical Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Priority to CN201710223761.7A priority Critical patent/CN108659896A/zh
Publication of CN108659896A publication Critical patent/CN108659896A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
    • C10L2250/08—Emulsion details
    • C10L2250/086—Microemulsion or nanoemulsion
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

本发明涉及一种提高生物醇基燃料热值配方及新方法。配制分四步进行，首先准备好原料。配方成份分别占原料总重量百分数，生物醇基燃料占50％；180#重油占45％，添加剂占5％，其中，油酸占2％，三乙醇胺、丙酮、正丁醇各占1％。其次选择电磁加热设备，将准备好的原料分别加热至80℃。并使其液态颗粒呈纳米化状态。再次将纳米化的原料先后加入到罐式搅拌剪切机中，搅拌和高速剪切20分钟。最后将剪切合成燃料油用泵输入到静态反应罐，静态反应24小时，即可成为稳定热值高的清洁燃料油。本发明配制的清洁燃料油热值高，成本低，热效率高，油耗省，减排效果显著，性价比明显优于目前市场推出的各种燃料油。

Description

一种提高生物醇基燃料热值配方及新方法
技术领域 本发明涉及提高燃油热值技术领域，特别涉及一种提高生物醇基燃料热值配方及新方法。
背景技术 用有机污水转化的生物醇基燃料热值低，必须提高热值才能满足工业锅炉对燃料出力和火焰温度的要求。采取传统的乳化法和调和法需要往生物醇基燃料里加入大量价格昂贵的乳化剂、添加剂及石化燃油，才能制成稳定高热值的燃料油，满足工业锅炉和国标的要求。但是，合成油品价格高，客户不接受。为克服上述不足，经过三年的实验研究，研发成功一种提高生物醇基燃料热值配方及新方法。用本发明制成的清洁燃料油热值高，成本低，热效率高，油耗省，减排效果显著，性价比明显优于目前市场推出的各种燃料油。产品已应用于国家能源局立项的宁波奉化生物醇基燃料实验工程。
发明内容 本发明由4个步骤内容组成。首先将占原料总质量50-60％的生物醇基燃料；40-50％的重质油，5-10％的添加剂，按要求数量准备好。其次，将三种原料分别在具有对水和油品加热和使液体颗粒呈小分子化功能的设备加热至60℃-80℃。再次，将加热和小分子化的配料先后加入到罐式搅拌剪切机中，搅拌和高速剪切10-20分钟。最后，将合成的燃料油用泵输入静态反应罐，经过12-24小时静态反应，便形成稳定高热值的清洁燃料油。
具体实施方式
实施例
配制高热值清洁燃料油重量为100kg。其中，生物醇基燃料占50％，重量为50kg，180#重油45％，重量为45kg，添加剂占5％，重量5Kg，包括油酸2％，重量为2kg，三乙醇胺1％，重量为1kg，丙酮1％，重量为1kg，正丁醇1％，重量为1kg。
配制步骤
首先，按上述配方要求准备好原料待用。
其次，选择电磁加热设备，分别加热配制的生物醇基燃料，180#重油及合成的添加剂，包括油酸、三乙醇胺、丙酮、正丁醇，加热至80℃。依靠加热和电磁波高频强辐射作用，切断水、油及醇的大分子团，使其液态颗粒呈纳米化状态。
再次，将形成纳米化液态颗粒的原料加入到罐式搅拌剪切机中，搅拌和高速剪切20分钟。
第四步，将剪切合成的燃料油用泵输入到静态反应罐，静态反应24小时，即可成为稳定热值高的清洁燃料油。

Claims (5)

1.本发明涉及一种提高生物醇基燃料热值配方及新方法。配方成份分别占原料总重量百分数，生物醇基燃料占50％；180#重油占45％，添加剂占5％。其中，油酸占2％，三乙醇胺、丙酮、正丁醇各占1％。
2.根据权利要求1所述，其特征在于，其配制步骤分四步进行。首先将占原料总重量50％的生物醇基燃料；45％的180#重油，5％的添加剂，按要求数量准备好。
3.根据权利要求1所述，其特征在于，将三种原料分别在具有对水和油品加热和使液体颗粒呈小分子化功能的设备加热至80℃。
4.根据权利要求1所述，其特征在于，将加热小分子化的配料先后加入到罐式搅拌剪切机中，搅拌和高速剪切20分钟。
5.根据权利要求1所述，其特征在于，将合成的燃料油用泵输送到静态反应罐，经过24小时静态反应，便形成稳定高热值的清洁燃料油。
CN201710223761.7A 2017-04-01 2017-04-01 一种提高生物醇基燃料热值配方及新方法 Pending CN108659896A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710223761.7A CN108659896A (zh) 2017-04-01 2017-04-01 一种提高生物醇基燃料热值配方及新方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710223761.7A CN108659896A (zh) 2017-04-01 2017-04-01 一种提高生物醇基燃料热值配方及新方法

Publications (1)

Publication Number Publication Date
CN108659896A true CN108659896A (zh) 2018-10-16

Family

ID=63784945

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710223761.7A Pending CN108659896A (zh) 2017-04-01 2017-04-01 一种提高生物醇基燃料热值配方及新方法

Country Status (1)

Country Link
CN (1) CN108659896A (zh)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101153226A (zh) * 2006-09-26 2008-04-02 周卫国 一种由渣油及重油乳化成的高速柴油机燃料及其制备方法
CN101250447A (zh) * 2008-03-20 2008-08-27 企业环保科技（香港）有限公司 环保节能的含海水及动、植物油、醇的微乳化生物汽油、柴油混合燃料及添加剂
CN101392204A (zh) * 2008-10-15 2009-03-25 赵熙汉 清洁复合柴油车用燃料
CN101475849A (zh) * 2008-01-05 2009-07-08 罗文成 高热值无烟无味醇基燃料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101153226A (zh) * 2006-09-26 2008-04-02 周卫国 一种由渣油及重油乳化成的高速柴油机燃料及其制备方法
CN101475849A (zh) * 2008-01-05 2009-07-08 罗文成 高热值无烟无味醇基燃料及其制备方法
CN101250447A (zh) * 2008-03-20 2008-08-27 企业环保科技（香港）有限公司 环保节能的含海水及动、植物油、醇的微乳化生物汽油、柴油混合燃料及添加剂
CN101392204A (zh) * 2008-10-15 2009-03-25 赵熙汉 清洁复合柴油车用燃料

Similar Documents

Publication Publication Date Title
Gole et al. Intensification of synthesis of biodiesel from nonedible oils using sonochemical reactors
Naveenkumar et al. Biodiesel production from Calophyllum inophyllum oil using zinc doped calcium oxide (Plaster of Paris) nanocatalyst
Tran Fast hydrothermal liquefaction for production of chemicals and biofuels from wet biomass–The need to develop a plug-flow reactor
Likozar et al. Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics and mass transfer based on fatty acid composition
Hajinezhad et al. Biodiesel production from Norouzak (Salvia lerifolia) seeds as an indigenous source of bio fuel in Iran using ultrasound
Levine et al. Biodiesel production from wet algal biomass through in situ lipid hydrolysis and supercritical transesterification
Lee et al. Integration of reactive extraction with supercritical fluids for process intensification of biodiesel production: Prospects and recent advances
Battista et al. Enzymatic hydrolysis at high dry matter content: The influence of the substrates’ physical properties and of loading strategies on mixing and energetic consumption
CN104211549B (zh) 混装乳化炸药的制备方法
Suranani et al. Process intensification using corning® advanced-flow™ reactor for continuous flow synthesis of biodiesel from fresh oil and used cooking oil
Frascari et al. A pilot-scale study of alkali-catalyzed sunflower oil transesterification with static mixing and with mechanical agitation
Jie et al. Biodiesel Pilot Plant System and Conversion Technology of Multiple Feedstocks
Bitire et al. Synthesis of beta-tricalcium phosphate catalyst from Herring fishbone for the transesterification of parsley seed oil
CN108659896A (zh) 一种提高生物醇基燃料热值配方及新方法
CN105018178A (zh) 一种利用糠醛渣制备高效植物颗粒及其制备工艺
Supardan et al. Effect of co-solvent addition on glycerolysis of waste cooking oil.
Anyanwu et al. A design algorithm for batch stirred tank transesterification reactors
CN202844895U (zh) 节能环保燃料油调制装置
Mirus et al. A short review on biodiesel production and costing
KR20170099331A (ko) 미세조류로부터 무촉매 에스터화반응을 이용한 바이오디젤 제조방법
CN103721702B (zh) 一种生产生物柴油用的催化剂的制备方法
Muley et al. Scale-up of a continuous microwave-assisted transesterification process of soybean oil for biodiesel production
Olutoye et al. Synthesis of fatty acid ethyl ester from chicken fat using ZnO/SiO2 heterogeneous catalyst
Gaona et al. The effect of fed-batch operation and rotational speed on high-solids enzymatic hydrolysis of hardwood substrates
CN101215482A (zh) 醇烃柴油机用液体燃料及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181016