US20080142125A1 - Coated Steel Sheet or Strip - Google Patents

Coated Steel Sheet or Strip Download PDF

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Publication number
US20080142125A1
US20080142125A1 US11/816,799 US81679906A US2008142125A1 US 20080142125 A1 US20080142125 A1 US 20080142125A1 US 81679906 A US81679906 A US 81679906A US 2008142125 A1 US2008142125 A1 US 2008142125A1
Authority
US
United States
Prior art keywords
weight
coating
strip
galvanizing bath
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/816,799
Other languages
English (en)
Inventor
Manfred Meurer
Sabine Zeizinger
Rudolf Schoenenberg
Wilhelm Warnecke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Steel AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp Steel AG filed Critical ThyssenKrupp Steel AG
Assigned to THYSSENKRUPP STEEL AG reassignment THYSSENKRUPP STEEL AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SCHOENENBERG, RUDOLF, ZEIZINGER, SABINE, MEURER, MANFRED, WARNECKE, WILHELM
Publication of US20080142125A1 publication Critical patent/US20080142125A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0222Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/16Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
    • C23C2/18Removing excess of molten coatings from elongated material
    • C23C2/20Strips; Plates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/30Fluxes or coverings on molten baths
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/38Wires; Tubes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips

Definitions

  • the invention relates to a coated steel sheet or strip, with a ground coating made of steel, onto at least one upper side of which a zinc coating is applied by hot-dip galvanizing.
  • the zinc coating ensures a high degree of corrosion resistance.
  • a conventionally alloyed zinc coating in a spray test according to DIN 50021 carried out on a bright, unpainted specimen, with a coating of 25 g/m 2 , red rust already occurs after 24 hours, while with a coating of 70 g/m red rust does not occur until after 120 hours.
  • the thickness of the coating required with the prior art for adequate corrosion resistance does, however, incur problems with regard to weldability. This applies in particular if the intention is that through-welding is to be produced by means of laser welding in the overlap joint without any joint gaps at high welding speeds, such as is required in the motor vehicle chassis construction sector or the domestic engineering sector.
  • the seam produced by such welding should be free of passage holes, should be largely free of cratering, and should not have any open pores.
  • the invention in one embodiment, features a flat steel product which possesses an optimum combination of high corrosion resistance and optimum weldability and which is particularly well-suited for use as a material for motor vehicle chassis construction or for the production of domestic appliances.
  • the invention features a coated steel sheet or strip, which has a ground coating made of steel, onto at least one upper side of which a coating is applied by hot-dip galvanizing, the coating being formed from a melt consisting of 0.05-0.30% by weight Al and 0.2-2.0% by weight Mg, the remainder being zinc and unavoidable impurities, and on each side, with a coating thickness of a maximum of 3.5 ⁇ m and a coating weight of a maximum of 25 g/m 2 , guarantees that the steel sheet, in the salt spray mist test carried out in accordance with DIN 50021-SS, shows the first formation of red rust at the earliest after 250 hours.
  • a hot-dip galvanized flat steel product according to the invention possesses surprisingly good corrosion resistance with a coating weight minimised in relation to the prior art coating weight of a maximum of 25 g/m 2 on each side.
  • the low coating weight and the low thickness of the coating associated with this, of a maximum of 3.5 ⁇ m on each side, in combination with the high corrosion resistance, makes sheet or strip according to the invention particularly well-suited for the production of components which are manufactured by the welding of individual sheet elements. Accordingly, with steel sheets produced in accordance with the invention, elements for motor vehicle chassis or domestic appliance technology can be manufactured in particular, in that the individual sheet components formed from sheet or strip according to the invention can be welded to one another by laser beam welding at high welding speeds economically and with optimum results.
  • the corrosion resistance according to the invention is determined on the basis of a salt spray mist test in accordance with DIN 50021-SS in a corrosion short-term test process on bright unpainted steel sheet, in which a neutral 5% NaCl solution, as the corrosive agent, is sprayed continuously at a temperature of 35 ⁇ 2° C. in a chamber.
  • the steel sheet samples are in this situation placed in the chamber at an angle of inclination to the horizontal of 65 to 75°.
  • the magnesium content in the melt intended for the coating remains essentially unchanged in the coating.
  • the Al content of the coating, in the finished steel strip according to the invention is as a rule 1.8 to 3.2 and in particular 2 to 3 times higher than in the melt.
  • An optimum corrosion protection is attained when the coating has an Mg content of 0.4-1.0% by weight, in particular at least 0.5% by weight.
  • the melt contains preferably less than 0.15% by weight of aluminium.
  • Al contents of the melt which are suitable for standard practice are in this case in the range of 0.12-0.14% by weight.
  • the Al content of the melt is preferably at least 0.15% by weight.
  • a further surprising property which makes a flat product according to the invention particularly suitable for use in chassis construction becomes apparent when such a sheet or strip is painted. Accordingly, a mandrel bend test carried out on the basis of DIN EN ISO 6860 for sheets or strips according to the invention at room temperature and at ⁇ 20° C. produces good paint adherence capacity. In particular, at a temperature of ⁇ 20° C. there is no indication of paint flaking or of flaking of the coating from the base material.
  • a full paint structure was applied onto a steel sheet specimen after alkaline cleaning and phosphating, this structure comprising a 20 ⁇ m thick cathodic dip paint coating, a 32 ⁇ m thick filler paint coating applied onto this and a 40 ⁇ m thick base coating.
  • the bending carried out over the conical mandrel did not lead to any detachment of the paint coating at room temperature or at ⁇ 20° C.
  • sheets or strips according to the invention have outstandingly good resistance to stone impact.
  • stone impact test carried out in accordance with DIN 65996-1B it was possible to demonstrate that, with steel sheets according to the invention, stone impact did not cause any flaking of the coating from the base coat.
  • a fine steel strip is subjected to a continuous hot-dip galvanizing process in a galvanizing plant operating at a strip speed of a typical 60 to 150 m/min.
  • the sheet or strip to be galvanized is firstly annealed in a furnace, such as a DFF furnace (Direct Fired Furnace) or, preferably, an RTF furnace (Radiant Type Furnace).
  • a furnace such as a DFF furnace (Direct Fired Furnace) or, preferably, an RTF furnace (Radiant Type Furnace).
  • the sheet or strip runs through the reduction furnace section, in which it is held under a protective gas atmosphere with 3.5-75% hydrogen.
  • the temperatures attained in the course of the annealing lie in the range from 720-850° C.
  • the sheet or strip annealed in this way is then conducted via what is referred to as a nozzle, with the exclusion of air, into the zinc bath, which is formed from a melt containing 0.05-0.30% by weight Al and 0.2-2.0% by weight Mg, in particular 0.4-1.0% by weight and 0.5-1.0% by weight respectively, the remainder being zinc and unavoidable impurities.
  • the thickness of the coating is restricted in an inherently known manner by means of stripper nozzles to a value of a maximum of 3.5 ⁇ m on each side, with the result that, with the flat product obtained according to the invention, the coating weight is restricted to a maximum of 25 g/m 2 per side.
  • an inert gas flow can be derived from the stripper nozzles which are used to adjust the thickness of the coating or can be supplied from separate nozzles, which distribute the inert gas in mist fashion over the surface of the bath.
  • the entire melt bath can be surrounded by a housing enclosure, in which an inert atmosphere is maintained. Especially suitable as the inert gas for this purpose is nitrogen.
  • the slag formation can also be reduced by adjusting the bath temperature to a range of 380-450° C.
  • the temperature of the strip can be restricted on immersion to 360-500° C. in order in particular to minimise the inclination to oxidise in the immersion area.
  • the coated strip After emerging from the melt bath the coated strip is cooled at a cooling speed of at least 10 K/s.
  • the coated is likewise subjected in-line to subsequent heating in the temperature range of 300-600° C., either a redistribution takes place inside the ZnMg coating or through-alloying is achieved into a ZnFeMg coating.
  • the melts used to produce such a coating preferably have an Al content of less than 0.15% by weight, and in particular 0.12-0.14% by weight.
  • the steel strip annealed in this way is then cooled, such that it is immersed at a melt bath immersion temperature of 465° C. into the melt bath, contained in a housing enclosure under a protective gas atmosphere containing a maximum of 10 ppm oxygen.
  • the melt bath consisted of a Zn melt, which as well as unavoidable impurities (e.g. Fe contents, which are drawn into the melt bath by the strip), contained 0.2% by weight Al, and 0.8% by weight Mg. Immersion time was two seconds.
  • the coating thickness on the steel strip applied on both sides was adjusted, while still inside the melt bath housing enclosure, by means of stripper nozzles, likewise arranged in the housing enclosure, to a coating thickness of 3 ⁇ m on each side (corresponding to a coating weight of 21 g/m 2 per side).
  • the stripping was likewise carried out by means of nitrogen gas.
  • the melt bath-coated steel strip obtained had Ra values of 1.8 ⁇ m, with Pc values of 46 cm ⁇ 1 determined in accordance with the StahlEisen Test Datasheet SEP 1940.
  • the ball impact hardness test in accordance with the StahlEisen Test Datasheet SEP 1931 was carried out on specimens taken from the finished coated steel strip in order to determine the adherence of the coating and its formability. The result could be classified as Stage 1, which corresponds to good adherence and likewise good ability to forming.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating With Molten Metal (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
US11/816,799 2005-02-22 2006-02-15 Coated Steel Sheet or Strip Abandoned US20080142125A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05003762A EP1693477A1 (de) 2005-02-22 2005-02-22 Beschichtetes Stahlblech oder -band
EP05003762.1 2005-02-22
PCT/EP2006/050955 WO2006089854A1 (de) 2005-02-22 2006-02-15 Beschichtetes stahlblech oder -band

Publications (1)

Publication Number Publication Date
US20080142125A1 true US20080142125A1 (en) 2008-06-19

Family

ID=34933875

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/816,799 Abandoned US20080142125A1 (en) 2005-02-22 2006-02-15 Coated Steel Sheet or Strip

Country Status (9)

Country Link
US (1) US20080142125A1 (ko)
EP (2) EP1693477A1 (ko)
JP (1) JP5270172B2 (ko)
KR (1) KR101268570B1 (ko)
CN (1) CN101128614B (ko)
AU (1) AU2006218005B2 (ko)
CA (1) CA2596825C (ko)
ES (1) ES2650741T3 (ko)
WO (1) WO2006089854A1 (ko)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100024925A1 (en) * 2006-05-15 2010-02-04 Thyssenkrupp Steel Ag Steel Sheet Product Provided with an Anticorrosion Coating and Process for Producing It
US20100055344A1 (en) * 2006-05-15 2010-03-04 Thyssenkrupp Steel Ag Process for Producing a Sheet Steel Product Coated with an Anticorrosion System
WO2014066584A1 (en) * 2012-10-24 2014-05-01 Magna International Inc. Laser metal deposition cladding of weld seams in automotive parts
GB2521363A (en) * 2013-12-17 2015-06-24 Eaton Ind Netherlands Bv Method for producing a housing for medium voltage switchgear and such a housing
US20150184275A1 (en) * 2012-08-01 2015-07-02 Dongkuk Steel Mill Co., Ltd. Method and apparatus for producing zinc-aluminum alloy-coated steel sheet with superior workability and corrosion resistance
US9279175B2 (en) 2010-08-31 2016-03-08 Thyssenkrupp Steel Europe Ag Method for hot dip coating a flat steel product
US9744743B2 (en) 2012-12-26 2017-08-29 Posco Zn—Mg alloy plated steel sheet, and method for manufacturing same
US20180002797A1 (en) * 2014-12-24 2018-01-04 Posco Zinc alloy plated steel material having excellent weldability and processed-part corrosion resistance and method of manufacturing same
US9863029B2 (en) * 2012-08-01 2018-01-09 Dongkuk Steel Mill Co., Ltd. Apparatus for forming nitrogen cloud to produce hot dip coated steel sheet
EP3332048B1 (de) * 2015-08-06 2020-02-19 ThyssenKrupp Steel Europe AG Verfahren zum erzeugen eines zink-magnesium-galvannealed-schmelztauchüberzugs und mit einem solchen überzug versehenes stahlflachprodukt
US20210292915A1 (en) * 2018-07-27 2021-09-23 Bayerische Motoren Werke Aktiengesellschaft Method for Coating a Motor Vehicle Bodyshell Part, and Motor Vehicle Bodyshell Part
US11332816B2 (en) 2017-12-26 2022-05-17 Posco Zinc alloy plated steel material having excellent surface quality and corrosion resistance
US11371128B2 (en) 2009-05-14 2022-06-28 Arcelormittal Coated metal band having an improved appearance

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007048504B4 (de) * 2007-10-10 2013-11-07 Voestalpine Stahl Gmbh Korrosionsschutzbeschichtung für Stahlbleche und Verfahren zum Konditionieren einer Korrosionsschutzbeschichtung
EP2055799A1 (de) * 2007-11-05 2009-05-06 ThyssenKrupp Steel AG Stahlflachprodukt mit einem vor Korrosion schützenden metallischen Überzug und Verfahren zum Erzeugen eines vor Korrosion schützenden metallischen Zn-Mg Überzugs auf einem Stahlflachprodukt
EP2141255B1 (en) * 2008-07-04 2020-03-18 Volvo Car Corporation Improved corrosion inhibiting structure
DE102011051731B4 (de) 2011-07-11 2013-01-24 Thyssenkrupp Steel Europe Ag Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts
DE102012101018B3 (de) 2012-02-08 2013-03-14 Thyssenkrupp Nirosta Gmbh Verfahren zum Schmelztauchbeschichten eines Stahlflachprodukts
EP2821520B1 (de) 2013-07-03 2020-11-11 ThyssenKrupp Steel Europe AG Verfahren zum beschichten von stahlflachprodukten mit einer metallischen schutzschicht
CN108018513A (zh) * 2016-10-28 2018-05-11 宝山钢铁股份有限公司 一种热浸镀锌铝镁镀层钢板及其制造方法
DE102019215050B4 (de) * 2019-09-30 2023-09-07 Thyssenkrupp Steel Europe Ag Verfahren zum Herstellen einer Laserlötverbindung zwischen beschichteten Stahlblechbauteilen
DE102019217912A1 (de) * 2019-11-20 2021-05-20 Volkswagen Aktiengesellschaft Verfahren zum Laserstrahllöten

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US4369211A (en) * 1980-04-25 1983-01-18 Nippon Steel Corporation Process for producing a hot dip galvanized steel strip
US5433796A (en) * 1991-12-06 1995-07-18 Kawasaki Steel Corporation Method for preparing galvanized steel strip having minimal uncoated defects

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Publication number Priority date Publication date Assignee Title
US4057424A (en) * 1975-06-13 1977-11-08 Italsider S.P.A. Zinc-based alloy for coating steel
US4369211A (en) * 1980-04-25 1983-01-18 Nippon Steel Corporation Process for producing a hot dip galvanized steel strip
US5433796A (en) * 1991-12-06 1995-07-18 Kawasaki Steel Corporation Method for preparing galvanized steel strip having minimal uncoated defects

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100055344A1 (en) * 2006-05-15 2010-03-04 Thyssenkrupp Steel Ag Process for Producing a Sheet Steel Product Coated with an Anticorrosion System
US8481172B2 (en) * 2006-05-15 2013-07-09 Thyssenkrupp Steel Ag Steel sheet product provided with an anticorrosion coating and process for producing it
US20100024925A1 (en) * 2006-05-15 2010-02-04 Thyssenkrupp Steel Ag Steel Sheet Product Provided with an Anticorrosion Coating and Process for Producing It
US11371128B2 (en) 2009-05-14 2022-06-28 Arcelormittal Coated metal band having an improved appearance
US9279175B2 (en) 2010-08-31 2016-03-08 Thyssenkrupp Steel Europe Ag Method for hot dip coating a flat steel product
US20150184275A1 (en) * 2012-08-01 2015-07-02 Dongkuk Steel Mill Co., Ltd. Method and apparatus for producing zinc-aluminum alloy-coated steel sheet with superior workability and corrosion resistance
US9863029B2 (en) * 2012-08-01 2018-01-09 Dongkuk Steel Mill Co., Ltd. Apparatus for forming nitrogen cloud to produce hot dip coated steel sheet
WO2014066584A1 (en) * 2012-10-24 2014-05-01 Magna International Inc. Laser metal deposition cladding of weld seams in automotive parts
US10279431B2 (en) 2012-10-24 2019-05-07 Magna International Inc. Laser metal deposition cladding of weld seams in automotive parts
US9744743B2 (en) 2012-12-26 2017-08-29 Posco Zn—Mg alloy plated steel sheet, and method for manufacturing same
GB2521363A (en) * 2013-12-17 2015-06-24 Eaton Ind Netherlands Bv Method for producing a housing for medium voltage switchgear and such a housing
US20180002797A1 (en) * 2014-12-24 2018-01-04 Posco Zinc alloy plated steel material having excellent weldability and processed-part corrosion resistance and method of manufacturing same
US10584407B2 (en) * 2014-12-24 2020-03-10 Posco Zinc alloy plated steel material having excellent weldability and processed-part corrosion resistance and method of manufacturing same
US11248287B2 (en) 2014-12-24 2022-02-15 Posco Zinc alloy plated steel material having excellent weldability and processed-part corrosion resistance
EP3332048B1 (de) * 2015-08-06 2020-02-19 ThyssenKrupp Steel Europe AG Verfahren zum erzeugen eines zink-magnesium-galvannealed-schmelztauchüberzugs und mit einem solchen überzug versehenes stahlflachprodukt
US11332816B2 (en) 2017-12-26 2022-05-17 Posco Zinc alloy plated steel material having excellent surface quality and corrosion resistance
US11643714B2 (en) 2017-12-26 2023-05-09 Posco Co., Ltd Method for manufacturing zinc alloy plated steel material having excellent surface quality and corrosion resistance
US20210292915A1 (en) * 2018-07-27 2021-09-23 Bayerische Motoren Werke Aktiengesellschaft Method for Coating a Motor Vehicle Bodyshell Part, and Motor Vehicle Bodyshell Part

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AU2006218005B2 (en) 2011-11-17
JP5270172B2 (ja) 2013-08-21
EP1851352A1 (de) 2007-11-07
JP2008531844A (ja) 2008-08-14
WO2006089854A1 (de) 2006-08-31
KR20070105371A (ko) 2007-10-30
CA2596825A1 (en) 2006-08-31
EP1851352B8 (de) 2017-10-18
CN101128614A (zh) 2008-02-20
CN101128614B (zh) 2012-07-18
CA2596825C (en) 2013-03-19
EP1693477A1 (de) 2006-08-23
ES2650741T3 (es) 2018-01-22
AU2006218005A1 (en) 2006-08-31
KR101268570B1 (ko) 2013-05-28
EP1851352B1 (de) 2017-09-06

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