US20060237315A1 - Gas sensor - Google Patents

Gas sensor Download PDF

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Publication number
US20060237315A1
US20060237315A1 US11/410,936 US41093606A US2006237315A1 US 20060237315 A1 US20060237315 A1 US 20060237315A1 US 41093606 A US41093606 A US 41093606A US 2006237315 A1 US2006237315 A1 US 2006237315A1
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US
United States
Prior art keywords
rear end
metal shell
detection element
sleeve
gas detection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US11/410,936
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English (en)
Inventor
Kouji Matsuo
Keiichi Noda
Yuichi Yamada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Niterra Co Ltd
Original Assignee
NGK Spark Plug Co Ltd
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Filing date
Publication date
Application filed by NGK Spark Plug Co Ltd filed Critical NGK Spark Plug Co Ltd
Assigned to NGK SPARK PLUG CO., LTD. reassignment NGK SPARK PLUG CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MATSUO, KOUJI, NODA, KEIICHI, YAMADA, YUICHI
Publication of US20060237315A1 publication Critical patent/US20060237315A1/en
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02D—CONTROLLING COMBUSTION ENGINES
    • F02D41/00—Electrical control of supply of combustible mixture or its constituents
    • F02D41/02—Circuit arrangements for generating control signals
    • F02D41/14—Introducing closed-loop corrections
    • F02D41/1438—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor
    • F02D41/1444—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor characterised by the characteristics of the combustion gases
    • F02D41/1454—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor characterised by the characteristics of the combustion gases the characteristics being an oxygen content or concentration or the air-fuel ratio
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/4062—Electrical connectors associated therewith
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • F01N11/007—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring oxygen or air concentration downstream of the exhaust apparatus

Definitions

  • the present invention relates to a gas sensor capable of measuring the concentration of a gas component, such as a component of an exhaust gas produced by an internal combustion engine, and more particularly to a gas sensor having a cylindrical sleeve and an axial hole formed therein for housing a gas detection element extending along an axial direction thereof.
  • gas sensors for measuring the concentration of a gas component, such as a component of an exhaust gas produced by an internal combustion engine.
  • gas sensors comprise: a cylindrical metal shell; a gas detection element located inside the metal shell and extending in a rod-like manner; a cylindrical sleeve holding and accommodating the gas detection element therein; and a connector attached at a rear end side of the gas detection element and electrically connected to an electrode terminal portion of the gas detection element.
  • Patent Document 1 A sectional view of a conventional gas sensor 900 is shown in FIG. 6 .
  • This gas sensor 900 includes: a cylindrical metal shell 910 ; a gas detection element 920 located inside the metal shell 910 and extending in a rod-like manner; a cylindrical sleeve 930 holding and accommodating the gas detection element 920 therein; and a connector 940 attached at a rear end side of the gas detection element 920 .
  • a protector 960 is fixed at a front end side of the metal shell 910 .
  • a first sleeve 970 surrounding the connector 940 , etc. is fixed at the rear end side of the metal shell 910
  • a second sleeve 975 is additionally fixed at the rear end side of the first sleeve 970 .
  • the gas detection element 920 projects from the metal shell 910 towards the front end side (lower part in the figure) and has a gas detection portion 921 , which can detect a gas concentration, in a front end portion 920 s thereof located inside the protector 960 . Moreover, the gas detection element 920 has four electrode terminal portions 923 in total, which are electrically connected to the gas detection portion 921 , etc., on an outer circumference face of a rear end portion 920 k projecting from the metal shell 910 towards the rear end side (upper part in the figure).
  • the sleeve 930 assumes a cylindrical form having an axial hole 931 , and most of the sleeve is located inside the metal shell 910 .
  • the axial hole 931 accommodates and holds the gas detection element 920 therein. Furthermore, a space between the gas detection element 920 and the sleeve 930 is filled with a glass sealing material 933 .
  • the connector 940 is largely opened toward the front end side and includes an indented portion 941 for accommodating a rear end portion 920 k of the gas detection element 920 .
  • Four connector terminal members 943 are provided, in resilient contact with and electrically connected to each electrode terminal portion 923 of the gas detection element 920 in a predetermined position of the indented portion 941 .
  • These connector terminal members 943 are electrically connected to leads 953 extending outside the gas sensor through the metal members 951 at the rear end side, respectively.
  • Patent Document 1 Japanese Patent Application Laid-open (kokai) No. 2001-188060
  • gas sensor 900 since sleeve 930 is in contact with a connector 940 , the heat from the sleeve 930 is directly conducted to the connector 940 when in use, thereby causing a temperature rise in the connector 940 . Thus, a rear end portion 920 k of the gas detection element 920 connected to the connector 940 also rises to a high temperature.
  • the gas detection element 920 has a solid electrolyte layer in which two or more via conductors electrically connected to electrode terminal portions 923 penetrate therethrough in the rear end portion 920 k , insulation performance of the solid electrolyte layer contained in the rear end portion 920 k will fail, resulting in a tendency to cause a leak between the via conductors. Consequently, gas concentration may not be accurately detected.
  • the present invention has been accomplished so as to solve the above problem, and an object of the invention is to provide a gas sensor capable of preventing leakage between via conductors that are provided in a rear end portion of the gas detection element.
  • a gas sensor comprising: a cylindrical metal shell; a gas detection element including a solid electrolyte layer, a front end portion of the gas detection element projecting from a front end portion of the metal shell and including a gas detection portion, an intermediate portion located inside the metal shell, and a rear end portion projecting from a rear end portion of the metal shell and including a plurality of electrode terminal portions and a plurality of via conductors electrically connected to corresponding electrode terminal portions; a cylindrical sleeve at least partially located inside the metal shell, and an axial hole penetrating through the sleeve and accommodating the gas detection element therein; a connector joined to the rear end portion of the gas detection element and spaced apart from the sleeve, the connector including a plurality of connector terminal portions electrically connected to corresponding electrode terminal portions.
  • the rear end portion of the gas detection element includes a plurality of via conductors electrically connected to the electrode terminal portion, however, the sleeve is isolated from the connector.
  • the heat from the sleeve is hardly conducted to the connector, thereby preventing a rise in temperature of the connector when in use. Consequently, leakage between via conductors due to high temperature is unlikely to occur, such that gas concentration may be more accurately detected than by a conventional gas sensor.
  • the gas sensor is not limited to any certain type of gas sensor, providing that the gas sensor satisfies the above-mentioned requirements.
  • the invention can be applied to a gas sensor, such as an oxygen sensor, an all range air-fuel ratio sensor and a NOx sensor.
  • the form of the gas detection element is not limited, providing that the above-mentioned requirements are satisfied.
  • the gas detection element can assume the form of a hollow-tube with a closed tip end or a plate-like shape or the like.
  • the via conductor is preferably formed so as to penetrate the solid electrolyte layer in the rear end portion and is not limited to any specific form.
  • the via conductor can assume a cylindrical form in which a through-hole penetrates therethrough or a pillar-shape in which a conductor is filled therein.
  • the invention provides a sensor according to (1) above, wherein the sleeve of the gas sensor further includes a projecting portion projecting from the rear end portion of the metal shell and supporting said gas sensor element.
  • an inner circumference face of the axial hole of the projection portion and an outer circumference face of the gas detection element may be in contact with each other or a small space may be left therebetween.
  • the invention provides a gas sensor according to (1) or (2) above, wherein the sleeve further includes: a large diameter portion having a larger diameter than that of the protruding portion and being located inside the metal shell, and a shoulder portion facing the rear side in the axial direction, and wherein the rear end portion of the metal shell is bent inwardly so as to crimp the shoulder portion.
  • the sleeve since the sleeve has a protruding portion at the rear end side projecting to the rear end side, the rear end side open end portion of the axial hole, which tends to serve as the initiating point of a crack, is isolated from the rear end portion (crimped portion) of the metal shell towards the rear end side. Therefore, when the rear end portion of the metal shell is bent and crimped, a large stress will not be imposed on the rear end side open end portion of the axial hole of the sleeve. Thus, the occurrence of a crack in the sleeve will be prevented.
  • the gas detection element preferably assumes the form of a plate, and the opening of the axial hole of the sleeve preferably assumes a rectangular form.
  • the sleeve has a rectangular-shaped opening with no protruding portion at the rear end side, a large tensile stress will be imposed on the corner of the opening. Consequently, a crack is likely to occur in the sleeve when the rear end portion of the metal shell is crimped.
  • the sleeve since the sleeve has a protruding portion at the rear end side, the rear end side open end portion of the axial hole where a crack tends to initiate is isolated from the rear end portion (crimped portion) of the metal shell to the rear side. Therefore, the occurrence of a crack in the sleeve will be prevented, because a large force will not be imposed on the rear end side open end portion of the axial hole 170 c when the rear end portion of the metal shell is crimped.
  • FIG. 1 is an external view showing a gas sensor according to a embodiment of the invention.
  • FIG. 2 is a sectional view showing a gas sensor according to the embodiment.
  • FIG. 3 is an exploded perspective view showing an insulating sleeve according to a gas sensor of the embodiment.
  • FIG. 4 is a decomposed perspective view showing a sensor element according to a gas sensor of the embodiment.
  • FIG. 5 is a perspective view showing an insulating sleeve according to comparative embodiment.
  • FIG. 6 is a sectional view showing a gas sensor according to the conventional art.
  • FIGS. 1 and 2 A gas sensor 100 of the present embodiment is illustrated in FIGS. 1 and 2 . Also, a ceramic sleeve (sleeve) 170 constituting the gas sensor 100 is illustrated in FIG. 3 . Further, a gas detection element 120 (see FIG. 2 ) constituting the gas sensor 100 is shown in detail in FIG. 4 .
  • a lower part of the figure will be called a front end side in an axial direction (hereinafter, also called a front end side), and an upper part of the figure will be called a rear end side in an axial direction (hereinafter, also called a rear end side).
  • the gas sensor 100 is attached to an exhaust pipe such that a front end side thereof is located inside the exhaust pipe.
  • the gas sensor 100 is an air-fuel ratio sensor for detecting oxygen concentration in an exhaust gas.
  • the gas sensor 100 includes a metal shell 110 assuming a cylindrical form as well as extending along an axis AX (axial direction); a plate-like gas detection element 120 extending in an axial direction and located inside the metal shell 110 ; a cylindrical ceramic sleeve 170 located inside the metal shell 110 and holding and accommodating the gas detection element 120 therein; and a connector 180 fixed at a rear end side of the gas detection element 120 and electrically connected thereto.
  • the gas sensor 100 further includes a protector 101 fixed at a front end side of the metal shell 110 ; a metal tube 103 fixed at a rear end side of the metal shell 110 ; a plurality of sensor lead wires 193 , 194 , 195 ; and a plurality of heater lead wires 196 , 197 extending outside the sensor.
  • the sensor detection element 120 includes an intermediate portion 120 t located inside the metal shell 110 , a front end portion 120 s projecting from the metal shell 110 to the front end side and a rear end portion 120 k projecting from the metal shell 110 to the rear end side. Also, a gas detection portion 121 capable of detecting oxygen concentration in an exhaust gas and a heater portion 123 capable of heating the gas detection portion 121 are formed at the front end portion 120 s .
  • three sensor electrode terminals (electrode terminal portions) 125 , 126 , 127 electrically connected to the gas detection portion 121 are formed in a first plate face 120 a of the rear end portion 120 k
  • two heater electrode terminals (electrode terminal portions) 128 , 129 electrically connected to the heater portion 123 are formed in a second plate face 120 b of the rear end portion 120 k.
  • the sensor detection element 120 is formed by laminating a plate-shaped detection element 130 extended in the axial direction (left to right direction in FIG. 4 ) and a plate-shaped heater element 160 also extending in the axial direction.
  • the left-hand side in the figure indicates the front end side and the right-hand side indicates the rear end side.
  • the detection element 130 is formed by laminating a protection layer 131 , a first solid electrolyte layer 137 , a spacer 145 and a second solid electrolyte layer 150 —all of which assume the form of a plate—in the order mentioned from the first plate face 120 a side to the second plate face 120 b side.
  • the protection layer 131 is mainly composed of alumina.
  • a porous body 132 is formed at the front end side of the protection layer 131 .
  • the three sensor electrode terminals 125 , 126 , 127 are formed perpendicular to the axial direction with a predetermined interval, near the rear end of a first face 131 a which constitutes the first plate face 120 a of the sensor detection element 120 .
  • the sensor electrode terminals 125 , 126 , 127 are electrically connected to three via conductors 133 , 134 , 135 formed and penetrating through the protection layer 131 near the rear end, as shown with a dotted line in FIG. 4 .
  • the first solid electrolyte layer 137 is composed mainly of zirconia which employs a solid solution of yttria as a stabilizing agent.
  • a first electrode portion 138 composed mainly of Pt, assuming a porous rectangular shape and located at the front end side, and a first lead portion 139 connected to the first electrode portion 138 as well as extending to the rear end side are formed on a first face 137 a (upper part in the figure) of a first solid electrolyte layer 137 .
  • the first lead portion 139 is electrically connected to the via conductor 133 formed in and penetrating through the protection layer 131 .
  • a second electrode portion 140 composed mainly of Pt, assuming a porous rectangular shape and located in the front end side, and a second lead portion 141 connected to the second electrode portion 140 as well as extending to the rear end side are formed on a second face 137 b (lower part in the figure) of the first solid electrolyte layer 137 .
  • a pair of via conductors 142 , 143 is formed near the rear end of the first solid electrolyte layer 137 and penetrates therethrough.
  • the via conductors 142 , 143 are electrically connected to the via conductors 134 , 135 formed in and penetrating through the protection layer 131 .
  • the second lead portion 141 is electrically connected to the via conductor 142 formed in and penetrating through the first solid electrolyte layer 137 .
  • a spacer 145 is composed mainly of alumina and includes a rectangular opening 145 c at the front end side.
  • the opening 145 c serves as a measurement gas chamber formed by the spacer 145 sandwiched between the first solid electrolyte layer 137 and the second solid electrolyte layer 150 .
  • a part of both side walls of the opening 145 c is composed of a porous body 146 limiting the ventilation between the inside and outside of the opening 145 c .
  • the porous body 146 is made of porous alumina.
  • a pair of via conductors 147 , 148 is formed near the rear end of the spacer 145 .
  • the via conductor 147 is electrically connected to the second lead portion 141 .
  • the via conductor 148 is electrically connected to the via conductor 143 formed in and penetrating through the first solid electrolyte layer 137 .
  • a second solid electrolyte layer 150 is composed mainly of zirconia which employs a solid solution of yttria as a stabilizing agent.
  • a third electrode portion 151 composed mainly of Pt, located at the front end side and having a porous rectangular shape, and a third lead portion 152 connected to the third electrode portion 151 as well as extending to the rear end side are formed on a first face 150 a (upper part in the figure) of the second solid electrolyte layer 150 .
  • the third lead portion 152 is electrically connected to a via conductor 147 formed in and penetrating through the spacer 145 .
  • a fourth electrode portion 153 located at the front end side and assuming a porous rectangular shape, and a fourth lead portion 154 connected to the fourth electrode portion 153 as well as extending to the rear end side are formed on a second face 150 b (lower part in the figure) of the second solid electrolyte layer 150 .
  • a via conductor 155 is formed near the rear end of the second solid electrolyte layer 150 and penetrates therethrough. The via conductor 155 is electrically connected to the fourth lead portion 154 and the via conductor 148 formed in and penetrating through the spacer 145 .
  • the heater element 160 is formed by laminating a first insulating layer 161 and a second insulating layer 162 , both of which are made of alumina and assume the form of a plate, in the order mentioned from a first plate face 120 a side to a second plate face 120 b side.
  • a heating resistive body 163 composed mainly of Pt, assuming a zigzag form and located at the front end side, and heater lead portions 164 , 165 connected to both ends of the heating resistive body 163 respectively, as well as extending to the rear end side are formed between the first insulating layer 161 and the second insulating layer 162 .
  • a pair of via conductors 166 , 167 is formed near the rear end of the second insulating layer 162 and penetrates therethrough. Furthermore, the heater electrode terminals 128 , 129 are formed side by side in a direction perpendicular to the axis at near the rear end of a second face 162 b , which constitutes the second plate face 120 b of the sensor detection element 120 .
  • the heater electrode terminal 128 is electrically connected to the heater lead portion 164 through the via conductor 166 .
  • the heater electrode terminal 129 is electrically connected to the heater lead portion 165 through the via conductor 167 .
  • the cylindrical metal shell 110 extends in the axial direction in which a platform portion 111 projecting radially inward is formed. Also, a cylindrical ceramic holder 113 made of alumina, a first powder filling layer 114 made of talc powder, glass powder or the like, a second powder filling layer 115 which is also made of talc powder, glass powder or the like and the cylindrical ceramic sleeve 170 made of alumina are formed in the metal shell 110 in the order mentioned from the front end side to rear end side. Further, a cylindrical metal cup 116 is located in the metal shell 110 . Furthermore, a crimping ring 117 is located between the ceramic sleeve 170 and a rear end portion 110 k of the metal shell 110 .
  • the ceramic holder 113 is located at the front end side of the metal cup 116 and engages the platform portion 111 of the metal shell 110 through the metal cup 116 .
  • the gas detection element 120 penetrates through the ceramic holder 113 .
  • the whole portion of the first powder filling layer 114 and a part of the front end side of the second powder filling layer 115 are located in the metal cup 116 .
  • the ceramic sleeve 170 which is located in the rear end side of the second powder filling layer 115 , assumes a cylindrical form having an axial hole 170 c therein that extends along an axis AX and has a rectangular opening.
  • the ceramic sleeve 170 includes a front end portion 170 s ; a protruding portion 170 k extending beyond the metal shell 110 toward the rear end side; and a large diameter portion 170 t located between the front end portion 170 s and the protruding portion 170 k and having a diameter larger than that of the front end portion 170 s and the protruding portion 170 k.
  • the axial length of the protruding portion 170 k is 6 mm in this embodiment.
  • the axial length of the protruding portion 170 k is preferably set within a range from 2 mm to 10 mm.
  • the area of the rear end face of the protruding portion is 35 mm 2 in this embodiment.
  • the area of the rear end face of the protruding portion is preferably set within a range from 30 mm 2 to 50 mm 2 .
  • the ceramic sleeve 170 holds the plate-shaped gas detection element 120 such that the gas detection element 120 penetrates through the axial hole 170 c which assumes a rectangular form. That is, in the ceramic sleeve 170 , the front end portion 170 s , the large diameter portion 170 t as well as the protruding portion 170 k hold and support the gas detection element 120 such that the gas detection element 120 penetrates therethrough.
  • the larger diameter portion 170 t of the ceramic sleeve 170 has a shoulder 170 tm which faces the rear end side. Then, the ceramic sleeve 170 is fixed inside the metal shell 110 by bending the rear end portion 110 k of the metal shell 110 inwardly, and crimping it to the shoulder 170 tm of the larger diameter portion 170 t through a crimping ring 117 .
  • the protector 101 having a closed front end is fixed at the front end side of the metal shell 110 by laser welding so as to cover the front end portion 120 s of the gas detection element 120 projecting from the metal shell 110 .
  • the protector 101 has a plurality of feeding holes 101 c in predetermined positions which allow the exhaust gas to flow into protector 101 .
  • the cylindrical metal tube 103 is fixed at the rear end side of the metal shell 110 by laser welding.
  • the metal tube 103 includes a first portion 104 located in the front end side and having the largest diameter; a second portion 105 located to the rear of the first portion 104 and crimped in a radially inward direction; a third portion 106 located to the rear of the second portion 105 ; and a fourth portion 107 located to the rear of the third portion 106 , crimped in a radially inward direction and having the smallest diameter.
  • a connector 180 is placed inside the first portion 104 and extends to the third portion 106 .
  • the connector 180 is composed of: a separator 181 made of ceramic, three sensor lead frames (connector terminal portion) 182 , 183 , 184 and a pair of heater lead frames (connector terminal portion) 185 , 186 .
  • the separator 181 accommodates the sensor lead frames 182 , 183 , 184 and the heater lead frames 185 , 186 so that they do not contact one another (i.e., so that they are isolated from one another).
  • the connector 180 is mounted on the rear end side of the gas detection element 120 so as to isolate the same from the ceramic sleeve 170 .
  • a part of the rear end side of the gas detection element 120 that projects from the protruding portion 170 k of the ceramic sleeve 170 is inserted into an opening 181 c of the separator 181 that opens at the front end side.
  • the sensor lead frames 182 , 183 , 184 are resiliently held in contact with and electrically connected to respective sensor electrode terminal 125 , 126 , 127 of the gas detection element 120 .
  • the heater lead frames 185 , 186 are resiliently in contact with and electrically connected to each heater electrode terminal 128 , 129 of the gas detection element 120 .
  • the axial distance between the rear end face of the sleeve 170 and the contact portion between the lead frames 182 to 186 and electrode terminals 125 to 129 of the gas detection element 120 is 9 mm.
  • This axial distance is preferably set to be within a range from 5 mm to 30 mm.
  • the connector 180 is held by the metal tube 103 by a biasing metal fitting 190 located around the connector 180 and assuming a generally cylindrical shape, while being biased at the rear end side so as to attach to a grommet 191 discussed below.
  • the biasing metal fitting 190 is located inside the second portion 105 of the metal tube 103 and crimped and fixed by the second portion 105 .
  • a grommet 191 made of a fluorocarbon rubber is provided inside the fourth portion 107 of the metal tube 103 , and two heater lead wires 196 , 197 and three sensor lead wires 193 , 194 , 195 are inserted in the grommet 191 .
  • the grommet 191 is fixedly crimped by the fourth portion 107 .
  • the front end side of each sensor lead 193 , 194 , 195 is inserted into a connector 180 and fixedly crimped by the sensor lead frames 182 , 183 , 184 so as to electrically connect respective sensor leads and sensor lead frames.
  • the front end side of each heater lead 196 , 197 is inserted into the connector 180 and fixedly crimped by the heater lead frame 185 , 186 so as to electrically connect respective heater leads and heater lead frames.
  • the gas detection element 120 includes first and second solid electrolyte layers 137 , 150 in a rear end portion 120 k thereof, and the via conductors 142 , 143 , 155 are formed in these electrolyte layers which penetrate therethrough (refer to FIG. 4 ).
  • the insulating capability of the first and second solid electrolyte layers 137 , 150 in the rear end portion 120 k will fail, whereby a leak between the via conductors 142 and 143 tends to occur. Consequently, the gas concentration may not be accurately detected.
  • the ceramic sleeve 170 is isolated from the connector 180 , the heat from the ceramic sleeve 170 is hardly conducted to the connector 180 , thereby preventing too high of a temperature increase of the connector 180 when in use. Consequently, leakage between via conductors 142 and 143 due to high temperature is unlikely to occur whereby the gas concentration may be more accurately detected than by a conventional gas sensor.
  • the ceramic sleeve 170 which holds and accommodates the gas detection element 120 penetrating therethrough, includes the protruding portion 170 k which extends beyond the metal shell 110 towards the rear end side and also holds the gas detection element 120 therein.
  • the protruding portion 170 k supports the gas detection element 120 , damage to the gas detection element 120 is efficiently prevented even if an external force is applied to the rear end side of the gas detection element 120 . Accordingly, the gas detection element 120 is better protected from breakage than in a conventional gas sensor, during a mounting process of mounting the connector 180 to the gas detection element 120 , or during a subsequent assembling process.
  • the gas detection element 120 is basically produced by a known technique. Then, the gas detection element 120 is inserted into the ceramic holder 113 , and the thus-assembled body is placed in the metal cup 116 . Subsequently, a talc ring is inserted into the metal cup 116 from the rear end side and pressed toward the front end side so as to fix the gas detection element 120 .
  • the protector 101 is fixed at the front end side of the metal shell 110 beforehand by laser welding. Then, the rear end portion 110 k of the metal shell 110 is bent toward the radially-inward direction and crimped toward the shoulder 170 tm of the larger diameter portion 170 t of the ceramic sleeve 170 through the crimping ring 117 , to thereby fix the ceramic sleeve 170 and the gas detection element 120 or the like to the metal shell 110 . In this manner, a lower assembly is completed.
  • the sleeve 170 is entirely located in the metal shell 110 and has no protruding portion 170 k (i.e., the form shown in FIG. 5 ), a large tensile stress will be imposed around a rear end side open end portion 870 ck of an axial hole 870 c when the rear end portion 110 k of the metal shell 110 is bent inwardly to crimp a sleeve 870 . Consequently, starting from the stressed portion, cracks may be generated in the sleeve 870 .
  • a large tensile stress is likely to be imposed, especially, on a corner of the rear end side open end portion 870 ck .
  • a crack tends to occur in the sleeve 870 when the rear end portion 110 k of the metal shell 110 is crimped.
  • the sleeve 170 since the sleeve 170 has a protruding portion 170 k projecting to the rear end side, the rear end side open end portion 170 ck of the axial hole 170 c where a crack tends to initiate is isolated from the rear end portion 110 k (crimped portion) of the metal shell 110 to the rear end side (see FIG. 2 ). Therefore, owing to such a stress dispersing structure, the occurrence of a crack in the sleeve 170 can be prevented.
  • the sensor lead frames 182 , 183 , 184 to which the sensor lead wires 193 , 194 , 195 are connected, respectively, and the heater lead frames 185 , 186 to which the heater leads 196 , 197 are connected, respectively, are located inside the separator 181 .
  • the biasing metal fitting 190 is attached in a predetermined position of an outer circumference of the separator 181 .
  • the grommet 191 is located at the rear end side of the separator 181 , and the thus-assembled body is inserted into the metal sleeve 103 from the grommet 191 side. Then, the second portion 105 of the metal tube 103 is crimped in the radially inward direction. This deforms the biasing metal fitting 190 located inside the metal sleeve, whereby the separator 181 is biased to the rear end side. Thus, the upper assembly is completed.
  • the rear end side of the gas detection element 120 is inserted into the opening 181 c of the connector 180 (separator 181 ) by relatively moving the upper assembly and the lower assembly toward one another.
  • the sensor lead frames 182 , 183 , 184 of the connector 180 and the heater lead frames 185 , 186 are in resilient contact with and electrically connected to corresponding sensor electrode terminals 125 , 126 , 127 of the gas detection element 120 and the heater electrode terminals 128 , 129 , respectively.
  • the fourth portion 107 of the metal tube 103 is crimped in the radially inward direction to thereby fix the grommet 190 located inside the metal tube. Further, the front end portion of the metal tube 103 is crimped in the radially inward direction and the thus-crimped portion is laser welded so that the metal tube 103 may be fixed to the metal shell 110 . In this way, the gas sensor 100 is completed.
  • samples of the gas sensors 100 according to the present embodiment were produced. Comparative samples including a ceramic sleeve 170 attached to the connector 180 , representative of a conventional configuration, were also prepared.
  • the gas sensors 100 were operated so that the temperature of the metal shell 110 , which was positioned 3 mm apart from a flange 110 n of the metal shell 110 (see FIG. 2 ) to the rear end side, reached a temperature of 700° C. Then, the temperature of the contact portion, which was positioned 26 mm apart from a flange 110 n of the metal shell 110 to the rear end side, between the gas detection element 120 (the sensor electrode terminals 125 , 126 , 127 and the heater electrode terminals 128 , 129 ) and the connector 180 (the sensor lead frames 182 , 183 , 184 and the heater lead frames 185 , 186 ) was measured. Moreover, the temperature of the grommet 191 , which was positioned 48 mm apart from the flange 110 n of the metal shell 110 to the rear end side, was measured.
  • the gas sensors 100 of the present embodiment samples and the comparative samples were operated so that the temperature of the metal shell 110 , which was positioned 3 mm apart from a flange 110 n of the metal shell 110 (see FIG. 2 ) to the rear end side, reached a temperature of 650° C. Similar to the above, the temperature of the contact portion, which was positioned 26 mm apart from a flange 110 n of the metal shell 110 to the rear end side, and the temperature of the grommet 191 , which was positioned 48 mm apart from the flange 100 n of the metal shell 110 to the rear end side, were measured, respectively. The results are collectively shown in Table 1. TABLE 1 Contact Portion Metal shell (° C.) (° C.) Grommet (° C.) Inventive 700 440 300 Samples 650 410 280 Comparative 700 500 320 Samples 650 450 300
  • the insulation performance of the first and second solid electrolyte layers 137 , 150 in the rear end portion 120 k can fail, thereby likely causing a leak between the via conductors 142 , 143 formed therein. Consequently, the gas concentration may not be accurately detected.
  • the ceramic sleeve 170 is isolated from the connector 180 in the present embodiment, the temperature rise of the contact portion, etc., is restrained. Therefore, by applying the present invention, the leakage between the via conductors 142 , 143 due to high temperature is more effectively prevented as compared to that of a conventional gas sensor, leading to accurate detection of the gas concentration.
  • ten lower assemblies each constituting the gas sensor 100 according to the above-mentioned embodiment were prepared. Further, another ten lower assemblies were prepared as comparative samples, in which the ceramic sleeve 870 as illustrated in FIG. 5 was employed instead of the ceramic sleeve 170 shown in FIG. 3 , and the rest of the constitution thereof was the same as the above-mentioned embodiment.
  • the ceramic sleeve 870 does not include the protruding portion at the rear end side. That is, the ceramic sleeve 870 is only comprised of: a front end portion 870 s equivalent to the front end portion 170 s of the ceramic sleeve 170 in FIG.
  • the axial hole 870 c having a rectangular-shaped opening is formed along the axis in the ceramic sleeve 870 .
  • the gas detection element 120 is protected from breakage, even if an external force is applied to the rear end side of the gas detection element 120 , by providing the protruding portion 170 k in the ceramic sleeve 170 and by holding and accommodating the gas detection element 120 therein. Therefore, the gas sensor according to the present invention, and specifically the gas detection element 120 , more effectively resists breakage when attaching the connector 180 to the gas detection element 120 or during subsequent assembly, as compared to a conventional gas sensor.

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US11/410,936 2005-04-26 2006-04-26 Gas sensor Abandoned US20060237315A1 (en)

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US20090223818A1 (en) * 2008-03-06 2009-09-10 Ngk Spark Plug Co., Ltd. Sensor
US20100084287A1 (en) * 2008-10-02 2010-04-08 Ngk Spark Plug Co., Ltd. Anomaly diagnosing apparatus and anomaly diagnosing method for gas sensor
US20100139379A1 (en) * 2008-12-10 2010-06-10 Ngk Spark Plug Co., Ltd. Sensor
US20140299469A1 (en) * 2013-04-08 2014-10-09 Ngk Spark Plug Co., Ltd. Sensor
US20160348933A1 (en) * 2014-02-21 2016-12-01 Daikin Industries, Ltd. Air conditioning apparatus
US9541533B2 (en) 2013-02-08 2017-01-10 Ngk Spark Plug Co., Ltd. Gas sensor
US20180217088A1 (en) * 2017-01-27 2018-08-02 Ngk Spark Plug Co., Ltd. Gas sensor
CN110454262A (zh) * 2019-09-11 2019-11-15 福建京科科技有限公司 摩托车微型氧传感器及其安装方法
US10761115B2 (en) * 2017-12-25 2020-09-01 Hioki Denki Kabushiki Kaisha Sensor and measuring apparatus
US11199474B2 (en) * 2018-04-09 2021-12-14 Ngk Spark Plug Co., Ltd. Sensor having tube cap restricting rearward movement of heat shield tube

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JP4865522B2 (ja) * 2006-12-12 2012-02-01 日本特殊陶業株式会社 ガスセンサの製造方法
JP5219167B2 (ja) * 2009-03-31 2013-06-26 日本特殊陶業株式会社 ガスセンサ
KR101613023B1 (ko) * 2014-12-05 2016-04-26 주식회사 현대케피코 차량용 가스센서의 완충구조
JP6491061B2 (ja) * 2015-08-26 2019-03-27 日本碍子株式会社 ガスセンサおよびガスセンサの製造方法
DE102017206308A1 (de) * 2017-04-12 2018-10-18 Robert Bosch Gmbh Abgassensor, insbesondere Partikelsensor
CN108119215B (zh) * 2018-02-01 2023-12-29 肇庆学院 一种车用氧传感器

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US20080277282A1 (en) * 2007-05-08 2008-11-13 Ngk Spark Plug Co., Ltd. Gas sensor and manufacturing method thereof
US8398837B2 (en) 2008-03-06 2013-03-19 Ngk Spark Plug Co., Ltd. Sensor
US8105470B2 (en) * 2008-03-06 2012-01-31 Ngk Spark Plug Co., Ltd. Sensor
US20090223818A1 (en) * 2008-03-06 2009-09-10 Ngk Spark Plug Co., Ltd. Sensor
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US8191414B2 (en) * 2008-12-10 2012-06-05 Ngk Spark Plug Co., Ltd. Sensor
US20100139379A1 (en) * 2008-12-10 2010-06-10 Ngk Spark Plug Co., Ltd. Sensor
US9541533B2 (en) 2013-02-08 2017-01-10 Ngk Spark Plug Co., Ltd. Gas sensor
US20140299469A1 (en) * 2013-04-08 2014-10-09 Ngk Spark Plug Co., Ltd. Sensor
US9482637B2 (en) * 2013-04-08 2016-11-01 Ngk Spark Plug Co., Ltd. Sensor
US20160348933A1 (en) * 2014-02-21 2016-12-01 Daikin Industries, Ltd. Air conditioning apparatus
US10234164B2 (en) * 2014-02-21 2019-03-19 Daikin Industries, Ltd. Air conditioning apparatus
US20180217088A1 (en) * 2017-01-27 2018-08-02 Ngk Spark Plug Co., Ltd. Gas sensor
US10732142B2 (en) * 2017-01-27 2020-08-04 Ngk Spark Plug Co., Ltd. Gas sensor
US10761115B2 (en) * 2017-12-25 2020-09-01 Hioki Denki Kabushiki Kaisha Sensor and measuring apparatus
US11199474B2 (en) * 2018-04-09 2021-12-14 Ngk Spark Plug Co., Ltd. Sensor having tube cap restricting rearward movement of heat shield tube
CN110454262A (zh) * 2019-09-11 2019-11-15 福建京科科技有限公司 摩托车微型氧传感器及其安装方法

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CN1854729A (zh) 2006-11-01
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JP4680662B2 (ja) 2011-05-11
FR2884922B1 (fr) 2011-11-25

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