US20050148484A9 - Enclosed bleach activators - Google Patents
Enclosed bleach activators Download PDFInfo
- Publication number
- US20050148484A9 US20050148484A9 US10/343,877 US34387703A US2005148484A9 US 20050148484 A9 US20050148484 A9 US 20050148484A9 US 34387703 A US34387703 A US 34387703A US 2005148484 A9 US2005148484 A9 US 2005148484A9
- Authority
- US
- United States
- Prior art keywords
- alkyl
- coating material
- weight
- particle
- bleach activator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000012190 activator Substances 0.000 title claims abstract description 33
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 35
- -1 amino alkyl nitrile Chemical class 0.000 claims abstract description 29
- 239000002245 particle Substances 0.000 claims abstract description 28
- 239000011248 coating agent Substances 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 23
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 11
- 229920002472 Starch Polymers 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 239000012188 paraffin wax Substances 0.000 claims description 9
- 235000019809 paraffin wax Nutrition 0.000 claims description 9
- 235000019271 petrolatum Nutrition 0.000 claims description 9
- 235000019698 starch Nutrition 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 235000010980 cellulose Nutrition 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229920000881 Modified starch Polymers 0.000 claims description 3
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 3
- 229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 150000001720 carbohydrates Chemical class 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 3
- 235000019426 modified starch Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical class CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical class [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical class [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 2
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims description 2
- 125000005228 aryl sulfonate group Chemical class 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
- 235000011180 diphosphates Nutrition 0.000 claims description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical class CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229940070765 laurate Drugs 0.000 claims description 2
- 125000005341 metaphosphate group Chemical group 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 description 20
- 239000012876 carrier material Substances 0.000 description 12
- 239000003599 detergent Substances 0.000 description 12
- 239000002689 soil Substances 0.000 description 10
- 239000008187 granular material Substances 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 8
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000003827 glycol group Chemical group 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 0 C.[1*]C([2*])([3*])CC#N Chemical compound C.[1*]C([2*])([3*])CC#N 0.000 description 3
- 229920001634 Copolyester Polymers 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 3
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229940071118 cumenesulfonate Drugs 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 2
- 229920000858 Cyclodextrin Polymers 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 238000004455 differential thermal analysis Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- 125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- SFHBJXIEBWOOFA-UHFFFAOYSA-N 5-methyl-3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OC(C)COC(=O)C2=CC=C1C=C2 SFHBJXIEBWOOFA-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920001612 Hydroxyethyl starch Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- QECVIPBZOPUTRD-UHFFFAOYSA-N N=S(=O)=O Chemical class N=S(=O)=O QECVIPBZOPUTRD-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 125000005011 alkyl ether group Chemical group 0.000 description 1
- 125000005263 alkylenediamine group Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000001046 glycoluril group Chemical group [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- DNZMDASEFMLYBU-RNBXVSKKSA-N hydroxyethyl starch Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O.OCCOC[C@H]1O[C@H](OCCO)[C@H](OCCO)[C@@H](OCCO)[C@@H]1OCCO DNZMDASEFMLYBU-RNBXVSKKSA-N 0.000 description 1
- 229940050526 hydroxyethylstarch Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical class COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
Definitions
- the present invention relates to enclosed bleach activators of the quaternized aminoalkylnitrile type.
- washing auxiliaries include diverse groups of active substances, such as foam regulators, antiredeposition agents, bleaches and color transfer inhibitors.
- active substances such as foam regulators, antiredeposition agents, bleaches and color transfer inhibitors.
- Auxiliaries of this type also include substances which aid the surfactant performance as a result of oxidative degradation of soilings located on the textile or those in the liquor. Analogous statements also apply to cleaners for hard surfaces.
- inorganic peroxygen compounds in particular hydrogen peroxide, and solid peroxygen compounds which dissolve in water to liberate hydrogen peroxide, such as sodium perborate and sodium carbonate perhydrate, have been used for a long time as oxidizing agents for disinfection and bleaching purposes.
- the oxidative effect of these substances greatly depends in dilute solutions on the temperature; thus, for example with H 2 O 2 or perborate in alkaline bleaching liquors, a sufficiently rapidly bleaching of soiled textiles only takes place at temperatures above about 60° C.
- bleach activators for which numerous proposals, primarily from the classes of substance of N- or O-acyl compounds, for example polyacylated alkylenediamines, in particular tetraacetylethylene-diamine, acylated glycolurils, in particular tetraacetylglycoluril, N-acylated hydantoins, hydrazides, triazoles, hydrotriazines, urazoles, diketopiperazines, sulfurylamides and cyanurates, and also carboxylic anhydrides, in particular phthalic anhydride, carboxylic esters, in particular sodium nonanoyloxybenzenesulfonate, sodium isononanoyloxy-benzenesulfonate and acylated sugar derivatives, such as pentaacetylglucose, have become known in the literature.
- the addition of these compounds for example polyacylated alkylenediamines, in particular tetraacetyl
- European patent application 0 464 880 discloses bleach-enhancing cationic nitriles of the general formula R′R′′R′′′N + —CR 1 R 2 —CN X ⁇ , in which R 1 and R 2 is hydrogen or a substituent with at least one carbon atom, R′ is a C 1-24 -alkyl, alkenyl or alkyl ether group or a group —CR 1 R 2 —CN, and R′′ and R′′′ is in each case a C 1-24 -alkyl or hydroxyalkyl group, and the counteranion X ⁇ is an organic sulfonate, an organic sulfate or a carboxylate.
- the present invention relates to particles containing bleach activator of the general formula (I), in which R 1 is —H, —CH 3 , a C 2-24 -alkyl or -alkenyl radical, a substituted C 2-24 -alkyl or -alkenyl radical having at least one substituent from the group —Cl, —Br, —OH, —NH 2 , —CN, an alkyl- or alkenylaryl radical with a C 1-24 -alkyl group, or is a substituted alkyl- or alkenylaryl radical with a C 1-24 -alkyl group and at least one other substituent on the aromatic ring, R 2 and R 3 , independently of one another, are chosen from —CH 2 —CN, —CH 3 , —CH 2 —CH 3 , —CH 2 —CH 2 —CH 3 , —CH(CH 3 )—CH 3 , —CH 2 —OH
- the anions X ⁇ include, in particular, the halides, such as chloride, fluoride, iodide and bromide, nitrate, hydroxide, phosphate, hydrogen phosphate, dihydrogen phosphate, pyrophosphate, metaphosphate, hexafluoro-phosphate, carbonate, hydrogen carbonate, sulfate, hydrogen sulfate, C 1-20 -alkyl sulfate, C 1-20 -alkyl-sulfonate, optionally C 1-18 -alkyl-substituted aryl-sulfonate, chlorate, perchlorate and/or the anions of C 1-24 -carboxylic acids, such as formate, acetate, laurate, benzoate or citrate, alone or in any desired mixtures.
- the halides such as chloride, fluoride, iodide and bromide, nitrate, hydroxide, phosphate, hydrogen phosphate, di
- X ⁇ is chloride, sulfate, hydrogen sulfate, ethosulfate, C 12/18 —, C 12/16 — or C 13/15 -alkyl sulfate, lauryl sulfate, dodecylbenzenesulfonate, toluenesulfonate, cumenesulfonate, xylenesulfonate or methosulfate or mixtures thereof.
- Toluenesulfonate and cumenesulfonate are understood here as meaning the anion of the ortho, meta or paraisomers of methylbenzenesulfonic acid and isopropylbenzenesulfonic acid, respectively, and any desired mixtures thereof. para-isopropylbenzenesulfonic acid is particular preferred.
- the compound according to general formula I can be used in solid form as it is or formulated in particulate form, i.e. applied to an organic and/or inorganic carrier material, as starting material for the enclosure according to the invention.
- the compound according to formula (I) can be applied to the carrier material by stirring the carrier material into a solution of the compound according to formula I, as formed during the course of its production, and stripping off the optionally aqueous solvent under reduced pressure, if desired at elevated temperature.
- Suitable carrier materials are all substances which do not interact in an unreasonably negative manner with the compound according to formula I, for example alkali metal cumenesulfonate, surfactants, organic acids and polymers, alkali metal carbonates, alkali metal sulfates, alkali metal hydrogen sulfates, alkali metal hydrogen carbonates, alkali metal phosphates, alkali metal dihydrogen phosphates, dialkali metal hydrogen phosphates and alkali metal silicates and mixtures thereof.
- silicatic carrier materials particularly suitable for the purposes of the present invention include, for example, alkali metal silicates, and also silicas, silica gels and clays, and mixtures thereof.
- the carrier material is preferably free from zeolites.
- the silicate-containing carrier material optionally comprises further particulate inert constituents which do not unreasonably impair the stability of the compounds according to the formula I.
- Silicas which have been produced by a thermal process (flame hydrolysis of SiCl 4 ) (so-called pyrogenic silicas) are equally suitable for use as are silicas produced by wet methods.
- Silica gels are colloidal silicas with an elastic to solid consistency and a substantially loose pore structure, resulting in a high liquid-uptake capacity. They can be produced by the action of mineral acids on waterglass.
- Clays are naturally occurring crystalline or amorphous silicates of aluminum, iron, magnesium, calcium, potassium and sodium, for example kaolin, talc, pyrophyllite, attapulgite, sepiolite, montmorillonite and bauxite.
- the use of aluminum silicate as a carrier material or as a component of a carrier material mixture is also possible.
- the carrier material preferably has particle sizes in the range from 100 ⁇ m to 1.5 ⁇ m.
- the coating materials should have proven as far as possible to be substantially chemically inert toward the bleach activator, i.e. the degradation rate for the particles containing the bleach activator according to formula (I) to be used according to the invention, which are stored for about 4 months, should be as low as possible.
- the coating materials must be sufficiently rapidly soluble in water or aqueous solutions so that the granules, as constituents of detergents or cleaners, upon use thereof in corresponding aqueous detergent or cleaner solutions, release the bleach activator at the desired point in time, or over the desired period of time.
- the use of the correspondingly enclosed particles in textile detergents often results in a greater avoidance of color damage of textiles washed therewith than does the use of the pure substance according to formula (I).
- Suitable coating materials for the purposes of this invention are, in particular, inorganic salts, such as alkali metal sulfates, alkali metal chlorides, alkali metal silicates, alkali metal phosphates and alkali metal phosphonates, alkaline earth metal sulfates and alkaline earth metal silicates, paraffin waxes, water-soluble saccharide-based polymeric compounds, such as starch or starch derivatives or cellulose derivatives, polymeric alcohols, for example polyvinyl alcohols and polyethylene glycols, homo- and copolymeric polycarboxylates, polyesters of dicarboxylic acids and optionally oligo- or polymeric alcohols, nonionic surfactants, anionic surfactants, hydroxy carboxylic acids, such as glycolic acid and citric acid, and/or fatty acids.
- inorganic salts such as alkali metal sulfates, alkali metal chlorides, alkali metal silicates, alkali metal phosphates
- sodium is the preferred alkali metal ion and magnesium is the preferred alkaline earth metal ion.
- Paraffin wax generally represents a complex substance mixture without a sharp melting point. For characterization, determination is usually made of its melting range by differential thermal analysis (DTA), as described in “The Analyst” 87 (1962), 420, and/or of its solidification point. This is understood as meaning the temperature at which molten material converts from the liquid state to the solid state by slow cooling. Preference is given to using waxes which solidify in the range from 20° C. to 70° C. Here, it must be taken into consideration that paraffin wax mixtures which appear solid at room temperature may also contain varying proportions of liquid paraffin. In the paraffin waxes which are particularly suitable for use according to the invention, the liquid fraction at 40° C. is as high as possible without being 100% at this temperature.
- DTA differential thermal analysis
- paraffin wax mixtures have, at 40° C., a liquid fraction of at least 50% by weight, in particular from 55% by weight to 80% by weight, and, at 60° C., a liquid fraction of at least 90% by weight. In addition, it must be ensured that the paraffins contain the smallest possible volatile fractions.
- Preferred paraffin waxes comprise less than 1% by weight, in particular less than 0.5% by weight, of fractions which can be vaporized at 110° C. and atmospheric pressure. Paraffin waxes which are particularly suitable for use according to the invention can be obtained, for example, under the trade names Lunaflex® from Fuller, and Deawax® from DEA Mineralöl AG.
- the water-soluble starch or cellulose derivatives which can be used as coating materials include, in particular, starch ethers and cellulose ethers.
- cellulose ethers are methylcellulose, ethylcellulose, hydroxyethylcellulose, methylhydroxyethylcellulose, methylhydroxypropylcellulose and carboxymethylcellulose, which is normally used as the sodium salt.
- Suitable as starch is, for example, depolymerized starch.
- Suitable starch ethers are, for example, carboxymethylstarch, hydroxyethylstarch and methyl-starch.
- Sodium carboxymethylcellulose and starch have proven to be particularly suitable. It is also particularly advantageous to use gelatin as coating material.
- Polyvinyl alcohols are not accessible by direct polymerization methods since the base monomer vinyl alcohol required therefor does not exist. Polyvinyl alcohols are therefore produced via polymer-analogous reactions by hydrolysis, but industrially, in particular, by alkali-catalyzed transesterification of polyvinyl acetates with alcohols (for example methanol) in solution.
- alcohols for example methanol
- Polyvinyl alcohols which are preferably used according to the invention which are usually supplied commercially as white-yellowish powders or granules, have molar masses in the range from 3000 g/mol to 320,000 g/mol, in particular 8000 g/mol to 200,000 g/mol (corresponding to degrees of polymerization in the range from about 75-8000, in particular about 200 to 5000). They preferably have degrees of hydrolysis of from 20% by weight to 100% by weight, in particular from 30% by weight to 90% by weight.
- these are completely or partially saponified polyvinyl alcohol esters, in particular polyvinyl acetates, with a residual content of acyl groups, in particular acetyl groups, up to about 80% by weight, in particular from 10% by weight to 70% by weight.
- the polyvinyl alcohols can be further characterized by quoting the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number and/or the solution viscosity. Transformation temperatures of the polyvinyl alcohols are dependent on the acetyl group content, the distribution of the acetyl groups along the chain and the tacticity of the polymers.
- Completely saponified polyvinyl alcohols have a glass transition temperature of 85° C., the value for partially saponified (87-89%) products being considerably lower at about 58° C.
- Polyvinyl alcohols which normally have a density of about 1.2-1.3 g/cm 3 , are, depending on the degree of hydrolysis, normally soluble in water and strongly polar organic solvents, such as formamide, dimethylformamide and dimethyl sulfoxide, and they are not attacked by (chlorinated) hydrocarbons, esters, fats and oils.
- Polyvinyl alcohols are classified as toxicologically acceptable and are biodegradable.
- Further suitable coating materials are polyethylene glycols which have, for example, a relative molecular mass between 10,000 and 20,000.
- homo- and copolymeric carboxylates such as polyacrylates, polymethacrylates and in particular copolymers of acrylic acid with maleic acid, preferably those containing about 50% by weight to 10% by weight of maleic acid.
- the relative molecular mass of these homopolymers is generally between 1000 and 100,000, that of the copolymers is between 2000 and 200,000, preferably 50,000 to 120,000, based on free acid.
- a particularly preferred acrylic acid-maleic acid, copolymer has a relative molecular mass of from 50,000 to 100,000.
- Further suitable compounds of this class are copolymers of acrylic acid or methacrylic acid with vinyl ethers, such as vinyl methyl ethers, in which the proportion of acid is preferably at least 50% by weight.
- a further embodiment of the invention arises through the use of so-called host molecules or compounds which, due to their structure or arrangement, can protect bleach activators which are able to enclose molecules such as said bleach activators optionally in their inside.
- a preferred cage compound is cyclodextrin.
- the bleach activator according to formula (I) and cyclodextrin are particularly advantageously used in a molar ratio of from 1:1 to 1:2.
- polyesters used as coating materials preference is given to those which impart soil-repelling properties to the laundry fibers and which, if present during the washing operation, aid the soil release capacity of the other detergent constituents. These are often referred to as soil release active substances or, due to their ability to give the treated surface of the fibers a soil-repelling property, as soil repellants. The same effect can also be observed when they are used in cleaners for hard surfaces. Due to their chemical similarity to polyester fibers, particularly effective and therefore preferred soil release active substances, which can, however, also exhibit the desired effect with fabrics or surfaces made of another material, are copolyesters which contain dicarboxylic acid units, alkylene glycol units and polyalkylene glycol units.
- Soil release copolyesters of said type and also their use in detergents have been known for a long time.
- German Laid-Open Specification DT 16 17 141 describes a washing process using polyethylene terephthalate-polyoxyethylene glycol copolymers.
- German Laid-Open Specification DT 22 00 911 relates to detergents which comprise nonionic surfactant and a copolymer of polyoxyethylene glycol and polyethylene terephthalate.
- German Laid-Open Specification DT 22 53 063 mentions acidic textile finishing agents which comprise a copolymer of a dibasic carboxylic acid and an alkylene or cycloalkylene polyglycol and optionally an alkylene or cycloalkylene glycol.
- European patent EP 066 944 relates to textile treatment agents which comprise a copolyester of ethylene glycol, polyethylene glycol, aromatic dicarboxylic acid and sulfonated aromatic dicarboxylic acid in certain molar ratios.
- European patent EP 0 185 427 discloses methyl- or ethyl group end-capped polyesters containing ethylene terephthalate and/or propylene terephthalate and polyethylene oxide terephthalate units and detergents which comprise such a soil release polymer.
- European patent EP 0 241 984 relates to a polyester which, in addition to oxyethylene groups and terephthalic acid units, also contains substituted ethylene units and glycerol units.
- European patent EP 0 241 985 discloses polyesters which, in addition to oxyethylene and terephthalic acid units, comprise 1,2-propylene, 1,2-butylene and/or 3-methoxy-1,2-propylene groups and glycerol units and are end-capped with C 1 - to C 4 -alkyl groups.
- European patent specification EP 0 253 567 relates to soil release polymers with a molar mass of from 900 to 9000 of ethylene terephthalate and polyethylene oxide terephthalate, where the polyethylene glycol units have molecular weights of from 300 to 3000 and the molar ratio of ethylene terephthalate to polyethylene oxide terephthalate is 0.6 to 0.95.
- European patent application EP 0 272 033 discloses polyesters with polypropylene terephthalate and polyoxyethylene terephthalate units which are end-capped at least in part by C 1-4 -alkyl or acyl radicals.
- European patent EP 0 274 907 describes sulfoethyl end-capped terephthalate-containing soil release polyesters.
- European patent application EP 0 357 280 soil release polyesters with terephthalate, alkylene glycol and poly-C 2-4 -glycol units are produced by sulfonation of unsaturated end groups.
- nonionic surfactants which are understood as meaning, in particular, polyalkoxylates of fatty alcohols solid at room temperature, and anionic surfactants, in particular C 9 -C 13 -alkylbenzenesulfonates, C 12 -C 18 -fatty alcohol sulfates, and C 12 -C 18 -fatty acids and salts thereof, and mixtures of these, where the anionic surfactants are usually in the form of the alkali metal salts, in particular sodium salts.
- the particles according to the invention have a content of bleach activator according to formula (I) of preferably at least 40% by weight and in particular from 50% by weight to 92% by weight; the coating material is present in the granules preferably in amounts up to 60% by weight, in particular from 3% by weight to 50% by weight and particularly advantageously from 10% by weight to 25% by weight, based on the sum of bleach activator and coating material.
- the granules can contain small amounts of free water not bound as water of crystallization or in a comparable form. These should be as low as possible, the amounts which may normally be tolerated being up to about 5% by weight. However, the granules preferably contain 0 to 3% by weight of water.
- the invention further provides a method for producing granules containing enclosed bleach activator according to formula (I) by spraying the bleach activator according to formula (I) present in solid, in particular pulverulent, form, if desired in a mixture with binder and/or solid filler or in the form of preproduced granules, with an organic enclosing material which is liquid or liquefied by heating, where the material to be enclosed is, preferably, kept in motion, for example by being in a fluidized bed, a mixer or granulator.
- Organic and also inorganic enclosing materials such as the alkali metal or alkaline earth metal salts mentioned, particularly when they are solid at room temperature, can also be applied in this way if they are converted beforehand into a solution or at least a pumpable and sprayable slurry, where water is the preferred solvent or slurrying agent, and if desired the solvent or slurrying agent can then at least partially be removed again subsequently to the enclosure operation by a drying step.
- the drying step can also, particularly when the enclosure is carried out in a fluidized bed with introduced air at temperatures of preferably 25° C. to 80° C. and in particular 45° C. to 75° C., be carried out at the same time as the enclosure operation.
- a further embodiment of the method according to the invention consists in introducing the bleach activator according to formula (I) into enclosing material liquefied by heating, cooling the resulting mixture to below the melting point or the softening point of the enclosing material and, during this or subsequently, converting it to granules in a manner known in principle, by, for example, pelleting, pastilling, extrusion or, if desired, grinding.
- Preferred enclosing materials in this process variant are the abovementioned waxes, polyesters and fatty acids, in particular stearic acid.
- the enclosed granules can be after-treated with customary powdering agents, for example finely divided silica or zeolites.
- Enclosed particles according to the invention or enclosed particles produced by the method according to the invention preferably have an average particle diameter in the range from 0.2 mm to 3 mm, in particular 0.4 mm to 1.8 mm. They are stable upon storage over prolonged periods, in particular against hydrolysis of the bleach activator according to formula (I), and are used in, in particular particulate, detergents and cleaners preferably in amounts such that these compositions have contents of from 0.1% by weight to 10% by weight, in particular from 0.2% by weight to 7% by weight of bleach activator according to formula (I).
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10038832.9 | 2000-08-04 | ||
DE10038832A DE10038832A1 (de) | 2000-08-04 | 2000-08-04 | Umhüllte Bleichaktivatoren |
PCT/EP2001/008598 WO2002012426A1 (de) | 2000-08-04 | 2001-07-25 | Umhüllte bleichaktivatoren |
Publications (2)
Publication Number | Publication Date |
---|---|
US20040067863A1 US20040067863A1 (en) | 2004-04-08 |
US20050148484A9 true US20050148484A9 (en) | 2005-07-07 |
Family
ID=7651826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/343,877 Abandoned US20050148484A9 (en) | 2000-08-04 | 2001-07-25 | Enclosed bleach activators |
Country Status (8)
Country | Link |
---|---|
US (1) | US20050148484A9 (ja) |
EP (1) | EP1305386B1 (ja) |
JP (1) | JP2004517160A (ja) |
AT (1) | ATE348870T1 (ja) |
AU (1) | AU2001289747A1 (ja) |
DE (2) | DE10038832A1 (ja) |
ES (1) | ES2277940T3 (ja) |
WO (1) | WO2002012426A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070244028A1 (en) * | 2004-05-17 | 2007-10-18 | Henkel Kgaa | Washing Agent With Bleach Boosting Transition Metal Complex Optionally Generated in Situ |
US20080090746A1 (en) * | 2005-06-08 | 2008-04-17 | Josef Penninger | Boosting the cleaning performance of laundry detergents by polymer |
US20110009304A1 (en) * | 2009-07-09 | 2011-01-13 | Nigel Patrick Somerville-Roberts | Compositions containing bleach co-particles |
US20110009305A1 (en) * | 2009-07-09 | 2011-01-13 | Nigel Patrick Somerville Roberts | Layered Particles and Compositions Comprising Same |
US8034123B2 (en) | 2005-06-08 | 2011-10-11 | Henkel Ag & Co., Kgaa | Boosting cleaning power of detergents by means of a polymer |
US20120104314A1 (en) * | 2010-10-29 | 2012-05-03 | Nigel Patrick Somerville Roberts | Bleach coparticle |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10159388A1 (de) * | 2001-12-04 | 2003-06-12 | Henkel Kgaa | Verfahren zur Herstellung von umhüllten Bleichaktivatorgranulaten |
EP1509493A2 (de) | 2002-05-31 | 2005-03-02 | Henkel Kommanditgesellschaft auf Aktien | Desodorierung von kationischen ammoniumacetonitrilderivaten |
AU2003270171A1 (en) * | 2002-09-20 | 2004-04-19 | Henkel Kommanditgesellschaft Auf Aktien | Dishwasher compositions (mgsm) provided with specially formulated bleach activators (iii) |
DE60327248D1 (de) | 2002-12-18 | 2009-05-28 | Procter & Gamble | Organischer aktivator |
WO2004058931A1 (de) | 2002-12-20 | 2004-07-15 | Henkel Kommanditgesellschaft Auf Aktien | Bleichmittelhaltige wasch- oder reinigungsmittel |
EP1592767B1 (de) * | 2003-02-10 | 2007-05-16 | Henkel Kommanditgesellschaft auf Aktien | Bleichmittelhaltige wasch- oder reinigungsmittel mit wasserlöslichem buildersystem und schmutzablösevermögendem cellulosederivat |
JP2006517245A (ja) * | 2003-02-10 | 2006-07-20 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | 発泡調節剤としてのセルロース誘導体の使用 |
JP4578465B2 (ja) * | 2003-02-10 | 2010-11-10 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 繊維製品の水吸収力の増大 |
DE10351321A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch eine Kombination von Cellulosderivaten |
DE10351325A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Wasch- oder Reinigungsmittel mit wasserlöslichem Buildersystem und schmutzablösevermögendem Cellulosederivat |
DE102004028494A1 (de) * | 2004-06-11 | 2005-12-29 | Clariant Gmbh | Mischungen von Ammoniumnitril-Bleichaktivatoren und Aminosäuren |
JP2007172716A (ja) * | 2005-12-20 | 2007-07-05 | Sony Corp | 再生装置、再生方法および再生プログラム、記録媒体およびデータ構造、ならびに、オーサリング装置、オーサリング方法およびオーサリングプログラム |
US8182785B2 (en) * | 2008-06-11 | 2012-05-22 | Nutech Ventures | Methods and compositions for generating singlet oxygen |
DE102014110847A1 (de) * | 2013-08-14 | 2015-02-19 | Budich International Gmbh | Mehrphasige Reinigungstablette |
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GB9012001D0 (en) * | 1990-05-30 | 1990-07-18 | Unilever Plc | Bleaching composition |
DE19740669A1 (de) * | 1997-09-16 | 1999-03-18 | Clariant Gmbh | Gecoatete Ammoniumnitril-Bleichaktivatorgranulate |
DE19857596A1 (de) * | 1998-12-15 | 2000-06-21 | Henkel Kgaa | Teilchenförmig konfektionierte Acetonitril-Derivate als Bleichaktivatoren in festen Reinigungsmitteln |
-
2000
- 2000-08-04 DE DE10038832A patent/DE10038832A1/de not_active Ceased
-
2001
- 2001-07-25 DE DE50111695T patent/DE50111695D1/de not_active Expired - Fee Related
- 2001-07-25 EP EP01969508A patent/EP1305386B1/de not_active Expired - Lifetime
- 2001-07-25 AT AT01969508T patent/ATE348870T1/de not_active IP Right Cessation
- 2001-07-25 WO PCT/EP2001/008598 patent/WO2002012426A1/de active IP Right Grant
- 2001-07-25 AU AU2001289747A patent/AU2001289747A1/en not_active Abandoned
- 2001-07-25 US US10/343,877 patent/US20050148484A9/en not_active Abandoned
- 2001-07-25 ES ES01969508T patent/ES2277940T3/es not_active Expired - Lifetime
- 2001-07-25 JP JP2002517717A patent/JP2004517160A/ja active Pending
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US3893929A (en) * | 1971-10-28 | 1975-07-08 | Procter & Gamble | Compositions for imparting renewable soil release finish to polyester-containing fabrics |
US4116885A (en) * | 1977-09-23 | 1978-09-26 | The Procter & Gamble Company | Anionic surfactant-containing detergent compositions having soil-release properties |
US5888419A (en) * | 1995-06-07 | 1999-03-30 | The Clorox Company | Granular N-alkyl ammonium acetontrile compositions |
US6451753B2 (en) * | 1996-03-14 | 2002-09-17 | Basf Aktiengesellschaft | Solid composition consisting of heterocyclic compounds and/or oxime esters and inert porous carrier materials and the use thereof as stable bleach activator component in detergents, bleaches and cleaners |
US6107266A (en) * | 1996-10-10 | 2000-08-22 | Clariant Gmbh | Process for producing coated bleach activator granules |
US6225274B1 (en) * | 1996-11-29 | 2001-05-01 | Henkel Kommandigesellschaft Auf Aktien | Acetonitrile derivatives as bleaching activators in detergents |
US6063750A (en) * | 1997-09-16 | 2000-05-16 | Clariant Gmbh | Bleach activator granules |
US6133216A (en) * | 1997-09-16 | 2000-10-17 | Clariant Gmbh | Coated ammonium nitrile bleach activator granules |
US6270690B1 (en) * | 1997-09-16 | 2001-08-07 | Clariant Gmbh | Storage stable bleach activator granules |
US6407045B1 (en) * | 1998-12-15 | 2002-06-18 | Henkel Kommanditgesellschaft Auf Aktien | Particulate acetonitrile derivatives as bleach activators in solid detergents |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070244028A1 (en) * | 2004-05-17 | 2007-10-18 | Henkel Kgaa | Washing Agent With Bleach Boosting Transition Metal Complex Optionally Generated in Situ |
US20080090746A1 (en) * | 2005-06-08 | 2008-04-17 | Josef Penninger | Boosting the cleaning performance of laundry detergents by polymer |
US7431739B2 (en) | 2005-06-08 | 2008-10-07 | Henkel Kommanditgesellschaft Auf Aktien | Boosting the cleaning performance of laundry detergents by polymer of styrene/methyl methacrylate/methyl polyethylene glycol |
US8034123B2 (en) | 2005-06-08 | 2011-10-11 | Henkel Ag & Co., Kgaa | Boosting cleaning power of detergents by means of a polymer |
US20110009304A1 (en) * | 2009-07-09 | 2011-01-13 | Nigel Patrick Somerville-Roberts | Compositions containing bleach co-particles |
US20110009305A1 (en) * | 2009-07-09 | 2011-01-13 | Nigel Patrick Somerville Roberts | Layered Particles and Compositions Comprising Same |
US20120104314A1 (en) * | 2010-10-29 | 2012-05-03 | Nigel Patrick Somerville Roberts | Bleach coparticle |
Also Published As
Publication number | Publication date |
---|---|
WO2002012426A1 (de) | 2002-02-14 |
DE10038832A1 (de) | 2002-03-28 |
US20040067863A1 (en) | 2004-04-08 |
ATE348870T1 (de) | 2007-01-15 |
ES2277940T3 (es) | 2007-08-01 |
DE50111695D1 (de) | 2007-02-01 |
AU2001289747A1 (en) | 2002-02-18 |
JP2004517160A (ja) | 2004-06-10 |
EP1305386B1 (de) | 2006-12-20 |
EP1305386A1 (de) | 2003-05-02 |
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Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN (HENKEL KG Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SPECKMANN, HORST-DIETER;LARSON, BERND;POETHKOW, JOERG;AND OTHERS;REEL/FRAME:013715/0278;SIGNING DATES FROM 20030131 TO 20030324 Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN (HENKEL KG Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SPECKMANN, HORST-DIETER;LARSON, BERND;POETHKOW, JOERG;AND OTHERS;SIGNING DATES FROM 20030131 TO 20030324;REEL/FRAME:013715/0278 |
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