US20050115295A1 - Method and installation for the production of an aluminum sheet with a textured surface - Google Patents

Method and installation for the production of an aluminum sheet with a textured surface Download PDF

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Publication number
US20050115295A1
US20050115295A1 US10/507,065 US50706504A US2005115295A1 US 20050115295 A1 US20050115295 A1 US 20050115295A1 US 50706504 A US50706504 A US 50706504A US 2005115295 A1 US2005115295 A1 US 2005115295A1
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US
United States
Prior art keywords
rolls
texturing
strip
roll
textured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/507,065
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English (en)
Inventor
Rene-Pierre Pont
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3A Composites International AG
Original Assignee
Alcan Technology and Management Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alcan Technology and Management Ltd filed Critical Alcan Technology and Management Ltd
Assigned to ALCAN TECHNOLOGY & MANAGEMENT LTD. reassignment ALCAN TECHNOLOGY & MANAGEMENT LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PONT, RENE-PIERRE
Assigned to CITICORP NORTH AMERICA, INC. reassignment CITICORP NORTH AMERICA, INC. SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NOVELIS CORPORATION, NOVELIS INC.
Publication of US20050115295A1 publication Critical patent/US20050115295A1/en
Assigned to NOVELIS INC., NOVELIS CORPORATION reassignment NOVELIS INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: CITICORP NORTH AMERICA, INC.
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/14Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls
    • B21B13/147Cluster mills, e.g. Sendzimir mills, Rohn mills, i.e. each work roll being supported by two rolls only arranged symmetrically with respect to the plane passing through the working rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/227Surface roughening or texturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/14Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B31/00Rolling stand structures; Mounting, adjusting, or interchanging rolls, roll mountings, or stand frames
    • B21B31/02Rolling stand frames or housings; Roll mountings ; Roll chocks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/28Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B2003/001Aluminium or its alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/02Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally
    • B21B2013/021Twin mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/02Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally
    • B21B2013/025Quarto, four-high stands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/005Rolls with a roughened or textured surface; Methods for making same
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B35/00Drives for metal-rolling mills, e.g. hydraulic drives
    • B21B35/10Driving arrangements for rolls which have only a low-power drive; Driving arrangements for rolls which receive power from the shaft of another roll

Definitions

  • the invention relates to a process and unit for producing a cold rolled strip of aluminium or an aluminium alloy with a textured surface comprising passing a cold rolled strip immediately after cold rolling through a roll gap of two textured rolls bearing a roughness pattern, wherein the roughness pattern is transferred to the surface of the strip as a result of the force of the textured rolls acting on the strip, and, thereafter, coiling the textured strip.
  • the strip manufacturer coats the cold rolled strip with an oil or a water-soluble dry lubricant and the prepared strip supplied to the sheet-forming company for the purposes of deep drawing.
  • the adhesion and distribution properties of dry lubricants on the strip surface can be markedly improved by providing the surface of the strip with a roughness pattern. To that end the roughening of the strip surface is effected by transferring the roughness pattern on the work rolls to the surface of the strip during cold rolling of the strip.
  • the roughness patterns provided on the surface of the aluminium strip to improve the adhesion and distribution of a dry lubricant there are produced by work rolls which are roughened e.g. by electrical discharge texturing (EDT), by electron beam texturing (EBT) or by the PRETEX method. All of these methods of roughen-ing result in a surface texture with irregularly distributed, closed “lubricant pockets”.
  • EDT electrical discharge texturing
  • EBT electron beam texturing
  • PRETEX PRETEX
  • the above mentioned roughness patterns are produced on the surface of the strip in an additional cold rolling pass using a roll pass involving a small thickness reduction approx. 0.05 to 15%. In practice this additional cold rolling pass incurs correspondingly greater production costs. In addition, in order to produce the roughness pattern, it is necessary to change the work rolls that have a conven-tional roll-grind pattern for textured rolls.
  • the object of the present invention is to provide a process and a unit of the kind described at the start, by means of which the production costs for manufacturing textured strips can be reduced.
  • a further objective is to avoid the loss of capacity on a production unit caused by an additional texturing roll pass.
  • the object of the invention is achieved by providing a process comprising passing a cold rolled strip immediately after cold rolling through a roll gap of two textured rolls bearing a roughness pattern, wherein the roughness pattern is transferred to the surface of the strip as a result of the force of the textured rolls acting on the strip, and, thereafter, coiling the textured strip.
  • the cold rolled strip is drawn through the roll gap and the texturing rolls turned by the tension on the strip.
  • the texturing rolls are preferably set at a constant roll force.
  • the texturing rolls are—to advantage—roughened using electrical discharge texturing (EDT).
  • the process according to the invention is also suitable for smoothing cold rolled strips.
  • the rolls are only ground over their outer surface direction, i.e. the roll grind comprises a plurality of parallel grooves distrib-uted over the outer surface of the rolls.
  • Preferred is an arrangement in which the texturing rolls in the texturing roll stand are supported by intermediate rolls, which are in turn supported by backing rolls.
  • the backing rolls may be arranged in several sets of rolls across the width of the intermediate rolls.
  • the backing rolls are preferably joined up in co-action to hydraulic pistons set at a constant force.
  • FIG. 1 the end view of a unit for producing a strip with a textured surface
  • FIG. 2 the front elevation of a texturing roll stand
  • FIG. 3 the cross-section through the roll arrangement of a roll stand shown in FIG. 2 .
  • a unit for producing an aluminium strip with a textured surface according to FIG. 1 comprises a cold rolling mill 17 with two work rolls 18 , 20 forming a roll gap 19 and two backing rolls 22 , 24 supporting the work rolls.
  • the work rolls 18 , 20 and the backing rolls 22 , 24 are mounted in a mill stand 26 in a known manner.
  • a texturing roll stand 28 which is smaller than the cold rolling mill 17 .
  • the texturing roll stand 28 exhibits two texturing rolls 38 , 40 which delimit a roll gap 39 and are supported by a pair of intermediate rolls 42 , 44 .
  • Each pair of intermediate rolls 42 , 44 is supported by five sets of three backing rolls 46 , 48 .
  • the backing rolls 46 , 48 are mounted in beams 50 , 52 which extend over the width of the rolls.
  • the upper beam 50 is supported by an upper part 54 of the roll stand frame via hydraulic pressure type pistons 58
  • the lower beam 52 lies directly on a lower part 56 of the roll stand frame. Both parts 54 , 56 of the roll stand frame may be moved towards and away from each other by means of hydraulic raising or lowering pistons 60 , 62 i.e.
  • the roll gap 39 can be opened as desired viz., when no texturing pass is required, or when the necessary dimension for a texturing pass is being adjusted.
  • the roll force is adjusted via the hydraulic pistons 58 and thus the reduction in strip thickness during the texturing roll pass.
  • the roll force is set by via the hydraulic compressive piston 58 and with that the reduction in thickness of the strip during the texturing pass.
  • a cold rolled strip coiled onto a reserve roll 14 is passed over a deflection roll 16 then fed in the rolling direction x to the roll gap 19 of the cold rolling mill 17 . After it emerges from the roll gap 19 , the strip 12 enters the roll gap 39 of the texturing mill stand 28 . On leaving the texturing mill stand 28 the strip 12 is deflected around two further deflection rolls 30 , 32 and coiled onto a spool 34 . The thickness of the strip is checked by a thick-ness measuring device 36 situated between the texturing mill stand 28 and the second deflection roll 30 . At the same time, the second deflection roll 30 serves to check the flatness of the textured strip 12 .
  • the work rolls 18 , 20 of the cold rolling mill 17 are driven and the strip 12 is drawn into the roll gap 19 by the rolls themselves.
  • the texturing rolls 38 , 40 are not driven, the strip 12 must be drawn through the texturing roll stand. This is done by the driven spool 34 .
  • the braking action of the texturing rolls 38 , 40 results in a stress- regulating effect, which leads to better flatness in the textured strip 12 .
  • the diameter of the texturing rolls 38 , 40 is of course smaller than the diameter of the driven work rolls 18 , 20 of the cold rolling mill 17 . This produces a better texture in the strip surface with the result that a smaller reduction in thickness is necessary.
  • the diameter of a texturing roll is e.g. around 350 mm.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Rolling (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Confectionery (AREA)
US10/507,065 2002-03-12 2003-02-28 Method and installation for the production of an aluminum sheet with a textured surface Abandoned US20050115295A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02405193A EP1344580A1 (de) 2002-03-12 2002-03-12 Verfahren und Anlage zur Herstellung eines Aluminiumbandes mit texturierter Oberfläche
EP02405193.0 2002-03-12
PCT/EP2003/002094 WO2003076094A1 (de) 2002-03-12 2003-02-28 Verfahren und anlage zur herstellung eines aluminiumbandes mit texturierter oberfläche

Publications (1)

Publication Number Publication Date
US20050115295A1 true US20050115295A1 (en) 2005-06-02

Family

ID=27763481

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/507,065 Abandoned US20050115295A1 (en) 2002-03-12 2003-02-28 Method and installation for the production of an aluminum sheet with a textured surface

Country Status (15)

Country Link
US (1) US20050115295A1 (pt)
EP (2) EP1344580A1 (pt)
JP (1) JP2006504529A (pt)
KR (1) KR20040084957A (pt)
CN (1) CN1638885A (pt)
AU (1) AU2003229553A1 (pt)
BR (1) BR0308314A (pt)
CA (1) CA2478648A1 (pt)
LT (1) LT5223B (pt)
LV (1) LV13244B (pt)
NO (1) NO20043808L (pt)
PL (1) PL370576A1 (pt)
RU (1) RU2004130432A (pt)
WO (1) WO2003076094A1 (pt)
ZA (1) ZA200407764B (pt)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070295229A1 (en) * 2006-03-07 2007-12-27 Raymond Sieffert Process for embossing a substrate material and substrate material
US20110219907A1 (en) * 2008-10-01 2011-09-15 Thyssenkrupp Presta Ag Sliding sleeve
WO2017055655A1 (es) * 2015-09-30 2017-04-06 Aludium Transformacion De Productos, S.L.U. Proceso de grabacion de superficies de aluminio
CN110560482A (zh) * 2019-08-23 2019-12-13 洛阳双瑞精铸钛业有限公司 一种高表面粗糙度冷轧钛卷的制备方法
US11213870B2 (en) * 2017-07-21 2022-01-04 Novelis Inc. Micro-textured surfaces via low pressure rolling
US20220285665A1 (en) * 2020-05-22 2022-09-08 Lg Energy Solution, Ltd. Electrode Rolling Apparatus Comprising Non-Coating Portion Pressing Part and Electrode Rolling Method Using the Same

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SI2572807T1 (sl) * 2011-09-22 2014-10-30 Constantia Teich Gmbh Postopek za izdelavo aluminijeve folije z integriranimi varnostnimi značilnostmi
US9457392B2 (en) 2011-11-11 2016-10-04 Alcoa Inc. Apparatus and method for imparting selected topographies to aluminum sheet metal and application there for
US20130122327A1 (en) * 2011-11-11 2013-05-16 Shen Sheu Apparatus and method for imparting selected topographies to aluminum sheet metal
AT512773B1 (de) 2012-10-29 2013-11-15 Constantia Teich Gmbh Verfahren zum Herstellen einer Aluminiumfolie mit integrierten Sicherheitsmerkmalen
SI2919925T1 (sl) * 2012-11-09 2019-08-30 Acr Ii Aluminium Group Cooperatief U.A. Naprava in postopek za prenašanje izbranih topografij na aluminijevo pločevino in uporabe za to
KR20240005179A (ko) * 2014-05-12 2024-01-11 아르코닉 테크놀로지스 엘엘씨 금속 압연 장치 및 방법
FR3025505B1 (fr) 2014-09-05 2019-03-22 Constellium Neuf-Brisach Procede de fabrication de capsules de bouchage metalliques mixtes texturees-lisses
DE102014226970A1 (de) * 2014-11-28 2016-06-02 Sms Group Gmbh Oberflächentexturierung von Umformungswerkzeugen
DE102015101580B3 (de) 2015-02-04 2016-06-02 Hydro Aluminium Rolled Products Gmbh Verfahren und Vorrichtung zum Prägewalzen eines Bandes
MX2018006809A (es) * 2015-12-04 2018-11-09 Arconic Inc Estampado para chapa texturizada por descarga electrica.
CN108723086A (zh) * 2018-06-06 2018-11-02 句容建荣汽配有限公司 压延机抽模装置
CN114535296A (zh) * 2022-02-18 2022-05-27 河南中孚高精铝材有限公司 一种铝板带edt表面轧制方法

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US2116107A (en) * 1937-06-08 1938-05-03 Wheeling Steel Corp Container, container stock, and method of making the same
US2277725A (en) * 1939-07-04 1942-03-31 Richard S Smith Decorating metallic surfaces
US2392323A (en) * 1941-12-20 1946-01-08 Joseph W Koss Rolling strip metal
US3077131A (en) * 1961-08-03 1963-02-12 Pittsburgh Steel Co Die rolling apparatus for knurling wire
US4289013A (en) * 1979-08-29 1981-09-15 Textron, Inc. Crown control for rolling mill
US5105638A (en) * 1990-07-12 1992-04-21 Mitsubishi Jukogyo Kabushiki Kaisha Method and machine for rolling a metal workpiece at a reduced rolling load
US5537851A (en) * 1993-01-05 1996-07-23 Aluminum Company Of America Sheet product produced by massive reduction in last stand of cold rolling process
US6187455B1 (en) * 1998-03-24 2001-02-13 Hunter Douglas International N.V. Decorative roll-patterned strip and process of making same
US6216516B1 (en) * 1993-03-27 2001-04-17 Sms Schloemann-Siemag Ag Reversing compact installation for cold rolling strip-shaped rolling material

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JPH06262203A (ja) * 1993-03-09 1994-09-20 Fuji Photo Film Co Ltd 平版印刷版用支持体の製造方法
EP0945198B1 (en) * 1998-03-24 2003-12-10 Hunter Douglas Industries B.V. Roll-patterned strip

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Publication number Priority date Publication date Assignee Title
US1905398A (en) * 1931-02-06 1933-04-25 Ternstedt Mfg Co Method and apparatus for making a sill plate
US2116107A (en) * 1937-06-08 1938-05-03 Wheeling Steel Corp Container, container stock, and method of making the same
US2277725A (en) * 1939-07-04 1942-03-31 Richard S Smith Decorating metallic surfaces
US2392323A (en) * 1941-12-20 1946-01-08 Joseph W Koss Rolling strip metal
US3077131A (en) * 1961-08-03 1963-02-12 Pittsburgh Steel Co Die rolling apparatus for knurling wire
US4289013A (en) * 1979-08-29 1981-09-15 Textron, Inc. Crown control for rolling mill
US5105638A (en) * 1990-07-12 1992-04-21 Mitsubishi Jukogyo Kabushiki Kaisha Method and machine for rolling a metal workpiece at a reduced rolling load
US5537851A (en) * 1993-01-05 1996-07-23 Aluminum Company Of America Sheet product produced by massive reduction in last stand of cold rolling process
US6216516B1 (en) * 1993-03-27 2001-04-17 Sms Schloemann-Siemag Ag Reversing compact installation for cold rolling strip-shaped rolling material
US6187455B1 (en) * 1998-03-24 2001-02-13 Hunter Douglas International N.V. Decorative roll-patterned strip and process of making same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070295229A1 (en) * 2006-03-07 2007-12-27 Raymond Sieffert Process for embossing a substrate material and substrate material
US20110219907A1 (en) * 2008-10-01 2011-09-15 Thyssenkrupp Presta Ag Sliding sleeve
US9010215B2 (en) * 2008-10-01 2015-04-21 Thyssenkrupp Presta Ag Sliding sleeve
WO2017055655A1 (es) * 2015-09-30 2017-04-06 Aludium Transformacion De Productos, S.L.U. Proceso de grabacion de superficies de aluminio
CN108472698A (zh) * 2015-09-30 2018-08-31 Acr第二铝业集团合作社 用于雕刻铝表面的方法
US20180272684A1 (en) * 2015-09-30 2018-09-27 ACR II Aluminium Group Cooperatief, U.A. Method for Engraving Aluminium Surfaces
US11198163B2 (en) 2015-09-30 2021-12-14 ACR II Aluminium Group Cooperatief, U.A. Method for engraving aluminium surfaces
US11213870B2 (en) * 2017-07-21 2022-01-04 Novelis Inc. Micro-textured surfaces via low pressure rolling
US11426777B2 (en) 2017-07-21 2022-08-30 Noveliss Inc. Systems and methods for controlling surface texturing of a metal substrate with low pressure rolling
US11638941B2 (en) * 2017-07-21 2023-05-02 Novelis Inc. Systems and methods for controlling flatness of a metal substrate with low pressure rolling
CN110560482A (zh) * 2019-08-23 2019-12-13 洛阳双瑞精铸钛业有限公司 一种高表面粗糙度冷轧钛卷的制备方法
US20220285665A1 (en) * 2020-05-22 2022-09-08 Lg Energy Solution, Ltd. Electrode Rolling Apparatus Comprising Non-Coating Portion Pressing Part and Electrode Rolling Method Using the Same

Also Published As

Publication number Publication date
AU2003229553A1 (en) 2003-09-22
JP2006504529A (ja) 2006-02-09
BR0308314A (pt) 2004-12-28
WO2003076094A1 (de) 2003-09-18
EP1487595A1 (de) 2004-12-22
CA2478648A1 (en) 2003-09-18
LT5223B (lt) 2005-05-25
CN1638885A (zh) 2005-07-13
PL370576A1 (en) 2005-05-30
EP1344580A1 (de) 2003-09-17
LT2004085A (en) 2005-02-25
ZA200407764B (en) 2005-07-01
LV13244B (en) 2005-04-20
RU2004130432A (ru) 2005-07-20
NO20043808L (no) 2004-09-20
KR20040084957A (ko) 2004-10-06

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