UA82887C2 - Process for making thermoplastic vulcanizates, thermoplastic vulcanizates and article made thereof - Google Patents
Process for making thermoplastic vulcanizates, thermoplastic vulcanizates and article made thereof Download PDFInfo
- Publication number
- UA82887C2 UA82887C2 UAA200600861A UAA200600861A UA82887C2 UA 82887 C2 UA82887 C2 UA 82887C2 UA A200600861 A UAA200600861 A UA A200600861A UA A200600861 A UAA200600861 A UA A200600861A UA 82887 C2 UA82887 C2 UA 82887C2
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- dispersed phase
- matrix
- ethylene
- component
- rubbers
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 70
- 229920006342 thermoplastic vulcanizate Polymers 0.000 title claims abstract description 10
- 230000008569 process Effects 0.000 title abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 24
- 238000004073 vulcanization Methods 0.000 claims abstract description 17
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000077 silane Inorganic materials 0.000 claims abstract description 10
- 239000011159 matrix material Substances 0.000 claims description 69
- 239000000203 mixture Substances 0.000 claims description 57
- 229920000642 polymer Polymers 0.000 claims description 47
- 238000004132 cross linking Methods 0.000 claims description 36
- 229920001971 elastomer Polymers 0.000 claims description 29
- -1 amine compound Chemical class 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 22
- 229920001169 thermoplastic Polymers 0.000 claims description 20
- 239000005060 rubber Substances 0.000 claims description 18
- 239000004416 thermosoftening plastic Substances 0.000 claims description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
- 239000005977 Ethylene Substances 0.000 claims description 13
- 238000011081 inoculation Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 239000000806 elastomer Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 10
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims description 10
- 229920006126 semicrystalline polymer Polymers 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- 229920006125 amorphous polymer Polymers 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 150000002978 peroxides Chemical class 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- 239000002033 PVDF binder Substances 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920003052 natural elastomer Polymers 0.000 claims description 5
- 229920001194 natural rubber Polymers 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 231100000331 toxic Toxicity 0.000 claims description 5
- 230000002588 toxic effect Effects 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
- 229920005549 butyl rubber Polymers 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920006324 polyoxymethylene Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 238000000071 blow moulding Methods 0.000 claims description 3
- 238000003490 calendering Methods 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000012764 mineral filler Substances 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical group CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- 238000005755 formation reaction Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims 3
- 229920001519 homopolymer Polymers 0.000 claims 2
- 150000007522 mineralic acids Chemical class 0.000 claims 2
- 150000002825 nitriles Chemical class 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 2
- 229920006301 statistical copolymer Polymers 0.000 claims 2
- 229920000459 Nitrile rubber Polymers 0.000 claims 1
- 238000009740 moulding (composite fabrication) Methods 0.000 claims 1
- 229920001384 propylene homopolymer Polymers 0.000 claims 1
- 238000010926 purge Methods 0.000 claims 1
- 238000012876 topography Methods 0.000 claims 1
- 210000002700 urine Anatomy 0.000 claims 1
- 238000002255 vaccination Methods 0.000 claims 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 6
- 239000012975 dibutyltin dilaurate Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 238000007664 blowing Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007580 dry-mixing Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920001198 elastomeric copolymer Polymers 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000006459 hydrosilylation reaction Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- HOZMLTCHTRHKRK-UHFFFAOYSA-N 2-methyl-1-silylprop-2-en-1-one Chemical class CC(=C)C([SiH3])=O HOZMLTCHTRHKRK-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012062 aqueous buffer Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BYOIQYHAYWYSCZ-UHFFFAOYSA-N prop-2-enoxysilane Chemical compound [SiH3]OCC=C BYOIQYHAYWYSCZ-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001525 retina Anatomy 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL15687003A IL156870A0 (en) | 2003-07-10 | 2003-07-10 | Process for making thermoplastic vulcanizates |
| PCT/IL2004/000615 WO2005005532A1 (en) | 2003-07-10 | 2004-07-08 | Process for making thermoplastic vulcanizates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA82887C2 true UA82887C2 (en) | 2008-05-26 |
Family
ID=32652260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200600861A UA82887C2 (en) | 2003-07-10 | 2004-08-07 | Process for making thermoplastic vulcanizates, thermoplastic vulcanizates and article made thereof |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7589154B2 (de) |
| EP (1) | EP1644439B1 (de) |
| JP (1) | JP2007518837A (de) |
| KR (1) | KR20060041217A (de) |
| CN (1) | CN1826378A (de) |
| AR (1) | AR045031A1 (de) |
| AT (1) | ATE427978T1 (de) |
| AU (1) | AU2004255942B2 (de) |
| BR (1) | BRPI0411870A (de) |
| CA (1) | CA2530754A1 (de) |
| CL (1) | CL2004001739A1 (de) |
| DE (1) | DE602004020476D1 (de) |
| IL (2) | IL156870A0 (de) |
| MX (1) | MXPA05014179A (de) |
| PE (1) | PE20050560A1 (de) |
| RU (1) | RU2006114387A (de) |
| UA (1) | UA82887C2 (de) |
| WO (1) | WO2005005532A1 (de) |
Families Citing this family (28)
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| WO2007147687A1 (en) * | 2006-06-23 | 2007-12-27 | Basell Poliolefine Italia S.R.L. | Polyolefin thermoplastic vulcanizate elastomers |
| WO2008059721A1 (fr) | 2006-11-17 | 2008-05-22 | Nippon Oil Corporation | Plaque de polarisation elliptique et affichage à cristaux liquides à alignement vertical |
| JP2009075533A (ja) | 2007-08-31 | 2009-04-09 | Nippon Oil Corp | 楕円偏光板および液晶表示装置 |
| WO2009056409A1 (en) * | 2007-10-31 | 2009-05-07 | Borealis Technology Oy | Silane-functionalised polyolefin compositions, products thereof and preparation processes thereof for wire and cable applications |
| WO2009056407A1 (en) * | 2007-10-31 | 2009-05-07 | Borealis Technology Oy | Silane-functionalised polyolefin compositions, products thereof and preparation processes thereof for wire and cable applications |
| WO2009095274A2 (en) * | 2008-02-02 | 2009-08-06 | Renolit Belgium N.V. | Photovoltaic modules and production process |
| JP2009300760A (ja) | 2008-06-13 | 2009-12-24 | Nippon Oil Corp | 楕円偏光板およびそれを用いた垂直配向型液晶表示装置 |
| JP2011526956A (ja) * | 2008-06-30 | 2011-10-20 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | 湿気架橋性ポリエチレン組成物 |
| US8426519B2 (en) * | 2008-08-01 | 2013-04-23 | Union Carbide Chemicals & Plastics Technology Llc | Silicone-thermoplastic polymer reactive blends and copolymer products |
| BR112014017476B1 (pt) | 2012-01-18 | 2021-03-30 | Iowa State University Research Foundation, Inc | Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico |
| CA2910680A1 (en) | 2013-05-20 | 2014-11-27 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
| US10040888B1 (en) | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
| US10100139B2 (en) | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
| US10371292B2 (en) | 2014-07-02 | 2019-08-06 | Cooper-Standard Automotive Inc. | Hose, abrasion resistant composition, and process of making a hose |
| WO2017138641A1 (ja) * | 2016-02-12 | 2017-08-17 | 古河電気工業株式会社 | 耐熱性塩素含有架橋樹脂成形体及びその製造方法、シランマスターバッチ、マスターバッチ混合物及びその成形体、並びに、耐熱性製品 |
| CN106009449B (zh) * | 2016-05-25 | 2020-06-02 | 北京化工大学 | 一种耐高温耐油热塑性硫化胶及其制备方法 |
| JP6901503B2 (ja) | 2016-12-10 | 2021-07-14 | クーパー−スタンダード・オートモーティブ・インコーポレーテッド | 固定用シール、組成物、およびこれらを作製する方法 |
| CN109563329A (zh) * | 2016-12-10 | 2019-04-02 | 库珀标准汽车公司 | 聚烯烃弹性体组合物及其制备方法 |
| EP3873980A1 (de) * | 2018-10-30 | 2021-09-08 | Dow Global Technologies LLC | Thermoplastisches vulkanisatartiges material |
| TWI704179B (zh) * | 2018-12-07 | 2020-09-11 | 財團法人工業技術研究院 | 熱塑性硫化彈性體及其製造方法 |
| WO2020129038A1 (en) | 2018-12-17 | 2020-06-25 | Carmel Olefins Ltd. | Thermoplastic shape-stable polymer compositions for storing thermal energy |
| US11413800B2 (en) * | 2019-05-20 | 2022-08-16 | Kraton Polymers Llc | Molding compositions and articles made thereof |
| CN110330692B (zh) * | 2019-07-23 | 2021-06-01 | 华侨大学 | 一种液体橡胶系动态交联剂及其应用 |
| JP2021147416A (ja) * | 2020-03-16 | 2021-09-27 | Ｍｃｐｐイノベーション合同会社 | 変性エラストマー組成物、架橋エラストマー組成物及びその射出成形体 |
| CN111484605B (zh) * | 2020-05-18 | 2022-04-26 | 郑州大学 | 一种用于与聚乳酸动态硫化的全生物基不饱和聚酯预聚物及其制备方法 |
| CN112694740A (zh) * | 2020-12-10 | 2021-04-23 | 常州迪声声学科技有限公司 | 一种抗冲击汽车前挡板减震垫及其制备方法 |
| EP4271752A1 (de) * | 2020-12-30 | 2023-11-08 | Avient Corporation | Polymermischungen aus thermoplastischem elastomer und vernetztem silangepfropftem polyolefin |
| CN112778990B (zh) * | 2021-02-05 | 2022-06-03 | 西南石油大学 | 一种用于油田注水井的污水混配暂堵剂及其制备方法 |
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| US4130534A (en) | 1976-12-27 | 1978-12-19 | Monsanto Company | Elastoplastic compositions of butyl rubber and polyolefin resin |
| US4183876A (en) | 1978-11-27 | 1980-01-15 | Monsanto Company | Thermoplastic compositions of polyalkenamer rubber and polyolefin resin |
| JPS59115351A (ja) * | 1982-12-22 | 1984-07-03 | Mitsubishi Petrochem Co Ltd | プロピレン系樹脂架橋体の製造方法 |
| US4614764A (en) | 1985-03-06 | 1986-09-30 | Mobil Oil Corporation | Linear low density ethylene polymers blended with modified linear low density ethylene polymers |
| US4803244A (en) | 1987-11-16 | 1989-02-07 | Union Carbide Corporation | Process for the preparation of thermoplastic elastomers |
| US4873042A (en) * | 1988-03-25 | 1989-10-10 | Union Carbide Chemicals And Plastics Company Inc. | Process for extruding a thermoplastic copolymer |
| IT1227341B (it) | 1988-09-13 | 1991-04-08 | Ausimont Spa | Composizioni poliolefiniche plasto-elastomeriche e procedimento per la loro preparazione con metodi di vulcanizzazione dinamica |
| JPH0618951B2 (ja) * | 1989-07-17 | 1994-03-16 | チッソ株式会社 | ポリオレフィン系熱可塑性エラストマー組成物の製造方法 |
| GB9308669D0 (en) | 1993-04-27 | 1993-06-09 | Du Pont Canada | Grafting of monomers onto polyolefins in presence of organic peroxides |
| DE4402943C2 (de) | 1994-02-01 | 1996-03-28 | Rustige Bernhard Gmbh & Co Kg | Polymerwerkstoff und Verfahren zu dessen Herstellung |
| US5623030A (en) * | 1994-12-01 | 1997-04-22 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Curable composition and process for producing molded articles using the same |
| US5840800A (en) * | 1995-11-02 | 1998-11-24 | Dow Corning Corporation | Crosslinked emulsions of pre-formed silicon modified organic polymers |
| US5672660A (en) | 1995-12-01 | 1997-09-30 | Advanced Elastomer Systems, L.P. | Hydrosilylation crosslinking |
| JP2001506681A (ja) | 1996-11-25 | 2001-05-22 | デュポン ダウ エラストマーズ エルエルシー | 形態が制御されたポリマーブレンド |
| BR9906549B1 (pt) | 1998-06-22 | 2009-01-13 | composições de elastÈmeros termoplásticos vulcanizados de silano e processo para a preparação das mesmas. | |
| US6222008B1 (en) | 1999-05-06 | 2001-04-24 | Shell Oil Company | Treatment of polymer solution with acid and ammonia to improve polymer color |
| DE69914175T2 (de) * | 1999-05-06 | 2004-09-02 | Fritz, Hans-Gerhard, Prof.Dr.-Ing. | Thermoplastische Zusammensetzung und Verfahren zur Herstellung derselben |
| US6476132B1 (en) * | 1999-07-23 | 2002-11-05 | Advanced Elastomer Systems, L.P. | Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set |
| DE10142555A1 (de) | 2001-08-30 | 2003-03-20 | Degussa | Mittel für die Verbesserung der Scorch-Bedingungen bei der Herstellung gepfropfter und/oder vernetzter Polymere sowie gefüllter Kunststoffe |
-
2003
- 2003-07-10 IL IL15687003A patent/IL156870A0/xx unknown
-
2004
- 2004-07-07 AR ARP040102384A patent/AR045031A1/es unknown
- 2004-07-07 PE PE2004000650A patent/PE20050560A1/es not_active Application Discontinuation
- 2004-07-08 AT AT04744955T patent/ATE427978T1/de not_active IP Right Cessation
- 2004-07-08 DE DE602004020476T patent/DE602004020476D1/de active Active
- 2004-07-08 KR KR1020067000494A patent/KR20060041217A/ko not_active Application Discontinuation
- 2004-07-08 CN CNA2004800195466A patent/CN1826378A/zh active Pending
- 2004-07-08 JP JP2006518495A patent/JP2007518837A/ja not_active Withdrawn
- 2004-07-08 BR BRPI0411870-7A patent/BRPI0411870A/pt not_active IP Right Cessation
- 2004-07-08 MX MXPA05014179A patent/MXPA05014179A/es unknown
- 2004-07-08 US US10/561,825 patent/US7589154B2/en active Active
- 2004-07-08 RU RU2006114387/04A patent/RU2006114387A/ru not_active Application Discontinuation
- 2004-07-08 WO PCT/IL2004/000615 patent/WO2005005532A1/en active Search and Examination
- 2004-07-08 AU AU2004255942A patent/AU2004255942B2/en not_active Expired - Fee Related
- 2004-07-08 EP EP04744955A patent/EP1644439B1/de not_active Not-in-force
- 2004-07-08 CA CA002530754A patent/CA2530754A1/en not_active Abandoned
- 2004-07-09 CL CL200401739A patent/CL2004001739A1/es unknown
- 2004-08-07 UA UAA200600861A patent/UA82887C2/uk unknown
-
2005
- 2005-12-22 IL IL172766A patent/IL172766A/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0411870A (pt) | 2006-08-08 |
| AU2004255942A1 (en) | 2005-01-20 |
| DE602004020476D1 (de) | 2009-05-20 |
| KR20060041217A (ko) | 2006-05-11 |
| JP2007518837A (ja) | 2007-07-12 |
| MXPA05014179A (es) | 2006-07-03 |
| IL156870A0 (en) | 2004-02-08 |
| RU2006114387A (ru) | 2007-11-20 |
| CA2530754A1 (en) | 2005-01-20 |
| ATE427978T1 (de) | 2009-04-15 |
| CN1826378A (zh) | 2006-08-30 |
| US20060155072A1 (en) | 2006-07-13 |
| WO2005005532A1 (en) | 2005-01-20 |
| EP1644439A1 (de) | 2006-04-12 |
| AR045031A1 (es) | 2005-10-12 |
| AU2004255942B2 (en) | 2008-11-06 |
| US7589154B2 (en) | 2009-09-15 |
| IL172766A0 (en) | 2006-04-10 |
| PE20050560A1 (es) | 2005-08-11 |
| IL172766A (en) | 2011-03-31 |
| CL2004001739A1 (es) | 2005-05-27 |
| EP1644439B1 (de) | 2009-04-08 |
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