UA76178C2 - Method for preparing a composite solid material based on metal hexacyanoferrate and method for fixing mineral pollutants using this material - Google Patents
Method for preparing a composite solid material based on metal hexacyanoferrate and method for fixing mineral pollutants using this material Download PDFInfo
- Publication number
- UA76178C2 UA76178C2 UA2004021276A UA2004021276A UA76178C2 UA 76178 C2 UA76178 C2 UA 76178C2 UA 2004021276 A UA2004021276 A UA 2004021276A UA 2004021276 A UA2004021276 A UA 2004021276A UA 76178 C2 UA76178 C2 UA 76178C2
- Authority
- UA
- Ukraine
- Prior art keywords
- hexacyanoferrate
- carrier
- solution
- specified
- solid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 159
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 60
- 239000002184 metal Substances 0.000 title claims abstract description 60
- 239000002131 composite material Substances 0.000 title claims abstract description 43
- 239000011343 solid material Substances 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 title claims description 87
- 239000003344 environmental pollutant Substances 0.000 title abstract description 3
- 231100000719 pollutant Toxicity 0.000 title abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 title abstract 2
- 239000011707 mineral Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 claims abstract description 81
- 239000007787 solid Substances 0.000 claims abstract description 79
- 238000005406 washing Methods 0.000 claims abstract description 43
- 239000007788 liquid Substances 0.000 claims abstract description 39
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 20
- 239000000243 solution Substances 0.000 claims description 88
- 238000005349 anion exchange Methods 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 230000008569 process Effects 0.000 claims description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 239000007864 aqueous solution Substances 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 19
- 150000001768 cations Chemical class 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- -1 alkali metal hexacyanoferrate Chemical class 0.000 claims description 14
- 229920002873 Polyethylenimine Polymers 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 230000002285 radioactive effect Effects 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 125000002091 cationic group Chemical group 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000005470 impregnation Methods 0.000 claims description 8
- 229920000620 organic polymer Polymers 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000011109 contamination Methods 0.000 claims description 6
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 6
- 125000001302 tertiary amino group Chemical group 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- AWDBHOZBRXWRKS-UHFFFAOYSA-N tetrapotassium;iron(6+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] AWDBHOZBRXWRKS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052742 iron Chemical class 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- 239000003295 industrial effluent Substances 0.000 claims 1
- VRWKTAYJTKRVCU-UHFFFAOYSA-N iron(6+);hexacyanide Chemical compound [Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] VRWKTAYJTKRVCU-UHFFFAOYSA-N 0.000 claims 1
- 150000002823 nitrates Chemical group 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 238000012876 topography Methods 0.000 claims 1
- 238000005243 fluidization Methods 0.000 abstract description 7
- 239000000047 product Substances 0.000 description 24
- 230000015572 biosynthetic process Effects 0.000 description 23
- 239000010408 film Substances 0.000 description 20
- 239000012535 impurity Substances 0.000 description 15
- 230000000737 periodic effect Effects 0.000 description 15
- 238000003786 synthesis reaction Methods 0.000 description 15
- 229910052792 caesium Inorganic materials 0.000 description 14
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 14
- 238000004132 cross linking Methods 0.000 description 13
- 229920000209 Hexadimethrine bromide Polymers 0.000 description 11
- 238000010924 continuous production Methods 0.000 description 11
- 229910052814 silicon oxide Inorganic materials 0.000 description 11
- 238000004140 cleaning Methods 0.000 description 10
- 238000009826 distribution Methods 0.000 description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000010409 thin film Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 238000000746 purification Methods 0.000 description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 6
- 229910017604 nitric acid Inorganic materials 0.000 description 6
- 239000007790 solid phase Substances 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- GTSHREYGKSITGK-UHFFFAOYSA-N sodium ferrocyanide Chemical compound [Na+].[Na+].[Na+].[Na+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] GTSHREYGKSITGK-UHFFFAOYSA-N 0.000 description 5
- 235000012247 sodium ferrocyanide Nutrition 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000010923 batch production Methods 0.000 description 4
- 239000007888 film coating Substances 0.000 description 4
- 238000009501 film coating Methods 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 235000010344 sodium nitrate Nutrition 0.000 description 4
- 239000004317 sodium nitrate Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000007853 buffer solution Substances 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000004017 vitrification Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000009881 electrostatic interaction Effects 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 2
- 238000001730 gamma-ray spectroscopy Methods 0.000 description 2
- 231100001240 inorganic pollutant Toxicity 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 239000005373 porous glass Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- SHKUUQIDMUMQQK-UHFFFAOYSA-N 2-[4-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COCCCCOCC1CO1 SHKUUQIDMUMQQK-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 241000632511 Daviesia arborea Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000010857 liquid radioactive waste Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000595 mu-metal Inorganic materials 0.000 description 1
- 238000005025 nuclear technology Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002901 radioactive waste Substances 0.000 description 1
- 239000002354 radioactive wastewater Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 239000000264 sodium ferrocyanide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DCXPBOFGQPCWJY-UHFFFAOYSA-N trisodium;iron(3+);hexacyanide Chemical compound [Na+].[Na+].[Na+].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCXPBOFGQPCWJY-UHFFFAOYSA-N 0.000 description 1
- 238000002255 vaccination Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/17—Organic material containing also inorganic materials, e.g. inert material coated with an ion-exchange resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31721—Of polyimide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0111005A FR2828819B1 (fr) | 2001-08-22 | 2001-08-22 | Procede de preparation d'un materiau solide composite a base d'hexacyanoferrates, et procede de fixation de polluants mineraux le mettant en oeuvre |
| PCT/FR2002/002906 WO2003018193A1 (fr) | 2001-08-22 | 2002-08-20 | Procede de preparation d'un materiau solide composite a base d'hexacyanoferrates, et procede de fixation de polluants mineraux le mettant en oeuvre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA76178C2 true UA76178C2 (en) | 2006-07-17 |
Family
ID=8866661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2004021276A UA76178C2 (en) | 2001-08-22 | 2002-08-20 | Method for preparing a composite solid material based on metal hexacyanoferrate and method for fixing mineral pollutants using this material |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20040178385A1 (fr) |
| EP (1) | EP1419009A1 (fr) |
| JP (1) | JP2005500158A (fr) |
| EA (1) | EA005634B1 (fr) |
| FR (1) | FR2828819B1 (fr) |
| UA (1) | UA76178C2 (fr) |
| WO (1) | WO2003018193A1 (fr) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2828818B1 (fr) * | 2001-08-22 | 2003-12-05 | Commissariat Energie Atomique | Materiau solide composite fixant des polluants mineraux, son procede de preparation et procede de fixation de polluants mineraux le mettant en oeuvre |
| FR2859924B1 (fr) * | 2003-09-23 | 2006-02-03 | Commissariat Energie Atomique | Dispositif et procede de fixation de polluants mineraux |
| UA82581C2 (uk) * | 2006-06-29 | 2008-04-25 | Фос Интернешонал С.А. | Спосіб дезактивації рідких радіоактивних відходів (варіанти) |
| FR2945756B1 (fr) * | 2009-05-20 | 2011-08-05 | Commissariat Energie Atomique | Materiau solide nanocomposite a base d'hexa-et octacyanometallates, son procede de preparation et procede de fixation de polluants mineraux le mettant en oeuvre. |
| CA2792512C (fr) | 2010-03-09 | 2018-01-02 | Kurion, Inc. | Separation et vitrification specifiques d'isotopes au moyen de milieux specifiques d'ions |
| WO2012006417A2 (fr) | 2010-07-07 | 2012-01-12 | The Regents Of The University Of Colorado, A Body Corporate | Système et procédé d'élimination de métaux |
| WO2012137752A1 (fr) * | 2011-04-07 | 2012-10-11 | 国立大学法人名古屋大学 | Matériau adsorbant de substances organiques et support adsorbant de substances organiques comportant ledit matériau adsorbant de substances organiques |
| JP5715591B2 (ja) * | 2011-05-06 | 2015-05-07 | 大日精化工業株式会社 | 紺青を含む複合体及びそれを用いた放射性セシウム吸着材 |
| JP5858473B2 (ja) * | 2011-05-06 | 2016-02-10 | 国立研究開発法人産業技術総合研究所 | 金属錯体を含む複合体及びそれを用いた放射性セシウム吸着材 |
| CA2744780C (fr) | 2011-06-23 | 2014-01-14 | Willard E. Wood | Materiel et procede servant a absorber des substances indesirables ou ciblees a partir d'un gaz ou d'un produit en phase vapeur |
| US9455054B2 (en) | 2011-08-19 | 2016-09-27 | The Foundation For The Promotion Of Industrial Science | Radioactive cesium adsorbent, method for producing the same, and method for removing radioactive cesium in environment with said adsorbent |
| CN104144883B (zh) * | 2011-12-23 | 2018-05-25 | 图萨尔公司 | 用于在炭介质上动态流化装载配体的系统和相关方法 |
| JP5725621B2 (ja) * | 2012-01-18 | 2015-05-27 | 大日精化工業株式会社 | 放射性ヨウ素・放射性セシウムの除去方法及び放射性ヨウ素・放射性セシウムの除去用の親水性樹脂組成物 |
| WO2013108892A1 (fr) * | 2012-01-18 | 2013-07-25 | 大日精化工業株式会社 | Procédé pour l'élimination de césium radioactif, composition de résine hydrophile pour l'élimination de césium radioactif, procédé pour l'élimination d'iode radioactif et de césium radioactif et composition de résine hydrophile pour l'élimination d'iode radioactif et de césium radioactif |
| DE102013004317A1 (de) | 2012-03-26 | 2013-09-26 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Lyocell-Formkörper zur selektiven Bindung von einwertigen Schwermetallionen, insbesondere von Thallium- und Caesiumionen und deren radioaktiven Isotopen |
| WO2013191781A2 (fr) | 2012-03-26 | 2013-12-27 | Kurion, Inc. | Régénération sélective de résines de milieux spécifiques à un isotope dans des systèmes pour séparation d'isotopes radioactifs de matières de déchets liquides |
| JP5980599B2 (ja) * | 2012-07-09 | 2016-08-31 | ユニチカトレーディング株式会社 | セシウム吸着用繊維構造物およびその製造方法 |
| JP2014018734A (ja) * | 2012-07-18 | 2014-02-03 | Dainichiseika Color & Chem Mfg Co Ltd | 被覆ゼオライト粒子及びそれを含むセシウム除去材 |
| JP2014108379A (ja) * | 2012-11-30 | 2014-06-12 | Dainippon Printing Co Ltd | セシウム吸着材 |
| JP6203534B2 (ja) * | 2013-05-16 | 2017-09-27 | ユニチカトレーディング株式会社 | セシウムイオン吸着用繊維構造物およびその製造方法 |
| JP6211838B2 (ja) * | 2013-07-12 | 2017-10-11 | ユニチカトレーディング株式会社 | セシウムイオン吸着用水処理担体及びその製造方法 |
| US10435528B2 (en) | 2013-09-17 | 2019-10-08 | Aquanano Llc | High-capacity anion exchange materials |
| US10946075B1 (en) * | 2014-03-15 | 2021-03-16 | Suzanne J Paxton-Pierson | Radioprotection, radiomitigation and radiorecovery |
| WO2016043808A1 (fr) * | 2014-09-17 | 2016-03-24 | Aquanano Llc | Matériau échangeur d'anions à haute capacité |
| FR3037583B1 (fr) * | 2015-06-17 | 2020-01-03 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Materiaux monolithiques inorganiques alveolaires echangeurs cationiques, leur procede de preparation, et procede de separation les mettant en œuvre. |
| JP7486148B2 (ja) * | 2018-12-20 | 2024-05-17 | 日揮ユニバーサル株式会社 | 汚染物質除去剤、汚染物質除去部材、及び汚染物質の除去方法 |
| RU2701530C1 (ru) * | 2018-12-28 | 2019-09-27 | Федеральное государственное автономное образовательное учреждение высшего образования "Дальневосточный федеральный университет" (ДВФУ) | Способ получения сорбента для извлечения ионов цезия |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1392506A (fr) * | 1963-11-08 | 1965-03-19 | Saint Gobain Nucleaire | Procédé de préparation du baryum 137 |
| GB1115258A (en) * | 1967-02-22 | 1968-05-29 | Saint Gobain Techn Nouvelles | Method of cesium removal |
| JP2560253B2 (ja) * | 1994-05-18 | 1996-12-04 | 工業技術院長 | セシウム分離用イオン交換体の製造および再生方法 |
| US5632887A (en) * | 1995-06-07 | 1997-05-27 | The Wardley Corporation | Fluidized bed aquarium filter |
| FR2737426A1 (fr) * | 1995-08-03 | 1997-02-07 | Stmi Soc Tech Milieu Ionisant | Procede de preparation de ferrocyanures et ferricyanures de metaux impregnes sur un support |
| KR19990087589A (ko) * | 1996-03-08 | 1999-12-27 | 스프레이그 로버트 월터 | 세슘 이온 흡착제 및 그 제조 방법과 사용 방법 |
| FR2765812B1 (fr) * | 1997-07-09 | 1999-09-24 | Commissariat Energie Atomique | Materiau solide composite fixant des polluants mineraux a base d'hexacyanoferrates et de polymere en couche pelliculaire, son procede de preparation, et procede de fixation de polluants mineraux le mettant en oeuvre |
| JP3749941B2 (ja) * | 1997-09-04 | 2006-03-01 | 独立行政法人産業技術総合研究所 | セシウム分離材の製造方法 |
-
2001
- 2001-08-22 FR FR0111005A patent/FR2828819B1/fr not_active Expired - Fee Related
-
2002
- 2002-08-20 EP EP02774878A patent/EP1419009A1/fr not_active Withdrawn
- 2002-08-20 WO PCT/FR2002/002906 patent/WO2003018193A1/fr active Application Filing
- 2002-08-20 JP JP2003522699A patent/JP2005500158A/ja active Pending
- 2002-08-20 US US10/486,829 patent/US20040178385A1/en not_active Abandoned
- 2002-08-20 EA EA200400327A patent/EA005634B1/ru not_active IP Right Cessation
- 2002-08-20 UA UA2004021276A patent/UA76178C2/uk unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005500158A (ja) | 2005-01-06 |
| US20040178385A1 (en) | 2004-09-16 |
| EP1419009A1 (fr) | 2004-05-19 |
| EA200400327A1 (ru) | 2004-08-26 |
| EA005634B1 (ru) | 2005-04-28 |
| FR2828819B1 (fr) | 2003-10-24 |
| FR2828819A1 (fr) | 2003-02-28 |
| WO2003018193A1 (fr) | 2003-03-06 |
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