UA74775C2 - High concentrated aqueous composition of the monoethanolammonium salt of n-phosphonomethylglycine and a method to control undesired plants - Google Patents
High concentrated aqueous composition of the monoethanolammonium salt of n-phosphonomethylglycine and a method to control undesired plants Download PDFInfo
- Publication number
- UA74775C2 UA74775C2 UA2001064346A UA2001064346A UA74775C2 UA 74775 C2 UA74775 C2 UA 74775C2 UA 2001064346 A UA2001064346 A UA 2001064346A UA 2001064346 A UA2001064346 A UA 2001064346A UA 74775 C2 UA74775 C2 UA 74775C2
- Authority
- UA
- Ukraine
- Prior art keywords
- composition
- glyphosate
- salt
- phosphonomethylglycine
- group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 227
- 150000003839 salts Chemical class 0.000 title claims abstract description 163
- 238000000034 method Methods 0.000 title claims description 20
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract description 196
- 239000004094 surface-active agent Substances 0.000 claims abstract description 138
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 68
- 239000007864 aqueous solution Substances 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000243 solution Substances 0.000 claims abstract description 28
- 239000002253 acid Substances 0.000 claims abstract description 25
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 239000012141 concentrate Substances 0.000 claims description 48
- -1 polyoxyethylene chains Polymers 0.000 claims description 45
- 239000004009 herbicide Substances 0.000 claims description 42
- 239000013543 active substance Substances 0.000 claims description 34
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 18
- 125000000129 anionic group Chemical group 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 125000006353 oxyethylene group Chemical group 0.000 claims description 15
- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- 229920006395 saturated elastomer Polymers 0.000 claims description 13
- 238000003860 storage Methods 0.000 claims description 12
- 125000003277 amino group Chemical group 0.000 claims description 11
- 150000007970 thio esters Chemical class 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 6
- 125000002312 hydrocarbylidene group Chemical group 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 6
- 150000003462 sulfoxides Chemical class 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000003568 thioethers Chemical group 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 235000013305 food Nutrition 0.000 claims 1
- 239000005562 Glyphosate Substances 0.000 description 145
- 229940097068 glyphosate Drugs 0.000 description 145
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 32
- 230000005484 gravity Effects 0.000 description 13
- 150000001412 amines Chemical class 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000013078 crystal Substances 0.000 description 10
- 239000004480 active ingredient Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 150000003973 alkyl amines Chemical group 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
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- 239000000654 additive Substances 0.000 description 5
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- 239000003093 cationic surfactant Substances 0.000 description 5
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- 238000005086 pumping Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 150000005215 alkyl ethers Chemical class 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- HUBANNPOLNYSAD-UHFFFAOYSA-N clopyralid Chemical group OC(=O)C1=NC(Cl)=CC=C1Cl HUBANNPOLNYSAD-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
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- 125000001165 hydrophobic group Chemical group 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 206010015946 Eye irritation Diseases 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 244000062793 Sorghum vulgare Species 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
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- YHKBGVDUSSWOAB-UHFFFAOYSA-N 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl}propanoic acid Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(CC(Cl)C(O)=O)=C(Cl)C=C1F YHKBGVDUSSWOAB-UHFFFAOYSA-N 0.000 description 2
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- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000005504 Dicamba Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000005595 Picloram Substances 0.000 description 2
- RORFESPGBUIBMY-UHFFFAOYSA-N Talcamine Natural products COC(=O)c1ccc(Oc2c(OC)ccc(CC3N(C)CCc4cc(OC)c(OC)c(Oc5cc6C(=O)N(C)CCc6cc5OC)c34)c2OC)cc1 RORFESPGBUIBMY-UHFFFAOYSA-N 0.000 description 2
- 239000005627 Triclopyr Substances 0.000 description 2
- 240000003864 Ulex europaeus Species 0.000 description 2
- 235000010730 Ulex europaeus Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- NUFNQYOELLVIPL-UHFFFAOYSA-N acifluorfen Chemical compound C1=C([N+]([O-])=O)C(C(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NUFNQYOELLVIPL-UHFFFAOYSA-N 0.000 description 2
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- 235000005822 corn Nutrition 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 2
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- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- QYPPRTNMGCREIM-UHFFFAOYSA-N methylarsonic acid Chemical compound C[As](O)(O)=O QYPPRTNMGCREIM-UHFFFAOYSA-N 0.000 description 2
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
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- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- PUIYMUZLKQOUOZ-UHFFFAOYSA-N isoproturon Chemical compound CC(C)C1=CC=C(NC(=O)N(C)C)C=C1 PUIYMUZLKQOUOZ-UHFFFAOYSA-N 0.000 description 1
- PMHURSZHKKJGBM-UHFFFAOYSA-N isoxaben Chemical compound O1N=C(C(C)(CC)CC)C=C1NC(=O)C1=C(OC)C=CC=C1OC PMHURSZHKKJGBM-UHFFFAOYSA-N 0.000 description 1
- CONWAEURSVPLRM-UHFFFAOYSA-N lactofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC(C)C(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 CONWAEURSVPLRM-UHFFFAOYSA-N 0.000 description 1
- ZTMKADLOSYKWCA-UHFFFAOYSA-N lenacil Chemical compound O=C1NC=2CCCC=2C(=O)N1C1CCCCC1 ZTMKADLOSYKWCA-UHFFFAOYSA-N 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XIGAUIHYSDTJHW-UHFFFAOYSA-N mefenacet Chemical compound N=1C2=CC=CC=C2SC=1OCC(=O)N(C)C1=CC=CC=C1 XIGAUIHYSDTJHW-UHFFFAOYSA-N 0.000 description 1
- VHCNQEUWZYOAEV-UHFFFAOYSA-N metamitron Chemical compound O=C1N(N)C(C)=NN=C1C1=CC=CC=C1 VHCNQEUWZYOAEV-UHFFFAOYSA-N 0.000 description 1
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 description 1
- MFSWTRQUCLNFOM-UHFFFAOYSA-N methyl 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MFSWTRQUCLNFOM-UHFFFAOYSA-N 0.000 description 1
- RBNIGDFIUWJJEV-UHFFFAOYSA-N methyl 2-(n-benzoyl-3-chloro-4-fluoroanilino)propanoate Chemical group C=1C=C(F)C(Cl)=CC=1N(C(C)C(=O)OC)C(=O)C1=CC=CC=C1 RBNIGDFIUWJJEV-UHFFFAOYSA-N 0.000 description 1
- NDNKHWUXXOFHTD-UHFFFAOYSA-N metizoline Chemical compound CC=1SC2=CC=CC=C2C=1CC1=NCCN1 NDNKHWUXXOFHTD-UHFFFAOYSA-N 0.000 description 1
- 229960002939 metizoline Drugs 0.000 description 1
- DSRNRYQBBJQVCW-UHFFFAOYSA-N metoxuron Chemical compound COC1=CC=C(NC(=O)N(C)C)C=C1Cl DSRNRYQBBJQVCW-UHFFFAOYSA-N 0.000 description 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000286 mucous membrane, eye irritation or corrosion testing Toxicity 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- NVGOPFQZYCNLDU-UHFFFAOYSA-N norflurazon Chemical compound O=C1C(Cl)=C(NC)C=NN1C1=CC=CC(C(F)(F)F)=C1 NVGOPFQZYCNLDU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- LLLFASISUZUJEQ-UHFFFAOYSA-N orbencarb Chemical compound CCN(CC)C(=O)SCC1=CC=CC=C1Cl LLLFASISUZUJEQ-UHFFFAOYSA-N 0.000 description 1
- UNAHYJYOSSSJHH-UHFFFAOYSA-N oryzalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(N)(=O)=O)C=C1[N+]([O-])=O UNAHYJYOSSSJHH-UHFFFAOYSA-N 0.000 description 1
- IOXAXYHXMLCCJJ-UHFFFAOYSA-N oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC2COC2)=N1 IOXAXYHXMLCCJJ-UHFFFAOYSA-N 0.000 description 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- JZPKLLLUDLHCEL-UHFFFAOYSA-N pentoxazone Chemical compound O=C1C(=C(C)C)OC(=O)N1C1=CC(OC2CCCC2)=C(Cl)C=C1F JZPKLLLUDLHCEL-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- IDOWTHOLJBTAFI-UHFFFAOYSA-N phenmedipham Chemical compound COC(=O)NC1=CC=CC(OC(=O)NC=2C=C(C)C=CC=2)=C1 IDOWTHOLJBTAFI-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- ISEUFVQQFVOBCY-UHFFFAOYSA-N prometon Chemical compound COC1=NC(NC(C)C)=NC(NC(C)C)=N1 ISEUFVQQFVOBCY-UHFFFAOYSA-N 0.000 description 1
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 description 1
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 description 1
- FROBCXTULYFHEJ-OAHLLOKOSA-N propaquizafop Chemical compound C1=CC(O[C@H](C)C(=O)OCCON=C(C)C)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 FROBCXTULYFHEJ-OAHLLOKOSA-N 0.000 description 1
- WJNRPILHGGKWCK-UHFFFAOYSA-N propazine Chemical compound CC(C)NC1=NC(Cl)=NC(NC(C)C)=N1 WJNRPILHGGKWCK-UHFFFAOYSA-N 0.000 description 1
- VXPLXMJHHKHSOA-UHFFFAOYSA-N propham Chemical compound CC(C)OC(=O)NC1=CC=CC=C1 VXPLXMJHHKHSOA-UHFFFAOYSA-N 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- RJKCKKDSSSRYCB-UHFFFAOYSA-N tebutam Chemical compound CC(C)(C)C(=O)N(C(C)C)CC1=CC=CC=C1 RJKCKKDSSSRYCB-UHFFFAOYSA-N 0.000 description 1
- BCQMBFHBDZVHKU-UHFFFAOYSA-N terbumeton Chemical compound CCNC1=NC(NC(C)(C)C)=NC(OC)=N1 BCQMBFHBDZVHKU-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- SRVJKTDHMYAMHA-WUXMJOGZSA-N thioacetazone Chemical group CC(=O)NC1=CC=C(\C=N\NC(N)=S)C=C1 SRVJKTDHMYAMHA-WUXMJOGZSA-N 0.000 description 1
- 229960003231 thioacetazone Drugs 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical class C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10953298P | 1998-11-23 | 1998-11-23 | |
| PCT/US1999/027602 WO2000030452A1 (en) | 1998-11-23 | 1999-11-19 | Highly concentrated aqueous glyphosate compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA74775C2 true UA74775C2 (en) | 2006-02-15 |
Family
ID=22328176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2001064346A UA74775C2 (en) | 1998-11-23 | 1999-11-19 | High concentrated aqueous composition of the monoethanolammonium salt of n-phosphonomethylglycine and a method to control undesired plants |
Country Status (26)
| Country | Link |
|---|---|
| US (2) | US6277788B1 (cs) |
| EP (1) | EP1133233B1 (cs) |
| JP (1) | JP4652573B2 (cs) |
| KR (1) | KR20010104684A (cs) |
| CN (1) | CN1277473C (cs) |
| AR (1) | AR018211A1 (cs) |
| AT (1) | ATE275342T1 (cs) |
| AU (1) | AU775094B2 (cs) |
| BR (1) | BR9915566B1 (cs) |
| CA (1) | CA2351386C (cs) |
| CO (1) | CO5210930A1 (cs) |
| CZ (1) | CZ304306B6 (cs) |
| DE (1) | DE69920035T2 (cs) |
| EA (1) | EA200100578A1 (cs) |
| ES (1) | ES2228161T3 (cs) |
| GT (1) | GT199900199A (cs) |
| HU (1) | HU229572B1 (cs) |
| IL (1) | IL143272A0 (cs) |
| MY (1) | MY122060A (cs) |
| NO (1) | NO20012502L (cs) |
| NZ (1) | NZ511850A (cs) |
| PL (1) | PL348907A1 (cs) |
| SK (1) | SK7072001A3 (cs) |
| TR (1) | TR200101524T2 (cs) |
| UA (1) | UA74775C2 (cs) |
| WO (1) | WO2000030452A1 (cs) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9819693D0 (en) | 1998-09-10 | 1998-11-04 | Zeneca Ltd | Glyphosate formulation |
| BR9915566B1 (pt) * | 1998-11-23 | 2011-11-01 | composição herbicida e processo herbicida. | |
| CA2369572A1 (en) * | 1998-12-23 | 2000-07-06 | Huntsman International Llc | Herbicidal compositions and surfactant concentrates |
| MY158895A (en) * | 2000-05-19 | 2016-11-30 | Monsanto Technology Llc | Potassium glyphosate formulations |
| WO2002032227A1 (en) * | 2000-10-17 | 2002-04-25 | Victorian Chemicals International Pty Ltd | Herbicide composition |
| JP2004527565A (ja) * | 2001-05-08 | 2004-09-09 | モンサント・ヨーロツプ・ソシエテ・アノニム | グリホサート組成物及びその使用 |
| US6485246B1 (en) * | 2001-07-20 | 2002-11-26 | New Holland North America, Inc. | Apparatus for raising ramps on an implement transporter |
| WO2003059068A1 (en) | 2001-12-21 | 2003-07-24 | Dow Agrosciences Llc | High-strength low-viscosity agricultural formulations |
| US20030224939A1 (en) * | 2002-05-31 | 2003-12-04 | David Miles | Adjuvant for pesticides |
| US20040138176A1 (en) * | 2002-05-31 | 2004-07-15 | Cjb Industries, Inc. | Adjuvant for pesticides |
| NZ543037A (en) * | 2003-04-22 | 2009-10-30 | Monsanto Technology Llc | Herbicidal compositions containing glyphosate and a pyridine analog |
| US20050026781A1 (en) | 2003-04-22 | 2005-02-03 | Monsanto Technology Llc | Herbicidal compositions containing glyphosate and a pyridine analog |
| PL221513B1 (pl) * | 2003-08-04 | 2016-04-29 | Dow Agrosciences Llc | Kompozycja chwastobójczego koncentratu o wysokiej mocy oraz sposób zwalczania niepożądanej roślinności |
| PL2821067T3 (pl) * | 2003-09-12 | 2018-02-28 | Amgen Inc. | Szybko rozpuszczający się preparat cynakalcetu |
| CN1960634A (zh) | 2004-03-10 | 2007-05-09 | 孟山都技术公司 | 含有n－膦酰基甲基甘氨酸和茁长素除草剂的除草剂组合物 |
| US20060009360A1 (en) * | 2004-06-25 | 2006-01-12 | Robert Pifer | New adjuvant composition |
| EP1781105B1 (en) | 2004-08-19 | 2008-12-03 | Monsanto Technology LLC | Glyphosate salt herbicidal composition |
| BRPI0516306A2 (pt) | 2004-10-04 | 2011-08-16 | Huntsman Petrochemical Llc | formulações de glifosato de carga alta |
| US8236731B2 (en) | 2005-05-24 | 2012-08-07 | Monsanto Technology Llc | Herbicide compatibility improvement |
| CA2672151A1 (en) | 2006-12-06 | 2008-06-12 | Akzo Nobel N.V. | Alkylamidopropyl dialkylamine surfactants as adjuvants |
| EP2099297B1 (en) | 2006-12-06 | 2017-05-17 | Akzo Nobel N.V. | Compatibility agents for herbicidal formulations comprising 2,4-(dichlorophenoxy) acetic acid salts |
| JP5455899B2 (ja) * | 2007-06-29 | 2014-03-26 | ダウ アグロサイエンシィズ エルエルシー | 置換フェノキシアルカン酸誘導体及びグリホサート誘導体を含有する相乗作用性除草組成物 |
| US8530385B2 (en) * | 2007-12-13 | 2013-09-10 | Donaghys Industries Limited | Herbicidal formulations for combinations of dimethylamine and potassium salts of glyphosate |
| RU2479205C2 (ru) * | 2007-12-13 | 2013-04-20 | Донагис Индастриз Лимитед | Гербицидный состав триэтаноламиновой соли глифосата и способы подавления роста растений с его использованием |
| AU2009260813B2 (en) * | 2008-06-18 | 2013-10-10 | Stepan Company | Ultra-high loading glyphosate concentrate |
| AU2009296340B2 (en) | 2008-09-29 | 2015-02-12 | Monsanto Technology Llc | Glyphosate formulations containing amidoalkylamine surfactants |
| EA018865B1 (ru) * | 2008-11-06 | 2013-11-29 | Сн Биотек Текнолоджис Сп. З О.О. Сп. К. | Жидкая однородная гербицидная композиция, способ борьбы с сорняками, способ получения жидкой однородной гербицидной композиции и применение жидкой однородной гербицидной композиции для борьбы с сорняками |
| CA2759702C (en) * | 2009-04-24 | 2017-09-26 | Huntsman Petrochemical Llc | Nitrogen containing isethionic acid salt in registerable, stable agricultural formulations |
| US9271488B2 (en) | 2009-04-24 | 2016-03-01 | Huntsman Petrochemical Llc | Isethionic acid salts in field ready spray and tank mixes |
| PL2445337T3 (pl) * | 2009-06-25 | 2018-09-28 | Dow Agrosciences Llc | Chwastobójcze kompozycje koncentratów zawierające sole glifosatu i dikamby |
| US20120142532A1 (en) | 2009-08-10 | 2012-06-07 | Monsanto Technology Llc | Low volatility auxin herbicide formulations |
| CN107148970B (zh) | 2009-09-02 | 2022-01-11 | 阿克苏诺贝尔化学品国际有限公司 | 用于农业的含氮表面活性剂 |
| AU2010317610B2 (en) | 2009-11-16 | 2015-05-14 | Imtrade Australia Pty Ltd | High load glyphosate formulations |
| AU2013202664B2 (en) * | 2010-10-01 | 2015-02-12 | Nufarm Australia Limited | Method for preparation of an aqueous glyphosate concentrate composition having mixture of amine salt |
| EP2621283B1 (en) * | 2010-10-01 | 2015-06-03 | Nufarm Australia Limited | Method for preparation of an aqueous glyphosate concentrate composition having mixture of amine salts |
| BR112013009948B1 (pt) | 2010-10-25 | 2018-08-14 | Stepan Company | formulação de glifosato |
| US8455396B2 (en) | 2011-07-11 | 2013-06-04 | Stepan Company | Alkali metal glyphosate compositions |
| US10334849B2 (en) | 2011-10-26 | 2019-07-02 | Monsanto Technology Llc | Salts of carboxylic acid herbicides |
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| ES2759302T3 (es) | 2014-07-02 | 2020-05-08 | Stepan Co | Composiciones agrícolas con toxicidad acuática reducida |
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| CN106538594A (zh) * | 2016-11-01 | 2017-03-29 | 山东科信生物化学有限公司 | 一种农用具有增粘增效助剂的草甘膦水剂及其制备方法 |
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| CN113930226B (zh) * | 2020-07-14 | 2023-05-02 | 中国石油化工股份有限公司 | 含聚醚季铵盐的表面活性剂组合物及其制备和提高油气产量的方法 |
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-
1999
- 1999-11-19 BR BRPI9915566-4A patent/BR9915566B1/pt not_active IP Right Cessation
- 1999-11-19 AT AT99965856T patent/ATE275342T1/de not_active IP Right Cessation
- 1999-11-19 IL IL14327299A patent/IL143272A0/xx unknown
- 1999-11-19 DE DE69920035T patent/DE69920035T2/de not_active Expired - Lifetime
- 1999-11-19 JP JP2000583350A patent/JP4652573B2/ja not_active Expired - Lifetime
- 1999-11-19 PL PL99348907A patent/PL348907A1/xx not_active Application Discontinuation
- 1999-11-19 CZ CZ2001-1787A patent/CZ304306B6/cs not_active IP Right Cessation
- 1999-11-19 HU HU0104355A patent/HU229572B1/hu unknown
- 1999-11-19 UA UA2001064346A patent/UA74775C2/uk unknown
- 1999-11-19 CA CA002351386A patent/CA2351386C/en not_active Expired - Lifetime
- 1999-11-19 EP EP99965856A patent/EP1133233B1/en not_active Expired - Lifetime
- 1999-11-19 WO PCT/US1999/027602 patent/WO2000030452A1/en not_active Application Discontinuation
- 1999-11-19 SK SK707-2001A patent/SK7072001A3/sk unknown
- 1999-11-19 TR TR2001/01524T patent/TR200101524T2/xx unknown
- 1999-11-19 NZ NZ511850A patent/NZ511850A/en not_active IP Right Cessation
- 1999-11-19 EA EA200100578A patent/EA200100578A1/ru unknown
- 1999-11-19 ES ES99965856T patent/ES2228161T3/es not_active Expired - Lifetime
- 1999-11-19 KR KR1020017006479A patent/KR20010104684A/ko not_active Withdrawn
- 1999-11-19 CN CNB998151955A patent/CN1277473C/zh not_active Expired - Lifetime
- 1999-11-19 AU AU21541/00A patent/AU775094B2/en not_active Expired
- 1999-11-22 AR ARP990105948A patent/AR018211A1/es not_active Application Discontinuation
- 1999-11-22 MY MYPI99005093A patent/MY122060A/en unknown
- 1999-11-22 US US09/444,768 patent/US6277788B1/en not_active Expired - Lifetime
- 1999-11-23 CO CO99073751A patent/CO5210930A1/es not_active Application Discontinuation
- 1999-11-25 GT GT199900199A patent/GT199900199A/es unknown
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2001
- 2001-04-03 US US09/825,480 patent/US6455473B2/en not_active Expired - Lifetime
- 2001-05-22 NO NO20012502A patent/NO20012502L/no not_active Application Discontinuation
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