UA57116C2 - Cуміш, придатна для застосування як гербіцид, спосіб одержання стабільної під час зберігання при низькій температурі диметенамідної суміші (варіанти) - Google Patents
Cуміш, придатна для застосування як гербіцид, спосіб одержання стабільної під час зберігання при низькій температурі диметенамідної суміші (варіанти) Download PDFInfo
- Publication number
- UA57116C2 UA57116C2 UA2000063198A UA2000063198A UA57116C2 UA 57116 C2 UA57116 C2 UA 57116C2 UA 2000063198 A UA2000063198 A UA 2000063198A UA 2000063198 A UA2000063198 A UA 2000063198A UA 57116 C2 UA57116 C2 UA 57116C2
- Authority
- UA
- Ukraine
- Prior art keywords
- dimethenamid
- mixture
- temperature
- dicamba
- agent
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical class NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000004062 sedimentation Methods 0.000 title 1
- 239000007787 solid Substances 0.000 claims abstract description 29
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical group COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 claims description 104
- 239000005504 Dicamba Substances 0.000 claims description 56
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 56
- 230000008021 deposition Effects 0.000 claims description 30
- 239000004009 herbicide Substances 0.000 claims description 28
- 230000002363 herbicidal effect Effects 0.000 claims description 26
- 238000001556 precipitation Methods 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- MRUDNSFOFOQZDA-UHFFFAOYSA-N 2,6-dichlorobenzoic acid Chemical compound OC(=O)C1=C(Cl)C=CC=C1Cl MRUDNSFOFOQZDA-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 239000003085 diluting agent Substances 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 150000005215 alkyl ethers Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001350 alkyl halides Chemical class 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 3
- 239000005580 Metazachlor Substances 0.000 claims description 3
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 claims description 3
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 claims description 3
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 2
- GLQWRXYOTXRDNH-UHFFFAOYSA-N thiophen-2-amine Chemical group NC1=CC=CS1 GLQWRXYOTXRDNH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000007865 diluting Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 29
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 28
- 239000000126 substance Substances 0.000 description 18
- 239000002244 precipitate Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 239000013049 sediment Substances 0.000 description 12
- 238000010790 dilution Methods 0.000 description 11
- 239000012895 dilution Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 6
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- 239000003849 aromatic solvent Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 150000001559 benzoic acids Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- -1 metochlor Chemical compound 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 150000003738 xylenes Chemical class 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000209510 Liliopsida Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 239000000729 antidote Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000012470 diluted sample Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- KJLLKLRVCJAFRY-UHFFFAOYSA-N mebutizide Chemical compound ClC1=C(S(N)(=O)=O)C=C2S(=O)(=O)NC(C(C)C(C)CC)NC2=C1 KJLLKLRVCJAFRY-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/46—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom rings with more than six members
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/963,280 US5977024A (en) | 1997-11-03 | 1997-11-03 | Mixtures and methods for suppressing precipitation of chloroacetamides |
| PCT/EP1998/006704 WO1999022594A1 (en) | 1997-11-03 | 1998-10-22 | Chloroacetamide mixtures with suppressed precipitation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA57116C2 true UA57116C2 (uk) | 2003-06-16 |
Family
ID=25507010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2000063198A UA57116C2 (uk) | 1997-11-03 | 1998-10-22 | Cуміш, придатна для застосування як гербіцид, спосіб одержання стабільної під час зберігання при низькій температурі диметенамідної суміші (варіанти) |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US5977024A (hu) |
| EP (1) | EP1043929B1 (hu) |
| JP (1) | JP4578677B2 (hu) |
| KR (1) | KR100554590B1 (hu) |
| CN (1) | CN1264405C (hu) |
| AR (1) | AR013745A1 (hu) |
| AT (1) | ATE318516T1 (hu) |
| AU (1) | AU758051B2 (hu) |
| BG (1) | BG64883B1 (hu) |
| BR (1) | BR9814840B1 (hu) |
| CA (1) | CA2250262C (hu) |
| CZ (1) | CZ296392B6 (hu) |
| DE (1) | DE69833677T2 (hu) |
| HU (1) | HU229669B1 (hu) |
| IL (1) | IL135665A (hu) |
| NZ (1) | NZ504391A (hu) |
| PL (1) | PL194322B1 (hu) |
| RU (1) | RU2216936C2 (hu) |
| SK (1) | SK285677B6 (hu) |
| UA (1) | UA57116C2 (hu) |
| WO (1) | WO1999022594A1 (hu) |
| ZA (1) | ZA989978B (hu) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104604872B (zh) * | 2013-11-04 | 2016-08-17 | 南京华洲药业有限公司 | 一种含麦草畏与吡草胺的除草组合物及其应用 |
| WO2016142280A1 (en) | 2015-03-06 | 2016-09-15 | Cheminova A/S | An emulsifiable concentrate composition comprising pethoxamid |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3013054A (en) * | 1958-08-04 | 1961-12-12 | Velsicol Chemical Corp | 2-methoxy-3, 6-dichlorobenzoates |
| US4411694A (en) * | 1980-06-03 | 1983-10-25 | American Cyanamid Company | Emulsifiable concentrates of 2-chloro-N-isopropyl-2',3'-dimethylacetanilide with improved resistance to crystallization and process for preparing the same |
| US4666502A (en) * | 1982-02-09 | 1987-05-19 | Sandoz Ltd. | Herbicidal N-thienyl-chloroacetamides |
| US4460406A (en) * | 1982-04-19 | 1984-07-17 | Monsanto Company | Herbicidal concentrated emulsions |
| US4695673A (en) * | 1985-11-20 | 1987-09-22 | Stauffer Chemical Company | Process for the production of acylated 1,3-dicarbonyl compounds |
| EP0347950B1 (en) * | 1985-12-30 | 1993-08-04 | Stauffer Chemical Company | Synergistic herbicide combinations and method of application |
| US4789393A (en) * | 1986-03-07 | 1988-12-06 | E. I. Du Pont De Nemours And Company | Herbicidal pyridine sulfonamides |
| US4923501A (en) * | 1987-11-04 | 1990-05-08 | Kumiai Chemical Industry Co., Ltd. | Pyrimidine derivatives, processes for their production, and herbicidal method and compositions |
| HU206242B (en) * | 1988-04-18 | 1992-10-28 | Sandoz Ag | Herbicidal compositions comprising substituted benzoyl bicyclodione derivatives as active ingredient |
| GB8901516D0 (en) * | 1989-01-24 | 1989-03-15 | Sandoz Ltd | Improvements in or relating to herbicides |
| TR24452A (tr) * | 1989-04-25 | 1991-11-01 | Sandoz Ltd | Pestisidler ve bitki bueyueme duezenleyicileri olarak heterosiklik dionlar |
| AU7077091A (en) * | 1990-01-11 | 1991-08-05 | E.I. Du Pont De Nemours And Company | Herbicidal pyrimidines and triazines |
| HU212435B (en) * | 1990-06-07 | 1996-06-28 | Sandoz Ag | Herbicidal compositions containing substituted phthalides and heterocyclic phthalides as active ingredient and process for preparation of their active ingredients. |
| HU213178B (en) * | 1991-12-06 | 1997-03-28 | Sandoz Ag | Herbicid composition containing phthalide derivative as active ingredient, process for thereof and preparing the active ingredients |
| US5457085A (en) * | 1992-11-16 | 1995-10-10 | Sandoz Ltd. | Optical isomer of dimethenamid |
| US5721191A (en) * | 1993-02-18 | 1998-02-24 | Sandoz Ltd. | Synergistic herbicidal compositions of dimethenamid and sulfonylureas |
| ATE249141T1 (de) * | 1993-02-18 | 2003-09-15 | Basf Ag | Herbizide mischungen |
-
1997
- 1997-11-03 US US08/963,280 patent/US5977024A/en not_active Expired - Lifetime
-
1998
- 1998-10-22 RU RU2000114822/04A patent/RU2216936C2/ru not_active IP Right Cessation
- 1998-10-22 CZ CZ20001631A patent/CZ296392B6/cs not_active IP Right Cessation
- 1998-10-22 WO PCT/EP1998/006704 patent/WO1999022594A1/en active IP Right Grant
- 1998-10-22 AT AT98955509T patent/ATE318516T1/de active
- 1998-10-22 SK SK574-2000A patent/SK285677B6/sk not_active IP Right Cessation
- 1998-10-22 EP EP98955509A patent/EP1043929B1/en not_active Expired - Lifetime
- 1998-10-22 KR KR1020007004763A patent/KR100554590B1/ko not_active IP Right Cessation
- 1998-10-22 HU HU0004263A patent/HU229669B1/hu not_active IP Right Cessation
- 1998-10-22 NZ NZ504391A patent/NZ504391A/xx not_active IP Right Cessation
- 1998-10-22 DE DE69833677T patent/DE69833677T2/de not_active Expired - Lifetime
- 1998-10-22 UA UA2000063198A patent/UA57116C2/uk unknown
- 1998-10-22 AU AU12312/99A patent/AU758051B2/en not_active Expired
- 1998-10-22 IL IL13566598A patent/IL135665A/en not_active IP Right Cessation
- 1998-10-22 BR BRPI9814840-0A patent/BR9814840B1/pt not_active IP Right Cessation
- 1998-10-22 JP JP2000518551A patent/JP4578677B2/ja not_active Expired - Lifetime
- 1998-10-22 PL PL98340252A patent/PL194322B1/pl unknown
- 1998-10-22 CN CNB988107368A patent/CN1264405C/zh not_active Expired - Fee Related
- 1998-11-02 ZA ZA9809978A patent/ZA989978B/xx unknown
- 1998-11-02 CA CA002250262A patent/CA2250262C/en not_active Expired - Lifetime
- 1998-11-03 AR ARP980105520A patent/AR013745A1/es active IP Right Grant
-
2000
- 2000-05-04 BG BG104401A patent/BG64883B1/bg unknown
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