UA117984C2 - Спосіб і установка для витягання радіоактивних нуклідів з відпрацьованих смоляних матеріалів - Google Patents

Спосіб і установка для витягання радіоактивних нуклідів з відпрацьованих смоляних матеріалів

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Publication number
UA117984C2
UA117984C2 UAA201706102A UAA201706102A UA117984C2 UA 117984 C2 UA117984 C2 UA 117984C2 UA A201706102 A UAA201706102 A UA A201706102A UA A201706102 A UAA201706102 A UA A201706102A UA 117984 C2 UA117984 C2 UA 117984C2
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UA
Ukraine
Prior art keywords
radioisotope
process solution
waste resin
recovery
organic acid
Prior art date
Application number
UAA201706102A
Other languages
English (en)
Inventor
Франц Штромер
Бельда Луіс Семпере
Original Assignee
Фраматоме Гмбх
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Фраматоме Гмбх filed Critical Фраматоме Гмбх
Publication of UA117984C2 publication Critical patent/UA117984C2/uk

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    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/34—Disposal of solid waste
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/60—Cleaning or rinsing ion-exchange beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/70—Regeneration or reactivation of ion-exchangers; Apparatus therefor for large scale industrial processes or applications
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21D—NUCLEAR POWER PLANT
    • G21D1/00—Details of nuclear power plant
    • G21D1/02—Arrangements of auxiliary equipment
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/20—Disposal of liquid waste
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G21F9/301—Processing by fixation in stable solid media
    • G21F9/307—Processing by fixation in stable solid media in polymeric matrix, e.g. resins, tars
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21G—CONVERSION OF CHEMICAL ELEMENTS; RADIOACTIVE SOURCES
    • G21G1/00—Arrangements for converting chemical elements by electromagnetic radiation, corpuscular radiation or particle bombardment, e.g. producing radioactive isotopes
    • G21G1/001—Recovery of specific isotopes from irradiated targets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00452—Means for the recovery of reactants or products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21G—CONVERSION OF CHEMICAL ELEMENTS; RADIOACTIVE SOURCES
    • G21G1/00—Arrangements for converting chemical elements by electromagnetic radiation, corpuscular radiation or particle bombardment, e.g. producing radioactive isotopes
    • G21G1/001—Recovery of specific isotopes from irradiated targets
    • G21G2001/0094—Other isotopes not provided for in the groups listed above
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Processing Of Solid Wastes (AREA)
  • Physical Water Treatments (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

В заявці описаний спосіб витягання радіоактивного ізотопу з відпрацьованої смоли на атомних електростанціях, який включає наступні стадії: а) обробка відпрацьованої смоли, навантаженої принаймні одним радіоізотопом, органічною кислотою або лужною сполукою з метою вивільнення принаймні одного радіоізотопу з відпрацьованої смоли і одержання технологічного розчину, який містить принаймні один радіоізотоп, б) відокремлення принаймні одного радіоізотопу від технологічного розчину по специфічній до радіоізотопу реакції, і таким чином одержують технологічний розчин, збіднений на принаймні один радіоізотоп, причому зазначений збіднений технологічний розчин містить органічну кислоту або лужну сполуку і факультативно радіоізотоп, що не прореагував, в) взаємодія органічної кислоти або лужної сполуки в збідненому технологічному розчині, одержаному на стадії б) по реакції термічного і/або фотохімічного окиснення, причому утворюються газоподібні продукти реакції, і г) повторне навантаження на відпрацьовану смолу технологічного розчину, одержаного на стадії в), який прореагував, для зв'язування радіоізотопу, що не прореагував, з відпрацьованою смолою. Крім того, описана установка для проведення зазначеного вище способу.
UAA201706102A 2014-11-19 2014-11-19 Спосіб і установка для витягання радіоактивних нуклідів з відпрацьованих смоляних матеріалів UA117984C2 (uk)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2014/075047 WO2016078704A1 (en) 2014-11-19 2014-11-19 Method and apparatus for the recovery of radioactive nuclides from spent resin materials

Publications (1)

Publication Number Publication Date
UA117984C2 true UA117984C2 (uk) 2018-10-25

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ID=51945871

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Country Status (9)

Country Link
US (1) US10163536B2 (uk)
EP (1) EP3221048B1 (uk)
KR (1) KR102287059B1 (uk)
CN (1) CN107004450B (uk)
AR (1) AR102622A1 (uk)
CA (1) CA2965404C (uk)
RU (1) RU2666415C1 (uk)
UA (1) UA117984C2 (uk)
WO (1) WO2016078704A1 (uk)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI615857B (zh) * 2016-07-15 2018-02-21 行政院原子能委員會核能研究所 放射性廢樹脂物料抽取裝置
DE102018131902B3 (de) * 2018-12-12 2020-02-27 Framatome Gmbh Verfahren zur Konditionierung von Ionenaustauscherharzen und Vorrichtung zur Durchführung des Verfahrens
CA3197027A1 (en) * 2020-10-30 2022-05-05 Kinectrics Inc. Process for the selective removal of anionic radionuclides
CN116635335A (zh) * 2020-12-24 2023-08-22 法玛通股份有限公司 放射性核素汽提过程中用掺硼金刚石电极矿化有机化合物
KR102499168B1 (ko) * 2021-02-04 2023-02-13 한국원자력연구원 방사성 탄소의 재활용 방법 및 이를 이용한 방사성 탄소를 포함하는 탄산염의 제조방법
CA3196511A1 (en) * 2022-01-24 2023-12-15 Remi Vachon Methods and systems for extracting, solidification and degassing of radioactive isotopes from spent ion exchange resins
CN114432888A (zh) * 2022-02-17 2022-05-06 厦门大学 一种压力和电场力耦合分离同位素的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2607292C2 (de) 1976-02-23 1985-08-29 Kraftwerk Union AG, 4330 Mülheim Verfahren zur Befreiung von im Kernreaktorbetrieb verbrauchten Ionenaustauscherharzen von radioaktiven Korrosionsprodukten
US4235713A (en) * 1978-06-06 1980-11-25 Redondo Abad Angel Luis Process for the elimination of accumulated iron in organic phases of fluid-fluid extraction that contain di-2-ethyl-hexyl phosphoric acid
CN85103922B (zh) * 1984-06-08 1987-04-15 株式会社日立制作所 处理废离子交换树脂的方法和装置
CA1250378A (en) 1985-01-28 1989-02-21 Leo P. Buckley Method of removing carbon-14 from particulate, ion exchange resin
JPH05327712A (ja) 1991-08-09 1993-12-10 Nec Corp 端末アダプタ
DE4423398A1 (de) 1994-07-04 1996-01-11 Siemens Ag Verfahren und Einrichtung zum Entsorgen eines Kationenaustauschers
DE10005681B4 (de) 2000-02-07 2005-06-16 Atc Dr. Mann E.K. Verfahren und Vorrichtung zur Dekontamination metallhaltiger Wässer
JP3656602B2 (ja) * 2002-01-08 2005-06-08 九州電力株式会社 化学除染廃液の処理方法
US6682646B2 (en) 2002-03-25 2004-01-27 Electric Power Research Institute Electrochemical process for decontamination of radioactive materials
RU2412495C1 (ru) * 2009-12-16 2011-02-20 Федеральное государственное унитарное предприятие "Научно-исследовательский технологический институт имени А.П. Александрова" Способ переработки радиоактивных ионообменных смол
CN102247808A (zh) * 2011-06-28 2011-11-23 中国原子能科学研究院 酸性溶液体系中分离提取锝的分离材料
JP5489124B2 (ja) * 2011-08-23 2014-05-14 日立Ｇｅニュークリア・エナジー株式会社 原子力発電所の廃樹脂処理方法及び処理システム
JP5883675B2 (ja) * 2012-02-22 2016-03-15 日立Ｇｅニュークリア・エナジー株式会社 放射性廃液の処理方法
JP5933992B2 (ja) * 2012-03-07 2016-06-15 荏原工業洗浄株式会社 放射性廃イオン交換樹脂の除染方法
EP2819125B1 (en) 2013-06-21 2018-08-08 Hitachi-GE Nuclear Energy, Ltd. Radioactive organic waste treatment method and system
CN103366850B (zh) * 2013-06-28 2015-11-11 清华大学 一种湿式催化氧化法处理放射性阴离子交换树脂的方法
CN103474123B (zh) * 2013-08-23 2016-02-10 清华大学 一种纳米Fe/Mn复合催化剂用于放射性废树脂氧化分解的方法
CN103589866B (zh) * 2013-11-29 2015-06-10 上海交通大学 利用硅基阴离子交换树脂对钍和铀进行分离回收的方法

Also Published As

Publication number Publication date
EP3221048B1 (en) 2018-10-10
CN107004450B (zh) 2019-05-21
EP3221048A1 (en) 2017-09-27
AR102622A1 (es) 2017-03-15
CA2965404C (en) 2021-07-06
RU2666415C1 (ru) 2018-09-07
KR102287059B1 (ko) 2021-08-09
CN107004450A (zh) 2017-08-01
US10163536B2 (en) 2018-12-25
CA2965404A1 (en) 2016-05-26
US20180308597A1 (en) 2018-10-25
WO2016078704A1 (en) 2016-05-26
KR20170088359A (ko) 2017-08-01

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