TWI716930B - 製造包括對齊於單一方向的紗的奈米碳管片之方法以及使用其所製造的奈米碳管片 - Google Patents
製造包括對齊於單一方向的紗的奈米碳管片之方法以及使用其所製造的奈米碳管片 Download PDFInfo
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- TWI716930B TWI716930B TW108124144A TW108124144A TWI716930B TW I716930 B TWI716930 B TW I716930B TW 108124144 A TW108124144 A TW 108124144A TW 108124144 A TW108124144 A TW 108124144A TW I716930 B TWI716930 B TW I716930B
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- carbon nanotube
- sheet
- yarn
- nanotube sheet
- carbon
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 291
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 256
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 256
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 claims abstract description 58
- 238000004804 winding Methods 0.000 claims abstract description 40
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 33
- 239000003054 catalyst Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 32
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- 230000003993 interaction Effects 0.000 claims description 27
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- 239000007789 gas Substances 0.000 description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020180152222A KR101962215B1 (ko) | 2018-11-30 | 2018-11-30 | 일 방향으로 정렬된 얀을 포함하는 탄소나노튜브 시트를 제조하는 방법 및 이에 의해 제조된 탄소나노튜브 시트 |
| KR10-2018-0152222 | 2018-11-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202021902A TW202021902A (zh) | 2020-06-16 |
| TWI716930B true TWI716930B (zh) | 2021-01-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108124144A TWI716930B (zh) | 2018-11-30 | 2019-07-09 | 製造包括對齊於單一方向的紗的奈米碳管片之方法以及使用其所製造的奈米碳管片 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11453591B2 (https=) |
| EP (1) | EP3887307A4 (https=) |
| JP (1) | JP7192176B2 (https=) |
| KR (1) | KR101962215B1 (https=) |
| CN (1) | CN113165878B (https=) |
| TW (1) | TWI716930B (https=) |
| WO (1) | WO2020111520A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101956153B1 (ko) | 2018-10-04 | 2019-06-24 | 어썸레이 주식회사 | 탄소나노튜브를 포함하는 얀의 제조방법 및 이로부터 제조된 얀 |
| KR101962215B1 (ko) | 2018-11-30 | 2019-03-26 | 어썸레이 주식회사 | 일 방향으로 정렬된 얀을 포함하는 탄소나노튜브 시트를 제조하는 방법 및 이에 의해 제조된 탄소나노튜브 시트 |
| KR101992745B1 (ko) | 2019-01-24 | 2019-06-26 | 어썸레이 주식회사 | 구조적 안정성이 우수하고 전자 방출 효율이 향상된 이미터 및 이를 포함하는 x-선 튜브 |
| KR102099410B1 (ko) | 2019-04-04 | 2020-04-09 | 어썸레이 주식회사 | 세라믹계 소재로 이루어진 집속전극을 포함하는 x-선 발생장치 |
| KR102099411B1 (ko) | 2019-07-26 | 2020-04-09 | 어썸레이 주식회사 | 구조적 안정성이 우수한 전계 방출 장치 및 이를 포함하는 x-선 튜브 |
| KR102488299B1 (ko) * | 2020-10-28 | 2023-01-13 | 숭실대학교산학협력단 | 구조적 안정성이 향상된 탄소나노튜브 시트 롤 이미터, 이의 제조방법 및 이를 이용한 전계 방출 소자 |
| US12590001B2 (en) | 2022-07-06 | 2026-03-31 | Technology Innovation Institute—Sole Proprietorship LLC | Method for producing superhydrophobic carbon nanotube sheets |
| JP7610655B1 (ja) | 2023-07-03 | 2025-01-08 | Ｔｐｒ株式会社 | カーボンナノチューブヤーン、それを含む熱電発電モジュールおよびその製造方法 |
| WO2026009468A1 (ja) * | 2024-07-01 | 2026-01-08 | 株式会社カーボンフライ | 複合体、複合体の製造方法、および複合体の用途 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120090383A (ko) * | 2011-02-07 | 2012-08-17 | 숭실대학교산학협력단 | 탄소나노튜브 섬유제조 |
| TW201726988A (zh) * | 2016-01-29 | 2017-08-01 | 日立造船股份有限公司 | 奈米碳管紗線的製造方法 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05347142A (ja) | 1992-06-15 | 1993-12-27 | Matsushita Electric Works Ltd | 光放射電子管 |
| US20030002627A1 (en) | 2000-09-28 | 2003-01-02 | Oxford Instruments, Inc. | Cold emitter x-ray tube incorporating a nanostructured carbon film electron emitter |
| JP5032721B2 (ja) | 2001-04-03 | 2012-09-26 | 富士通株式会社 | 導電性電極材料、電極部品、静電偏向器及び荷電粒子ビーム露光装置 |
| US20070003472A1 (en) | 2003-03-24 | 2007-01-04 | Tolt Zhidan L | Electron emitting composite based on regulated nano-structures and a cold electron source using the composite |
| JP2007536434A (ja) * | 2003-07-11 | 2007-12-13 | ケンブリッジ・ユニヴァーシティ・テクニカル・サーヴィシズ・リミテッド | 気相からの凝集物の製造 |
| GB0316367D0 (en) * | 2003-07-11 | 2003-08-13 | Univ Cambridge Tech | Production of agglomerates from gas phase |
| CN105696138B (zh) * | 2004-11-09 | 2019-02-01 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| KR100721921B1 (ko) | 2005-10-13 | 2007-05-28 | 주식회사 포스코 | 천이원소 금속이 나노 코팅된 전계방출 발광소재용탄소나노튜브 제조방법 |
| CN100555529C (zh) | 2005-11-04 | 2009-10-28 | 清华大学 | 一种场发射元件及其制备方法 |
| JP4869107B2 (ja) * | 2007-02-28 | 2012-02-08 | 京セラ株式会社 | 繊維束整列装置 |
| US8709372B2 (en) * | 2007-10-02 | 2014-04-29 | Los Alamos National Security, Llc | Carbon nanotube fiber spun from wetted ribbon |
| BRPI1014162A2 (pt) | 2009-04-10 | 2016-04-26 | Applied Nanostructured Sols | método e aparelho para uso de um forno vertical para infundir nanotubos de carbono á fibra |
| CN101665247A (zh) | 2009-09-25 | 2010-03-10 | 天津大学 | 碳纳米管膜制备方法和装置 |
| JP2011148689A (ja) | 2009-12-25 | 2011-08-04 | Mefs Kk | カーボンナノチューブから成る集合体および糸条体の製造方法 |
| CN102918754B (zh) | 2010-05-27 | 2015-03-11 | 矢崎总业株式会社 | 感应电动机的转子、以及使用该转子的感应电动机 |
| GB2485339B (en) * | 2010-11-02 | 2018-10-03 | Cambridge Entpr Ltd | Method of making carbon nanotubes |
| CN102502587B (zh) * | 2011-11-08 | 2013-06-05 | 北京富纳特创新科技有限公司 | 碳纳米管膜及其制备方法 |
| KR101284226B1 (ko) | 2012-05-31 | 2013-07-09 | 경희대학교 산학협력단 | 탄소나노튜브 복합체 전계방출원 및 제조방법 |
| US9165737B2 (en) | 2012-10-04 | 2015-10-20 | Nuflare Technology, Inc. | High-brightness, long life thermionic cathode and methods of its fabrication |
| CN103730302B (zh) | 2012-10-10 | 2016-09-14 | 清华大学 | 场发射电子源及场发射装置 |
| TW201441445A (zh) | 2013-04-26 | 2014-11-01 | Ind Tech Res Inst | 導電紗線的製備方法 |
| US9556542B2 (en) | 2013-06-18 | 2017-01-31 | Lg Chem, Ltd. | Device for manufacturing carbon nanotube fibers and method for manufacturing carbon nanotube fibers using same |
| RU2675791C2 (ru) | 2014-02-10 | 2018-12-25 | Люксбрайт Аб | Рентгеновское устройство |
| JP6388387B2 (ja) | 2014-08-25 | 2018-09-12 | 東芝電子管デバイス株式会社 | Ｘ線管 |
| CN107075744B (zh) | 2014-10-28 | 2020-03-03 | Lg化学株式会社 | 用于制备碳纳米管纤维的装置以及使用其制备碳纳米管纤维的方法 |
| KR20160102743A (ko) | 2015-02-23 | 2016-08-31 | 주식회사바텍 | 전계 방출 엑스선 소스 장치 |
| JP6462458B2 (ja) * | 2015-03-31 | 2019-01-30 | 日立造船株式会社 | カーボンナノチューブ集合体の製造方法 |
| KR20160118637A (ko) | 2015-04-02 | 2016-10-12 | 주식회사바텍 | 전계 방출 엑스선 소스 장치 |
| JP6482966B2 (ja) * | 2015-06-25 | 2019-03-13 | 日立造船株式会社 | カーボンナノチューブウェブの製造方法、カーボンナノチューブ集合体の製造方法およびカーボンナノチューブウェブの製造装置 |
| KR102043009B1 (ko) | 2015-10-07 | 2019-11-12 | 주식회사 엘지화학 | 탄소나노튜브 기상합성장비 |
| JP6649100B2 (ja) * | 2016-02-04 | 2020-02-19 | 日立造船株式会社 | Ｃｎｔ積層体の製造方法およびカーボンナノチューブ撚糸の製造方法 |
| KR101718784B1 (ko) | 2016-02-11 | 2017-03-22 | 전남대학교산학협력단 | 고순도 및 고밀도 탄소나노튜브 섬유 제조장치 |
| KR102133624B1 (ko) | 2016-10-21 | 2020-07-13 | 주식회사 엘지화학 | 탄소나노튜브 섬유 집합체 제조 방법 |
| KR101876076B1 (ko) | 2016-11-16 | 2018-07-06 | 경희대학교 산학협력단 | 디지털 광원장치 |
| CN207330368U (zh) | 2017-09-29 | 2018-05-08 | 中山国安火炬科技发展有限公司 | 一种用流化床生产碳纳米管的设备 |
| KR101956153B1 (ko) | 2018-10-04 | 2019-06-24 | 어썸레이 주식회사 | 탄소나노튜브를 포함하는 얀의 제조방법 및 이로부터 제조된 얀 |
| KR101962215B1 (ko) * | 2018-11-30 | 2019-03-26 | 어썸레이 주식회사 | 일 방향으로 정렬된 얀을 포함하는 탄소나노튜브 시트를 제조하는 방법 및 이에 의해 제조된 탄소나노튜브 시트 |
| KR101992745B1 (ko) * | 2019-01-24 | 2019-06-26 | 어썸레이 주식회사 | 구조적 안정성이 우수하고 전자 방출 효율이 향상된 이미터 및 이를 포함하는 x-선 튜브 |
-
2018
- 2018-11-30 KR KR1020180152222A patent/KR101962215B1/ko active Active
-
2019
- 2019-07-09 TW TW108124144A patent/TWI716930B/zh active
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- 2019-10-24 WO PCT/KR2019/014068 patent/WO2020111520A1/en not_active Ceased
- 2019-10-29 US US16/666,834 patent/US11453591B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120090383A (ko) * | 2011-02-07 | 2012-08-17 | 숭실대학교산학협력단 | 탄소나노튜브 섬유제조 |
| TW201726988A (zh) * | 2016-01-29 | 2017-08-01 | 日立造船股份有限公司 | 奈米碳管紗線的製造方法 |
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| CN113165878A (zh) | 2021-07-23 |
| EP3887307A4 (en) | 2022-08-31 |
| KR101962215B1 (ko) | 2019-03-26 |
| US11453591B2 (en) | 2022-09-27 |
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