TWI622212B - 用於鋰離子電池的陰極組成物 - Google Patents
用於鋰離子電池的陰極組成物 Download PDFInfo
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- TWI622212B TWI622212B TW103128497A TW103128497A TWI622212B TW I622212 B TWI622212 B TW I622212B TW 103128497 A TW103128497 A TW 103128497A TW 103128497 A TW103128497 A TW 103128497A TW I622212 B TWI622212 B TW I622212B
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- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 26
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- 229910052744 lithium Inorganic materials 0.000 claims description 13
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
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- 238000004458 analytical method Methods 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
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- 229910020771 KK-50S Inorganic materials 0.000 description 1
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- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 description 1
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- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
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- 238000007756 gravure coating Methods 0.000 description 1
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- 239000012535 impurity Substances 0.000 description 1
- 239000005414 inactive ingredient Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
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- 238000010902 jet-milling Methods 0.000 description 1
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- 150000002641 lithium Chemical group 0.000 description 1
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- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
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- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229940053662 nickel sulfate Drugs 0.000 description 1
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- 125000004430 oxygen atom Chemical group O* 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Composite Materials (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
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| US201361868905P | 2013-08-22 | 2013-08-22 | |
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| TW (1) | TWI622212B (enExample) |
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| PL3474978T3 (pl) * | 2016-06-23 | 2022-01-31 | 6K Inc. | Materiały akumulatora litowo-jonowego |
| KR102095508B1 (ko) | 2016-11-22 | 2020-03-31 | 주식회사 엘지화학 | 리튬 코발트 산화물을 포함하는 코어 및 리튬 코발트 인산화물을 포함하는 쉘을 포함하는 양극 활물질 입자 및 이의 제조 방법 |
| JP6658608B2 (ja) * | 2017-02-22 | 2020-03-04 | 株式会社Ｇｓユアサ | 非水電解質蓄電素子用の正極、非水電解質蓄電素子及び正極合材ペーストの製造方法 |
| WO2018156607A1 (en) * | 2017-02-22 | 2018-08-30 | Lionano Inc. | Core-shell electroactive materials |
| JP6442633B2 (ja) * | 2017-05-29 | 2018-12-19 | 太平洋セメント株式会社 | リチウムイオン二次電池用正極活物質複合体又はナトリウムイオン二次電池用正極活物質複合体、これらを用いた二次電池、並びにこれらの製造方法 |
| KR20210148250A (ko) | 2019-04-05 | 2021-12-07 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법, 이차 전지의 제작 방법, 및 이차 전지 |
| KR20230029836A (ko) | 2020-06-25 | 2023-03-03 | 6케이 인크. | 마이크로복합 합금 구조 |
| KR102513972B1 (ko) * | 2020-08-28 | 2023-03-24 | 주식회사 에코프로비엠 | 양극 활물질 및 이를 포함하는 리튬 이차전지 |
| US20220073367A1 (en) * | 2020-09-08 | 2022-03-10 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing secondary battery and secondary battery |
| KR102518213B1 (ko) * | 2020-10-12 | 2023-04-05 | 주식회사 에코프로비엠 | 양극 활물질 및 이를 포함하는 리튬 이차전지 |
| EP4275239A4 (en) | 2021-01-11 | 2024-12-18 | 6K Inc. | METHODS AND SYSTEMS FOR RECLAIMING LI-ION CATHODE MATERIALS USING MICROWAVE PLASMA TREATMENT |
| JP7473828B2 (ja) | 2021-07-26 | 2024-04-24 | 日亜化学工業株式会社 | 非水電解質二次電池用正極及びその製造方法 |
| WO2023229928A1 (en) | 2022-05-23 | 2023-11-30 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| WO2024044498A1 (en) | 2022-08-25 | 2024-02-29 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (pip) |
| CN115763765B (zh) * | 2022-12-09 | 2025-08-29 | 万华化学集团股份有限公司 | 一种高电压低钴三元正极材料、其制备方法及用途 |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
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| CN101682074A (zh) * | 2007-05-07 | 2010-03-24 | 3M创新有限公司 | 锂混合金属氧化物阴极组合物以及采用该组合物的锂离子电化学电池 |
| WO2013016426A1 (en) * | 2011-07-25 | 2013-01-31 | A123 Systems, Inc. | Blended cathode materials |
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| CN104064729B (zh) * | 2005-05-17 | 2018-01-30 | 株式会社村田制作所 | 正极活性物质，正极活性物质的制造方法和电池 |
| KR100819741B1 (ko) * | 2006-06-16 | 2008-04-07 | 주식회사 엘 앤 에프 | 리튬 이차 전지용 양극 활물질, 이의 제조방법 및 이를포함하는 리튬 이차 전지 |
| KR101240174B1 (ko) * | 2010-04-30 | 2013-03-07 | 주식회사 엘지화학 | 양극 활물질 및 이를 이용한 리튬 이차전지 |
| US20130330616A1 (en) * | 2011-02-18 | 2013-12-12 | 3M Innovative Properties Company | Composite Particles, Methods of Making the Same, and Articles Including the Same |
| US9315894B2 (en) * | 2011-03-30 | 2016-04-19 | Asm Ip Holding B.V. | Atomic layer deposition of metal phosphates and lithium silicates |
| CN103620834A (zh) * | 2011-06-24 | 2014-03-05 | 旭硝子株式会社 | 锂离子二次电池用活性物质颗粒的制造方法、电极以及锂离子二次电池 |
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- 2014-08-06 KR KR1020167007024A patent/KR20160045783A/ko not_active Withdrawn
- 2014-08-06 JP JP2016536283A patent/JP2016528707A/ja active Pending
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- 2014-08-06 US US14/910,840 patent/US20160197341A1/en not_active Abandoned
- 2014-08-06 CN CN201480045637.0A patent/CN105474436B/zh not_active Expired - Fee Related
- 2014-08-06 EP EP14838149.4A patent/EP3036786A4/en not_active Withdrawn
- 2014-08-19 TW TW103128497A patent/TWI622212B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101682074A (zh) * | 2007-05-07 | 2010-03-24 | 3M创新有限公司 | 锂混合金属氧化物阴极组合物以及采用该组合物的锂离子电化学电池 |
| WO2013016426A1 (en) * | 2011-07-25 | 2013-01-31 | A123 Systems, Inc. | Blended cathode materials |
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| WO2015026525A1 (en) | 2015-02-26 |
| TW201521273A (zh) | 2015-06-01 |
| KR20160045783A (ko) | 2016-04-27 |
| CN105474436A (zh) | 2016-04-06 |
| JP2016528707A (ja) | 2016-09-15 |
| CN105474436B (zh) | 2018-06-15 |
| US20160197341A1 (en) | 2016-07-07 |
| EP3036786A4 (en) | 2017-01-11 |
| EP3036786A1 (en) | 2016-06-29 |
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