TWI619674B - 一氧化氮之精製方法 - Google Patents
一氧化氮之精製方法 Download PDFInfo
- Publication number
- TWI619674B TWI619674B TW102125341A TW102125341A TWI619674B TW I619674 B TWI619674 B TW I619674B TW 102125341 A TW102125341 A TW 102125341A TW 102125341 A TW102125341 A TW 102125341A TW I619674 B TWI619674 B TW I619674B
- Authority
- TW
- Taiwan
- Prior art keywords
- nitric oxide
- gas
- adsorbent
- inorganic
- aqueous solution
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 192
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000007670 refining Methods 0.000 title claims abstract description 23
- 238000001179 sorption measurement Methods 0.000 claims abstract description 73
- 239000003463 adsorbent Substances 0.000 claims abstract description 64
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 104
- 239000007864 aqueous solution Substances 0.000 claims description 33
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 32
- 239000012535 impurity Substances 0.000 claims description 28
- 238000010521 absorption reaction Methods 0.000 claims description 27
- 150000007522 mineralic acids Chemical class 0.000 claims description 15
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 14
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- 239000010457 zeolite Substances 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 238000002203 pretreatment Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 description 35
- 229960003753 nitric oxide Drugs 0.000 description 32
- 239000002994 raw material Substances 0.000 description 23
- 238000000746 purification Methods 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000007086 side reaction Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000011261 inert gas Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 235000019391 nitrogen oxide Nutrition 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000012670 alkaline solution Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 nitrogen oxide compound Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gas Separation By Absorption (AREA)
- Drying Of Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012215065A JP6196434B2 (ja) | 2012-09-27 | 2012-09-27 | 一酸化窒素の精製方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201420495A TW201420495A (zh) | 2014-06-01 |
| TWI619674B true TWI619674B (zh) | 2018-04-01 |
Family
ID=50355328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW102125341A TWI619674B (zh) | 2012-09-27 | 2013-07-16 | 一氧化氮之精製方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6196434B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR102101999B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN103693629B (cg-RX-API-DMAC10.html) |
| TW (1) | TWI619674B (cg-RX-API-DMAC10.html) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111547690B (zh) * | 2020-06-19 | 2024-03-29 | 大连大特气体有限公司 | 一种高纯度的电子级一氧化氮生产装置 |
| CN112591722B (zh) * | 2020-12-16 | 2022-05-17 | 四川金象赛瑞化工股份有限公司 | 一种工业级硝酸与电子级硝酸的联产方法 |
| CN113753868A (zh) * | 2021-10-14 | 2021-12-07 | 苏州金宏气体股份有限公司 | 一氧化氮气体的提纯方法、提纯装置和生产装置 |
| CN115814573A (zh) * | 2022-11-29 | 2023-03-21 | 四川力达世环保技术有限公司 | 用于生产矿源硝基腐植酸与硝基黄腐酸的综合处理系统 |
| CN118651826A (zh) * | 2024-06-20 | 2024-09-17 | 中船(邯郸)派瑞特种气体股份有限公司 | 一种一氧化氮气体的精制方法 |
| CN119303430B (zh) * | 2024-11-20 | 2026-01-16 | 中船(邯郸)派瑞特种气体股份有限公司 | 一种一氧化氮气体的纯化装置及方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW354768B (en) * | 1994-07-07 | 1999-03-21 | Boc Group Inc | Process for the purification of nitric oxide |
| JP2004305869A (ja) * | 2003-04-04 | 2004-11-04 | Idemitsu Kosan Co Ltd | 硫黄化合物除去用吸着剤及び燃料電池用水素の製造方法 |
| JP2007169108A (ja) * | 2005-12-22 | 2007-07-05 | Sumitomo Seika Chem Co Ltd | 一酸化窒素精製方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4153429A (en) | 1975-05-21 | 1979-05-08 | Union Carbide Corporation | Selective adsorption of NOx from gas streams |
| US5328673A (en) * | 1992-11-23 | 1994-07-12 | Olin Corporation | Process for removal of NOx and SOx oxides from waste gases with chloric acid |
| JPH07163837A (ja) * | 1993-12-14 | 1995-06-27 | Kobe Steel Ltd | 窒素酸化物の除去法 |
| KR100978805B1 (ko) | 2008-07-11 | 2010-08-30 | (주)이노메이트 | 극저온 냉동 트랩을 이용한 고순도 일산화질소 제조방법 및그의 제조장치 |
-
2012
- 2012-09-27 JP JP2012215065A patent/JP6196434B2/ja active Active
-
2013
- 2013-07-16 TW TW102125341A patent/TWI619674B/zh active
- 2013-09-05 KR KR1020130106887A patent/KR102101999B1/ko active Active
- 2013-09-26 CN CN201310445107.2A patent/CN103693629B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW354768B (en) * | 1994-07-07 | 1999-03-21 | Boc Group Inc | Process for the purification of nitric oxide |
| JP2004305869A (ja) * | 2003-04-04 | 2004-11-04 | Idemitsu Kosan Co Ltd | 硫黄化合物除去用吸着剤及び燃料電池用水素の製造方法 |
| JP2007169108A (ja) * | 2005-12-22 | 2007-07-05 | Sumitomo Seika Chem Co Ltd | 一酸化窒素精製方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201420495A (zh) | 2014-06-01 |
| KR102101999B1 (ko) | 2020-04-17 |
| JP6196434B2 (ja) | 2017-09-13 |
| JP2014069977A (ja) | 2014-04-21 |
| KR20140041339A (ko) | 2014-04-04 |
| CN103693629A (zh) | 2014-04-02 |
| CN103693629B (zh) | 2017-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6575050B2 (ja) | 二酸化炭素の回収方法及び回収装置 | |
| CN1309454C (zh) | 气体纯化的方法和设备 | |
| TWI511773B (zh) | 空氣的純化 | |
| TW201420495A (zh) | 一氧化氮之精製方法 | |
| JP5906074B2 (ja) | 水素製造システム | |
| JPH01172204A (ja) | 混合ガスから炭酸ガスを吸着分離回収する方法 | |
| JP2000317244A (ja) | ガス精製方法及び装置 | |
| CN104334250B (zh) | 空气纯化 | |
| WO2009101669A1 (ja) | 吸着剤を利用したバイオ発酵ガスからのメタンの回収、精製方法 | |
| TW200536786A (en) | Ingredient and process for producing copper (I) chloride, adsorbent and adsorbing method for reductive gas each with the use of copper (I) chloride, and recovering method of carbon monoxide gas | |
| BR112018067886B1 (pt) | Processo de adsorção com modulação de temperatura | |
| KR20090117886A (ko) | 일산화탄소 흡착제, 이를 이용한 가스 정제방법 및 가스 정제장치 | |
| JP7145935B2 (ja) | 温度スイング吸着方法 | |
| KR20190052018A (ko) | 수소 또는 헬륨의 정제방법 및 수소 또는 헬륨의 정제장치 | |
| EP4417574A1 (en) | Pressure swing adsorption apparatus for purifying high-purity hydrogen from ammonia cracking and hydrogen purification method using same | |
| KR101115206B1 (ko) | 배기가스의 처리 방법 및 처리 장치 | |
| JP7684438B2 (ja) | 圧力変動吸着を用いたアンモニアからの水素の製造方法 | |
| CN108778464A (zh) | 变温吸附方法 | |
| JP2013180931A (ja) | オゾンガスに含まれる窒素酸化物除去用吸着剤の前処理方法と窒素酸化物除去用吸着剤および前処理装置。 | |
| JP2024152220A (ja) | 二酸化炭素回収システムおよび二酸化炭素の回収方法 | |
| JP4313882B2 (ja) | クローズドｔｓａ法によるメタノール分解ガス中の有機不純物の除去方法 | |
| JPS6245543A (ja) | 高純度アセチレンガスの製造法 | |
| TWI793793B (zh) | 去除氧分子之方法及一氧化碳之純化方法 | |
| JPS6214481B2 (cg-RX-API-DMAC10.html) | ||
| JP2012130861A (ja) | 生命維持ガス浄化装置 |