TWI595926B - 具增進之活性及水熱穩定性之經磷改質的裂解催化劑 - Google Patents

具增進之活性及水熱穩定性之經磷改質的裂解催化劑 Download PDF

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Publication number
TWI595926B
TWI595926B TW101141079A TW101141079A TWI595926B TW I595926 B TWI595926 B TW I595926B TW 101141079 A TW101141079 A TW 101141079A TW 101141079 A TW101141079 A TW 101141079A TW I595926 B TWI595926 B TW I595926B
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TW
Taiwan
Prior art keywords
catalyst
phosphorus
weight
zeolite
rare earth
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TW101141079A
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English (en)
Chinese (zh)
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TW201328778A (zh
Inventor
傅齊
西普 凱卡爾
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巴地斯公司
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/106—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
TW101141079A 2011-11-04 2012-11-05 具增進之活性及水熱穩定性之經磷改質的裂解催化劑 TWI595926B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201161555637P 2011-11-04 2011-11-04

Publications (2)

Publication Number Publication Date
TW201328778A TW201328778A (zh) 2013-07-16
TWI595926B true TWI595926B (zh) 2017-08-21

Family

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TW101141079A TWI595926B (zh) 2011-11-04 2012-11-05 具增進之活性及水熱穩定性之經磷改質的裂解催化劑

Country Status (15)

Country Link
US (1) US8940652B2 (enExample)
EP (1) EP2773459A4 (enExample)
JP (2) JP6148243B2 (enExample)
KR (1) KR102038335B1 (enExample)
CN (1) CN104245136B (enExample)
AR (1) AR088662A1 (enExample)
BR (1) BR112014010790B1 (enExample)
CA (1) CA2854610C (enExample)
IN (1) IN2014CN04033A (enExample)
MX (1) MX361541B (enExample)
MY (1) MY164957A (enExample)
RU (1) RU2632913C2 (enExample)
TW (1) TWI595926B (enExample)
WO (1) WO2013067481A1 (enExample)
ZA (1) ZA201404009B (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150174559A1 (en) * 2013-12-19 2015-06-25 Basf Corporation Phosphorus-Modified FCC Catalysts
US9441167B2 (en) 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
US9796932B2 (en) 2013-12-19 2017-10-24 Basf Corporation FCC catalyst compositions containing boron oxide and phosphorus
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
ES2816018T3 (es) 2015-06-22 2021-03-31 Exelus Inc Alquilación catalizada mejorada, catalizadores de alquilación, y métodos de fabricación de catalizadores de alquilación
CN112209400B (zh) * 2019-07-09 2022-08-05 中国石油化工股份有限公司 一种稀土y型分子筛及其制备方法
US11891577B2 (en) 2020-02-10 2024-02-06 Hindustan Petroleum Corporation Limited FCC additive composition for bottoms cracking and a process for preparation thereof
EP4200070A4 (en) * 2020-08-19 2024-11-13 Basf Corporation Fluid catalytic cracking catalyst composition for enhanced butylenes yields with metal passivation functionality
US12605700B2 (en) * 2020-10-09 2026-04-21 Basf Corporation Phosphorus stabilized zeolites
CN116323872A (zh) 2020-11-04 2023-06-23 巴斯夫公司 包括磷稳定的mse框架型沸石的催化剂、其制备和其在流化催化应用中的用途

Citations (2)

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US5378670A (en) * 1993-04-16 1995-01-03 W. R. Grace & Co.-Conn. Phosphorus zeolites/molecular sieves
US5993645A (en) * 1995-12-08 1999-11-30 Engelhard Corporation Catalyst for cracking oil feedstocks contaminated with metal

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US3595611A (en) * 1969-02-03 1971-07-27 Grace W R & Co Cation and thermal stabilization of faujasite-type zeolites
US4498975A (en) * 1982-05-24 1985-02-12 Exxon Research & Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
US4504382A (en) * 1982-10-14 1985-03-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
US4493902A (en) * 1983-02-25 1985-01-15 Engelhard Corporation Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making
JPH07106317B2 (ja) * 1987-02-13 1995-11-15 触媒化成工業株式会社 炭化水素油の接触分解用触媒組成物の製造方法
US5312792A (en) * 1990-10-05 1994-05-17 W. R. Grace & Co.-Conn. Catalytic compositions
US5395809A (en) * 1993-11-01 1995-03-07 Engelhard Corporation Modified microsphere FCC catalysts
BR9400475A (pt) * 1994-02-09 1995-09-19 Petroleo Brasileiro Sa Processo de preparação de zeólita modificada e zeólita modificada
ES2227619T3 (es) * 1995-12-08 2005-04-01 Engelhard Corporation Catalizador para craquear materias primas del petroleo contaminadas con metales.
US6069012A (en) * 1997-05-23 2000-05-30 Kayser Technology, Inc. Versatile fluidized bed reactor
CN1275855C (zh) * 2003-03-28 2006-09-20 中国石油化工股份有限公司 用高岭土合成的纳米级y型沸石及其制备方法
CN101134172B (zh) * 2006-08-31 2010-10-27 中国石油化工股份有限公司 一种烃类转化催化剂

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US5378670A (en) * 1993-04-16 1995-01-03 W. R. Grace & Co.-Conn. Phosphorus zeolites/molecular sieves
US5993645A (en) * 1995-12-08 1999-11-30 Engelhard Corporation Catalyst for cracking oil feedstocks contaminated with metal

Also Published As

Publication number Publication date
BR112014010790A2 (pt) 2017-04-25
EP2773459A4 (en) 2015-07-15
RU2632913C2 (ru) 2017-10-11
AR088662A1 (es) 2014-06-25
JP6148243B2 (ja) 2017-06-14
JP2017196618A (ja) 2017-11-02
KR20140099471A (ko) 2014-08-12
MY164957A (en) 2018-02-28
CN104245136B (zh) 2016-12-28
JP6486989B2 (ja) 2019-03-20
IN2014CN04033A (enExample) 2015-10-23
WO2013067481A1 (en) 2013-05-10
BR112014010790B1 (pt) 2020-02-04
MX2014005436A (es) 2014-08-22
KR102038335B1 (ko) 2019-10-31
JP2015511869A (ja) 2015-04-23
ZA201404009B (en) 2015-08-26
US8940652B2 (en) 2015-01-27
CN104245136A (zh) 2014-12-24
MX361541B (es) 2018-12-10
TW201328778A (zh) 2013-07-16
CA2854610C (en) 2020-03-31
US20130115164A1 (en) 2013-05-09
CA2854610A1 (en) 2013-05-10
EP2773459A1 (en) 2014-09-10
RU2014122451A (ru) 2015-12-10

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