CN104245136B - 具有增强的活性和水热稳定性的磷改性裂化催化剂 - Google Patents

具有增强的活性和水热稳定性的磷改性裂化催化剂 Download PDF

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Publication number
CN104245136B
CN104245136B CN201280066003.4A CN201280066003A CN104245136B CN 104245136 B CN104245136 B CN 104245136B CN 201280066003 A CN201280066003 A CN 201280066003A CN 104245136 B CN104245136 B CN 104245136B
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China
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catalyst
technique
phosphorus
zeolite
kaolin
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Chinese (zh)
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CN104245136A (zh
Inventor
C·P·科尔卡
Q·傅
G·史密斯
B·耶尔马兹
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BASF Corp
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BASF Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/106—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201280066003.4A 2011-11-04 2012-11-05 具有增强的活性和水热稳定性的磷改性裂化催化剂 Expired - Fee Related CN104245136B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161555637P 2011-11-04 2011-11-04
US61/555,637 2011-11-04
PCT/US2012/063526 WO2013067481A1 (en) 2011-11-04 2012-11-05 Phosphorus modified cracking catalysts with enhanced activity and hydrothermal stability

Publications (2)

Publication Number Publication Date
CN104245136A CN104245136A (zh) 2014-12-24
CN104245136B true CN104245136B (zh) 2016-12-28

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CN201280066003.4A Expired - Fee Related CN104245136B (zh) 2011-11-04 2012-11-05 具有增强的活性和水热稳定性的磷改性裂化催化剂

Country Status (15)

Country Link
US (1) US8940652B2 (enExample)
EP (1) EP2773459A4 (enExample)
JP (2) JP6148243B2 (enExample)
KR (1) KR102038335B1 (enExample)
CN (1) CN104245136B (enExample)
AR (1) AR088662A1 (enExample)
BR (1) BR112014010790B1 (enExample)
CA (1) CA2854610C (enExample)
IN (1) IN2014CN04033A (enExample)
MX (1) MX361541B (enExample)
MY (1) MY164957A (enExample)
RU (1) RU2632913C2 (enExample)
TW (1) TWI595926B (enExample)
WO (1) WO2013067481A1 (enExample)
ZA (1) ZA201404009B (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150174559A1 (en) * 2013-12-19 2015-06-25 Basf Corporation Phosphorus-Modified FCC Catalysts
US9441167B2 (en) 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
US9796932B2 (en) 2013-12-19 2017-10-24 Basf Corporation FCC catalyst compositions containing boron oxide and phosphorus
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
ES2816018T3 (es) 2015-06-22 2021-03-31 Exelus Inc Alquilación catalizada mejorada, catalizadores de alquilación, y métodos de fabricación de catalizadores de alquilación
CN112209400B (zh) * 2019-07-09 2022-08-05 中国石油化工股份有限公司 一种稀土y型分子筛及其制备方法
US11891577B2 (en) 2020-02-10 2024-02-06 Hindustan Petroleum Corporation Limited FCC additive composition for bottoms cracking and a process for preparation thereof
EP4200070A4 (en) * 2020-08-19 2024-11-13 Basf Corporation Fluid catalytic cracking catalyst composition for enhanced butylenes yields with metal passivation functionality
US12605700B2 (en) * 2020-10-09 2026-04-21 Basf Corporation Phosphorus stabilized zeolites
CN116323872A (zh) 2020-11-04 2023-06-23 巴斯夫公司 包括磷稳定的mse框架型沸石的催化剂、其制备和其在流化催化应用中的用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3595611A (en) * 1969-02-03 1971-07-27 Grace W R & Co Cation and thermal stabilization of faujasite-type zeolites
US5378670A (en) * 1993-04-16 1995-01-03 W. R. Grace & Co.-Conn. Phosphorus zeolites/molecular sieves
CN1203623A (zh) * 1995-12-08 1998-12-30 恩格尔哈德公司 被金属污染的油原料裂化用催化剂
CN101134172A (zh) * 2006-08-31 2008-03-05 中国石油化工股份有限公司 一种烃类转化催化剂

Family Cites Families (10)

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US4498975A (en) * 1982-05-24 1985-02-12 Exxon Research & Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
US4504382A (en) * 1982-10-14 1985-03-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
US4493902A (en) * 1983-02-25 1985-01-15 Engelhard Corporation Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making
JPH07106317B2 (ja) * 1987-02-13 1995-11-15 触媒化成工業株式会社 炭化水素油の接触分解用触媒組成物の製造方法
US5312792A (en) * 1990-10-05 1994-05-17 W. R. Grace & Co.-Conn. Catalytic compositions
US5395809A (en) * 1993-11-01 1995-03-07 Engelhard Corporation Modified microsphere FCC catalysts
BR9400475A (pt) * 1994-02-09 1995-09-19 Petroleo Brasileiro Sa Processo de preparação de zeólita modificada e zeólita modificada
US5993645A (en) * 1995-12-08 1999-11-30 Engelhard Corporation Catalyst for cracking oil feedstocks contaminated with metal
US6069012A (en) * 1997-05-23 2000-05-30 Kayser Technology, Inc. Versatile fluidized bed reactor
CN1275855C (zh) * 2003-03-28 2006-09-20 中国石油化工股份有限公司 用高岭土合成的纳米级y型沸石及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3595611A (en) * 1969-02-03 1971-07-27 Grace W R & Co Cation and thermal stabilization of faujasite-type zeolites
US5378670A (en) * 1993-04-16 1995-01-03 W. R. Grace & Co.-Conn. Phosphorus zeolites/molecular sieves
CN1203623A (zh) * 1995-12-08 1998-12-30 恩格尔哈德公司 被金属污染的油原料裂化用催化剂
CN101134172A (zh) * 2006-08-31 2008-03-05 中国石油化工股份有限公司 一种烃类转化催化剂

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Publication number Publication date
BR112014010790A2 (pt) 2017-04-25
EP2773459A4 (en) 2015-07-15
RU2632913C2 (ru) 2017-10-11
AR088662A1 (es) 2014-06-25
JP6148243B2 (ja) 2017-06-14
JP2017196618A (ja) 2017-11-02
KR20140099471A (ko) 2014-08-12
MY164957A (en) 2018-02-28
TWI595926B (zh) 2017-08-21
JP6486989B2 (ja) 2019-03-20
IN2014CN04033A (enExample) 2015-10-23
WO2013067481A1 (en) 2013-05-10
BR112014010790B1 (pt) 2020-02-04
MX2014005436A (es) 2014-08-22
KR102038335B1 (ko) 2019-10-31
JP2015511869A (ja) 2015-04-23
ZA201404009B (en) 2015-08-26
US8940652B2 (en) 2015-01-27
CN104245136A (zh) 2014-12-24
MX361541B (es) 2018-12-10
TW201328778A (zh) 2013-07-16
CA2854610C (en) 2020-03-31
US20130115164A1 (en) 2013-05-09
CA2854610A1 (en) 2013-05-10
EP2773459A1 (en) 2014-09-10
RU2014122451A (ru) 2015-12-10

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Granted publication date: 20161228