TWI586689B - Modified polytetrafluoroethylene powder and uniaxially stretched porous body - Google Patents
Modified polytetrafluoroethylene powder and uniaxially stretched porous body Download PDFInfo
- Publication number
- TWI586689B TWI586689B TW105131365A TW105131365A TWI586689B TW I586689 B TWI586689 B TW I586689B TW 105131365 A TW105131365 A TW 105131365A TW 105131365 A TW105131365 A TW 105131365A TW I586689 B TWI586689 B TW I586689B
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- TW
- Taiwan
- Prior art keywords
- ocf
- fine powder
- modified polytetrafluoroethylene
- uniaxially stretched
- polytetrafluoroethylene fine
- Prior art date
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- 229920001343 polytetrafluoroethylene Polymers 0.000 title claims description 165
- 239000004810 polytetrafluoroethylene Substances 0.000 title claims description 165
- 239000000843 powder Substances 0.000 title claims description 121
- -1 polytetrafluoroethylene Polymers 0.000 title claims description 53
- 238000001125 extrusion Methods 0.000 claims description 60
- 238000006116 polymerization reaction Methods 0.000 claims description 47
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims description 46
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 43
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 41
- 239000011737 fluorine Substances 0.000 claims description 41
- 229910052731 fluorine Inorganic materials 0.000 claims description 41
- 239000004094 surface-active agent Substances 0.000 claims description 36
- 238000002844 melting Methods 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 18
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 150000001340 alkali metals Chemical class 0.000 claims description 11
- 239000011164 primary particle Substances 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 7
- 230000005484 gravity Effects 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 4
- 239000003513 alkali Substances 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims 1
- 239000010408 film Substances 0.000 description 57
- 239000006185 dispersion Substances 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 31
- 239000011148 porous material Substances 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 26
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- 238000006243 chemical reaction Methods 0.000 description 13
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- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 12
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- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
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- 239000000203 mixture Substances 0.000 description 8
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
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- 238000005096 rolling process Methods 0.000 description 6
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- 230000004931 aggregating effect Effects 0.000 description 5
- 238000011088 calibration curve Methods 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
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- 239000007870 radical polymerization initiator Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
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- 229930195734 saturated hydrocarbon Natural products 0.000 description 4
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- 239000003381 stabilizer Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
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- 150000002500 ions Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000003566 sealing material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- SNGREZUHAYWORS-UHFFFAOYSA-M 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate Chemical compound [O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-M 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000004520 agglutination Effects 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
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- 239000011258 core-shell material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- KDQPSPMLNJTZAL-UHFFFAOYSA-L disodium hydrogenphosphate dihydrate Chemical compound O.O.[Na+].[Na+].OP([O-])([O-])=O KDQPSPMLNJTZAL-UHFFFAOYSA-L 0.000 description 2
- DGLRDKLJZLEJCY-UHFFFAOYSA-L disodium hydrogenphosphate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O DGLRDKLJZLEJCY-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
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- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
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- 238000000465 moulding Methods 0.000 description 2
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- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
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- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
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- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
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- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/11—Melt tension or melt strength
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/24—Polymer with special particle form or size
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/26—Use as polymer for film forming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polymerisation Methods In General (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013248706 | 2013-11-29 |
Publications (2)
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| TW201708277A TW201708277A (zh) | 2017-03-01 |
| TWI586689B true TWI586689B (zh) | 2017-06-11 |
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| TW105131365A TWI586689B (zh) | 2013-11-29 | 2014-12-01 | Modified polytetrafluoroethylene powder and uniaxially stretched porous body |
| TW103141906A TW201533125A (zh) | 2013-11-29 | 2014-12-01 | 改性聚四氟乙烯細粉及單軸拉伸多孔質體 |
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| TW103141906A TW201533125A (zh) | 2013-11-29 | 2014-12-01 | 改性聚四氟乙烯細粉及單軸拉伸多孔質體 |
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| EP (1) | EP3053937B1 (enExample) |
| JP (2) | JP5930008B2 (enExample) |
| CN (1) | CN105793300B (enExample) |
| TW (2) | TWI586689B (enExample) |
| WO (1) | WO2015080289A1 (enExample) |
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| JP5823601B2 (ja) | 2013-11-29 | 2015-11-25 | 旭化成イーマテリアルズ株式会社 | 高分子電解質膜 |
| JP5862751B2 (ja) | 2013-11-29 | 2016-02-16 | ダイキン工業株式会社 | 多孔質体、高分子電解質膜、フィルター用濾材及びフィルターユニット |
| CN105794031B (zh) | 2013-11-29 | 2019-01-29 | 旭化成株式会社 | 高分子电解质膜 |
| JP6801660B2 (ja) * | 2015-08-19 | 2020-12-16 | Ａｇｃ株式会社 | 変性ポリテトラフルオロエチレンの水性乳化液、ファインパウダーおよび延伸多孔体の製造方法 |
| CN106632796B (zh) * | 2015-12-15 | 2019-02-05 | 浙江汉丞科技有限公司 | 膨体高分子量四氟乙烯共聚分散树脂的微孔材料 |
| JP6244490B1 (ja) * | 2016-03-20 | 2017-12-06 | 株式会社潤工社 | ポリテトラフルオロエチレンチューブ |
| WO2017163912A1 (ja) * | 2016-03-20 | 2017-09-28 | 株式会社 潤工社 | ポリテトラフルオロエチレンチューブ |
| US20180036936A1 (en) * | 2016-08-04 | 2018-02-08 | General Electric Company | Apparatus and method of processing a continuous sheet of polymer material |
| EP3828208A4 (en) | 2018-07-23 | 2022-07-13 | Daikin Industries, Ltd. | POLYTETRAFLUOROETHYLENE AND STRETCHED BODY |
| JP7227507B2 (ja) * | 2018-09-28 | 2023-02-22 | ダイキン工業株式会社 | エアフィルタ濾材、フィルタパック、エアフィルタユニット、およびこれらの製造方法 |
| US12152093B2 (en) | 2018-12-10 | 2024-11-26 | Daikin Industries, Ltd. | Tetrafluoroethylene polymer, air filter medium, filter pack, and air filter unit |
| JP7316893B2 (ja) * | 2019-09-27 | 2023-07-28 | 三井・ケマーズ フロロプロダクツ株式会社 | 高強度小孔径のポリテトラフルオロエチレン多孔膜 |
| WO2023054723A1 (ja) * | 2021-09-30 | 2023-04-06 | ダイキン工業株式会社 | ポリテトラフルオロエチレンファインパウダー |
| JP2024025761A (ja) | 2022-08-10 | 2024-02-26 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレン、及び、延伸体 |
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| JP5823601B2 (ja) | 2013-11-29 | 2015-11-25 | 旭化成イーマテリアルズ株式会社 | 高分子電解質膜 |
| TWI713443B (zh) | 2013-11-29 | 2020-12-21 | 日商大金工業股份有限公司 | 雙軸拉伸多孔質膜 |
| JP5862751B2 (ja) | 2013-11-29 | 2016-02-16 | ダイキン工業株式会社 | 多孔質体、高分子電解質膜、フィルター用濾材及びフィルターユニット |
| CN105794031B (zh) | 2013-11-29 | 2019-01-29 | 旭化成株式会社 | 高分子电解质膜 |
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- 2014-12-01 JP JP2014242997A patent/JP5930008B2/ja active Active
- 2014-12-01 EP EP14865651.5A patent/EP3053937B1/en active Active
- 2014-12-01 TW TW103141906A patent/TW201533125A/zh unknown
- 2014-12-01 CN CN201480064966.XA patent/CN105793300B/zh active Active
- 2014-12-01 US US15/038,307 patent/US11084895B2/en active Active
- 2014-12-01 WO PCT/JP2014/081771 patent/WO2015080289A1/ja not_active Ceased
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2016
- 2016-04-26 JP JP2016087804A patent/JP6369499B2/ja active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1898282A (zh) * | 2003-12-22 | 2007-01-17 | 大金工业株式会社 | 非熔融加工性聚四氟乙烯及其细粉 |
| CN101287766A (zh) * | 2005-10-17 | 2008-10-15 | 旭硝子株式会社 | 聚四氟乙烯水性乳化液、由其制得的聚四氟乙烯细粉和多孔体 |
| CN102356095A (zh) * | 2009-03-30 | 2012-02-15 | 大金工业株式会社 | 聚四氟乙烯及其制造方法 |
| WO2013027850A1 (ja) * | 2011-08-25 | 2013-02-28 | ダイキン工業株式会社 | ポリテトラフルオロエチレン水性分散液の製造方法 |
| WO2013115278A1 (ja) * | 2012-02-02 | 2013-08-08 | 旭硝子株式会社 | ポリテトラフルオロエチレンファインパウダーの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6369499B2 (ja) | 2018-08-08 |
| JP2015127411A (ja) | 2015-07-09 |
| WO2015080289A1 (ja) | 2015-06-04 |
| TWI561567B (enExample) | 2016-12-11 |
| CN105793300A (zh) | 2016-07-20 |
| US11084895B2 (en) | 2021-08-10 |
| JP2016164273A (ja) | 2016-09-08 |
| JP5930008B2 (ja) | 2016-06-08 |
| CN105793300B (zh) | 2018-01-05 |
| EP3053937A4 (en) | 2017-05-17 |
| TW201708277A (zh) | 2017-03-01 |
| EP3053937A1 (en) | 2016-08-10 |
| US20160289361A1 (en) | 2016-10-06 |
| TW201533125A (zh) | 2015-09-01 |
| EP3053937B1 (en) | 2019-02-27 |
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