TWI542681B - Shading material - Google Patents
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- Publication number
- TWI542681B TWI542681B TW102123223A TW102123223A TWI542681B TW I542681 B TWI542681 B TW I542681B TW 102123223 A TW102123223 A TW 102123223A TW 102123223 A TW102123223 A TW 102123223A TW I542681 B TWI542681 B TW I542681B
- Authority
- TW
- Taiwan
- Prior art keywords
- magnesium hydroxide
- resin
- heat shielding
- shielding material
- heat
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 22
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 31
- 239000000347 magnesium hydroxide Substances 0.000 claims description 31
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 31
- 239000013078 crystal Substances 0.000 claims description 25
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- 239000011342 resin composition Substances 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 7
- 238000004381 surface treatment Methods 0.000 description 6
- 238000002834 transmittance Methods 0.000 description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 5
- -1 alkali metal salt Chemical class 0.000 description 5
- 239000001632 sodium acetate Substances 0.000 description 5
- 235000017281 sodium acetate Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 238000000975 co-precipitation Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 159000000003 magnesium salts Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000012756 surface treatment agent Substances 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001361 allenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229920005557 bromobutyl Polymers 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 description 1
- 229920005556 chlorobutyl Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 229920005558 epichlorohydrin rubber Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920005575 poly(amic acid) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/02—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of crystals, e.g. rock-salt, semi-conductors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B2001/7691—Heat reflecting layers or coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/254—Roof garden systems; Roof coverings with high solar reflectance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description
本發明係關於紅外線的反射能力優異，且對可見光的穿透性優異之遮熱材。
能源價格有日漸高漲的傾向，省能源在廣範圍領域中已成為共通的課題。利用在屋頂塗佈遮熱塗料、或在窗玻璃上黏貼加入有遮熱材的樹脂薄膜，俾抑制因夏季的太陽光而造成的室內溫度上升的方法正急遽拓展。又，農業領域中，為了使可見光穿透，但防止溫室內必要以上的溫度上升，俾良好地保持農作物的育成，係使用遮熱薄膜或薄片。
此種遮熱製品所使用的遮熱材係鋁或銀的金屬薄片、氧化鈦、氧化鋅、珍珠顏料等。該等遮熱材會將溫度上升原因的紅外線予以反射，在夏季時防止室內溫度上升，在冬季時防止室內溫度下降。但是，該等遮熱材具有透明性差、成形品表面粗糙、容易著色等缺點。因此，若黏貼於窗戶便會導致視界變差。又，農業用溫室內的植物生育係由於植物所需要的可見光之穿透減少，因而有所阻礙。又，有不易製作透明、無色的塗料等問題。
本發明之目的係在於提供：對溫度上升原因的紅外線之反射能力優異，且對可見光穿透性優異的遮熱材。又，本發明之目的
係在於提供：含有該遮熱材的樹脂組成物及成形品。
本發明者發現高寬深比板狀結晶氫氧化鎂的紅外線反射能力優異，且對可見光的穿透性優異，遂完成本發明。
即，本發明的遮熱材係以結晶的橫寬為1μm以上，且結晶的厚度為0.2μm以下之板狀結晶氫氧化鎂作為有效成分。又，本發明的樹脂組成物係含有100重量份的樹脂、及1~50重量份的上述遮熱材。又，本發明的成形品係將上述樹脂組成物予以成形而得。又，本發明的將板狀結晶氫氧化鎂使用為紅外線遮熱材之方法，該板狀結晶氫氧化鎂係結晶的橫寬為1μm以上，且結晶的厚度為0.2μm以下。
本發明的遮熱材係以結晶的橫寬較大且結晶的厚度較薄之高寬深比板狀結晶氫氧化鎂作為有效成分。高寬深比板狀結晶氫氧化鎂的結晶橫寬為1μm以上、較佳為2μm以上、更佳為3μm以上。又，結晶的厚度為0.2μm以下、較佳為0.1μm以下、更佳為0.05μm以下。
上述板狀結晶氫氧化鎂在樹脂中的配向性優異、光反射率高。結果，能將溫度上升原因的紅外線良好地反射，俾使其穿透率降低。寬深比係定義為結晶的橫寬/厚度之比。
高寬深比板狀結晶氫氧化鎂的結晶橫寬越大，則配向性(成形面與結晶的橫向呈平行)越佳，越接近鏡面反射，遮熱效果提升。
另一方面，結晶的厚度越薄，則越提升可見光的穿透率，透明性良好。習知的氫氧化鎂結晶係橫寬約為1μm以下，且厚度約為0.5μm以上。因此，結晶的配向性不良且厚度較厚，故透明性差、遮熱效果小。
為提升與樹脂間之相溶性、分散性，高寬深比板狀結晶氫氧化鎂可經表面處理後使用。作為表面處理劑，係使用：高級脂肪酸或其鹼金屬鹽、磷酸酯、陰離子系界面活性劑；矽烷、鋁、鈦酸酯等偶合劑等等。表面處理係可藉由相對於高寬深比板狀結晶氫氧化鎂的重量，使0.1~10重量%的表面處理劑溶解於水或醇等有機溶劑中，在水等液狀介質中施行攪拌下添加高寬深比板狀結晶氫氧化鎂的濕式法實施。或者，亦可藉由將板狀結晶氫氧化鎂粉末利用諸如漢歇爾攪拌機等攪拌機施行攪拌下，添加上述表面處理劑之所謂乾式法實施。
為提升其容積比重俾使與樹脂進行混練時的加工性良好，板狀結晶氫氧化鎂亦可經成形為例如直徑0.5~5mm之粒狀後使用。成形係可使用擠出造粒、滾動造粒等以往公知手段實施。
高寬深比板狀結晶氫氧化鎂係在微結晶氫氧化鎂與單羧酸/或其金屬鹽之共存下，於100℃以上、較佳係150~250℃施行攪拌下，施行較佳2~10小時的水熱處理便可製造。
單羧酸亦可在利用於水溶性鎂鹽水溶液中添加當量以上的NaOH等鹼，較佳於0~40℃進行反應的共沉法製造氫氧化鎂的階段，於共沉反應前添加至鎂的鹵化物、硝酸鹽、單羧酸鹽等水溶性鎂鹽，利用氫氧化鈉等鹼進行共沉後，施行水熱處理。單羧酸係相對於氫氧化鎂，依莫耳比添加較佳0.01以上、更佳係0.1~1.0。
作為水溶性鎂鹽，較佳係可列舉如：氯化鎂、硝酸鎂、醋酸鎂。單羧酸較佳係可列舉如：醋酸、丙酸、丁酸、甘醇酸、乳酸。
再者，本發明的樹脂組成物係含有100重量份的樹脂、及1~50重量份的上述遮熱材。
作為樹脂，較佳係從熱可塑性樹脂、熱硬化性樹脂及橡膠所構成群組中選擇之至少一種樹脂。作為樹脂，係可例示：聚乙烯、乙烯與α-烯烴的共聚合體；乙烯與醋酸乙烯酯、丙烯酸乙酯或丙烯酸甲酯的共聚合體、聚丙烯、丙烯與其他α-烯烴的共聚合體、聚丁烯-1、聚4-甲基戊烯-1、聚苯乙烯、苯乙烯與丙烯腈、乙烯與丙二烯橡膠或丁二烯的共聚合體、聚醋酸乙烯酯、聚乙烯醇、聚丙烯酸酯、聚甲基丙烯酸酯、聚胺甲酸酯、聚酯、聚醚、聚醯胺、ABS、聚碳酸酯、聚苯硫醚等熱可塑性樹脂；酚樹脂、三聚氰胺樹脂、環氧樹脂、不飽和聚酯樹脂、醇酸樹脂等熱硬化性樹脂；EPDM、SBR、NBR、乙烯與其他α-烯烴(例如丙烯、辛烯等)的共聚合橡膠、丁基橡膠、氯化戊二烯橡膠、異戊二烯橡膠、氯磺化橡膠、矽橡膠、氟橡膠、氯化丁基橡膠、溴化丁基橡膠、表氯醇橡膠、氯化聚乙烯橡膠等。
作為樹脂組成物，係可列舉遮熱塗料。此情況，作為樹脂，係可含有例如：酚樹脂塗料、醇酸樹脂塗料、胺基醇酸樹脂塗料、氯乙烯樹脂塗料、丙烯酸系樹脂塗料、環氧樹脂塗料、矽樹脂塗料、聚胺甲酸酯樹脂塗料、氟樹脂塗料、油性塗料等。
相對於100重量份的樹脂，遮熱材在樹脂組成物中的含量係0.1~100重量份、較佳係1~50重量份。
樹脂組成物係在將樹脂與上述遮熱材進行混合後，利用以往公知的混練手段便可製造。例如，將樹脂與遮熱材利用雙螺桿擠出機施行加熱熔融混合後，予以顆粒化便可製造。
將樹脂組成物利用擠出成形、射出成形、真空成形、充氣成形、狹縫成形等慣用成形機、手段，予以成形為薄膜、薄片、厚壁成形品等便可獲得成形品。作為成形品，係可列舉：黏貼於窗戶玻璃上的遮熱薄膜、屋頂等處所使用的遮熱塗料、用以調節溫室內溫度的農業用遮熱薄膜或薄片、戶外使用的樹脂成形品等。
本發明係包含將結晶的橫寬為1μm以上，且結晶的厚度為0.2μm以下的高寬深比板狀結晶氫氧化鎂使用為紅外線遮熱材之方法。
以下，利用實施例說明本發明，惟本發明並不僅侷限於該等實施例。
在一級試劑氯化鎂與醋酸鈉之混合水溶液(Mg=2莫耳/L、醋酸鈉=1.2莫耳/L、30℃)20L中，於攪拌下，添加8莫耳/L的一級試劑氫氧化鈉水溶液(30℃)8L，使其進行共沉反應。將該反應物裝入容量50L熱壓鍋中，於170℃施行8小時水熱處理。取出水熱處理物，經減壓過濾、水洗後，利用攪拌機使濾餅分散於水中。加熱至約
80℃後，於攪拌下添加將40g硬脂酸(純度90%)利用氫氧化鈉中和並加熱溶解而成的水溶液1L，施行表面處理。然後，將施行強制過濾、水洗所獲得之濾餅利用造粒用雙螺桿擠出機造粒成直徑約2mm，利用烤箱於約120℃乾燥。
採取表面處理前的一部分試料，施行利用X射線繞射、SEM、及液態氮吸附法之BET比表面積測定。
X射線繞射的結果係鑑定為氫氧化鎂。SEM測定的結果，各個結晶係接近六角形的板狀結晶外形，厚度為0.07μm、橫寬為3.2μm。所因此，寬深比為50。BET比表面積為12m2/g。
相對於LLDPE(直鏈低密度聚乙烯)100重量份，將造粒物10重量份、抗氧化劑(IRGANOX 1010)0.1重量份進行混合後，使用布拉班德粉質儀(Brabender)施行熔融混練。將混練物使用壓製成形機成形為厚度1mm、長134mm、寬99mm的薄片。針對該薄片使用分光光度計，測定可見光(380~780nm)穿透率與近紅外線(780~2500nm)反射率。結果示於表1。
將該薄片裝設於僅1方向設有40mm見方之窗口且經利用絕熱劑覆蓋的紙製箱體之窗部分，距離10.5cm照射紅外線燈(185W)，測定箱體內的溫度及薄片溫度。結果示於表1。結果可知，調配有本發明遮熱材的樹脂薄片係透明性良好(因為可見光線穿透率高)，且可抑制室內溫度上升。
在實施例1中，依高寬深比板狀結晶氫氧化鎂的製造條件，除取代醋酸鈉，改為使用丙酸鈉1.6莫耳之外，其餘均與實施例1同樣地實施而製造氫氧化鎂。表面處理前的該物質經X射線繞射的結果係鑑定為氫氧化鎂。SEM測定的結果，各個結晶係接近六角形的板狀結晶外形，厚度為0.05μm、橫寬為4.5μm。因此，寬深比為90。BET比表面積為8.2m2/g。
將所獲得之造粒物依照與實施例1同樣的方式成形為薄片並施行遮熱試驗。結果示於表1。可知實施例2亦呈現與實施例1同樣的傾向。
將市售氫氧化鎂(厚度0.3μm、橫寬0.9μm、BET比表面積6m2/g、寬深比3)依照與實施例1同樣的方式利用硬脂酸鈉施行表面處理後，與實施例1同樣地施行遮熱試驗，結果示於表1。由表1可知，市售氫氧化鎂的透明性差，近紅外線反射率、遮熱性均劣於本發明的遮熱材。
使用在橫寬約15μm雲母的表面上形成有氧化鈦的珍珠顏料系市售遮熱材，依照與實施例1同樣的方式製成LLDPE薄片。其評估結果示於表1。由表1可知，市售遮熱材的透明性差。
本發明的遮熱材係紅外線反射能力優異，且可見光穿透性優異。又，本發明的樹脂組成物及成形品係具有呈現透明性優異、表面光澤優異的高級感之外觀。
本發明的遮熱材係可應用於以遮熱為目的之任何用途。可列舉如：黏貼於住家、汽車等的窗玻璃上之遮熱薄膜、屋頂等處所使用的遮熱塗料、用以調節溫室內溫度的農業用遮熱薄膜或薄片、戶外使用的傢俱等樹脂成形品等等。
Claims (8)
- 一種遮熱材，係以結晶的橫寬為1μm以上，且結晶的厚度為0.2μm以下之高寬深比板狀結晶氫氧化鎂作為有效成分，該遮熱材係直徑為0.5~5mm之粒狀者。
- 如申請專利範圍第1項之遮熱材，其中，高寬深比板狀結晶氫氧化鎂的橫寬為2μm以上，且厚度為0.1μm以下。
- 如申請專利範圍第1項之遮熱材，其中，高寬深比板狀結晶氫氧化鎂的橫寬為3μm以上，且厚度為0.1μm以下。
- 如申請專利範圍第1項之遮熱材，其中，高寬深比板狀結晶氫氧化鎂的橫寬為3μm以上，且厚度為0.05μm以下。
- 一種樹脂組成物，係含有100重量份的樹脂、及1~50重量份的申請專利範圍第1項之遮熱材。
- 一種成形品，係將申請專利範圍第5項之樹脂組成物予以成形而得。
- 如申請專利範圍第6項之成形品，其係薄膜。
- 一種將申請專利範圍第1項之遮熱材使用為紅外線遮熱材之方法。
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| JP4022957B2 (ja) * | 1997-04-18 | 2007-12-19 | 東ソー株式会社 | 難燃発泡性シート、難燃発泡シート及びそれよりなる壁紙並びに床材 |
| JPH11315146A (ja) * | 1998-05-06 | 1999-11-16 | Optec Kikaku Kaihatsu Kk | 高分子粒子 |
| WO2000035808A1 (fr) * | 1998-12-14 | 2000-06-22 | Kyowa Chemical Industry Co., Ltd. | Particules d'hydroxyde de magnesium, procede de production correspondant, et composition de resine renfermant lesdites particules |
| GB0229810D0 (en) * | 2002-12-20 | 2003-01-29 | Vantico Ag | Flame retardant polymer compositions |
| WO2007027114A1 (en) * | 2005-09-01 | 2007-03-08 | Instytut Wlokien Naturalnych (Institute Of Natural Fibres) | An intumescent fire retardant and the method of its manufacture |
| TW200916561A (en) * | 2007-05-07 | 2009-04-16 | Martinswerk Gmbh | Flame retarded thermosets |
| JP5421045B2 (ja) * | 2008-10-01 | 2014-02-19 | 富士フイルム株式会社 | フィルムおよびフィルムの製造方法 |
| PL2628710T3 (pl) * | 2010-10-12 | 2019-01-31 | Kyowa Chemical Industry Co., Ltd. | Wodorotlenek magnezu o wysokim współczynniku kształtu |
| KR101899631B1 (ko) * | 2012-01-20 | 2018-09-17 | 교와 가가꾸고교 가부시키가이샤 | 열 전도 개량제 |
| RU2603369C2 (ru) * | 2012-04-05 | 2016-11-27 | Киова Кемикал Индастри Ко., Лтд. | Композиция смолы |
| WO2013154200A1 (ja) * | 2012-04-10 | 2013-10-17 | 協和化学工業株式会社 | 複合難燃剤、樹脂組成物および成形品 |
-
2013
- 2013-06-27 US US14/408,710 patent/US20150177430A1/en not_active Abandoned
- 2013-06-27 RU RU2015102757A patent/RU2015102757A/ru not_active Application Discontinuation
- 2013-06-27 KR KR20147033781A patent/KR20150024823A/ko not_active Application Discontinuation
- 2013-06-27 EP EP13809005.5A patent/EP2868825A4/en not_active Withdrawn
- 2013-06-27 JP JP2014522720A patent/JPWO2014003201A1/ja active Pending
- 2013-06-27 CN CN201380034111.8A patent/CN104411897A/zh active Pending
- 2013-06-27 WO PCT/JP2013/068305 patent/WO2014003201A1/ja active Application Filing
- 2013-06-27 CA CA2881314A patent/CA2881314A1/en not_active Abandoned
- 2013-06-27 MX MX2014015875A patent/MX2014015875A/es unknown
- 2013-06-28 TW TW102123223A patent/TWI542681B/zh not_active IP Right Cessation
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2014
- 2014-12-23 ZA ZA2014/09501A patent/ZA201409501B/en unknown
- 2014-12-29 CL CL2014003548A patent/CL2014003548A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2014003201A1 (ja) | 2016-06-02 |
| RU2015102757A (ru) | 2016-08-20 |
| US20150177430A1 (en) | 2015-06-25 |
| ZA201409501B (en) | 2016-08-31 |
| CA2881314A1 (en) | 2014-01-03 |
| CN104411897A (zh) | 2015-03-11 |
| EP2868825A1 (en) | 2015-05-06 |
| MX2014015875A (es) | 2015-03-19 |
| TW201408763A (zh) | 2014-03-01 |
| WO2014003201A1 (ja) | 2014-01-03 |
| EP2868825A4 (en) | 2016-03-23 |
| CL2014003548A1 (es) | 2015-04-06 |
| KR20150024823A (ko) | 2015-03-09 |
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