TWI537327B - 供用於電線及電纜應用之無鹵素阻燃劑組成物 - Google Patents
供用於電線及電纜應用之無鹵素阻燃劑組成物 Download PDFInfo
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- TWI537327B TWI537327B TW100141590A TW100141590A TWI537327B TW I537327 B TWI537327 B TW I537327B TW 100141590 A TW100141590 A TW 100141590A TW 100141590 A TW100141590 A TW 100141590A TW I537327 B TWI537327 B TW I537327B
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- flame retardant
- propylene
- polypropylene
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- 239000000203 mixture Substances 0.000 title claims description 86
- 239000003063 flame retardant Substances 0.000 title claims description 49
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 42
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 65
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 60
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- OCBMNKXTDPSDKN-UHFFFAOYSA-N decan-1-amine;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCN OCBMNKXTDPSDKN-UHFFFAOYSA-N 0.000 claims description 2
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims description 2
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- AAOADXIHXYIOMT-UHFFFAOYSA-N 1,1'-biphenyl;phosphoric acid Chemical compound OP(O)(O)=O.C1=CC=CC=C1C1=CC=CC=C1 AAOADXIHXYIOMT-UHFFFAOYSA-N 0.000 description 3
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- LAUIXFSZFKWUCT-UHFFFAOYSA-N [4-[2-(4-phosphonooxyphenyl)propan-2-yl]phenyl] dihydrogen phosphate Chemical compound C=1C=C(OP(O)(O)=O)C=CC=1C(C)(C)C1=CC=C(OP(O)(O)=O)C=C1 LAUIXFSZFKWUCT-UHFFFAOYSA-N 0.000 description 2
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- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
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- PZRHRDRVRGEVNW-UHFFFAOYSA-N milrinone Chemical compound N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C PZRHRDRVRGEVNW-UHFFFAOYSA-N 0.000 description 1
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- NLJASJZSFGKTQT-UHFFFAOYSA-N n-(2-hydroxypropyl)-n-prop-2-enylnitrous amide Chemical compound CC(O)CN(N=O)CC=C NLJASJZSFGKTQT-UHFFFAOYSA-N 0.000 description 1
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- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
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- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- YVURAEQQLUQPFO-UHFFFAOYSA-N phosphoric acid;styrene Chemical compound OP(O)(O)=O.C=CC1=CC=CC=C1 YVURAEQQLUQPFO-UHFFFAOYSA-N 0.000 description 1
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- 229920005633 polypropylene homopolymer resin Polymers 0.000 description 1
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- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
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- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/292—Protection against damage caused by extremes of temperature or by flame using material resistant to heat
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/5205—Salts of P-acids with N-bases
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L2201/02—Flame or fire retardant/resistant
Landscapes
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- Health & Medical Sciences (AREA)
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- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
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|---|---|---|---|
| PCT/CN2010/079933 WO2012079243A1 (en) | 2010-12-17 | 2010-12-17 | Halogen-free, flame retardant composition for wire and cable applications |
Publications (2)
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| TW201226462A TW201226462A (en) | 2012-07-01 |
| TWI537327B true TWI537327B (zh) | 2016-06-11 |
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| KR101802012B1 (ko) * | 2011-06-21 | 2017-11-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 피페라진계 팽창성 난연제를 포함하는 할로겐-비함유 난연성 중합체 조성물 |
| KR102141475B1 (ko) * | 2012-12-17 | 2020-08-05 | 가부시키가이샤 아데카 | 난연제 조성물 및 난연성 합성 수지 조성물 |
| JP2015042730A (ja) * | 2014-04-25 | 2015-03-05 | 株式会社Adeka | 難燃性熱可塑性ポリウレタンエラストマー組成物 |
| CA2950207C (en) * | 2014-05-28 | 2023-05-23 | Low & Bonar | Fire retardant darkening screen |
| WO2016208656A1 (ja) * | 2015-06-24 | 2016-12-29 | 株式会社フジクラ | 難燃性樹脂組成物、及び、これを用いたケーブル並びに光ファイバケーブル |
| US9696510B1 (en) * | 2015-12-30 | 2017-07-04 | Hitachi Cable America Inc. | Small form factor flame resistant low smoke halogen free fiber optic cable |
| AU2016398212B2 (en) * | 2016-03-14 | 2019-05-16 | Borealis Ag | Polypropylene composition comprising flame retardant |
| CA3037976C (en) | 2016-09-28 | 2023-10-03 | Dow Global Technologies Llc | Formulation of elastomer copolymer and block copolymer |
| EP3635072B1 (en) * | 2017-06-07 | 2023-08-02 | General Cable Technologies Corporation | Fire retardant cables formed from halogen-free and heavy metal-free compositions |
| WO2019108362A1 (en) * | 2017-11-28 | 2019-06-06 | Corning Research & Development Corporation | Cable component including a halogen-free flame retardant composition |
| WO2019117049A1 (ja) * | 2017-12-14 | 2019-06-20 | 株式会社Adeka | 組成物及び難燃性樹脂組成物 |
| EP3505566A1 (en) * | 2017-12-28 | 2019-07-03 | Borealis AG | Cable jacket |
| KR102141732B1 (ko) * | 2018-07-27 | 2020-08-05 | 한국전력공사 | 절연재 조성물을 이용한 전력케이블용 절연재 |
| CN112011128A (zh) * | 2019-05-29 | 2020-12-01 | 合肥杰事杰新材料股份有限公司 | 一种聚丙烯中空挤出复合板材及其制备方法 |
| EP4025647A4 (en) * | 2019-10-15 | 2023-09-13 | Avient Corporation | HALOGEN-FREE FLAME-RETARDANT THERMOPLASTIC ELASTOMER |
| EP4077533B1 (en) * | 2019-12-18 | 2025-08-27 | Dow Global Technologies LLC | Halogen free flame retardant polymeric compositions |
| EP4413070A1 (en) * | 2021-10-05 | 2024-08-14 | Borealis AG | Cable |
| US11840656B2 (en) * | 2021-11-05 | 2023-12-12 | Industrial Technology Research Institute | Halogen free flame-retardant materials and method for manufacturing the same |
| CN118488988A (zh) * | 2021-12-28 | 2024-08-13 | Sabic环球技术有限责任公司 | 包含物体和层的制品 |
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-
2010
- 2010-12-17 US US13/990,084 patent/US9336927B2/en active Active
- 2010-12-17 EP EP10860760.7A patent/EP2652033B1/en active Active
- 2010-12-17 WO PCT/CN2010/079933 patent/WO2012079243A1/en not_active Ceased
- 2010-12-17 MX MX2013006823A patent/MX2013006823A/es active IP Right Grant
- 2010-12-17 JP JP2013543487A patent/JP2013545858A/ja active Pending
- 2010-12-17 CA CA2821015A patent/CA2821015C/en active Active
- 2010-12-17 CN CN201080071217.1A patent/CN103370368B/zh active Active
- 2010-12-17 BR BR112013013867-0A patent/BR112013013867B1/pt active IP Right Grant
- 2010-12-17 KR KR1020137018567A patent/KR20130127493A/ko not_active Ceased
-
2011
- 2011-11-15 TW TW100141590A patent/TWI537327B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2821015A1 (en) | 2012-06-21 |
| MX2013006823A (es) | 2013-08-26 |
| EP2652033B1 (en) | 2016-10-19 |
| KR20130127493A (ko) | 2013-11-22 |
| WO2012079243A1 (en) | 2012-06-21 |
| JP2013545858A (ja) | 2013-12-26 |
| BR112013013867A2 (pt) | 2016-09-13 |
| CA2821015C (en) | 2017-09-26 |
| EP2652033A1 (en) | 2013-10-23 |
| EP2652033A4 (en) | 2014-05-14 |
| BR112013013867B1 (pt) | 2019-09-17 |
| CN103370368B (zh) | 2015-11-25 |
| US20150155075A1 (en) | 2015-06-04 |
| TW201226462A (en) | 2012-07-01 |
| US9336927B2 (en) | 2016-05-10 |
| CN103370368A (zh) | 2013-10-23 |
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