TWI469951B - 具多層疊合結構之多孔性碳製品、製造方法及其應用 - Google Patents

具多層疊合結構之多孔性碳製品、製造方法及其應用 Download PDF

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TWI469951B
TWI469951B TW101109036A TW101109036A TWI469951B TW I469951 B TWI469951 B TW I469951B TW 101109036 A TW101109036 A TW 101109036A TW 101109036 A TW101109036 A TW 101109036A TW I469951 B TWI469951 B TW I469951B
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carbon
template
inner layer
porous
microporosity
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TW101109036A
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TW201305085A (zh
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克里斯汀 諾伊曼
約爾格 貝克
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何瑞斯廓格拉斯公司
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C03B19/14—Other methods of shaping glass by gas- or vapour- phase reaction processes
    • C03B19/1484—Means for supporting, rotating or translating the article being formed
    • C03B19/1492—Deposition substrates, e.g. targets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/005—Manufacture of flakes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/524—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632—Organic additives
    • C04B35/636—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • C04B38/0032—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors one of the precursor materials being a monolithic element having approximately the same dimensions as the final article, e.g. a paper sheet which after carbonisation will react with silicon to form a porous silicon carbide porous body
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    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6028—Shaping around a core which is removed later
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
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    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Nanotechnology (AREA)
TW101109036A 2011-04-08 2012-03-16 具多層疊合結構之多孔性碳製品、製造方法及其應用 TWI469951B (zh)

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Application Number Priority Date Filing Date Title
DE102011016468A DE102011016468B3 (de) 2011-04-08 2011-04-08 Poröses Kohlenstofferzeugnis mit Schichtverbundstrucktur, Verfahren für seine Herstellung und Verwendung desselben

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TWI469951B true TWI469951B (zh) 2015-01-21

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US (1) US9520594B2 (enExample)
JP (1) JP5916841B2 (enExample)
CN (1) CN103460451B (enExample)
DE (1) DE102011016468B3 (enExample)
TW (1) TWI469951B (enExample)
WO (1) WO2012136513A1 (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012011946A1 (de) 2012-06-18 2013-12-19 Heraeus Quarzglas Gmbh & Co. Kg Verfahren für die Herstellung von Kompositpulver ausKohlenstoff, sowie für einen unter Einsatz des Kompositpulvers erzeugten porösen Verbundwerkstoff für elektrochemische Elektroden
DE102012109720A1 (de) * 2012-10-11 2014-04-30 Heraeus Quarzglas Gmbh & Co. Kg Komposit aus porösem Kohlenstoff und Schwefel-haltigem Aktivmaterial sowie Verfahren für dessen Herstellung
JP6389468B2 (ja) * 2012-12-19 2018-09-12 シオン・パワー・コーポレーション 電極構造体およびその製造方法
CN103219501B (zh) * 2013-03-25 2015-04-15 华中科技大学 限制多硫化物溶出的锂硫电池正极材料、电极片和电池
WO2015002968A1 (en) 2013-07-01 2015-01-08 Dale Adams Process for sintering silicon carbide
US9556073B2 (en) 2013-07-01 2017-01-31 Dale Adams Process for sintering silicon carbide
DE102014109441B4 (de) * 2013-07-10 2023-10-12 GM Global Technology Operations LLC (n. d. Ges. d. Staates Delaware) Oberflächenbeschichtungsverfahren und verfahren zur herstellung einer elektrode für eine lithium-basierte batterie
US10062898B2 (en) 2013-07-10 2018-08-28 GM Global Technology Operations LLC Surface coating method and method for improving electrochemical performance of an electrode for a lithium based battery
PL229976B1 (pl) * 2014-01-24 2018-09-28 Zachodniopomorski Univ Technologiczny W Szczecinie Sposób otrzymywania nanoporowatych materiałów węglowych
EP2899158B1 (de) 2014-01-24 2016-11-16 Heraeus Quarzglas GmbH & Co. KG Poröse kohlenstoffteilchen mit kern-hülle-struktur sowie verfahren zur herstellung derselben
WO2015166030A1 (en) 2014-05-01 2015-11-05 Basf Se Electrode fabrication methods and associated articles
CN106663797B (zh) * 2014-07-15 2020-06-19 东丽株式会社 电极材料、锂硫电池电极、锂硫电池和电极材料的制造方法
CN104319402B (zh) * 2014-10-28 2016-08-24 上海交通大学 一种多层碳空心球负极材料的制备方法
US10312501B2 (en) 2014-12-10 2019-06-04 GM Global Technology Operations LLC Electrolyte and negative electrode structure
US20160172710A1 (en) 2014-12-10 2016-06-16 The Regents Of The University Of California Electrolyte and negative electrode structure
US10113095B2 (en) 2015-07-20 2018-10-30 Microsoft Technology Licensing, Llc Reinforced graphitic material
JP7043077B2 (ja) * 2016-01-20 2022-03-29 コーネル ユニバーシティ マルチドメイン硫黄電極及びその製造方法
EP3476815B1 (en) 2017-10-27 2023-11-29 Heraeus Quarzglas GmbH & Co. KG Production of a porous product including post-adapting a pore structure
EP3476475B1 (en) * 2017-10-27 2022-04-06 Heraeus Battery Technology GmbH Production of a porous carbon product
WO2019178533A1 (en) * 2018-03-16 2019-09-19 University Of Maryland, College Park All solid-state sodium-sulfur or lithium-sulfur battery prepared using cast-annealing method
US12334538B2 (en) * 2018-08-29 2025-06-17 Panasonic Intellectual Property Management Co., Ltd. Non-aqueous electrolyte secondary battery
CZ308296B6 (cs) * 2019-08-01 2020-04-22 Univerzita Tomáše Bati ve Zlíně Způsob přípravy materiálu katody pro lithium-sírovou baterii
US11806693B2 (en) 2020-06-16 2023-11-07 Sigma-Aldrich Co. Llc HPLC carbon with narrow particle size distribution
KR20220054049A (ko) * 2020-10-23 2022-05-02 주식회사 엘지에너지솔루션 코어-쉘 구조의 다공성 탄소재, 이의 제조방법, 이를 포함하는 황-탄소 복합체, 및 리튬 이차 전지
CN119230805B (zh) * 2024-12-03 2025-03-18 河南中新绿动能源有限公司 一种氟化碳化硅复合材料及其制备方法
CN120463179B (zh) * 2025-05-30 2025-11-28 广东韩研活性炭科技股份有限公司 一种具有三维状孔洞的硬碳制备方法及应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101444710A (zh) * 2007-11-28 2009-06-03 三星Sdi株式会社 中空胶囊结构及其制备方法
CN101916844A (zh) * 2010-07-29 2010-12-15 吴壮雄 一种锂离子电池用准球形负极材料及其制备方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6296324A (ja) * 1985-10-22 1987-05-02 Seiko Epson Corp 平板マイクロレンズアレイの製造方法
US6210831B1 (en) * 1997-12-19 2001-04-03 Moltech Corporation Cathodes comprising electroactive sulfur materials and secondary batteries using same
US6261469B1 (en) * 1998-10-13 2001-07-17 Honeywell International Inc. Three dimensionally periodic structural assemblies on nanometer and longer scales
US6395066B1 (en) 1999-03-05 2002-05-28 Ube Industries, Ltd. Partially carbonized asymmetric hollow fiber separation membrane, process for its production, and gas separation method
JP4081956B2 (ja) * 1999-03-05 2008-04-30 宇部興産株式会社 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法
JP3951567B2 (ja) * 2000-07-10 2007-08-01 東ソー株式会社 多孔質炭素材料およびその製造方法
WO2003006372A1 (en) 2001-07-13 2003-01-23 Kent State University Imprinted mesoporous carbons and a method of manufacture thereof
US6730398B2 (en) * 2001-08-31 2004-05-04 Showa Denko K.K. Fine carbon and method for producing the same
US7678495B2 (en) * 2005-01-31 2010-03-16 Alcatel-Lucent Usa Inc. Graphitic nanostructured battery
DE102005043289B3 (de) 2005-09-09 2006-09-14 Heraeus Tenevo Gmbh Verfahren zur Herstellung eines Halbzeugs für ein optisches Bauteil hoher Homogenität, zur Durchführung des Verfahrens geeigneter Rohling sowie Verwendung des Rohlings und des Halbzeugs
KR100741078B1 (ko) * 2005-11-22 2007-07-20 삼성에스디아이 주식회사 중형 다공성 탄소, 그 제조방법 및 이를 이용한 연료전지
JP4961953B2 (ja) * 2005-12-28 2012-06-27 株式会社豊田中央研究所 多孔質カーボン配列体及びその製造方法
CN101012057A (zh) 2007-01-19 2007-08-08 华东师范大学 一种介孔碳材料的合成方法
US8173302B2 (en) * 2008-06-11 2012-05-08 Toyota Motor Engineering & Manufacturing North America, Inc. Sulfur-carbon material
JP2010095390A (ja) * 2008-09-16 2010-04-30 Tokyo Institute Of Technology メソポーラス炭素複合材料およびこれを用いた二次電池
US20100203391A1 (en) * 2009-02-09 2010-08-12 Applied Materials, Inc. Mesoporous carbon material for energy storage
JP2010208887A (ja) * 2009-03-10 2010-09-24 Toyo Tanso Kk 多孔質炭素及びその製造方法
WO2011028804A2 (en) * 2009-09-02 2011-03-10 Ut-Battelle, Llc Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101444710A (zh) * 2007-11-28 2009-06-03 三星Sdi株式会社 中空胶囊结构及其制备方法
CN101916844A (zh) * 2010-07-29 2010-12-15 吴壮雄 一种锂离子电池用准球形负极材料及其制备方法

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