TWI455875B - 多孔性碳製品之製造方法及其應用 - Google Patents

多孔性碳製品之製造方法及其應用 Download PDF

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TWI455875B
TWI455875B TW101106128A TW101106128A TWI455875B TW I455875 B TWI455875 B TW I455875B TW 101106128 A TW101106128 A TW 101106128A TW 101106128 A TW101106128 A TW 101106128A TW I455875 B TWI455875 B TW I455875B
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template
particles
precursor
template particles
carbon
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TW201236969A (en
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Christian Neumann
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Heraeus Quarzglas
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C—CHEMISTRY; METALLURGY
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • C04B38/0032—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors one of the precursor materials being a monolithic element having approximately the same dimensions as the final article, e.g. a paper sheet which after carbonisation will react with silicon to form a porous silicon carbide porous body
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96—Carbon-based electrodes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00853—Uses not provided for elsewhere in C04B2111/00 in electrochemical cells or batteries, e.g. fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Claims (15)

  1. 一種多孔性碳製品之製造方法，該方法包含下列步驟：(a)由無機模板材料製備模板，該模板具有彼此連通之孔洞，(b)製備一種碳之前驅物質，(c)以該前驅物質滲透模板之孔，(d)碳化該前驅物質，(e)去除該模板，以形成多孔性碳製品，其特徵為，該前驅物質粒子係由可熔化原料以及模板粒子製成，並由該粒子產生一種粉末混合物，該粉末混合物依方法步驟(d)於碳化時或之前加熱，使前驅物質熔化物滲入模板粒子之孔洞內，模板粒子之製作包含一種煤灰沈積程序在內，使用一種經水解或熱解變成模板粒子之材料，該粒子係於一沈積表面，以形成模板材料煤灰體之方式沈積出來，而煤灰體再經粉碎成為模板粒子。
  2. 根據申請專利範圍第1項所述之方法，其特徵為，模板粒子具有非球形之形態。
  3. 根據申請專利範圍第2項所述之方法，其特徵為，模板粒子為片狀或長條狀，其結構比至少為5。
  4. 根據申請專利範圍第2項所述之方法，其特徵為，模板粒子為片狀或長條狀，其結構比至少為10。
  5. 根據申請專利範圍第1項所述之方法，其特徵為，模板粒子之平均厚度範圍為10μm至500μm。
  6. 根據申請專利範圍第1項所述之方法，其特徵為，模板粒子之平均厚度範圍為20μm至100μm。
  7. 根據申請專利範圍第1項所述之方法，其特徵為，模板粒子之平均厚度範圍小於50μm。
  8. 根據申請專利範圍第1項所述之方法，其特徵為，前驅物質粒子為球形，而且平均粒子大小小於50μm。
  9. 根據申請專利範圍第1項所述之方法，其特徵為，前驅物質粒子為球形，而且平均粒子大小小於20μm。
  10. 根據申請專利範圍第1項所述之方法，其特徵為，前驅物質粒子和模板粒子係以範圍在0.05和1.6間之體積比例彼此混合。
  11. 根據申請專利範圍第1項所述之方法，其特徵為，前驅物質粒子和模板粒子係以範圍在0.1和0.8間之體積比例彼此混合。
  12. 根據申請專利範圍第1項所述之方法，其特徵為，模板材料為二氧化矽。
  13. 根據申請專利範圍第1項所述之方法，其特徵為，碳前驅物質係採用瀝青。
  14. 根據申請專利範圍第1項所述之方法，其特徵為，採用碳水化合物做為碳前驅物質。
  15. 根據申請專利範圍第1項所述之方法，其特徵為，碳製品被粉碎成具多孔性粒子之細小碳元素。
TW101106128A 2011-03-04 2012-02-24 多孔性碳製品之製造方法及其應用 TWI455875B (zh)

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DE102011013075.6A DE102011013075B4 (de) 2011-03-04 2011-03-04 Verfahren zur Herstellung eines porösen Kohlenstofferzeugnisses

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US9212062B2 (en) 2011-07-27 2015-12-15 Heraeus Quarzglas Gmbh & Co. Kg Porous carbon product and method for producing an electrode for a rechargeable lithium battery
DE102012011946A1 (de) * 2012-06-18 2013-12-19 Heraeus Quarzglas Gmbh & Co. Kg Verfahren für die Herstellung von Kompositpulver ausKohlenstoff, sowie für einen unter Einsatz des Kompositpulvers erzeugten porösen Verbundwerkstoff für elektrochemische Elektroden
DE102012109720A1 (de) 2012-10-11 2014-04-30 Heraeus Quarzglas Gmbh & Co. Kg Komposit aus porösem Kohlenstoff und Schwefel-haltigem Aktivmaterial sowie Verfahren für dessen Herstellung
CN103785355A (zh) * 2012-11-02 2014-05-14 中国科学院上海硅酸盐研究所 介孔/大孔多级孔块体胆红素吸附剂材料及其制备方法
CN103447003B (zh) * 2013-08-16 2015-11-18 中国科学院上海硅酸盐研究所 多级孔碳块体作为油质有机物的吸附/回收材料的应用
DE102013110453A1 (de) * 2013-09-20 2015-03-26 Heraeus Quarzglas Gmbh & Co. Kg Verfahren zur Herstellung eines porösen Kohlenstofferzeugnisses
DE102014009554A1 (de) * 2014-06-12 2015-12-17 Daimler Ag Elektrodenmaterial für einen elektrochemischen Speicher, Verfahren zur Herstellung eines Elektrodenmaterials sowie elektrochemischer Energiespeicher
WO2016018192A1 (en) 2014-07-29 2016-02-04 Agency For Science, Technology And Research Method of preparing a porous carbon material
EP3476815B1 (en) * 2017-10-27 2023-11-29 Heraeus Quarzglas GmbH & Co. KG Production of a porous product including post-adapting a pore structure
EP3476475B1 (en) * 2017-10-27 2022-04-06 Heraeus Battery Technology GmbH Production of a porous carbon product
TWI666441B (zh) * 2017-12-07 2019-07-21 國立清華大學 石墨烯材料的數量表面積的定量方法
CN110304629B (zh) * 2018-03-25 2021-03-02 北京金羽新能科技有限公司 一种分级多孔炭材料及其制备的超级电容器
JP7333684B2 (ja) * 2018-04-26 2023-08-25 三菱鉛筆株式会社 超音波探触子
CN110316715B (zh) * 2019-06-28 2022-08-23 上海交通大学 一种原位制备金属衍生碳基光子晶体的方法
CN111320161A (zh) * 2020-03-08 2020-06-23 大连理工大学 一种沥青基碳纳米片的制备方法及其应用

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DE102011013075A1 (de) 2012-09-06
CN103415492B (zh) 2018-06-05
DE102011013075B4 (de) 2019-03-28
CN103415492A (zh) 2013-11-27
WO2012119666A1 (en) 2012-09-13
KR101924804B1 (ko) 2018-12-05
TW201236969A (en) 2012-09-16
JP2014518534A (ja) 2014-07-31
KR20140018909A (ko) 2014-02-13
JP5797783B2 (ja) 2015-10-21

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