TWI440659B - 由聚乙烯縮醛與塑化劑環己烷-1,2-二羧酸酯製成之含塑化劑薄膜 - Google Patents
由聚乙烯縮醛與塑化劑環己烷-1,2-二羧酸酯製成之含塑化劑薄膜 Download PDFInfo
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- TWI440659B TWI440659B TW098115066A TW98115066A TWI440659B TW I440659 B TWI440659 B TW I440659B TW 098115066 A TW098115066 A TW 098115066A TW 98115066 A TW98115066 A TW 98115066A TW I440659 B TWI440659 B TW I440659B
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- film
- plasticizer
- weight
- ester
- polyvinyl acetal
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- 239000004014 plasticizer Substances 0.000 title claims description 109
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 title claims description 42
- 229920002554 vinyl polymer Polymers 0.000 title claims description 30
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 title claims 11
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical class OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 title description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 52
- -1 polyethylene Polymers 0.000 claims description 28
- 239000004065 semiconductor Substances 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical compound CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 claims description 4
- 125000004185 ester group Chemical group 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 claims description 3
- 239000005340 laminated glass Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- FUNRFPIDKUMSSH-UHFFFAOYSA-N C(CCCCC(=O)OOCCOCCCC)(=O)OOCCOCCCC Chemical compound C(CCCCC(=O)OOCCOCCCC)(=O)OOCCOCCCC FUNRFPIDKUMSSH-UHFFFAOYSA-N 0.000 claims description 2
- 150000007514 bases Chemical class 0.000 claims description 2
- BTZQCSUZZWDBIU-UHFFFAOYSA-N bis(2-butoxyethyl) pentanedioate Chemical compound CCCCOCCOC(=O)CCCC(=O)OCCOCCCC BTZQCSUZZWDBIU-UHFFFAOYSA-N 0.000 claims description 2
- MYYFGPCJFLAATK-UHFFFAOYSA-N bis(2-hexoxyethyl) decanedioate Chemical compound CCCCCCOCCOC(=O)CCCCCCCCC(=O)OCCOCCCCCC MYYFGPCJFLAATK-UHFFFAOYSA-N 0.000 claims description 2
- FBXNUYNATQIVEX-UHFFFAOYSA-N bis[2-(2-butoxyethoxy)ethyl] decanedioate Chemical compound CCCCOCCOCCOC(=O)CCCCCCCCC(=O)OCCOCCOCCCC FBXNUYNATQIVEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-M pimelate(1-) Chemical compound OC(=O)CCCCCC([O-])=O WLJVNTCWHIRURA-UHFFFAOYSA-M 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 2
- ZYVMGEYDARMBAK-UHFFFAOYSA-N 6-(2-hexoxyethoxy)-6-oxohexanoic acid Chemical compound CCCCCCOCCOC(=O)CCCCC(O)=O ZYVMGEYDARMBAK-UHFFFAOYSA-N 0.000 claims 1
- WBSKBEUOPIUOAF-UHFFFAOYSA-N C(CCCCC(=O)OOCCOCCCCCC)(=O)OOCCOCCCCCC Chemical compound C(CCCCC(=O)OOCCOCCCCCC)(=O)OOCCOCCCCCC WBSKBEUOPIUOAF-UHFFFAOYSA-N 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
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- 150000001241 acetals Chemical class 0.000 description 36
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- 238000006359 acetalization reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000005336 safety glass Substances 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 11
- HORIEOQXBKUKGQ-UHFFFAOYSA-N bis(7-methyloctyl) cyclohexane-1,2-dicarboxylate Chemical compound CC(C)CCCCCCOC(=O)C1CCCCC1C(=O)OCCCCCCC(C)C HORIEOQXBKUKGQ-UHFFFAOYSA-N 0.000 description 11
- 239000003513 alkali Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000004448 titration Methods 0.000 description 9
- 238000005259 measurement Methods 0.000 description 7
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000004806 diisononylester Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 6
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- 238000012360 testing method Methods 0.000 description 5
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 4
- 125000001033 ether group Chemical group 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 3
- 239000011654 magnesium acetate Substances 0.000 description 3
- 229940069446 magnesium acetate Drugs 0.000 description 3
- 235000011285 magnesium acetate Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 3
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
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- 230000007935 neutral effect Effects 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229940116351 sebacate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WLHQGPQHTQJEJM-UHFFFAOYSA-N 1,2-bis(8-methylnonyl)cyclohexane-1,2-dicarboxylic acid Chemical compound CC(C)CCCCCCCC1(C(O)=O)CCCCC1(CCCCCCCC(C)C)C(O)=O WLHQGPQHTQJEJM-UHFFFAOYSA-N 0.000 description 1
- WOSKKIDAXRPURV-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl 2-ethylbutanoate Chemical compound CCC(CC)C(=O)OCCOCCOCCO WOSKKIDAXRPURV-UHFFFAOYSA-N 0.000 description 1
- WVDVRNPRYVOYBD-UHFFFAOYSA-N 2-o-heptyl 1-o-hexyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC WVDVRNPRYVOYBD-UHFFFAOYSA-N 0.000 description 1
- ZUDPXPYGTYNSCK-UHFFFAOYSA-N 6-(1-hexylcyclohexyl)oxy-6-oxohexanoic acid Chemical compound OC(=O)CCCCC(=O)OC1(CCCCCC)CCCCC1 ZUDPXPYGTYNSCK-UHFFFAOYSA-N 0.000 description 1
- BJIUNQZHYLBUNL-UHFFFAOYSA-N 6-heptoxy-6-oxohexanoic acid Chemical compound CCCCCCCOC(=O)CCCCC(O)=O BJIUNQZHYLBUNL-UHFFFAOYSA-N 0.000 description 1
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
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- TXYFMRLDRVQNHH-UHFFFAOYSA-N C(CCCCC)OCCOC(C(=O)O)(CCCC(=O)O)OCCOCCCCCC Chemical compound C(CCCCC)OCCOC(C(=O)O)(CCCC(=O)O)OCCOCCCCCC TXYFMRLDRVQNHH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
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- VVKREWPWSWPBGC-UHFFFAOYSA-N benzoic acid;2-(2-hydroxypropoxy)propan-1-ol Chemical compound CC(O)COC(C)CO.OC(=O)C1=CC=CC=C1 VVKREWPWSWPBGC-UHFFFAOYSA-N 0.000 description 1
- KZBSIGKPGIZQJQ-UHFFFAOYSA-N bis(2-butoxyethyl) decanedioate Chemical compound CCCCOCCOC(=O)CCCCCCCCC(=O)OCCOCCCC KZBSIGKPGIZQJQ-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- BUOCZPSVAWQIOT-UHFFFAOYSA-N bis(2-hexoxyethyl) hexanedioate Chemical compound CCCCCCOCCOC(=O)CCCCC(=O)OCCOCCCCCC BUOCZPSVAWQIOT-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- JEELFTYNBPTQCD-UHFFFAOYSA-N bis[2-(2-hexoxyethoxy)ethyl] hexanedioate Chemical compound CCCCCCOCCOCCOC(=O)CCCCC(=O)OCCOCCOCCCCCC JEELFTYNBPTQCD-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
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- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
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- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 1
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 1
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- OJXOOFXUHZAXLO-UHFFFAOYSA-M magnesium;1-bromo-3-methanidylbenzene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C1=CC=CC(Br)=C1 OJXOOFXUHZAXLO-UHFFFAOYSA-M 0.000 description 1
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- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
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- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000008029 phthalate plasticizer Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
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- 230000003746 surface roughness Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10605—Type of plasticiser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Joining Of Glass To Other Materials (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Photovoltaic Devices (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008001655A DE102008001655A1 (de) | 2008-05-08 | 2008-05-08 | Weichmacherhaltige Folien aus Polyvinylacetal mit Cyclohexan-1,2-dicarbon-säureestern als Weichmacher |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201008986A TW201008986A (en) | 2010-03-01 |
TWI440659B true TWI440659B (zh) | 2014-06-11 |
Family
ID=41152421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW098115066A TWI440659B (zh) | 2008-05-08 | 2009-05-07 | 由聚乙烯縮醛與塑化劑環己烷-1,2-二羧酸酯製成之含塑化劑薄膜 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9657149B2 (fr) |
EP (1) | EP2274366B1 (fr) |
JP (1) | JP5419966B2 (fr) |
CN (1) | CN102282200B (fr) |
DE (1) | DE102008001655A1 (fr) |
TW (1) | TWI440659B (fr) |
WO (1) | WO2009135928A1 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112012024610A2 (pt) * | 2010-03-31 | 2016-05-31 | Kuraray Co | filme de poli (vinil-acetal) e seu uso |
DE102010019941B4 (de) | 2010-05-08 | 2014-11-13 | Horst Pabst | Vorrichtung zur Coextrusion von thermoplastischen Schmelzeströmen zur Herstellung von Verbundglasscheiben |
CN103044826A (zh) * | 2011-10-14 | 2013-04-17 | 武汉泓锦旭隆新材料有限公司 | 一种用于太阳能光伏组件的pvb膜片及其制备方法 |
CN102675788B (zh) * | 2012-05-03 | 2016-04-20 | 浙江圣瑞塑胶有限公司 | 一种光伏级聚乙烯醇缩丁醛的加工助剂 |
JP6276837B2 (ja) | 2013-03-15 | 2018-02-07 | ゼネラル・エレクトリック・カンパニイ | 複合材料用スラリー |
MX2016012444A (es) * | 2014-03-28 | 2017-01-06 | Sekisui Chemical Co Ltd | Pelicula interestratificada para vidrio laminado, y vidrio laminado. |
US10000039B2 (en) | 2014-12-08 | 2018-06-19 | Solutia Inc. | Multilayer interlayers having high Tg and high modulus |
US10086590B2 (en) | 2014-12-08 | 2018-10-02 | Solutia Inc. | High Tg monolithic poly(vinyl acetal) sheet |
AU2016216328A1 (en) | 2015-02-05 | 2017-08-17 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass, and laminated glass |
WO2018055119A1 (fr) * | 2016-09-26 | 2018-03-29 | Henkel Ag & Co. Kgaa | Pastilles parfumées en dispersions de masse fondue contenant des solides |
KR102260893B1 (ko) * | 2018-06-11 | 2021-06-07 | 주식회사 엘지화학 | 가소제 조성물 및 이를 포함하는 수지 조성물 |
KR102297786B1 (ko) * | 2018-12-21 | 2021-09-02 | 한화솔루션 주식회사 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
Family Cites Families (31)
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US4355886A (en) * | 1980-05-13 | 1982-10-26 | Xerox Corporation | Polyvinyl acetal coated carrier particles for magnetic brush cleaning |
DE3569904D1 (en) | 1984-12-24 | 1989-06-08 | Huels Troisdorf | Process for producing films, especially those based on polyvinyl butyral with a slight surface tackiness |
FR2644112B1 (fr) | 1989-03-10 | 1991-05-10 | Saint Gobain Vitrage | |
DE3913572A1 (de) * | 1989-04-25 | 1990-10-31 | Hoechst Ag | Neue polyvinylacetale und ihre verwendung |
FR2690918B1 (fr) * | 1992-05-06 | 2001-12-28 | Poudres & Explosifs Ste Nale | Utilisation d'un arylsulfonyluréthanne comme résine garnissante dans les vernis à ongles nitrocellulosiques. Nouveaux arylsulfonyluréthannes et nouveaux vernis à ongles nitrocellulosiques. |
JPH0848547A (ja) | 1994-08-10 | 1996-02-20 | Sekisui Chem Co Ltd | 合わせガラス用中間膜及び合わせガラス |
US6559212B1 (en) | 1995-12-29 | 2003-05-06 | Monsanto Company | Plasticized polyvinyl butyral and sheet |
US6801652B1 (en) | 1998-09-29 | 2004-10-05 | Siemens Aktiengesellschaft | Method for checking the presentation of components to an automatic onserting unit |
DE19951444A1 (de) | 1999-10-25 | 2001-04-26 | Huels Troisdorf | Verfahren und Folie zur Herstellung von Verbundsicherheitsscheiben |
US20010046595A1 (en) * | 1999-12-14 | 2001-11-29 | Moran James R. | Intrusion resistant glass laminates |
JP4076730B2 (ja) * | 2000-03-02 | 2008-04-16 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
CN1318372C (zh) * | 2001-02-16 | 2007-05-30 | 巴斯福股份公司 | 环己烷二羧酸及其衍生物的制备方法 |
DE10116812A1 (de) | 2001-04-04 | 2002-10-17 | Basf Ag | Kunststoffe mit kernhydrierten Phthalat-Weichmachern |
DE10129422A1 (de) | 2001-06-19 | 2003-01-02 | Huels Troisdorf | Weichmacherhaltige PVB-Folie |
DE10143190A1 (de) | 2001-09-04 | 2003-03-20 | Kuraray Specialities Europe | Hochmolekulare, vernetzte Polyvinylbutyrale, Verfahren zu deren Herstellung sowie deren Verwendung |
AU2003223239A1 (en) | 2002-03-12 | 2003-09-29 | E. I. Du Pont De Nemours And Company | Low-color stiff pvb laminates |
DE10217186A1 (de) * | 2002-04-18 | 2003-11-13 | Oxeno Olefinchemie Gmbh | Benzoesäureisononylester und deren Verwendung |
DE10319198A1 (de) | 2002-07-04 | 2004-01-15 | Kuraray Specialities Europe Gmbh | Vernetzte Polyvinylacetale |
US7511096B2 (en) | 2003-01-09 | 2009-03-31 | Kuraray Europe Gmbh | Crosslinked polyvinyl acetals |
AU2003293853A1 (en) | 2003-01-09 | 2004-08-10 | Kuraray Specialities Europe Gmbh | Crosslinked polyvinly acetals |
JP4493645B2 (ja) * | 2003-03-14 | 2010-06-30 | ビーエーエスエフ ソシエタス・ヨーロピア | シクロヘキサポリカルボン酸誘導体を用いた印刷インク |
DE10343385A1 (de) | 2003-09-19 | 2005-04-14 | Kuraray Specialities Europe Gmbh | Polyvinylacetal-haltige Zusammensetzungen, Folien und Verbundgläser sowie Verfahren zu deren Herstellung |
DE102004030411A1 (de) * | 2004-06-23 | 2006-01-19 | Kuraray Specialities Europe Gmbh | Solarmodul als Verbundsicherheitsglas |
DE102004043907A1 (de) | 2004-09-10 | 2006-03-16 | Kuraray Specialities Europe Gmbh | Weichmacherhaltige PVB-Folien mit Etherbindungen enthaltenden Carbonsäureestern als Co-Weichmacher |
DE102005028752A1 (de) | 2005-06-22 | 2007-01-04 | Oxeno Olefinchemie Gmbh | Gemisch von Diisononylestern der 1,2-Cyclohexandicarbonsäure, Verfahren zu deren Herstellung und Verwendung dieser Gemische |
ATE446976T1 (de) * | 2006-05-23 | 2009-11-15 | Basf Se | Verfahren zur herstellung von ethylencopolymeren |
DE202006014595U1 (de) | 2006-09-20 | 2006-11-23 | Wulfmeier Besitzgesellschaft Mbh & Co. Kg | Photovoltaikmodul |
US7943845B2 (en) * | 2007-02-07 | 2011-05-17 | E. I. Du Pont De Nemours And Company | Solar cells encapsulated with poly(vinyl butyral) |
DE102007000818A1 (de) * | 2007-10-05 | 2009-04-09 | Kuraray Europe Gmbh | Photovoltaikmodule mit weichmacherhaltigen Folien geringer Feuchtigkeitsaufnahme |
DE102007000816A1 (de) * | 2007-10-05 | 2009-04-09 | Kuraray Europe Gmbh | Photovoltaikmodule mit weichmacherhaltigen Folien auf Basis von Polyvinylacetal mit hohem spezifischen Widerstand |
US8604101B2 (en) * | 2010-03-24 | 2013-12-10 | Basf Se | Process for producing aqueous dispersions of thermoplastic polyesters |
-
2008
- 2008-05-08 DE DE102008001655A patent/DE102008001655A1/de not_active Withdrawn
-
2009
- 2009-05-07 TW TW098115066A patent/TWI440659B/zh not_active IP Right Cessation
- 2009-05-08 EP EP09742146A patent/EP2274366B1/fr active Active
- 2009-05-08 US US12/991,570 patent/US9657149B2/en active Active
- 2009-05-08 CN CN200980116478.8A patent/CN102282200B/zh active Active
- 2009-05-08 JP JP2011507934A patent/JP5419966B2/ja active Active
- 2009-05-08 WO PCT/EP2009/055577 patent/WO2009135928A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
JP2011528382A (ja) | 2011-11-17 |
TW201008986A (en) | 2010-03-01 |
DE102008001655A1 (de) | 2009-11-12 |
EP2274366A1 (fr) | 2011-01-19 |
CN102282200A (zh) | 2011-12-14 |
US20110061714A1 (en) | 2011-03-17 |
US9657149B2 (en) | 2017-05-23 |
EP2274366B1 (fr) | 2012-12-05 |
JP5419966B2 (ja) | 2014-02-19 |
WO2009135928A1 (fr) | 2009-11-12 |
CN102282200B (zh) | 2015-04-15 |
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MM4A | Annulment or lapse of patent due to non-payment of fees |