TWI432497B - 聚碳酸酯之安定化 - Google Patents
聚碳酸酯之安定化 Download PDFInfo
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- TWI432497B TWI432497B TW097118699A TW97118699A TWI432497B TW I432497 B TWI432497 B TW I432497B TW 097118699 A TW097118699 A TW 097118699A TW 97118699 A TW97118699 A TW 97118699A TW I432497 B TWI432497 B TW I432497B
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- Prior art keywords
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- component
- composition
- compound
- polycarbonate
- Prior art date
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- 239000004417 polycarbonate Substances 0.000 title claims description 104
- 229920000515 polycarbonate Polymers 0.000 title claims description 104
- 230000006641 stabilisation Effects 0.000 title claims description 17
- 238000011105 stabilization Methods 0.000 title claims description 17
- 239000000203 mixture Substances 0.000 claims description 155
- 229920000642 polymer Polymers 0.000 claims description 67
- 150000001875 compounds Chemical class 0.000 claims description 60
- 239000000126 substance Substances 0.000 claims description 37
- 238000002156 mixing Methods 0.000 claims description 34
- -1 polyethylene Polymers 0.000 claims description 20
- 229920001577 copolymer Polymers 0.000 claims description 14
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000005060 rubber Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 10
- 238000001746 injection moulding Methods 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 9
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 9
- 229920000638 styrene acrylonitrile Polymers 0.000 claims description 9
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical group C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000012963 UV stabilizer Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000000748 compression moulding Methods 0.000 claims description 4
- 238000004898 kneading Methods 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000004611 light stabiliser Substances 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
- 229920007019 PC/ABS Polymers 0.000 description 23
- WHBHBVVOGNECLV-OBQKJFGGSA-N 11-deoxycortisol Chemical compound O=C1CC[C@]2(C)[C@H]3CC[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 WHBHBVVOGNECLV-OBQKJFGGSA-N 0.000 description 22
- 238000004383 yellowing Methods 0.000 description 22
- 239000006096 absorbing agent Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 239000000654 additive Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 230000000996 additive effect Effects 0.000 description 9
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 3
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 229920001898 acrylonitrile–EPDM–styrene Polymers 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 238000000429 assembly Methods 0.000 description 3
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 239000004597 plastic additive Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical compound CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- SENMPMXZMGNQAG-UHFFFAOYSA-N 3,4-dihydro-2,5-benzodioxocine-1,6-dione Chemical compound O=C1OCCOC(=O)C2=CC=CC=C12 SENMPMXZMGNQAG-UHFFFAOYSA-N 0.000 description 1
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 229940122361 Bisphosphonate Drugs 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- ZIXVIWRPMFITIT-UHFFFAOYSA-N cadmium lead Chemical compound [Cd].[Pb] ZIXVIWRPMFITIT-UHFFFAOYSA-N 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000001032 cobalt pigment Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- DGXKDBWJDQHNCI-UHFFFAOYSA-N dioxido(oxo)titanium nickel(2+) Chemical compound [Ni++].[O-][Ti]([O-])=O DGXKDBWJDQHNCI-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- PHTQWCKDNZKARW-UHFFFAOYSA-N isopentyl alcohol Natural products CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 1
- 239000001035 lead pigment Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- OHFCLJNYYRPINY-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butylphenyl)-2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(O)CC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1 OHFCLJNYYRPINY-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07108964 | 2007-05-25 | ||
| EP07122395 | 2007-12-05 | ||
| EP07122394 | 2007-12-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200906939A TW200906939A (en) | 2009-02-16 |
| TWI432497B true TWI432497B (zh) | 2014-04-01 |
Family
ID=39713961
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097118699A TWI432497B (zh) | 2007-05-25 | 2008-05-21 | 聚碳酸酯之安定化 |
| TW097118730A TWI432498B (zh) | 2007-05-25 | 2008-05-21 | 聚碳酸酯及聚碳酸酯摻混物之安定化 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097118730A TWI432498B (zh) | 2007-05-25 | 2008-05-21 | 聚碳酸酯及聚碳酸酯摻混物之安定化 |
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| EP (2) | EP2152798B1 (enExample) |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US8748518B2 (en) * | 2007-05-25 | 2014-06-10 | Clariant Finance (Bvi) Limited | Stabilization of polycarbonates |
| WO2012111718A1 (ja) * | 2011-02-16 | 2012-08-23 | 三菱化学株式会社 | ポリカーボネート樹脂組成物及び成形品 |
| KR102049410B1 (ko) | 2013-06-11 | 2019-11-27 | 에스케이케미칼 주식회사 | 자동차, 전기전자기기, 가전기기, 사무기기 또는 생활용품용 부품 |
| US9462319B2 (en) * | 2014-08-08 | 2016-10-04 | GM Global Technology Operations LLC | Method and apparatus for sensor synthesis and arbitration between mobile devices and vehicles |
| KR102119445B1 (ko) * | 2014-10-31 | 2020-06-16 | 에스케이케미칼 주식회사 | 오버헤드콘솔용 내화학성 고분자 수지 조성물 |
| JP6298935B2 (ja) * | 2015-12-08 | 2018-03-20 | 日本エイアンドエル株式会社 | 熱可塑性樹脂組成物 |
| KR102166306B1 (ko) * | 2018-08-20 | 2020-10-15 | 주식회사 엘지화학 | 폴리카보네이트 수지 조성물 및 이를 포함하는 광학 성형품 |
| CN110256829B (zh) * | 2019-05-27 | 2021-02-19 | 中广核俊尔(浙江)新材料有限公司 | 一种高流动聚碳酸酯组合物及其制备方法和应用 |
| WO2021171262A1 (en) | 2020-02-28 | 2021-09-02 | Shpp Global Technologies B.V. | High heat polycarbonate copolymer formulations |
| CN116096812A (zh) * | 2020-08-28 | 2023-05-09 | 电化株式会社 | 树脂组合物、成型体以及化妆品容器 |
Family Cites Families (19)
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| GB9100257D0 (en) | 1991-01-07 | 1991-02-20 | Sandoz Ltd | Improvements in or relating to organic compounds |
| JPH04159354A (ja) * | 1990-10-20 | 1992-06-02 | Kanegafuchi Chem Ind Co Ltd | 耐候性に優れた熱可塑性樹脂組成物 |
| GB9316893D0 (en) * | 1992-08-17 | 1993-09-29 | Sandoz Ltd | Use of hals compounds |
| WO1997039052A1 (en) * | 1996-04-12 | 1997-10-23 | Clariant Finance (Bvi) Limited | Stabilization of polyolefins |
| GB9607565D0 (en) | 1996-04-12 | 1996-06-12 | Clariant Int Ltd | Stabilizer composition |
| KR100496096B1 (ko) * | 1996-04-12 | 2005-09-27 | 클라리언트 파이넌스 (비브이아이) 리미티드 | 안정화제조성물 |
| US5955521A (en) * | 1997-07-17 | 1999-09-21 | Mannington Mills, Inc. | Ultra-violet stabilized polyvinyl chloride resins and methods to impart ultra-violet stabilization to polyvinyl chloride resins |
| US5990208A (en) * | 1997-12-15 | 1999-11-23 | Ciba Specialty Chemicals Corporation | Stabilization of polycarbonate/ABS blends with mixtures of hindered amines and UV absorbers |
| GB2332678B (en) * | 1997-12-23 | 2000-09-27 | Ciba Sc Holding Ag | Stabilizer mixtures containing a sterically hindered amine |
| US6297377B1 (en) * | 1998-06-22 | 2001-10-02 | Cytec Technology Corporation | Benzocycle-substituted triazine and pyrimidine ultraviolet light absorbers |
| US6262153B1 (en) * | 1998-10-12 | 2001-07-17 | Clariant Finance (Bvi) Limited | Colored wax articles |
| JP2002284957A (ja) * | 2001-03-23 | 2002-10-03 | Denki Kagaku Kogyo Kk | ゴム変性スチレン系樹脂組成物及びそのシート状物 |
| US7081213B2 (en) | 2002-05-14 | 2006-07-25 | Clariant Finance (Bvi) Limited | Stabilizer mixtures for the protection of polymer substrates |
| JP2006513310A (ja) * | 2003-01-13 | 2006-04-20 | イーストマン ケミカル カンパニー | ポリマーブレンド |
| JP5270162B2 (ja) * | 2004-09-30 | 2013-08-21 | チバ ホールディング インコーポレーテッド | 光安定剤を補充または導入する方法 |
| JP4759245B2 (ja) * | 2004-10-22 | 2011-08-31 | 出光興産株式会社 | ポリカーボネート系光拡散性樹脂組成物 |
| WO2007064003A1 (ja) * | 2005-12-02 | 2007-06-07 | Mitsui Chemicals, Inc. | 単層膜およびこれからなる親水性材料 |
| US8748518B2 (en) * | 2007-05-25 | 2014-06-10 | Clariant Finance (Bvi) Limited | Stabilization of polycarbonates |
| US8759428B2 (en) * | 2007-08-22 | 2014-06-24 | Sabic Innovative Plastics Ip B.V. | Polycarbonate compositions |
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2008
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- 2008-05-21 HU HUE08759823A patent/HUE031014T2/en unknown
- 2008-05-21 HU HUE08750357A patent/HUE029678T2/en unknown
- 2008-05-21 WO PCT/EP2008/056217 patent/WO2008145573A1/en not_active Ceased
- 2008-05-21 TW TW097118699A patent/TWI432497B/zh active
- 2008-05-21 CN CN200880017340A patent/CN101688023A/zh active Pending
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- 2008-05-21 WO PCT/EP2008/056218 patent/WO2008145574A1/en not_active Ceased
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- 2008-05-21 KR KR1020097024435A patent/KR101438250B1/ko not_active Expired - Fee Related
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- 2008-05-21 PL PL08759823T patent/PL2152797T3/pl unknown
- 2008-05-21 JP JP2010508829A patent/JP5264894B2/ja not_active Expired - Fee Related
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- 2008-05-21 KR KR1020097024436A patent/KR101524321B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| PL2152798T3 (pl) | 2017-05-31 |
| CN101688022A (zh) | 2010-03-31 |
| KR20100035632A (ko) | 2010-04-05 |
| CN101688023A (zh) | 2010-03-31 |
| CN101688022B (zh) | 2012-07-25 |
| TW200906939A (en) | 2009-02-16 |
| US20100179257A1 (en) | 2010-07-15 |
| WO2008145574A1 (en) | 2008-12-04 |
| TWI432498B (zh) | 2014-04-01 |
| EP2152797A1 (en) | 2010-02-17 |
| KR101524321B1 (ko) | 2015-05-29 |
| EP2152798B1 (en) | 2016-08-17 |
| EP2152797B1 (en) | 2016-07-13 |
| ES2599363T3 (es) | 2017-02-01 |
| HUE029678T2 (en) | 2017-03-28 |
| EP2152798A1 (en) | 2010-02-17 |
| JP2010528144A (ja) | 2010-08-19 |
| US8748518B2 (en) | 2014-06-10 |
| PL2152797T3 (pl) | 2017-03-31 |
| ES2593089T3 (es) | 2016-12-05 |
| JP5048125B2 (ja) | 2012-10-17 |
| US20100163814A1 (en) | 2010-07-01 |
| KR101438250B1 (ko) | 2014-09-05 |
| TW200904873A (en) | 2009-02-01 |
| JP2010528143A (ja) | 2010-08-19 |
| JP5264894B2 (ja) | 2013-08-14 |
| WO2008145573A1 (en) | 2008-12-04 |
| HUE031014T2 (en) | 2017-06-28 |
| KR20100017306A (ko) | 2010-02-16 |
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