TWI384063B - 香料粒子及香菸用濾嘴 - Google Patents
香料粒子及香菸用濾嘴 Download PDFInfo
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Fats And Perfumes (AREA)
- Manufacture Of Tobacco Products (AREA)
Description
本發明係有關香料粒子及含有該香料粒子之香菸用濾嘴。
在菸絲中所添加之香料中含有做為外部調味料(casing sauce)之第1香料與做為前端香料(top flavor)之第2香料。第2香料之成分揮發性較高,且易受熱分解。因此,具有第2香料之香菸在其存放中第2香料即揮發,不只吸菸時之香味減少,且在具備木炭濾嘴之香菸中,第2香料轉移至木炭被吸附,使香味更為減少。吸附有第2香料之木炭會降低去除香菸主流煙中之成分的能力。
日本專利第2709077號說明書揭示以天然多醣類進行微膠囊化,且將該微膠囊經由所謂洞穴填充,而將第2香料添加至香菸濾嘴中。由於香料已封入由天然多醣類形成之微膠囊內,故存放時不會發生香料轉移、揮發,因此,即使同時使用木炭濾嘴,也不會使木炭濾嘴降低去除香菸主流煙中之成分的能力。
然而,微化膠囊中之香料係在吸菸時需先經由手指壓碎、擦碎(應用外力)後才能品嚐。然而,應用外力甚為不便,而且經由應用外力而流出之香料無法均勻分布至整個濾嘴,結果造成吸菸時之菸味不固定。
因此,本發明之目的係提供在非吸菸時能抑制香料之
揮發.轉移,且在吸菸時無須應用外力,即能穩定地品嚐到香味之香料粒子及香菸用濾嘴。
根據本發明之1態樣,可提供包含粒子狀載體、由前述粒子狀載體所支撐之葡聚糖(glucan)膜、與香料之香料粒子;前述香料係以藉由前述葡聚糖膜抑制其香氣放出,而藉由前述葡聚糖膜係由香料粒子所載持,與香菸主流煙接觸使該膜至少一部分溶解而放出其香氣之方式載持於香料粒子。
此外,根據本發明之其他態樣,可提供含有本發明之香料粒子之香菸用濾嘴。
以下,參照圖式說明本發明之各種態樣。在所有圖式中,同樣要素係由同樣符號所表示。
本發明之香料粒子包含粒子狀載體、由前述粒子狀載體所支撐之葡聚糖膜、與香料。香料係以藉由葡聚糖膜抑制其香氣放出,而藉由前述葡聚糖膜與香菸主流煙接觸使該膜至少一部分溶解而放出其香氣之方式載持於香料粒子。
在本發明之第1態樣中,葡聚糖膜含有香料,且直接覆蓋在粒子狀載體之表面。由第1態樣形成之香料粒子具備有粒子狀載體與覆蓋在前述載體表面之含有香料之葡聚糖膜。
在本發明之第2態樣中,香料係固體香料,且該固體香料直接覆蓋在粒子狀載體之表面後,再將葡聚糖膜覆蓋在固體香料膜上。由第2態樣形成之香料粒子具備有粒子狀載體、覆蓋於前述載體表面所形成之薄荷腦(menthol)
膜、及覆蓋前述薄荷腦膜表面之葡聚糖膜。
本發明中所使用之粒子狀載體可由碳酸鈣粒子、活性碳粒子、糖結晶粒子(例如:砂糖)及咖啡豆粒子等構成。粒子狀載體係平均粒徑在75 μm至2000 μm者,例如可適用平均粒徑為75 μm至350 μm者。
葡聚糖膜係由例如:聚三葡萄糖(pullulan)、麥芽糊精、羥丙纖維素等所構成,為水溶性。
香料可使用食品用香料及香菸用香料。此種香料可舉例如:薰衣草、肉桂、小豆蔻、芹菜、丁香、卡藜皮、肉豆蔻、白檀、佛手柑、天竺葵、蜂蜜精華、玫瑰油、香草、檸檬、柑橘、薄荷、桂皮、香旱芹菜、白蘭地、茉莉、黃金菊、薄荷腦、桂皮(cassia)、香水樹、鼠尾草、綠薄荷、小茴香、青椒、薑、大茴香、胡荽、咖啡等之精油等。
第1圖係有關本發明之1態樣之香料粒子10之放大示意剖面圖。此香料粒子10係在粒子狀載體(核)12之表面覆蓋上葡聚糖膜14者。在葡聚糖膜14中含有香料。
含有香料之葡聚糖膜14可由香料與葡聚糖之水溶液或水分散液等形成。在此水溶液或水分散液中,香料使用量以相當於葡聚糖重量之20%以下(超過0%)為佳。葡聚糖膜14之厚度雖無特別限制,但從吸菸時放出香料之能力之觀點來看,以使用相當於最後香料粒子重量之0.25%至5%之葡聚糖形成之葡聚糖膜為佳。
由第1態樣形成之香料粒子可依照例如下述方法製造。亦即,將碳酸鈣等粒子狀載體放入流動造粒乾燥機中,
一面送入例如80℃以下之熱風,同時將含有上述香料之葡聚糖水溶液或水分散液連續性地或間歇性地噴灑在粒子狀載體之表面上並乾燥。此時,香料之種類係依葡聚糖溶液之組成使其迅速冷卻。如此,在粒子狀載體之表面上形成保有香料之葡聚糖膜。
由第1態樣形成之香料粒子的香料係包含於透氣性低之葡聚糖膜內部,故可降低存放時香料之揮發、變質。而且,在吸菸時與香菸主流煙接觸之後,經由香菸主流煙中之主要高極性成分(水分等)將葡聚糖膜之一部分開始溶解,且內部所包含之香料成分擴散至主流煙中,而能穩定地品嚐到香料之香味。本發明之香料粒子無須為了品嚐香味而像微膠囊之情形一樣應用外力。
第2圖係有關本發明之其他態樣之香料粒子20之放大示意剖面圖。此香料粒子20係將粒子狀載體(核)22之全表面覆蓋上如薄荷腦之固體香料膜24後,再將固體香料膜24之全表面覆蓋上葡聚糖膜26者。
固體香料膜24,如後所述,係由將例如薄荷腦之類的固體香料之結晶經由微粉末化後與粒子狀載體12混合,再將固體香料微粉末附著於粒子狀載體22上,並將它在粒子狀載體22上加熱熔融後,經由冷卻再結晶化而形成。在此冷卻時,為了不使薄荷腦等固體香料成長成柱狀結晶,較好預先在固體香料中添加脂肪酸、甘油、丙二醇等結晶成長抑制劑。此結晶成長抑制劑可使用相當於薄荷腦等固體香料之重量的0.1至1.0%之量。此外,在固體香料膜14
中亦可含有固體香料以外之香料。
固體香料膜24之厚度並無特別限制,但固體香料膜24較好是由相當於最後香料粒子重量之1至20%的固體香料形成者為佳。
葡聚糖膜26可由葡聚糖之水溶液、水分散液等形成。葡聚糖膜26之厚度並無特別限制,但是由葡聚糖膜26於非吸菸時之固體香料的保香性及吸菸時之薄荷腦之釋出能力之觀點而言,較好是由相當於最後香料粒子重量之0.25%至5%的葡聚糖形成為佳。
關於第2態樣之香料粒子,可依照例如下述方法製造。亦即,將粒子狀載體與固體香料結晶之微粉末、及視需要加結晶成長抑制劑、其他香料等,以螺條混合機(ribbon mixer)混合.加熱。在混合初期,固體香料結晶之微粉末附著於各粒子狀載體之表面上,經由加熱使溫度達到固體香料之融點(例如:薄荷腦約為42℃),固體香料結晶之微粉末即開始熔融。藉由持續攪拌混合,將熔融之固體香料均勻塗布於各粒子狀載體之表面。加熱混合後,可經由例如將螺條混合機罐體冷卻、或者將冷風送入螺條混合機內,而將粒子狀載體迅速冷卻。經由此冷卻,熔融之固體香料產生再結晶化,而以膜狀覆蓋在各粒子狀載體之表面。將此被固體香料膜覆蓋之粒子狀載體放入流動造粒乾燥機中,例如一面送入40℃以下之熱風,同時間歇性地噴灑葡聚糖之水溶液或葡聚糖之水分散液等,然後冷卻。如此,即在粒子狀載體表面所形成之固體香料膜之表面形
成葡聚糖之薄膜。
或者,如上述在粒子狀載體之表面上塗布固體香料膜後,直接在螺條混合機中、或在轉動造粒機中,在具有固體香料膜之粒子狀載體上噴灑葡聚糖之水溶液或水分散液,並於葡聚糖膜覆蓋固體香料膜後冷卻,也能製造有關第2態樣之香料粒子。
由第2態樣形成之香料粒子由於粒子狀載體之表面所設置之固體香料膜係由透氣性低之葡聚糖膜予以覆蓋,故在一般存放時薄荷腦不會揮發、或被木炭吸附。若經由吸菸產生之主流煙中之水分等與親水性成分接觸,則因葡聚糖膜一部分形狀改變並溶解而從下層之固體香料膜釋放出香氣,而能品嚐到香料之香味。本發明之香料粒子無須為了品嚐香味而須如微膠囊之情形一樣必須施用外力。
本發明之香菸用濾嘴係含有本發明之香料粒子。
以下,參照第3圖及第4圖說明具有本發明之濾嘴之香菸。在第3圖及第4圖中,相同要素係由相同參照符號表示。
第3圖係有關本發明之1態樣之具備濾嘴之香菸(附濾嘴之香菸)30之示意剖面圖。附濾嘴之香菸30係具備將菸絲等香菸填料321以香菸捲紙322包捲成之香菸部32。香菸部32與一般香菸相同。
在香菸部32之一端附設有濾嘴部34。濾嘴部34係包括直接連接於香菸部32之一端所設置之木炭濾嘴區段341、與相對於主流煙之流動方向於木炭濾嘴區段之下游側
端所設置之含有香料粒子之濾嘴區段342。
木炭濾嘴區段341係由將木炭粒子341b分散之,例如,醋酸纖維素纖維341a,以濾嘴捲紙341c包捲而成者,且為與一般香菸同樣者。
含有香料粒子之濾嘴區段342係將使本發明之香料粒子FB分散之,例如醋酸纖維素纖維342a,以濾嘴捲紙342b包捲而成者。
由濾嘴區段341及342組成之濾嘴部34係藉由前端紙36安裝於香菸部32上。
第4圖係本發明之其他態樣之具備有濾嘴之香菸(附濾嘴之香菸)40之示意剖面圖。在此附濾嘴之香菸40中,藉由前端紙36安裝於香菸部32上之濾嘴部42係包括:直接安裝於香菸部32之一端上之木炭濾嘴區段341、與此木炭濾嘴區段341隔開所設置之無紋飾(plain)濾嘴區段422,且其全體皆由濾嘴捲紙46所包捲。無紋飾濾嘴區段422係由例如醋酸纖維素纖維422a之整體組成。在木炭濾嘴區段341與無紋飾濾嘴區段422之間的空洞44中係填充本發明之香料粒子FB。
以下,藉由具體實施例說明本發明,但本發明並非受該等具體實施例所限定。
在預先調製之10重量%之聚三葡萄糖水分散液中添加咖啡油2重量%。將此混合液在乳化機中強力攪拌(乳化機轉速2500rpm),而製得香料分散液。另一方面,將平均
粒徑250 μm之碳酸鈣粒子100g放入流動造粒乾燥機中,以0.6m/秒之流速送入75℃之熱風,同時迅速地間歇性地噴灑(噴灑1分鐘後停止噴灑30分鐘反覆循環)上述香料分散液,將合計10g之香料分散液噴灑在碳酸鈣粒子表面並乾燥之。然後,迅速地將流動層內之溫度冷卻至室溫,而得到所需之香料粒子。
將平均粒徑250 μm之碳酸鈣粒子100g放入流動造粒乾燥機中,以1.0m/秒之流速送入30℃之熱風,同時連續性地噴灑含有已添加香草醛(vanillin)之香菸用香料1重量%與聚三葡萄糖9重量%之香料混合水溶液,將合計5g之混合水溶液噴灑在碳酸鈣粒子表面並乾燥之。然後,迅速地將熱風溫度降至室溫,且以0.4m/秒之流速冷卻,而得所需之香料粒子。
在預先調製之10重量%之聚三葡萄糖水分散液中添加咖啡油1重量%及卵磷脂0.5重量%。將此混合液在乳化機中強力攪拌(乳化機轉速7500rpm,15分鐘),而製得香料分散液。另一方面,將粒徑250 μm至1.4mm之粉碎咖啡豆粒子300g放入轉動流動造粒乾燥機(Freund產業(股)製SFC-MINI)中,且使底部旋轉格子板以約500rpm、使造粒防止用攪拌翼以約400rpm旋轉,並以流速0.6m/秒送入75℃之熱風,而形成粉碎咖啡豆粒子之流動層。然後將保溫40℃之上述香料分散液連續性地噴灑至流動層
中,將合計90g之香料分散液噴灑在咖啡豆粒子之表面並乾燥之。然後,迅速地將熱風溫度降至室溫,且以0.4m/秒之流速冷卻,而得所需之香料粒子。
分別使用在實施例1至3中所得之各香料粒子,製作如第3圖所示之附濾嘴香菸。在各情形中,添加於濾嘴區段342中之香料粒子之量最多每10mm濾嘴為100mg。此等香菸在存放時皆未產生香料之香氣。但是,在吸此菸時則能穩定地品嚐到香料之香味。
將平均粒徑約200 μm之碳酸鈣粒子90g、與粉碎薄荷腦結晶而得之薄荷腦微粉末10g、及甘油0.5g放入螺條混合機中,一面攪拌混合同時將全體加熱至40℃,且進一步混.合5分鐘。使所有薄荷腦熔化且附著、包覆於碳酸鈣粒子上,然後將15℃之冷風送入螺條混合機內冷卻。如此,得到表面已由薄荷腦結晶之膜所覆蓋之碳酸鈣粒子。將具有此等薄荷腦膜之碳酸鈣粒子放入流動造粒機中,一面以1.0m/秒之流速送入40℃之熱風,同時迅速地間歇性地噴灑聚三葡萄糖之5重量%水溶液,將合計15g之聚三葡萄糖水溶液噴灑在碳酸鈣粒子上。然後,冷卻至25℃,而得所需之薄荷腦香料粒子。
使用實施例5所得之薄荷腦香料粒子,製作如第3圖所示之附濾嘴之香菸。添加於濾嘴區段342之薄荷腦香料
粒子之量係,換算成薄荷腦量為每1支3mg。此香菸在一般存放條件下未產生薄荷腦之香氣。但是,在吸此菸時則能品嚐到薄荷腦之香味。
10‧‧‧香料粒子
12‧‧‧粒子狀載體(核)
14‧‧‧葡聚糖膜
20‧‧‧香料粒子
22‧‧‧粒子狀載體(核)
24‧‧‧固體香料膜
26‧‧‧葡聚糖膜
30‧‧‧附濾嘴之香菸
32‧‧‧香菸部
321‧‧‧香菸填料
322‧‧‧香菸捲紙
34‧‧‧濾嘴部
341‧‧‧木炭濾嘴區段
341a‧‧‧醋酸纖維素纖維
341b‧‧‧木炭粒子
341c‧‧‧濾嘴捲紙
342‧‧‧含有香料粒子濾嘴區段
342a‧‧‧醋酸纖維素纖維
342b‧‧‧濾嘴捲紙
36‧‧‧前端紙
40‧‧‧附濾嘴之香菸
42‧‧‧濾嘴部
422‧‧‧無紋飾濾嘴區段
422a‧‧‧醋酸纖維素纖維
44‧‧‧空洞
46‧‧‧濾嘴捲紙
第1圖係有關本發明之1態樣之香料粒子之放大示意剖面圖。
第2圖係有關本發明之其他態樣之香料粒子之放大示意剖面圖。
第3圖係有關本發明之1態樣之具備濾嘴之香菸之示意縱剖面圖。
第4圖係本發明之其他態樣之具備濾嘴之香菸之示意縱剖面圖。
10‧‧‧香料粒子
12‧‧‧粒子狀載體(核)
14‧‧‧葡聚糖膜
Claims (7)
- 一種香料粒子,係包含:粒子狀載體、由前述粒子狀載體所支撐之由聚三葡萄糖(pullulan)、麥芽糊精或羥丙纖維素所構成之葡聚糖膜、與香料;前述香料係以藉由前述葡聚糖膜抑制其香氣釋出,而藉由前述葡聚糖膜與香菸主流煙接觸使該膜至少一部分溶解,因而釋出其香氣之方式載持於香料粒子,而為(i)前述葡聚糖膜含有相當於葡聚糖重量20%以下之前述香料,且係直接覆蓋於前述粒子狀載體之表面,或(ii)前述香料係固體香料,且直接覆蓋在粒子狀載體表面而形成膜,前述葡聚糖膜係覆蓋在前述固體香料膜上,而前述固體香料膜係使用相當於香料粒子總重量之1至20%的固體香料所形成之香料粒子。
- 如申請專利範圍第1項之香料粒子,其中,該粒子狀載體係選自由碳酸鈣粒子、活性碳粒子、糖結晶粒子及咖啡豆粒子之組群者。
- 如申請專利範圍第1項之香料粒子,其中,該葡聚糖膜係由聚三葡萄糖所構成者。
- 如申請專利範圍第1項之香料粒子,其中,前述香料係選自薰衣草、肉桂、小豆蔻、芹菜、丁香、卡藜皮、肉豆蔻、白檀、佛手柑、天竺葵、蜂蜜精華、玫瑰油、香草、檸檬、柑橘、薄荷、桂皮、香旱芹菜、白蘭地、茉莉、黃金菊、薄荷腦、桂皮、香水樹、鼠尾草、綠薄荷、小茴香、青椒、薑、大茴香、胡荽及咖啡之精油者。
- 如申請專利範圍第1項之香料粒子,其中,前述葡聚糖膜係使用相當於香料粒子總重量之0.25%至5%之量的葡聚糖所形成者。
- 如申請專利範圍第1項之香料粒子,其中,前述固體香料係包含薄荷腦者。
- 一種香菸用濾嘴,係含有申請專利範圍第1項之香料粒子者。
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Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5138765B2 (ja) * | 2008-03-18 | 2013-02-06 | 日本たばこ産業株式会社 | シガレット主流煙成分吸着剤およびシガレット用フィルタ |
WO2009157240A1 (ja) * | 2008-06-25 | 2009-12-30 | 日本たばこ産業株式会社 | 喫煙物品 |
TW201032739A (en) * | 2009-01-08 | 2010-09-16 | Japan Tobacco Inc | Filter for cigarette |
GB2469842A (en) * | 2009-04-29 | 2010-11-03 | British American Tobacco Co | Aerosol generating material for a smoking article |
GB0910373D0 (en) * | 2009-06-16 | 2009-07-29 | Filtrona Int Ltd | Tabacco smoke filter |
KR101720739B1 (ko) * | 2009-11-30 | 2017-04-11 | (주)아모레퍼시픽 | 항산화 효과를 갖는 천연 향료 조성물 |
JP2011205914A (ja) * | 2010-03-29 | 2011-10-20 | British American Tobacco (Investments) Ltd | 喫煙品 |
US20110271968A1 (en) * | 2010-05-07 | 2011-11-10 | Carolyn Rierson Carpenter | Filtered Cigarette With Modifiable Sensory Characteristics |
EP2401929A1 (en) * | 2010-06-30 | 2012-01-04 | Philip Morris Products S.A. | Filter for a smoking article |
ES2662327T3 (es) * | 2010-10-18 | 2018-04-06 | Japan Tobacco, Inc. | Método de producción de gránulos que liberan sabor, gránulos que liberan sabor, y un filtro de cigarrillo que contiene gránulos que liberan sabor |
EP2462822A1 (en) * | 2010-12-13 | 2012-06-13 | Philip Morris Products S.A. | Smoking article including flavour granules |
CN102068038A (zh) * | 2010-12-31 | 2011-05-25 | 贵州中烟工业有限责任公司 | 一种卷烟热敏性保润中线滤棒的制备方法 |
RU2448589C1 (ru) * | 2011-01-21 | 2012-04-27 | Олег Иванович Квасенков | Способ получения некурительного изделия из махорки |
IT1404015B1 (it) * | 2011-02-04 | 2013-11-08 | Hsd Holding Smart Device S R L | Uso di un polimero di destrano reticolato come filtro contro l'inalazione di sostanze nocive per la salute |
GB201110369D0 (en) | 2011-06-17 | 2011-08-03 | Filtrona Filter Prod Dev Co | Tobacco smoke filter with activated carbon |
GB201110863D0 (en) | 2011-06-27 | 2011-08-10 | British American Tobacco Co | Smoking article filter and insertable filter unit thereof |
CN107034015B (zh) * | 2011-07-15 | 2021-04-06 | 日本烟草产业株式会社 | 香料担载低吸附性粒子的制造方法 |
KR20140038549A (ko) * | 2011-07-15 | 2014-03-28 | 니뽄 다바코 산교 가부시키가이샤 | 향료 담지 흡착제 입자, 궐련용 필터, 필터 부착 궐련 및 향료 담지 흡착제 입자의 제조방법 |
EP2554060A1 (en) * | 2011-08-01 | 2013-02-06 | JT International S.A. | Filter element incorporating a breakable capsule, method of manufacturing a cigarette having a filter element incorporating a breakable capsule and apparatus for manufacturing the cigarette having a filter element incorporating a breakable capsule |
CN102432921B (zh) * | 2011-09-16 | 2013-04-17 | 中国烟草总公司郑州烟草研究院 | 普鲁兰多糖添加剂及其在卷烟中的应用 |
UA112328C2 (uk) * | 2011-11-07 | 2016-08-25 | Філіп Морріс Продактс С.А. | Ментолвмісний курильний виріб |
CN102533445B (zh) * | 2012-02-05 | 2013-09-18 | 云南正邦生物技术有限公司 | 一种卷烟主动释放型补香颗粒的制备方法 |
KR102183809B1 (ko) * | 2012-08-02 | 2020-11-30 | 필립모리스 프로덕츠 에스.에이. | 멘톨 필터를 구비한 흡연 물품 |
CN102823945A (zh) * | 2012-09-17 | 2012-12-19 | 川渝中烟工业有限责任公司 | 一种香精粒子添加剂及其制备方法和应用 |
CN102987563A (zh) * | 2012-11-28 | 2013-03-27 | 红塔烟草(集团)有限责任公司 | 一种含兰花香味的卷烟纸质滤材 |
CN103054184A (zh) * | 2012-11-28 | 2013-04-24 | 红塔烟草(集团)有限责任公司 | 一种含薰衣草香味的卷烟纸质滤材 |
GB2516104A (en) * | 2013-07-12 | 2015-01-14 | British American Tobacco Co | Material for inclusion in a smoking article |
US10849358B2 (en) * | 2014-10-29 | 2020-12-01 | Altria Client Services Llc | E-vaping cartridge |
EA202191171A3 (ru) | 2014-10-29 | 2021-12-31 | Олтриа Клайент Сервисиз Ллк | Включающий гелевую рецептуру картридж электронного устройства для вейпинга |
CN104856223B (zh) * | 2015-04-29 | 2019-05-10 | 湖北中烟工业有限责任公司 | 一种烟用固体加香珠及其制备方法 |
CN104997158B (zh) * | 2015-05-29 | 2017-01-18 | 湖北中烟工业有限责任公司 | 辛香型烟用香料提取物的制备方法及其应用 |
CN105029700A (zh) * | 2015-06-17 | 2015-11-11 | 云南中烟工业有限责任公司 | 一种植物组合三醋酸甘油酯提取物及其在卷烟中的应用 |
CN104939307B (zh) * | 2015-07-17 | 2019-08-09 | 云南中烟工业有限责任公司 | 一种烟用极性香料载核及应用 |
CN105001988B (zh) * | 2015-07-17 | 2018-07-24 | 云南中烟工业有限责任公司 | 一种三层夹心结构香料缓释滤嘴添加剂的制备装置及其应用方法 |
CN105105327B (zh) * | 2015-07-21 | 2019-07-23 | 中国烟草总公司广东省公司 | 一种含有全组分烟草提取物的香薰烟及其制备方法 |
CN105231480B (zh) * | 2015-11-10 | 2017-07-04 | 江苏中烟工业有限责任公司 | 一种碳酸钙作为加香载体在再造烟叶涂布液中应用的方法 |
US20170265517A1 (en) * | 2016-03-15 | 2017-09-21 | Rai Strategic Holdings, Inc. | Multi-Layered Micro-Beads for Electronic Cigarettes |
ITUA20162010A1 (it) * | 2016-03-24 | 2017-09-24 | Gd Spa | Articolo da fumo e metodo per la sua realizzazione. |
GB201608943D0 (en) * | 2016-05-20 | 2016-07-06 | British American Tobacco Co | Capsule for tobacco industry product |
WO2018033977A1 (ja) * | 2016-08-17 | 2018-02-22 | 日本たばこ産業株式会社 | フィルタ及びたばこ製品 |
CN106590931A (zh) * | 2016-12-14 | 2017-04-26 | 江西中烟工业有限责任公司 | 一种烟用蛋白质‑多糖复合乳液载体体系的制备方法及在卷烟中的应用 |
CN107022414A (zh) * | 2017-04-27 | 2017-08-08 | 河南中烟工业有限责任公司 | 一种卷烟爆珠用香草味香精及其在卷烟中的应用 |
US10492522B2 (en) | 2017-05-03 | 2019-12-03 | R.J. Reynolds Tobacco Company | Flavored menthol-containing objects for application to smoking article components |
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CN108523217A (zh) * | 2018-06-08 | 2018-09-14 | 滁州卷烟材料厂 | 一种具有降焦增香性能的卷烟滤棒 |
CN110574961A (zh) * | 2018-06-08 | 2019-12-17 | 湖南中烟工业有限责任公司 | 一种烟用柠檬香精的制备方法及烟用爆珠和爆珠烟 |
CN108851214B (zh) * | 2018-08-06 | 2020-06-30 | 江西中烟工业有限责任公司 | 一种含有单固态香珠颗粒的细支烟嘴棒及其制备方法 |
CN110629590A (zh) * | 2019-09-20 | 2019-12-31 | 河南中烟工业有限责任公司 | 一种雪茄风味香精、雪茄风味光油及卷烟用接装纸 |
CN110801049B (zh) * | 2019-11-07 | 2022-02-01 | 云南中烟工业有限责任公司 | 一种烟用滤嘴香气缓释颗粒及其制备方法 |
CN110934333A (zh) * | 2019-12-27 | 2020-03-31 | 山东中烟工业有限责任公司 | 一种基于纳米纤维结构的香烟滤嘴及香烟 |
WO2021177023A1 (ja) * | 2020-03-04 | 2021-09-10 | 日本たばこ産業株式会社 | たばこ製品の香料担持構成部材、たばこ製品およびこれらの製造方法 |
RU2767511C2 (ru) * | 2020-07-13 | 2022-03-17 | Бритиш Америкэн Тобэкко (Инвестментс) Лимитед | Вставной фильтрующий элемент для нагреваемого без горения продукта |
KR102571393B1 (ko) * | 2020-08-28 | 2023-08-25 | 주식회사 케이티앤지 | 향 지속성이 개선된 필터 및 이를 포함하는 흡연 물품 |
CN112914144B (zh) * | 2020-12-31 | 2022-10-21 | 中国农业科学院烟草研究所 | 一种加热卷烟烟草基段及其制作方法 |
CN114775333B (zh) * | 2022-04-13 | 2023-09-19 | 江苏卫星新材料股份有限公司 | 一种甜味剂接装纸及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5070891A (en) * | 1989-07-12 | 1991-12-10 | International Flavors & Fragrances, Inc. | Method for imparting flavors and aromas, flavor-imparting articles, and methods for preparation and use thereof |
US20060272662A1 (en) * | 2005-02-04 | 2006-12-07 | Philip Morris Usa Inc. | Cigarette and filter with cellulosic flavor addition |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3297041A (en) * | 1965-03-15 | 1967-01-10 | American Filtrona Corp | Tobacco smoke filter or the like |
JPS5932108B2 (ja) * | 1977-04-20 | 1984-08-06 | 日本たばこ産業株式会社 | 香料を芯物質としたマイクロカプセルおよびこれを含有するたばこ製品 |
US5060676A (en) * | 1982-12-16 | 1991-10-29 | Philip Morris Incorporated | Process for making a carbon heat source and smoking article including the heat source and a flavor generator |
JP2709077B2 (ja) | 1987-05-29 | 1998-02-04 | 日本たばこ産業株式会社 | 煙草用フィルター |
US5258185A (en) * | 1989-08-23 | 1993-11-02 | Bauer Kurt H | Highly active, rapidly absorbable formulations of glibenclamide, processes for the production thereof and their use |
US5144964A (en) * | 1991-03-14 | 1992-09-08 | Philip Morris Incorporated | Smoking compositions containing a flavorant-release additive |
TR28670A (tr) * | 1993-06-02 | 1996-12-17 | Procter & Gamble | Zeolitleri iceren parfüm birakma sistemi. |
US5396909A (en) * | 1993-12-16 | 1995-03-14 | R. J. Reynolds Tobacco Company | Smoking article filter |
US5845649A (en) * | 1994-01-26 | 1998-12-08 | Japan Tobacco Inc. | Flavor-tasting article |
CN1044436C (zh) * | 1994-01-26 | 1999-08-04 | 日本烟业产业株式会社 | 非燃烧型香味制品 |
JPH0928366A (ja) * | 1995-07-24 | 1997-02-04 | Japan Tobacco Inc | シガレット |
MY135471A (en) * | 2002-01-09 | 2008-04-30 | Philip Morris Prod | Cigarette filter with beaded carbon |
US20050100640A1 (en) * | 2002-02-11 | 2005-05-12 | Pearce Tony M. | Microcapsule edibles |
CN100363085C (zh) * | 2002-06-12 | 2008-01-23 | 创普太克公司 | 包封的活性颗粒及其制备和使用方法 |
US20050172976A1 (en) * | 2002-10-31 | 2005-08-11 | Newman Deborah J. | Electrically heated cigarette including controlled-release flavoring |
US7381277B2 (en) * | 2004-07-29 | 2008-06-03 | R.U. Reynolds Tobacco Company | Flavoring a cigarette by using a flavored filter plug wrap |
US20060144410A1 (en) * | 2004-12-30 | 2006-07-06 | Philip Morris Usa Inc. | Surface-modified activated carbon in smoking articles |
EP1871756A1 (en) * | 2005-04-19 | 2008-01-02 | Flexitral, Inc. | Benzo (b) cycloprop (d) pyran-2-(1h)-one derivatives |
CA2612665C (en) * | 2005-06-21 | 2013-01-15 | V. Mane Fils | Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule |
US20070231387A1 (en) * | 2006-04-04 | 2007-10-04 | Luigi Levi | Film-coated solid dosage forms |
US8356606B2 (en) * | 2007-06-01 | 2013-01-22 | Philip Morris Usa Inc. | Production of micronized encapsulated tobacco particles for tobacco flavor delivery from an oral pouch |
JP5138765B2 (ja) * | 2008-03-18 | 2013-02-06 | 日本たばこ産業株式会社 | シガレット主流煙成分吸着剤およびシガレット用フィルタ |
-
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5070891A (en) * | 1989-07-12 | 1991-12-10 | International Flavors & Fragrances, Inc. | Method for imparting flavors and aromas, flavor-imparting articles, and methods for preparation and use thereof |
US20060272662A1 (en) * | 2005-02-04 | 2006-12-07 | Philip Morris Usa Inc. | Cigarette and filter with cellulosic flavor addition |
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WO2008072627A1 (ja) | 2008-06-19 |
EP2093276B1 (en) | 2012-11-21 |
KR20090089357A (ko) | 2009-08-21 |
EP2093276A4 (en) | 2010-02-17 |
RU2405810C1 (ru) | 2010-12-10 |
JPWO2008072627A1 (ja) | 2010-04-02 |
JP4876296B2 (ja) | 2012-02-15 |
CA2671004A1 (en) | 2008-06-19 |
ES2396593T3 (es) | 2013-02-22 |
KR101148254B1 (ko) | 2012-05-25 |
CN101558143B (zh) | 2012-09-26 |
CN101558143A (zh) | 2009-10-14 |
EP2093276A1 (en) | 2009-08-26 |
US20090235941A1 (en) | 2009-09-24 |
HK1133034A1 (en) | 2010-03-12 |
CA2671004C (en) | 2013-03-12 |
TW200848505A (en) | 2008-12-16 |
MY157908A (en) | 2016-08-15 |
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