TWI369493B - Time-temperature indicator based on valence isomerizations - Google Patents

Time-temperature indicator based on valence isomerizations

Info

Publication number
TWI369493B
TWI369493B TW094103041A TW94103041A TWI369493B TW I369493 B TWI369493 B TW I369493B TW 094103041 A TW094103041 A TW 094103041A TW 94103041 A TW94103041 A TW 94103041A TW I369493 B TWI369493 B TW I369493B
Authority
TW
Taiwan
Prior art keywords
isomerizations
valence
time
temperature indicator
indicator based
Prior art date
Application number
TW094103041A
Other languages
English (en)
Other versions
TW200530581A (en
Inventor
Yoav Levy
Dietrich Haarer
Original Assignee
Freshpoint Holdings Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Freshpoint Holdings Sa filed Critical Freshpoint Holdings Sa
Publication of TW200530581A publication Critical patent/TW200530581A/zh
Application granted granted Critical
Publication of TWI369493B publication Critical patent/TWI369493B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/337—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/12—Radicals substituted by halogen atoms or nitro or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/24—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
    • C08K5/357—Six-membered rings
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
    • G01N31/229—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating time/temperature history

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Immunology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biophysics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Measuring Temperature Or Quantity Of Heat (AREA)
TW094103041A 2004-02-02 2005-02-01 Time-temperature indicator based on valence isomerizations TWI369493B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54055804P 2004-02-02 2004-02-02
US56423204P 2004-04-22 2004-04-22

Publications (2)

Publication Number Publication Date
TW200530581A TW200530581A (en) 2005-09-16
TWI369493B true TWI369493B (en) 2012-08-01

Family

ID=34841104

Family Applications (1)

Application Number Title Priority Date Filing Date
TW094103041A TWI369493B (en) 2004-02-02 2005-02-01 Time-temperature indicator based on valence isomerizations

Country Status (9)

Country Link
US (1) US8277749B2 (zh)
EP (1) EP1711809A2 (zh)
JP (1) JP4685033B2 (zh)
KR (1) KR101173524B1 (zh)
CN (1) CN1914509B (zh)
AU (1) AU2005210754B2 (zh)
MX (1) MXPA06008688A (zh)
TW (1) TWI369493B (zh)
WO (1) WO2005075978A2 (zh)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9835498B2 (en) 2003-11-20 2017-12-05 Freshpoint Quality Assurance Ltd. Method and system for determining the condition of a time-temperature indicator
ATE404233T1 (de) * 2004-10-21 2008-08-15 Novo Nordisk As Injektionsvorrichtung mit mitteln zur meldung der zeit seit der letzten injektion
US8267576B2 (en) 2004-11-08 2012-09-18 Freshpoint Holdings Sa Time-temperature indicating device
JP2007031649A (ja) * 2005-07-29 2007-02-08 Japan Atomic Energy Agency 量子ビーム照射と光照射又は加熱により可逆的に着色／脱色する有機分子を含んだ樹脂組成物とナノパターン形成方法
DE102005051471A1 (de) * 2005-10-21 2007-05-16 Bizerba Gmbh & Co Kg Vorrichtung zur Bereitstellung von aktivierten Indikatoren zur Warenkennzeichnung, Warenkennzeichnung und Verfahren zur Bereitstellung von Indikatoren zur Warenkennzeichnung
DE102005051470A1 (de) 2005-10-21 2007-04-26 Bizerba Gmbh & Co. Kg Aktivierungsvorrichtung für aktivierbare Indikatoren zur Warenkennzeichnung, Vorrichtung zur Bereitstellung von aktivierten Indikatoren und Verfahren zur Aktivierung von Indikatoren
DE102006009733B4 (de) * 2006-03-02 2011-02-24 Odu-Steckverbindungssysteme Gmbh & Co. Kg Teil einer elektronischen Kuppelvorrichtung
CN101529245B (zh) * 2006-10-26 2011-12-28 西巴控股有限公司 用于光致变色体系的光吸收层
WO2008083925A1 (en) 2007-01-11 2008-07-17 Freshpoint Holdings Sa Photostabilized time temperature indicator
EP2102306B1 (en) 2007-01-11 2010-11-24 Basf Se Tti indicator with balanced photochemical processes
BRPI0720907A2 (pt) * 2007-01-11 2014-04-01 Freshpoint Holdings Sa Indicador de tempo-temperatura
US20110059545A1 (en) * 2007-01-22 2011-03-10 Freshpoint Holdings Sa Time-temperature indicator based on oligomeric spiroaromatics
EP2115454A1 (en) * 2007-02-27 2009-11-11 Basf Se Color changing indicator
US7861550B2 (en) * 2007-03-26 2011-01-04 Natural Choice Corporation Water dispenser
DE102007056915A1 (de) * 2007-11-27 2009-05-28 Bizerba Gmbh & Co. Kg Drucker und Verfahren zur Warenkennzeichnung
WO2009104192A2 (en) * 2008-02-22 2009-08-27 Skyrad Ltd Disposable measuring device for uv radiation
EP2269056A1 (en) * 2008-04-16 2011-01-05 Basf Se Optimized time temperature indicator
CN102036994A (zh) * 2008-05-21 2011-04-27 巴斯夫欧洲公司 包含含n-乙酰氨基侧链或n-乙酰酯侧链的假吲哚基螺吡喃的时间温度指示剂
WO2009156285A1 (en) 2008-06-23 2009-12-30 Freshpoint Holdings Sa Time temperature indicator
US20100043694A1 (en) * 2008-08-20 2010-02-25 Patel Gordhanbhai N Tamper evident indicating devices
US8501053B2 (en) * 2008-10-02 2013-08-06 Basf Se Multi color, photoactive, color changing compositions and UV dosimeters
KR20110106434A (ko) 2009-01-08 2011-09-28 바스프 에스이 광변색 잉크의 제조
RU2011132941A (ru) * 2009-01-08 2013-02-20 Басф Се Временно-температурный индикатор, содержащий спиро-пираны на основе индоленина
AU2010212957A1 (en) * 2009-02-12 2011-09-01 Freshpoint Holdings Sa Time-temperature indicator based on thioalkyl and thioaryl substituted spiroaromatics
WO2011045361A1 (en) 2009-10-14 2011-04-21 Novo Nordisk A/S Time delay indicator
ES2376559B1 (es) 2011-04-11 2013-01-24 Universidad Pública de Navarra Dispositivo de monitorización de condiciones de tiempo y temperatura.
NO20110590A1 (no) * 2011-04-15 2012-04-02 Keep It Tech As Tid-temperatur indikatorsystem, fremgangsmåte for dets fremstilling samt kombinasjon som omfatter nevnte tid-temperatur indikatorsystem.
NO331993B1 (no) 2011-04-15 2012-05-21 Keep It Technologies As Tid-temperatur indikatorsystem
US9618398B2 (en) 2011-06-29 2017-04-11 Suzhou Qualimark Technology Co., Ltd. Time-temperature indicator and monitoring method for monitoring quality state of thermally sensitive article
GB2534113B (en) 2014-09-12 2020-11-18 Domino Uk Ltd Ink composition
DE102014115910A1 (de) 2014-10-31 2016-05-04 Schreiner Group Gmbh & Co. Kg Etikett zum Beschriften mit einer zunächst verborgenen Innenbeschriftung
CN105602346B (zh) * 2016-03-12 2018-10-23 北京化工大学 一种紫外荧光油墨及其制备方法
CN109410738A (zh) * 2017-08-16 2019-03-01 中国科学院苏州纳米技术与纳米仿生研究所 一种热敏感标签、其制备方法和使用方法
CN107828283A (zh) * 2017-12-21 2018-03-23 宝艺新材料股份有限公司 纸板印刷用水性防伪油墨及其制备方法
GB2586101B (en) * 2018-03-14 2023-03-08 Temptime Corp Descending and ascending temperature indicators utilizing deep eutectics
MX2020012015A (es) 2018-05-11 2021-03-25 Temptime Corp Indicador de temperatura activable con retardo de tiempo.
CN112197883B (zh) * 2020-10-09 2023-06-02 南京工业大学 一种流体表面温度场分布显示与检测方法
CN115326229B (zh) * 2022-07-26 2023-08-01 东八(北京)材料科技有限公司 一种面向冷链的应用于tti的温度响应显示剂

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3038812A (en) 1959-06-25 1962-06-12 Ncr Co Process for detecting interim thawing of edibles
US3397059A (en) 1964-07-01 1968-08-13 American Cyanamid Co Photochromic polymethylmethacrylate element on contact with polyester resinous material
JPS6113118A (ja) * 1984-06-28 1986-01-21 Matsumoto Kosan Kk 温度指示シ−ト
JP2607365B2 (ja) * 1986-05-29 1997-05-07 フマキラー 株式会社 薬効指示性組成物
US5376511A (en) * 1990-04-18 1994-12-27 Masahiro Irie Optical recording medium
JPH0820768A (ja) * 1994-07-07 1996-01-23 Tokuyama Corp フォトクロミック組成物
JPH08291176A (ja) * 1995-04-20 1996-11-05 Nissho Iwai Bentonaito Kk イオン性スピロピラン化合物およびこれを粘土と複合化したホトクロミック材料
JPH09113500A (ja) * 1995-10-23 1997-05-02 Toyo Ink Mfg Co Ltd 時間表示材料
US5710420A (en) * 1995-12-05 1998-01-20 Xerox Corporation Method for embedding and recovering machine-readable information
US6084702A (en) * 1998-10-15 2000-07-04 Pleotint, L.L.C. Thermochromic devices
US6629057B2 (en) * 1999-11-05 2003-09-30 Beckman Coulter, Inc. Comprehensive verification systems and methods for analyzer-read clinical assays
EP1281080A4 (en) * 2000-05-08 2006-03-22 Jp Lab Inc COLOR-CHANGING VAPOR STERILIZATION INDICATOR
JP4231210B2 (ja) * 2001-03-02 2009-02-25 株式会社リコー 温度履歴表示材料
WO2002102923A1 (fr) * 2001-06-15 2002-12-27 Mitsubishi Chem Corp Materiau photochrome et chromodosimetre utilisant ledit materiau

Also Published As

Publication number Publication date
AU2005210754A1 (en) 2005-08-18
AU2005210754B2 (en) 2010-12-02
JP2007531873A (ja) 2007-11-08
KR20060124740A (ko) 2006-12-05
CN1914509B (zh) 2012-11-28
KR101173524B1 (ko) 2012-08-14
WO2005075978A3 (en) 2005-10-06
WO2005075978A2 (en) 2005-08-18
US8277749B2 (en) 2012-10-02
MXPA06008688A (es) 2007-02-16
US20070172951A1 (en) 2007-07-26
JP4685033B2 (ja) 2011-05-18
EP1711809A2 (en) 2006-10-18
CN1914509A (zh) 2007-02-14
TW200530581A (en) 2005-09-16

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MM4A Annulment or lapse of patent due to non-payment of fees