TWI364257B - Seed dressing for controlling phytopathogenic fungi - Google Patents
Seed dressing for controlling phytopathogenic fungi Download PDFInfo
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- TWI364257B TWI364257B TW094120358A TW94120358A TWI364257B TW I364257 B TWI364257 B TW I364257B TW 094120358 A TW094120358 A TW 094120358A TW 94120358 A TW94120358 A TW 94120358A TW I364257 B TWI364257 B TW I364257B
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
1364257 九、發明說明: 【發明所屬之技術領域】 本發明係關於供處理種子用作殺真菌的活性羧醯胺 類’相關於包含這些羧醯胺類之種子敷料,相關於用於控制 - 植物致病性真菌之方法,係以具殺真菌活性之羧醯胺類處理 種子,以及關於己經過殺真菌活性羧醯胺類處理過的種子。 • 【先前技術】 已知有某些的羧醯胺類具有殺真菌的性質,於是’例 10 如’ N-P-O,3-二曱基丁基)噻吩-3-基]-1-甲基-3-(三氟甲 基)-1Η-吡唑-4-羧醯胺(EP-A 0 737 682),N-[2-(l,3-二曱基 丁基)苯基]-5-氟-1,3-二甲基-間比峻-4-竣醯胺(WO 03/010149)與N-[2-(l,3-二曱基丁基)苯基]_1_曱基-4-三氟 曱基-1H-吡咯羧醯胺(WO 02/38542)各為已知的適於作為 15 供控制植物致病性真菌之葉面喷灑劑,但這些化合物可供處 φ 理種子以保護種子免於植物致病性真菌之攻擊的用途尚未 . 被揭露,明確地說,使用這類化合物作為種子敷料可供保護 免於受到下述種類的致病菌之攻擊:棕褐色斑點菌 (Pyrenophora),葉枯病菌(Rhizoctonia),腥黑粉菌(Tilletia) 2〇 以及黑穗菌(Ustilago)。 【發明内容】 己發現,具一般化學式(I)之羧醯胺類 (i) 1364257
5 其中 Μ 代表下面的Ml至Μ4環之一
3 Ml M2 M3 M4 10 其中以標記之鍵係附接至醯胺,而以“#”標記之鍵 是附接至院基鏈, R 代表氫,氟,氯或曱基, R1代表氫,鹵素,具有1至7個氟、氯及/或溴原子之Ci-q-烧基或Ci_C3-_基烧基5 A 代表下面A1至A8的基之一:
-6- 20 1364257 )
5 R 代表C1-C3-烧基,
R3代表氫,鹵素’具有1至7個氟,氣及/或溴原子之c_c_ 燒基或crc3-鹵基炫基, 13 r4代表氫’鹵素或q-CV烷基, 10 R5代表鹵素’具有1至7個氟,氯及/或溴原子之 烧基或crc3-鹵基炫基, 3 R6代表氫,鹵素,Cl-C3-烧基,胺基,單_或二(Ci_C3_院 基)-胺基, 。 R7代表氫,鹵素,具有1至7個氟,氯及/或淳; 烧基或CKV齒基炫基, 1_C3'
g R 代表鹵素’具有1至7個氟,氯及/或溴原子之Ci_C3_ 烧基或crc3-_*院基, R 代表齒素’具有1至7個乱’氣及/或漠原子之 院基或(^1-〇3**_基烧基, R 代表氯’齒素,具有1至7個氣’氣及/或、;臭原子之c ^ _Cj_ 烧基或Ci-C3·鹵基院基, R11代表氫,鹵素,具有1至7個氟,氯及/或溴原子之Ci_c3_ 烧基或C1-C3-鹵基烧基, 這類化合物極適於供處理(塗敷)種子以對抗植物致病 20 真菌之攻擊。 令人驚訝地,利用本發明的活性化合物作為種子敷料, 悔某些植物致病真g,㈣面賴處理方4能有效地受 式(I)代表可被用於處理種子的羧醯胺類之一 佳的式(I)化合物,其中各基的定義如下。 Μ ϋ复a代表Μ-卜 Μ也复复延l代表Μ-2。 R 產复4代表氫。 R,如果Μ代表M-1,也渔_宜_也代表氟,其中氟特別適宜 座係位於酿替苯胺基之4_,5•或6_位置,極特別適宦 鱼係位於4-或6-位置,尤其是4-位置。 R,如果Μ代表,也代表氣,其中 虚係位於醯絲胺基之4-,5·或6-位置,極t 渔係位於4_或6_位置,尤其是4位置。 R,如果]Vi代表也適宜地代表甲基,其中曱基特別 盘係位於醯替苯胺基之3_位置[參考上述式⑴]。 R,如果Μ代表Μ·2,Μ 3或μ 4,也適宜地代丧曱基, 其中甲基楚激係位於5-位置(Μ-2,Μ-3),或位 於3-位置(]VM)。
Rl 代表氳,氟,氯,甲基,乙基,正-丙基,異丙 基二氟甲基,二氟甲基,三氟甲基,單氯甲基,二氯 甲基或二氣甲基。
Ri 代表氫,氟’氯’甲基’乙基或三氟甲基。 1364257 R1 極特別適宜地代表氫或曱基。 R1尤其是代表氫。 R1也尤其是代表甲基。 A 適宜地代表A1,A2,A3,A4或A5之基。 5 A 特別適宜地代表Al,A2,A3或A5之基。 A 極特別適宜地代表A1基。 A 也極特別適宜地代表A2基。
10 A 也極特別適宜地代表A3基。 A 也極特別適宜地代表A5基。 R2 適宜地代表甲基,乙基,正-丙基或異丙基。 R2特別適宜地代表曱基或異丙基。 R2 極特別適宜地代表甲基。 R3適宜地代表蛾,曱基,二氟曱基或三氟曱基。 R3特別適宜地代表甲基,二氟甲基或三氟甲基。 15 R3 極特別適宜地代表曱基。 R4 適宜地代表氫,氟,氣或甲基。 R4 特別適宜地代表氫或氣。 R4 極特別適宜地代表氟。 R5適宜地代表氣,溴,碘,曱基,二氟曱基或三氟曱基。 R5特別適宜地代表埃,二氟曱基或三氟曱基。 R5 極特別適宜地代表碘或三氟甲基。 R6 適宜地代表氫,氯,甲基或胺基。 R6特別適宜地代表代表甲基或胺基。 R6 極特別適宜地代表曱基。 20 R7適宜地代表氫,氯,曱基,二氟曱基或三氟曱基。 R7特別適宜地代表氯,甲基,二氟甲某成三氤甲某。 R7極特別適宜地代表代表甲基,二氟曱基或三氟曱基。 R8 適宜地代表氣,溴,碘,曱基或三氟曱基。 R8 特別適宜地代表漠,碘,曱基或三氟曱基。 R8極特別適宜地代表代表溴,碘或甲某。 R9適宜地代表氯,溴,碘,甲基,異丙基或三氟曱基。 R9 特別適宜地代表甲基,異丙基或三氟曱基。 R9 極特別適宜地代表甲基或三氟甲基。 R10適宜地代表說,氯,甲基或三氟曱基。 R10特別適宜地代表氮或三氟甲基。 R10極特別適宜地代表氣〇 R11適宜地代表氣,碘,甲基,二氟曱基或三氟曱基。 R11特別適宜地代表甲基,二氤甲某或三氣甲某。 R11極特別適宜地代表三氤甲某。 極特別適宜地適合供處理種子者為式(I-a)之羧醯胺類
其中R,R1,R2,R3與R4等的定義如前且R1特別是代表氫 或甲基。 極特別適宜地適合供處理種子者也為式(I-b)之羧醯胺
其中i^R1與R5等的定義如前且R1特別是代表氫或曱基。 極特別適宜地適合供處理種子者也為式(I-c)之羧醯胺 類
其中J^R^R6與R7等的定義如前且R1特別是代表氫或曱 基。 極特別適宜地適合供處理種子者也為式(I-d)之羧醯胺 類
其中R^R1與R8等的定義如前且R1特別是代表氫或曱基。 極特別適宜地適合供處理種子者也為式(I-e)之羧醯胺 類 -11 -
其中R,R1與R11等的定義如前且R1特別是代表氫或甲基。 極特別適宜地適合供處理種子者也為式(I-f)之羧醯胺 類
其中R,R1,R2,R3與R4等的定義如前且R1特別是代表氫 或曱基。 極特別適宜地適合供處理種子者也為式(I-g)之羧醯胺 類
其中R,!^1與R5等的定義如前且R1特別是代表氫或甲基。 極特別適宜地適合供處理種子者也為式(I-h)之羧醯胺 類 -12- 1364257
(I-h) 5 其中R,R1,R6與R7等的定義如前且R1特別是代表氫或曱 基。 '極特別適宜地適合供處理種子者也為式(I-j)之羧醯胺 ▲ 類 10
其中R,R1與R8等的定義如前且R1特別是代表氫或甲基。 15 極特別適宜地適合供處理種子者也為式(I-k)之羧醯胺 類
其中I^R1與R11等的定義如前且R1特別是代表氫或 甲基。 式(I)化合物包含特別是下述的適於供種子處理之羧醯 -13- 1364257 (i-i)具下式之Λ42-(1,3-二曱基丁基)苯基]-i,3-二曱基 -l/ί-吡唑-4-羧醯胺 5
(得知自:JP-A 10-251240)
10 (1-2)具下式之#-[2-(1,3-二曱基丁基)苯基]-5-氣-1,3-二甲 基-1/f-吡唑-4-羧醯胺
(得知自:WO 03/010149) 15
(1-3)具下式之#-[2-(1,3-二曱基丁基)苯基]-5-氯-1,3-二甲 基_1丑_吡唑-4-羧醯胺
(得知自:JP-A 10-251240) (1-4)具下式之3-(二氟曱基)-N-[2-(l,3-二曱基丁基)苯基]-1-曱基-1H-吡唑-4-羧醯胺 -14- 20 1364257
(得知自:JP-A 10-310577) 5 (1-5)具下式之3-(三氟曱基)善[2-(l,3-二曱基丁基)笨基]- 5-氟-1-曱基比唾_4_鼓醯胺
(得知自:DE-A 103 03 589) 10 (1-6)具下式之3-(三氟曱基)-Α42-(1,3-二曱基丁基)苯基]-5-氣-1-曱基比唑·4_羧醯胺
(得知自:JP-A 10-251240) (1-7)具下式之1,3_二曱基·#[2-(1,3,3三甲基丁基)苯基]_ li/-吡唑I羧醯胺 H (得知自:JP-A 10-251240) -15- (1-8)具下式之5-氟-1,3-二甲基_沁[2-(1,3,3·三曱基丁基)笨 基]-I//-*1比嗅-4-叛酿胺
(得知自:WO 03/010149) (1-9)具下式之3-(二氟甲基)小甲基三甲基丁 基)苯基]-1//-吡唾_4-竣醯胺
(得知自:DE-A 103 52 082) σ,具下式之3·(三I甲基)小甲基,2 (1,33三甲基丁 基)苯基]-1好-吡唑-4-羧醯胺
(得知自:DE-A 103 52 082) 0-11)具下式之3-(三氟甲基)_5•盡 風]-甲基-;V-[2-(l,3,3-三甲 基丁基)苯基]-1仏β比唑-4-羧醯胺 • 16 -
(得知自:DE-A 103 03 589) (2)具下式之3-(三氟曱基)-5-氣+甲基各[2 (^3-三曱 基丁基)笨基]幾酿胺
(得知自:JP-A 10-251240) (LU)具下式之N-2-(l,3-二甲基丁基)苯基]_2_碘苯曱醢胺
(得知自:DE-A 102 29 595) (1-14)具下式之2-碘-AK1,3,3-三甲基丁基)苯基]苯曱醯胺
(得知自:DE-A 102 29 595) (1-15)具下式之# _[2_(1,3-二曱基丁基)苯基]-2-(三氟曱基) -17- 笨甲醯胺
(得知自:DE-A 102 29 595) (1-16)具下式之 笨曱酿胺 2·(三氟甲基)1[2-(1,3,3-三甲基丁基)苯基]
(得知自 DE-A 102 29 595) (H7)具下式之3-(二氟曱基二甲基丁基)苯 基]-1-曱基-1月外匕洛-4-幾醯胺
(得知自:WO 02/38542) (1-18)具下式之3<三氣甲基)士-[2_(1,3,3-三甲基丁基)苯 1申基吡咯-4_羧醯胺 基]—卜丁
1364257
參 (1 2〇)具下式之3-(三氟甲基)养[2-(1,3· 基]-1-甲基比略_4._缓醯胺
曱基丁基)苯 (得知自:W0 02/38542) (1_21)具下式之’ΙΧ1,3·二曱基丁基)-3-噻吩基]-1,3-二甲 基-1瓜吡唑_4_羧醯胺
(得知自:EP-A 0737 682) (1-22)具下式之3_(二氟曱基)善[2 (1,3-二曱基丁基)3_噻 吩基]-1-甲基比0坐_4-羧醯胺
(得知自:ΕΡ-Α 0737 682) -19- 20 1364257 (工23)具下式之3-(三氟曱基)_#_[2_(1,3-二甲基丁基)_3_噻 分基H-甲基比唑-4-羧醯胺 (得知自:EP-A 0737 682) (1-24)具下式之3_(三氟曱基)·〗_曱基·沁[2_(1,3 3三曱基丁 基)-3-噻吩基]-1H-吡唑-4-羧醯胺 (得知自:EP-A 0 737 682) 15
d-25)具下式之沁[2 (1,3_二甲基丁基)_3噻吩基]_2氣苯曱 醒胺 (得知自:EP-A 0737 682) (1_26)具下式之2-氯-沁[>(1,3,3-三曱基丁基)-3-噻吩基]苯 曱酿胺 20 1364257
(得知自:EP-A Ο 737 682) 5 (Ι·27)具下式之3-(二氟甲基)善[2-(1,3-二曱基丁基)-3-嗔 吩基]-1-甲基-1丑^比0各_4_缓醯胺
10
(得知自:W0 02/38542) (1-28)具下式之3-(三氟曱基)_沁(1,3,3_三甲基丁基)3_噻吩 基]-1-曱基-1丹-°比°各-4-敌醯胺 15
(1-29)具下式之3-(二氟甲基)-iV-[2-(l,3,3-二曱基丁基)-3-噻 吩基]-1-甲基-1好-吡咯-4-羧醯胺
(1-30)具下式之3-(三氟曱基)-W-[2-(l,3-二曱基丁基)-3-0塞 -21 - 20 1364257 吩基]-1-甲基-1//-吼嘻-4-敌醯胺
(得知自:W0 02/3 8542)
10 15
根據本發明之活性化合物具有極佳的殺真菌的性質, 且,於種子處理方面,特別適於供控制植物致病性真菌,例 如’子囊菌綱(Ascomycetes)與擔子菌綱(Basidi〇mycetes)A 菌;於種子處理上,根據本發明之活性化合物特別適於供控 制棕褐色斑點菌(Pyrenophora) ’葉枯病菌(Rhizoct〇nia),腥 黑粉菌(Tilletia)以及黑穗菌(Ustilago)之菌種。 一些被列於上述屬名下可造成真菌疾病之病原菌,順便 值得一提者如下,但不限於: 棕褐色斑點菌屬諸種(Pyrenophora species),例如, allosuri ’ P. alternarina,P. avenae,P. bartramiae,P. bondarze-wii,P. bromi,P. bryophila,P. buddleiae,P, bupleuri,P. calvertii,P, calvescens var. moravica,P. carthami ,P. centranthi ,P. cerastii ,P. chengii ,P. chrysanthemi,P. convolvuli f P. coppeyana,P. cytisi,P, dactylidis,P. dictyoides,P. echinopis,尸.ephemera,P. eryngicola,P. erythrospila,P. euphorbiae ’ P. freticola ’ P. gr amine a,P. heraclei,P: hordei,P. horrida,P. hyperici, p. japonica,P. kugitangi,P. lithophila,P. lolu,P. -22- 20 macrospora,P. metasequoiae ,尸.minuartiae-hirsutae,P. moravica,P. moroczkovskii,P. muscomm,P. osmanthi,P. phlei,P. pimpinellae,P. pitiospori,P. polytricha,P. polytricha,P. pontresinerisis,P. pulsatillae,P. raetica,P· rayssiae > P. rugosa,P. saviczii,P. schroeteri,P, scirpi, P. scirpicola,P. secalis,P. semeniperda,P. semiusta,P. seseli f. poterii ’ P· seseli ’ P. sobolevskii ’ P. subalpina , P. subantarctica,P. sudetica,P. syntrichiae,P. szaferiana ’ P. teres f. maculata,P. teres subsp. graminea,P. teres,P. tetrarrhenae,P. tranzschelii,P. trifolii,P. tritici-repentis, i3. ,P. ws/iwwin’e似,i3· ,葉枯病菌屬諸種 (Rhizoctonia species)» ίΗ-kp ^ Rh. aerea fRh. alba >Rh. alpina f Rh. anaticula ,Rh. anomala ’ Rh. apocynacearum,Rh. arachnion,Rh. asclerotica,Rh. bataticola,Rh. borealis, Rh. callae,Rh· Candida,Rh. carotae,Rh. cerealis,Rh. choussii,Rh. coniothecioides,Rh. dichotoma,Rh. dimorpha, Rh. endophytica var. filicata ,Rh. endophytica , Rh. ferruginea,Rh. floccosa,Rh. fragariae,Rhfraxini,Rh. fuliginea , Rh. fumiga.ta , Rh. globularis , Rh. goodyerae-repentis , Rh. gossypii var. anatolica , Rh. gossypii,Rh. gracilis,Rh. grisea,Rh. hiemalis,Rh. juniperi, Rh. lamellifera,Rh. leguminicola,Rh. lilacina,Rh. lupini, Rh. macrosclerotia,Rh. melongenae,Rh. microsclerotia,Rh, monilioides,Rh. monteithiana,Rh. muneratii,Rh. nandorii ’ 1364257
10 15
Rh. oryzae ,Rh. oryzae-sativae , Rh. pallida , Rh. pini-insignis,Rh. praticola,Rh. quercus f Rh. ramicola > Rh. robusta,Rh. rubi,Rh. rubiginosa,Rh. sclerotica,Rh. solani,Rh. solani f· paroketea,Rh. solani forma specialis, Rh. solani var. cedri-deodarae,Rh. solani var. fuchsiae,Rh. solani var. hortensis,Rh. stahlii,Rh. subtilis var. nigra,Rh. subtilis,Rh, tomato,Rh· iuliparum,Rh. versicolor,Rh. zeae, 醒·黑粉菌屬諸種(Tilletia species),例如,,71 aegopogonis ,T. ahmadiana ,T. airina ,T. ajrekari,T. alopecuri,T. anthoxanthi,Ί\ apludae,T. arundinellae,T. asperifolia,T. asperitolioides,T. atacamensis,T. baldrati, T. bambusae,T. banarasae,T\ bangalorensis,T. barclayana ’ T. biharica,T. bolayi,T. boliviensis,T. boutelouae,T. brachypodii ,T. brachypodii-ramosi ,T. brevifaciens,T, bromi. ,T. bromina,T. bromi-tectorum,T. brunkii,T. buchloeana ,T. caries ,T. cathcartae ,T. cerebrina ,T. chloridicola,T. controversa,T. controversa var. elymi,T. controversa var. prostrata ,T. corona ,T. cynosuri ,T. dacamarae,T. deyeuxiae,T. digitariicola,T. durangensis, T. ear lei ,Γ. echinochloae f.foliicola ’ T. echinochloae,T. echinosperma,T. ehrhartae,T. eleusines,T, elymandrde, T. elymi,T. elymicola f T. elytrophori,T. eragrostidis,T. euphorbiae , T. fahrendorfii , T. festuca-octoflorana , T. foetida f T. fusca > T. fusca var. bromi-tectorum f T. fusca var. -24- 20 1364257
10 aspora,T. goloskokovii,T. haynaldiae,T. heterospora,Ί. hold,T. horde i var· spontanei,T. horrida,T. hyalospora var. cuzcoensis,T. hyparrheniae,T. indica,T. intermedia,T. iowensis ’ T. ixophori ’ T. koeleriae,T. kuznetzoviana,T. laevis,T. laguri,T. leptochloae,T. lepturi,T. lycuroides, T. maclaganii ’ T. macrotuberculata,T. madeirensis,T. makutensis,T. milii-vernalis ’ T. milli,T. montana,T. montemartinii ’ T. nanifica , T. narasimhanii , T. 15
narayanaraoana , T. narduri , T. nigrifaciens , T. obscura-reticulata , T. oklahomae , T. okudairae , T. opiismeni-cristati,T. pachyderma,T. pallida,T. panici,T. panici-humilis,T. paradoxa,T. paspali,T. pennisetina,T. perotidis,T. phalaridis ,T. poae ,T. polypogonis,T. poonensis,T. prostrata,T. pulcherrima var. brachiariae,T. redfieldiae ,T. rhei , T. rugispora , T. sabaudiae ,T. saizmannii,T. savilei ’ T. scrobiculata ,Γ. setariae,T. setariae-palmiflorae,T. setariicola ’ T. sphaerococca,T. sphenopi,T. sphenopodis,T. sterilis,T. taiana,T, texana, T. themedae-anatherae,T. themedicola,T. togwateei,T. trachypogonis,T. transiliensis,T. transvaalensis,T. tritici [var.] nanijica , T. tritici f. monococci,T. tritici var. controversa,T. tritici var. laevis,T. tritici-repentis,T. triticoides,T. tuberculata,T. vetiveriae,T. viennotii,T. vittata var. burmannii,T, vittata,T. walkeri,T. youngii,T. zundelii. -25- 20 黑穗菌屬諸種(Ustilago species),例如,(7. ,ίΛ aegilopsidis,U. aeluropodis,U. affinis var. hilariae > U. agrestis , U. agropyrina , U. agrostis-palustris , U. ahmadiana ’ U. airae-caespitosae , U. alismatis , U. alopecurivora,U. alsineae > U. altilis,U. amadelpha var. glabriuscula , U. amphilophidis , U. amplexa , U. andropogonis-tectorum,U. aneilemae,U. anhweiana,U. anomala [var.] microspora ^ U. anomala var. avicularis > U. anomala var. cornea f U. anomala var. cordaif U. anomala var. muricata,U. anomala var. tovarae ’ U. anthoxanthi ’ U, apscheronica ,U. arabidia-alpinae , U. arctagrostis , U. arctica ’ U. arenariae-bryophyllae , U. argentina ’ U. aristidarius,U. arundinellae-hirtae,U. asparagi-pygmaei, U. asprellae,U. avenae f.sp. perennans,U. avenae subsp. alba ,U. avicularis,U, bahuichivoensis,U. barberi,U. beckeropsis ’ U. belgiana ,U. bethelii ,U. bicolor ,U. bistortarum var. marginalis , U. bistortarum var. pustulata } U. bistortarum var. ustilaginea , U. borealis , U. bothriochloae,U. bothriochloae-intermediae,U. bouriqueti, U. braziliensis , U. brizae , U. bromi-arvensis , U. bromi-erecti > JJ. bromi-mollis > U. bromina > U. bromivora f. brachypodii,U. bromivora var. microspora } U. bullata f. brachypodii-distachyi,U. bullata var. bonariensis,U. bullata var. macrospora ’ U. bungeana ,U. calamagrostidis var. scrobiculata , U. calamagrostidis var. typica } U. calamagrostidis ’ U. cardamines , U. cariciphila , U. caricis-wallichianae,Ιλ cornea,U. catherinae,U. caulicola, U. centrodomis,U. ceparum,U. cephalariae,U. chacoensis, U. chloridii , U. chloridionis , U. chrysopogonis , U. chubutensis ’ U. cichorii,U. cilinodis,U. clelandii,U. clintoniana f U. coloradensis f U. commelinae > U. compacta f U. concelata , U. condigna , U. consimilis , U. constantineanui,U. controversa,U. convertere-sexualis,U. cordai,U· coronariae f U. coronata,U. cortaderiae var. araucana , U. courtoisii , U. crus-galli var. minor , U. cryptica , U. curia , U. custanaica , U. cynodontis f. ovariicola,U. cynodontis,U. cyperi-lucidi,U. davisii,U, deccanii ,U. decipiens ,U. deformis ,U. dehiscens ,U. delicata,U. deyeuxiae,U. dianthorum,U. distichlidis,U. dubiosa , U. dumosa , U. earlei , U. echinochloae , U. ehrhartana,U. eleocharidis,U. eleusines > U. elymicola ’ U. elytrigiae , U. enneapogonis , U. epicampida , U. eragrostidis-japonicana,U. eriocauli,U. eriochloae,U· euphorbiae } U. fagopyri,U. festucae,U. festucarum,U. filamenticola,U. fingerhuthiae,U.flectens,U.flowersii,U. foliorum,U.formosana,U.fueguina,U. gageae,U. garcesi, U. gardneri,U. gaussenii,U. gigantispora,Ιλ gigantospora, U. glyceriae,U. goyazana,U. gregaria > U. grossheimii > -27- 1364257
10
U. gunnerae , U. haesendocki var. chloraphorae ’ U. halophiloides var· vargasii,U. halophiloides,U. haynaldiae ’ U. heleochloae,U. helictotrichi,U. herteri var. bicolor,U. hierochloae-odoratae , U. hieronymi var. insularis , U. hieronymi var. minor,U. hilariicola,U, himalensis,U. hitchcockiana,U. holci-avenacei,U. holubii,U. hordei ’ U. hordei f.sp. avenae } U. hsuii f U. hyalino-bipolaris,U. hydropiperis,U. hyparrheniae,U. hypodytesf. congoensis ’ U. hypodytesf. sporoboli,U. hypodytes var. agrestis,U. idonea * U. imperatae 9 U. induta f U. inouyei > U. intercedens f U. iranica , U. isachnes , U. ischaemi-akoensis , U. ischaemi-anthephoroidis,U. ixiolirii,U. ixophori,U. jacksonii var. ventanensis,U. jacksonii,U. jaczevskyana var. sibirica, U. jaczevskyana var. typica , U. jaczevskyana , U, jagdishwari,U. jamalainenii,U. jehudana,U. johnstonii, U. kairamoi , U. kazachstanica , U. kenjiana , U. kweichowensis , U. kyllingae , U. lachrymae-jobi , U. lepyrodiclidis,U. lidii,U. liebenbergii,U. linderi,U. linearis,Ιλ liroae,U. loliicola,U, longiflora,U. longiseti, U. longissima var. dubiosa f U. longissima var. paludificans ^ U. longissima var. typica,U. lupini,U. lychnidis-dioicae, U. iycoperdiformis,U. lyginiae,U. machili,U. magellanica, U. mariscana,U. maydis,U. megalospora,U. melicae,U. merxmuellerana , U. mesatlantica , U. michnoana , U. -28 - 20 1364257 -;
10
microspora var. paspalicola f U. microspora » U. microstegii > U. microthelis > U. milli f U. modesta } U. moehringiae > U. moenchiae-manticae , U. monermae , U. montagnei var. minor f U. morinae > U. morobiana } U. muehlenbergiae var. tucumanensis , U. muricata , U. muscari-botryoidis , U. nagornyi,U. nannfeldtii,U. nelsoniana,U. nepalensis,U. neyraudiae,U. nigra,U. nivalis,U. nuda > U. nuda var. hordei,U. nuda var. tritici,Ιλ nyassae,U. okudairae,U. olida * U. olivacea var. macrospora > U. onopordi} U. onumae f U. opiziicola,U. opiismeni,U. orientalis,U. otophora,U. overeemii,U. pamirica,U. panici-geminati,U. panjabensis, U. pappophori var. magdalensis , U. pappophori , U. parasnathii,U. parodii,U. parvula,U. paspalidiicola,U. patagonica,U. penniseti var. verruculosa,U. perrara,U. persicariae , U. petrakii , U. phalaridis ,U. phlei,U. phlei-pratensis,U. phragmites,U. picacea,U, pimprina ’ U. piperi [var.] rosulata,U. poae,U. poae-bulbosae,U. poae-nemoralis,U. polygoni-alati,U. polygoni-alpini,U. polygoni-punctati,U. polygoni-serrulati,U. polytocae,U. polytocae-barbatae , U.pospelovii , U. prostrata , U. pseudohieronymi , U. pueblaensis , U. puellaris , U. pulverulenta,U. raciborskiana,U. radians,U. ravida,U. rechingeri,U. reticulata,U. reticulispora,U· rhei ’ U. rhynchelytri > U. rwandensis,U. sabouriana,U. salviae,U. •29- 20 1364257 •η 5
sanctae-catharinae,U. scaura,Ιλ scillae,U. scitaminea var, sacchari-barberi,U. scitaminea var. sacchari-officinarum, U. scitaminea,IL scleranthi,U. scrobiculata,U. scutulata, U. secalis var· elymi,U. semenoviana,U. serena,U. serpens, U. sesleriae,U. setariae-mombassanae,U. shastensis,U. shimadae > U. silenes-inflatae , U. silenes-nutantis , U. sinkiangensis,U. sitanii * U. sleumeri,U. sonoriana,U. sorghi-stipoidei,U. spadicea,U. sparti,U. speculariae, U. spegazzinii var. agrestis,U. spegazzinii,U. spermophora var. orientalis ’ U. spermophoroides , U. spinulosa , U. sporoboli-indici ’ U. sporoboli-tremuli ,U. stellariae ,U. sterilis,U. ste-wartii,U. stipae,U. striaeformis f. agrostidis, U. striaeformis f. phlei,U. striaeformis f. poaeannuae > U. striaeformis f. poae-pratensis , U. striiformis f. hierochloes-odoratae ,U. striiformis var. agrostidis , U. striiformis var. dactylidis , U. striiformis var. hold f U. striiformis var· phlei,U. striiformis var. poae,U. stygia,U. sumnevicziana f U. superba f U. sydowiana f U. symbiotica } U. taenia,U. taiana,U. tanakae,U. tenuispora,U. thaxteri, U. tinantiae,U. to gat a,U. tourneuxii,U. tovarae,U. trachyniae,U. trachypogonis,U. tragana ’ U. tragi,U. tragica,U. tragi-racemosi,U. tHchoneurana,U. trichophora var. crus-galli,U. trichophora var. panici-frumentacei,U. triseti,U. tritici forma specialis,U. trochophora var. -30- 20 1364257
10 15
padfica,U. tuberculata,U. tucumanensis ’ U. tumeformis ’ U. turcomanica var. prostrata,U· turcomanica var. typica ’ U. turcomanica , U. ugamica , U. ugandensis var. macrospora,U. underwoodii,U. urginede,U. urochloana, U. ustilaginea, U. utriculosa var. cordai,U. utriculosa var. reticulata,U. valentula,U. vavilovi,U. verecunda ’ U. verruculosa > U. versatilis,U. vetiveriae,U. violacea var. stellariae,U. violaceo-irregularis,U. violaceoverrucosa , U. williamsii,U. wynaadensis,U. zambettakisii,U. zernae。 由於在被使用於控制植物疾病所需要的活性化合物濃 度下,植物可充分忍受的事實下’得以處理種子,因此,本 發明的活性化合物可被使用作為種子敷料。 由植物致病性真菌引起的對作物植物之大部分傷害,儘 早出現於當種子於儲存期間及被播種至土壌後,在萌芽7期間 或萌發之後受到攻擊,這一階段為特別關鍵時刻,係由於生 長中植物的根系與幼苗特別地敏感且甚至是微量傷害即足 以導致整株植物之死亡,藉由適當的組成物保護種子^ 中的植物也就特別有利。 x 對於傷害萌發後植物之植物致病性真菌的控制,主 以作物保護劑處理土壌及地表上的作物部分,:於 : 物保護劑會對環境及人類及動㈣健康造成衝擊 少活性化合物之施用量。 而方刀减 藉由處理植物種子以控制植物致病性直 來被知道的方式’且持續在改良中,然而,處 •31 · 20 無法以滿意的方式被解決的問題,故,有需要發展一 处、供保護種子與萌芽巾植物,在_及植物萌發後,其 刀佈在額外施用的作物保護劑巾,或至少減少另外的施 用另外也有必要使用最適量的活性化合物以提供種子與萌 I中植物最大的保護’免於植物致病性真菌之攻擊,但又不 曰傷害到植物本身’特職,供處理種子的方法也應將轉殖 基因植物的内在的殺真菌性質列入考慮,以便使用最少的作 物保羞劑達到最佳的種子與萌發中植物的最適當保護。 本發明因此特別也關於一種保護種子與萌發中植物,使 其免於文到植物致病性真菌的攻擊之方法,係藉由以根據本 發明的組成物處理種子。 本發明同樣地係關於本發明的組成物之用途,供處理種 子以保護種子與萌發中植物,使其免於受到植物致病性真菌 的感染。 此外’本發明為關於一種種子’其係已被根據本發明的 組成物處理過,故能提供保護作用免於感染植物致病性真 菌。 本發明的優點之一為,根據本發明的化合物的全身性性 質,意指經這些組成物處理過後,不僅保護種子本物,也使 植物在萌芽後得以免於受到植物致病性真菌的攻擊,以這種 方式處理,作物在播種或之後很短的時間内,可經分配得到 處理。 此外’值得被考慮的優點為,根據本發明的混合物也可 被應用於基因轉殖的種子。 •32- 根據本發明的組成物適於供保護任何植物品種之禮 子,其等被使用在農業、溫室、森林裡或在園藝方面,特別 是榖物(例如小麥、大麥、黑麥、小米和燕麥),玉米,棉花, 大丑’米,馬鈐薯’向日葵,豆,咖啡、甜菜(例如糖鉗菜 和飼料甜菜)’花生,蔬菜(譬如蕃茄、黃瓜、蔥和萵苣),草 坪和裝飾植物等之種子形式,尤其重要的是榖物(例如小 麥、大麥、黑麥和燕麥),玉米和稻米種子的處理特別重要。 就本發明的說明書中,根據本發明的組成物係單獨地或 被作成適當的配製劑被施用至種子上,較佳地,種子係以被 處理時足以避免傷害的穩定狀態被處理,通常’種子可在收 穫與播種間任一時間點下被處理 ,所用的種子通常為已分離 自植物且不帶穗軸、殼、莖、外殼、鬚或果肉者,於是,例 如’有可能使用剛收割的種子、經清理與乾燥使水分低於 15%重量計的種子,或者,也可使用乾燥後,經水處理後再 乾無的種子。 處理種子時,應小心使用根據本發明的組成物之量施用 至種子及/或選用的添加物之量,以免種子萌發後造成負面 影響’或導致植物傷害,應銘記在心的是,特別是活性化合 物可能在某一施用率下具有植物毒性。 根據本發明的化合物可被直接地施用,意指不再包含另 外的組成分且不經稀釋下被使用,通常,宜呈適當的配製劑 型式對種子施用組成物,供處理種子之適當的配製劑與方法 為從事本行的行家所知道者,且被揭露於,例如,下述文件
中:Us 4,272,417 A,US 4,245,432 A,US 4,808,430 A,US 1364257 »· 5,876,739 A » US 2003/0176428 A1 > WO 2002/080675 A1 » WO 2002/028186 A2。 可根據本發明被使用之活性化合物組成物,可被轉變成 習用的種子塗敷配製劑,例如溶液、乳液、懸浮液、粉劑、 5 泡沫物、漿液或其他的供塗覆種子之敷料,也包括ULV配 製劑。 這些配製劑係用已知的方式,藉由混合活性化合物或活 I"生化合物之組合物與習用的添加物而成’添加物例如,習用 的增量劑與溶劑或稀釋劑,染料,潤濕劑,分散劑,乳化劑, ίο 抑泡劑,防腐劑,二級增稠劑,粘著劑,激勃劑(gibberellins) 與選擇的水等。 可能存在於本發明的種子敷料配製劑中的適當的染料 包括習用於此目的之所有的染料,難溶於水的色素,與可溶 於水的染料均可被使用,可提及的實例包括得知自下述的染 15 料類:deslgnatlons rh〇damine B,C.I. Pigment Red 112, and C.I· Solvent Red 1 〇 • 可能存在於本發明的種子敷料配製劑中的適當的潤濕 劑包括可促進潮濕且為習用於活性農業化學物質的配製中 之所有物質,較佳者係使用烷基萘_磺酸鹽類,例如二異丙 20 基-或二異丁基蓁_磺酸鹽類。 可能存在於本發明的種子敷料配製劑中的適當的分散 及/或乳化劑包括戶斤有非離子的、陰離子的與陽離子之分 散劑’其等為習用於活性農#化學的配製劑中之物質,較佳 地’其可此使用非離子或陰離子分散劑或非離子或陰離子分 -34- 政劑的混合物’特別適當地非離子分散劑為氧化乙烯-氧化 2烯之成塊聚合物,烷基笨酚聚甘醇醚類,與三笨乙烯苯酚 I甘醇驗類,以及其填酸化或硫酸化的衍生物類,特別適當 的陰離子刀政劑為木質續酸鹽類(lignosulphonates),聚丙稀 酸鹽類,與芳基磺酸鹽類_甲醛濃縮物。 可能存在於本發明的種子敷料配製劑中的適當的抑泡 劑包括常被配製於活性農業化學物質的配製劑中之所有的 抑制泡沬之物質,較佳者,其可能使用矽酮抑泡劑類與硬脂 酸鎮。 "T月b存在於本發明的種子敷料配製劑中的適當的防腐 劑類包括可被使用於活性農業化學組成物中供此種目的使 用之所有的物質,順便一提者為,二氯芬(dichi〇r〇phen)與笨 曱醇半甲酸(benzyl alcohol hemiformal)。 可能存在於本發明的種子敷料配製劑中的適當的二級 增稠劑類包括可被使用於活性農業化學組成物中供此種目 的使用之所有物質’較佳者為纖維素衍生物類,丙烯酸衍生 物類,黃原膠(xanthan),經修飾的粘土類,與高度分散的二 氧化矽。 可能存在於本發明的種子敷料配製劑中的適當的粘著 劑類包括所有可被使用於種子敷料中之習用粘結劑,較佳者 為’由聚乙烯吡咯酮,聚乙烯乙酸酯,聚乙烯醇與侵填體 (tylose)組成者。 可能存在於本發明的種子敷料配製劑中的適當的激勃 素(gibberellins)包括,較佳地為具有式(11)之物質 1364257
其中 R12代表氫或經基,且
10 虛線代表在環中的位置可能出現C-C單鍵或C-C雙鍵。 可被提及的式(II)之激勃素的實例包括下列的:
特別佳者為式(II-2)之激勃素。 (IM)激勃素A1 (II-2)激勃素A3 (=激勃素酸) (II-3)激勃素A4 (II-4) 激勃素A7 •36- 1364257 式(II)之激勃素為已知化合物(參考:R. Wegler "Chemie der Pflanzen-schutz- and Schadlingsbekampfungsmittel", Volume 2, Springer Verlag, Berlin-Heidelberg-New York, 1970, pages 401 - 412)。 .5 根據本發明被使用之種子敷料配製劑可被直接使用或 經水稀釋後使用,例如’由其濃縮物或配製劑,以水稀釋的 方式’可被使用於穀物的種子,例如小麥,大麥,黑麥,燕 φ 麥,與黑小麥(triticale),以及玉米,稻,油菜籽,豌豆,田 豆,棉花,向日葵,與甜菜,或任何種類的蔬菜種子,本發 10 明之適當的種子敷料配製劑或其稀釋製劑可被使用於供塗 敷轉殖基因植物之種子,本說明中’增效的效果也出現在與 形成自表現的物質之交互作用上。 使用本發明的種子敷料配方或藉由添加水而由其配製 成之製劑供處理種子之適當的混合設備,包括所有一般可被 15 用塗敷的混合設備,當進行塗敷時,特殊的經改編的過程包 括引入種子進入混合機,添加特別的所要量的種子敷料配方 (以現狀或經水稀釋後)’進行混合’直到配製劑被均勻分佈 在種子上’選擇地’在之後進行烘乾操作。 • 根據本發明將被使用的種子敷料之施用比率可在很大 20 的範圍間變化,視在配製劑中之個別的活性化合物之含量與 在種子上的量而定,通常,活性化合物組合物之施用率,對 於每公斤的種子為施用介於0.001與5〇克間的量,較好對 於每公斤的種子施用介於0.01與15克間的量。 根據本發明將被使用的活性化合物用於處理種子之良 -37- 1364257 好的殺真菌作用,在下面的實例中被證明。 【實施方式】 J途實例
實例A 立枯絲核菌試驗(Rhiz〇ct〇nia s〇lani)(棉花}/種子處理 活性化合物作為乾燥種子敷料被施用,將活性化
10 ^田礦物混合成極均勻的粉末混合物再均勻分佈於種子^ 表面- 起置於封閉的玻璃 為了塗敷種子,將種子敷料與種子一 瓶内搖動三分鐘。 將2 X 5G粒玉米種子播種於種子淺箱内之標準化土壤 15
内’將撕⑽細·(5毫升/種子淺箱)散播於種子間並 覆上Lecaton,然後將種子置於溫室内,於約22。〇下及每天 U小時光照下培養。 7-8天後,檢視所有萌發的及生病的植物,採用Abb〇t 的方法計#其影響,%代表其效力相當於對照組值,而100% 代表沒有感染被觀察到。 -38- 1364257
表 A 立枯絲核菌試驗(Rhizoctonia solani)(棉花)/種子處理 活性組成分 活性化合物之施用率 (克/100公斤種子) 效力(%)
50 50 100 100
-39- 1364257
實例B
Pyrenophora graminea試驗(大麥)/種子處理/戶外試驗 穀物品種: 園地大小: 每塊園地中的種子量: 重復數:
10 夏季大麥 2平方公尺 40克 3 開始萌芽 檢視時之發展階段: 活性化合物係以市售配方被施用。 置於塗敷振搖 直到達成均勻 。。為了塗敷,先將配製劑送至塗敷燒杯内並 器上’加入經感染的種子並搖動約2-3分鐘, 塗佈。 15
以習用方式準備好土壤後,在有利於感染疾 行播種。 外進 在所有疾病症狀已清楚呈現後進行評估,%代表其效力 相當於對照組值,而100%代表沒有發現被感染。 • 40- 1364257
表B
Pyreuophora graminea試驗(大麥)/種子處理/戶外試驗 活性組成分 活性化合物之施用率 乂克/100公斤種子) 效力(%)
夏季大麥栽培品種”Frisia”中的感染為10.1 %。 -41 · 1364257 ·-· 實例c 立枯絲核菌試驗(稻米)/種子處理 將稻米種子(栽培品種K〇shihik叫浸在! 中經10天’移至新鮮的水中,通風換氣下,在 -天;’然後在室溫下將種子賴數小時;錢管 二 克的試驗物質被溶解於微升的丙咐,加人—八旦.笔 子(相當於3.8克的乾種子量)’將樣品混合物,抽刀除^種 種子被播種在直徑為75公分的塑膠管中之土襄、 15
32〇C ’ =度下黑暗中培養3天,再將幼苗置於平均溫产^ 22C的溫室中栽培2星期,各情況下,將每5株幼苗二ς'、,、 個具有12公分直徑的塑料中,置於平均溫度為 ,5 室中栽培5·6星期,將已在無菌的大麥榖粒上生^溫 及切/仍π·之菌絲置於水稻植栽的根部(離土表、的 公分)並在玻璃室中,平均27。〇的溫度下之高濕度下培I。5 培養七天後,檢視感染的程度及計算效力。 。。 坪姑祐疾病感染(疾病比率)的罈準 疾病比率 植物疾病之垂直蔓延度(公分) 〇 0 0.5 1 2 3 4 <1.5 3-5 6-11 12 13-23 -42- 20 1364257 5 效力(%)= 1 >24 感染的植物之疾病比率 X 100 5 未處理之對照組之疾病比率
-43- 1364257 表c 立枯絲核菌試驗(Rhizoctonia solani)(稻米)/種子塗敷 活性組成分 活性化合物之施用率 效力(%) (克/100公斤種子) 1364257
實例D
Ustilagonuda試驗(大麥)/種子處理/戶外試驗 夏李大麥 40克 2平方公尺 3 開花中期 穀物品種: 每塊園地中的種子量: 園地大小: 重復數:
發展階段: ίο 活性化合物係以市售配方被施用。 為了塗敷,先將配製劑送至塗敷燒杯内並置於塗敷振搖 器上,加入經感染的種子並搖動約2-3分鐘,直到達成均勻塗 佈。 以習用方式準備好土壤後,在有利於感染疾病的戶外進 15 行播種。 在所有疾病症狀已清楚呈現後進行評估,%代表其效力 胃相當於對照組值,而100%代表沒有發現被感染。 -45- 1364257
10 100 10 99
表D
Ustilagonuda試驗(大麥)/種子處理/戶外試驗 活性化合物之施用率 活性組成分 效力(%) ) (克/100公,斤種子) 夏季大麥栽培品種”Frisia”中的感染為10.1%。 -46-
Claims (1)
13&4257 4 專利申猜案第94120358號 ROC Patent Appln. No. 94120358 修正竽無《磚申請卓利範团中文本-附件(二> Amended Claims in Chinese - Encl.nn (民國101年1月20日送呈^ (Submitted on January 20,2012) Wl k日修正本I 十、申請專利範園·· 1. 一種具式(I-a)的羧醯胺類之用途,
.5 r代表氫或氟, R代表氫’氟,氯,甲基,乙基或三氟曱基, φ R2代表曱基,乙基,正_丙基或異丙基, R3代表碘’曱基,二氟曱基或三氟曱基, r4代表氫,氟,氣或甲基, 10 用於處理種子以對抗及/H.zociom.a如/⑽/菌之攻擊。 2.根據申請專利範圍第丨項的用途,用於處理水稻種子以 繁亂 Rhizoctonia solani 菌 t 皮擊。 t> 3.根據申請專利範圍第1項的用途,用於處理棉籽以對抗 Rhizoctonia solani 菌之皮擊。 4. 一種用於處理種子以對抗及♦菌攻擊之組 成物,其中組成物包含至少一種根據申請專利範圍第j 2〇 項的式(I-a)之叛醯胺。 5.根據申請專利範圍第4項之組成物,用於處理水稻種子 -47- 1364257 以對抗Rhizoctonia solctni菌之攻擊。 6. 根據申凊專利範圍第4項之組成物,用於處理棉籽以對 抗j Rhizoctonia solani 篦之攻擊。 5 7. —種用於控制⑽/⑽/菌之方法,特徵為其中 * 種子係以至少一種根據申請專利範圍第1項的式(I_a)之 叛酿胺處理。 10 8·根據申請專利範圍第7項之方法,用於控制水稻種子上 之 Rhizoctonia solani 菌。 9.根據申請專利範圍第7項之方法,用於控制棉籽上之 Rhizoctonia solani 8 ° 15 €j • 48 -
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DE102004029972A DE102004029972A1 (de) | 2004-06-21 | 2004-06-21 | Beizmittel zur Bekämpfung von phytopathogenen Pilzen |
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DE19716257A1 (de) | 1997-04-18 | 1998-10-22 | Bayer Ag | Fungizide Wirkstoffkombination |
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DE102004005787A1 (de) | 2004-02-06 | 2005-08-25 | Bayer Cropscience Ag | Carboxamide |
DE102004005786A1 (de) * | 2004-02-06 | 2005-08-25 | Bayer Cropscience Ag | Haloalkylcarboxamide |
DE102004045242A1 (de) | 2004-09-17 | 2006-03-23 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
PL1796465T4 (pl) * | 2004-09-27 | 2017-11-30 | E.I. Du Pont De Nemours And Company | Mieszaniny grzybobójcze pochodnej tiofenu |
DE102005015677A1 (de) * | 2005-04-06 | 2006-10-12 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
DE102005015850A1 (de) * | 2005-04-07 | 2006-10-12 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
GB0507123D0 (en) * | 2005-04-08 | 2005-05-11 | Isis Innovation | Method |
DE102005022147A1 (de) * | 2005-04-28 | 2006-11-02 | Bayer Cropscience Ag | Wirkstoffkombinationen |
DE102005023835A1 (de) * | 2005-05-24 | 2006-12-07 | Bayer Cropscience Ag | Fungizide Wirkstoffkombination |
DE102005025989A1 (de) * | 2005-06-07 | 2007-01-11 | Bayer Cropscience Ag | Carboxamide |
TWI324908B (en) * | 2006-01-05 | 2010-05-21 | Du Pont | Liquid formulations of carboxamide arthropodicides |
WO2008006541A2 (en) * | 2006-07-12 | 2008-01-17 | Syngenta Participations Ag | Method of controlling or preventing pathogenic damage in a plant propagation material |
EP2027773A1 (de) * | 2007-08-24 | 2009-02-25 | Bayer CropScience AG | Verwendung von N-[2-(1,3-Dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid |
BRPI0905841A2 (pt) * | 2008-02-05 | 2015-06-30 | Basf Se | "método para melhorar a saúde de uma planta, uso de uma amida, misturas fungicidas, método para controlar pragas e semente" |
JP2011511032A (ja) * | 2008-02-05 | 2011-04-07 | ビーエーエスエフ ソシエタス・ヨーロピア | 植物体健康組成物 |
WO2010046380A2 (en) * | 2008-10-21 | 2010-04-29 | Basf Se | Use of carboxamides on cultivated plants |
EP2272345A1 (en) | 2009-07-07 | 2011-01-12 | Bayer CropScience AG | Process for improving seedling growth and/or early emergence of crops |
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BR0115200B1 (pt) * | 2000-11-08 | 2012-08-07 | composto, processo para a preparaÇço do mesmo, composiÇço para o controle de microorganismos e para a prevenÇço contra o ataque e infestaÇço de plantas, uso do composto, e, mÉtodo de controle ou de prevenÇço contra a infestaÇço de plantas cultivadas por microorganismos fitopatogÊnicos. | |
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DE10229595A1 (de) * | 2002-07-02 | 2004-01-15 | Bayer Cropscience Ag | Phenylbenzamide |
JP2004123587A (ja) * | 2002-10-01 | 2004-04-22 | Mitsui Chemicals Inc | 芝病害防除剤 |
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DE10349501A1 (de) * | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
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US7786148B2 (en) * | 2004-02-12 | 2010-08-31 | Bayer Cropscience S.A. | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the transport of electrons of the respiratory chain in phytopathogenic fungal organisms |
EP1732389A1 (de) * | 2004-03-26 | 2006-12-20 | Basf Aktiengesellschaft | Fungizide mischungen |
DE102005022147A1 (de) * | 2005-04-28 | 2006-11-02 | Bayer Cropscience Ag | Wirkstoffkombinationen |
EP2272345A1 (en) * | 2009-07-07 | 2011-01-12 | Bayer CropScience AG | Process for improving seedling growth and/or early emergence of crops |
-
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- 2005-06-16 US US11/629,982 patent/US20080139389A1/en not_active Abandoned
- 2005-06-16 DE DE502005011000T patent/DE502005011000D1/de active Active
- 2005-06-16 CA CA002570978A patent/CA2570978A1/en not_active Abandoned
- 2005-06-16 WO PCT/EP2005/006483 patent/WO2005122770A2/de active Application Filing
- 2005-06-16 MX MXPA06014646A patent/MXPA06014646A/es not_active Application Discontinuation
- 2005-06-16 EP EP05751644A patent/EP1761128B1/de not_active Not-in-force
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- 2005-06-20 PE PE2005000701A patent/PE20060085A1/es not_active Application Discontinuation
- 2005-06-20 TW TW094120358A patent/TWI364257B/zh active
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- 2007-01-18 NO NO20070341A patent/NO20070341L/no not_active Application Discontinuation
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