TWI332488B - Crystallized glass article having patterns and method of producing the same - Google Patents

Crystallized glass article having patterns and method of producing the same Download PDF

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Publication number
TWI332488B
TWI332488B TW095127471A TW95127471A TWI332488B TW I332488 B TWI332488 B TW I332488B TW 095127471 A TW095127471 A TW 095127471A TW 95127471 A TW95127471 A TW 95127471A TW I332488 B TWI332488 B TW I332488B
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TW
Taiwan
Prior art keywords
glass
crystalline
crystallized
crystalline glass
patterns
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TW095127471A
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English (en)
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TW200708492A (en
Inventor
Kuo Chuan Hsu
Original Assignee
Jian Quan Glass Dev Company Ltd
Kuo Chuan Hsu
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Application filed by Jian Quan Glass Dev Company Ltd, Kuo Chuan Hsu filed Critical Jian Quan Glass Dev Company Ltd
Publication of TW200708492A publication Critical patent/TW200708492A/zh
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Publication of TWI332488B publication Critical patent/TWI332488B/zh

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/09Other methods of shaping glass by fusing powdered glass in a shaping mould
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/20Uniting glass pieces by fusing without substantial reshaping
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B32/00Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
    • C03B32/02Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
    • C03C10/0045Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/345Surface crystallisation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Glass Compositions (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)

Description

!332488 九、發明說明: 【發明所屬之技術領域】 本發明是關於一種結晶化玻璃物品及其製造方法,尤其關於 一種具有圖樣之結晶化玻璃物品及其製造方法,其應用於建築物 外裝材、内裝材或家具面板材以及辦公桌面板材等。 【先前技術】 作為建築物外裝材、内裝材或家具面板材以及辦公桌面板 材’呈現各種圖樣的結晶化玻璃物品被要求著。 作為使用於這些用途的結晶化玻璃,以往就有各種材料被提 案’例如’在專利文獻1中以冷-石夕灰石(石·w〇llast〇nite,冷-CaO .
Si〇2)為主結晶析出而成之結晶化玻璃被提案,在專利文獻2中以 透輝石(diopside,CaO · MgO · 2Si02)為主結晶析出而成之結晶化 玻璃被發表’在專利文獻3中以/3-矽灰石(β-CaO . Si02)和透輝 石(CaO · MgO · 2Si〇2)為主結晶析出而成之結晶化玻璃被發表。 然而,使用上述結晶化玻璃作為天然大理石結晶化玻璃物品 時’使用的製造方法為集積法,也就是說,將複數個結晶性玻璃 t體堆積於耐火性模型内,藉由熱處理使其結晶化。使用集積法, f因為上述的任何一種結晶化玻璃都不含核形成劑,結晶從結晶 ^玻璃表面向内部幾乎垂直析出,亦即,所謂表面結晶化型的結 ” °這—類型的結晶化玻璃’利用_等方法作成板狀玻 ϊΐί ’ ’將板狀玻璃熱處理使其結晶化,表面也不會顯現 出圖樣’因此,無法得到天然大理石圖樣。 數個集ΐ法作成的天然大理石結晶化玻璃物品時,複 的結晶被該結晶性玻璃替娜㈣㈣丨玻璃中 立方㈣體的錄所限制’ _該結晶的存在及 咖、而且單料其缺點。 L寻和文獻1] 特公昭53-39884號公報 [專利文獻2] 特開平3-205323號公報 1332488 【圖式簡單說明】 圖1 (A)顯示本發明之具有圖樣之結晶化玻璃物品的製造方法 的一個實施形式的侧面圖,是(A)的概略平面圖。 圖2 (A)顯示本發明之具有圖樣之結晶化玻璃物品的製造方法 的另一個實施形式的側面圖’(B)是(A)的概略平面圖。 圖3 (A)是在實施例4中得到之具有圖樣之結晶化玻璃物品的 照片’(B)是習知之結晶化玻璃物品的照片。 元件符號說明: 10、20耐火物模具 12、22 結晶性玻璃小體 14A、14B 結晶性玻璃板 24A ^ 24B 結晶性玻璃板
28 、公

Claims (1)

1332488 99年8月20曰修正替換頁 95127471 (無劃線)、 十、申請專利範圍: 一 1. 一種具有圖樣之結晶化玻璃物品,包含: -第-結晶化玻璃層,其是由—片或多片第—結晶性玻璃板 '、、至加熱軟化及/或融著並析出結晶而形成,其巾該第—結晶性 板經由加工而具有預定形狀或圖形;以及 二結晶化玻璃層,層疊於該第一結晶化玻璃層之上或之 下,該第二結晶化玻璃層是由多個結晶性玻璃小體、及/或一片戋 多片第二結晶,玻璃板經加熱軟化及/或融著並析出結晶而形成; 其中,該第一結晶性玻璃板是由析出々_石夕灰石或透輝石為主 結晶之一結晶性玻璃材料所形成,該結晶性玻璃材料在高於軟、化 點的溫度被燒成時,結晶會從該結晶性玻璃材料表面 出,而該第一結晶性玻璃板產生軟化及/或融著並依據該第一結晶 性玻璃板之預定加工形狀或圖形及/或多片該第一結晶性 組合方式的變化而產生不同圖樣。 2. 如,請專利範圍第丨項所述之具有圖樣之結晶化玻璃物品,其 中該第二結晶化玻璃層是由一種以0 _矽灰石或透輝石為主結晶析 出而成之結晶化玻璃所形成。 3. 如申請專利範圍第1項所述之具有圖樣之結晶化玻璃物品,其 中該第一結晶性玻璃板、該結晶性玻璃小體以及該第二結晶性玻 璃板於熱處理後之熱膨脹係數的差值介於OdOxiO-YC。 29
TW095127471A 2005-08-30 2006-07-27 Crystallized glass article having patterns and method of producing the same TWI332488B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005248768 2005-08-30
JP2006146549A JP4451860B2 (ja) 2005-08-30 2006-05-26 模様付き結晶化ガラス物品及びその製造方法

Publications (2)

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TW200708492A TW200708492A (en) 2007-03-01
TWI332488B true TWI332488B (en) 2010-11-01

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TW095127471A TWI332488B (en) 2005-08-30 2006-07-27 Crystallized glass article having patterns and method of producing the same
TW099127915A TWI399348B (zh) 2005-08-30 2006-07-27 具有圖樣之結晶化玻璃物品之製造方法

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US (2) US7615284B2 (zh)
EP (1) EP1760050B1 (zh)
JP (1) JP4451860B2 (zh)
CN (1) CN1923736B (zh)
AT (1) ATE528266T1 (zh)
ES (1) ES2372505T3 (zh)
PT (1) PT1760050E (zh)
TW (2) TWI332488B (zh)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4523021B2 (ja) * 2007-07-18 2010-08-11 建權玻璃開発股▲はん▼有限公司 模様付き結晶化ガラス物品及びその製造方法
JP2009023865A (ja) * 2007-07-18 2009-02-05 Jian Quan Glass Development Co Ltd 模様付き結晶化ガラス物品及びその製造方法
DE102007062979B4 (de) * 2007-12-21 2013-03-07 Schott Ag Verfahren zur Herstellung eines Glasgegenstands in Form einer Gargeräte-Innenscheibe, Glasscheibenpaket und Haushalts-Gargerätetür
CN102134156B (zh) * 2010-01-21 2012-10-10 江苏拜富科技有限公司 深色微晶玻璃熔块及深色微晶玻璃陶瓷复合板制备方法
JP5652742B2 (ja) * 2010-02-12 2015-01-14 日本電気硝子株式会社 強化板ガラス及びその製造方法
JP5644129B2 (ja) * 2010-02-12 2014-12-24 日本電気硝子株式会社 強化板ガラス及びその製造方法
JP2010270003A (ja) * 2010-08-24 2010-12-02 Jian Quan Glass Development Co Ltd 模様付き結晶化ガラス物品及びその製造方法
JP5603207B2 (ja) * 2010-11-08 2014-10-08 湖州大享玻璃制品有限公司 結晶化ガラスの連続成形方法および結晶化ガラスの連続成形装置
JP5661479B2 (ja) * 2011-01-11 2015-01-28 建權玻璃開発股▲はん▼有限公司 模様付き結晶化ガラス物品
CN102180658A (zh) * 2011-03-09 2011-09-14 李训竹 低熔点高韧性陶瓷材料及其制备方法和使用
CN102417303A (zh) * 2011-08-06 2012-04-18 蚌埠玻璃工业设计研究院 一种含有合成透辉石的玻璃配合料
CN102674695A (zh) * 2012-05-25 2012-09-19 南昌航空大学 废灯管玻璃快速烧结制备钙铝硅微晶玻璃的方法
CA2787584A1 (en) 2012-08-22 2014-02-22 Hy-Power Nano Inc. Method for continuous preparation of indium-tin coprecipitates and indium-tin-oxide nanopowders with substantially homogeneous indium/tin composition, controllable shape and particle size
CN104058581A (zh) * 2014-06-30 2014-09-24 四川一名微晶科技股份有限公司 微晶玻璃厚板及其加工方法
KR101695950B1 (ko) * 2014-10-27 2017-01-12 주식회사 엘지화학 결정화 유리 및 그 제조 방법
CN105667050B (zh) * 2016-01-20 2017-09-12 广西柳州中嘉知识产权服务有限公司 多层色彩微晶石瓷砖的加工方法
CN105669037B (zh) * 2016-01-20 2017-09-12 广西柳州中嘉知识产权服务有限公司 分层微晶石瓷砖的加工方法
CN113003939A (zh) * 2019-12-19 2021-06-22 湖州大享玻璃制品有限公司 SiO2-CaO系结晶化玻璃及其制造方法
CN114230183B (zh) * 2021-12-24 2024-01-12 晋城市光机电产业协调服务中心(晋城市光机电产业研究院) 陶瓷玻璃、曲面陶瓷玻璃及其制备方法

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US3847582A (en) 1971-06-01 1974-11-12 M Kozmin Method of continuous fabrication of glass-crystalline materials with rib configuration
CA1007051A (en) * 1972-01-22 1977-03-22 Shigeharu Nakamura Crystallized glass article having a pattern and method for producing the same
BE794258A (en) 1972-01-22 1973-05-16 Nippon Electric Glass Co Crystallised glass - exhibiting granite,marble etc effects for high strength decorative articles eg wall panels
CN1066834A (zh) * 1991-05-20 1992-12-09 中国科学院上海硅酸盐研究所 白色系列微晶玻璃高级建材的制造方法
JPH0624768A (ja) 1992-07-01 1994-02-01 Nippon Electric Glass Co Ltd 天然大理石様結晶化ガラス物品及びその製造方法
TW349933B (en) * 1996-02-28 1999-01-11 Nippon Electric Glass Co Process for preparing crystalline glasses using these for an architectural material having a marble effect

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Publication number Publication date
JP2007091575A (ja) 2007-04-12
CN1923736A (zh) 2007-03-07
US7615284B2 (en) 2009-11-10
EP1760050A1 (en) 2007-03-07
ATE528266T1 (de) 2011-10-15
TW200708492A (en) 2007-03-01
EP1760050B1 (en) 2011-10-12
JP4451860B2 (ja) 2010-04-14
TW201100339A (en) 2011-01-01
CN1923736B (zh) 2011-07-20
ES2372505T3 (es) 2012-01-20
TWI399348B (zh) 2013-06-21
US20100018253A1 (en) 2010-01-28
US7913516B2 (en) 2011-03-29
US20070048529A1 (en) 2007-03-01
PT1760050E (pt) 2011-12-16

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