TWI332488B - Crystallized glass article having patterns and method of producing the same - Google Patents
Crystallized glass article having patterns and method of producing the same Download PDFInfo
- Publication number
- TWI332488B TWI332488B TW095127471A TW95127471A TWI332488B TW I332488 B TWI332488 B TW I332488B TW 095127471 A TW095127471 A TW 095127471A TW 95127471 A TW95127471 A TW 95127471A TW I332488 B TWI332488 B TW I332488B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- crystalline
- crystallized
- crystalline glass
- patterns
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title abstract description 6
- 239000013078 crystal Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 230000001376 precipitating effect Effects 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 5
- 230000008025 crystallization Effects 0.000 claims description 5
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052637 diopside Inorganic materials 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 239000006082 mold release agent Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/09—Other methods of shaping glass by fusing powdered glass in a shaping mould
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/20—Uniting glass pieces by fusing without substantial reshaping
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/345—Surface crystallisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Description
!332488 九、發明說明： 【發明所屬之技術領域】 本發明是關於一種結晶化玻璃物品及其製造方法，尤其關於 一種具有圖樣之結晶化玻璃物品及其製造方法，其應用於建築物 外裝材、内裝材或家具面板材以及辦公桌面板材等。 【先前技術】 作為建築物外裝材、内裝材或家具面板材以及辦公桌面板 材’呈現各種圖樣的結晶化玻璃物品被要求著。 作為使用於這些用途的結晶化玻璃，以往就有各種材料被提 案’例如’在專利文獻1中以冷-石夕灰石（石·w〇llast〇nite，冷-CaO .
Si〇2)為主結晶析出而成之結晶化玻璃被提案，在專利文獻2中以 透輝石(diopside，CaO · MgO · 2Si02)為主結晶析出而成之結晶化 玻璃被發表’在專利文獻3中以/3-矽灰石（β-CaO . Si02)和透輝 石(CaO · MgO · 2Si〇2)為主結晶析出而成之結晶化玻璃被發表。 然而，使用上述結晶化玻璃作為天然大理石結晶化玻璃物品 時’使用的製造方法為集積法，也就是說，將複數個結晶性玻璃 t體堆積於耐火性模型内，藉由熱處理使其結晶化。使用集積法， f因為上述的任何一種結晶化玻璃都不含核形成劑，結晶從結晶 ^玻璃表面向内部幾乎垂直析出，亦即，所謂表面結晶化型的結 ” °這—類型的結晶化玻璃’利用_等方法作成板狀玻 ϊΐί ’ ’將板狀玻璃熱處理使其結晶化，表面也不會顯現 出圖樣’因此，無法得到天然大理石圖樣。 數個集ΐ法作成的天然大理石結晶化玻璃物品時，複 的結晶被該結晶性玻璃替娜㈣㈣丨玻璃中 立方㈣體的錄所限制’ _該結晶的存在及 咖、而且單料其缺點。 L寻和文獻1] 特公昭53-39884號公報 [專利文獻2] 特開平3-205323號公報 1332488 【圖式簡單說明】 圖1 (A)顯示本發明之具有圖樣之結晶化玻璃物品的製造方法 的一個實施形式的侧面圖，是(A)的概略平面圖。 圖2 (A)顯示本發明之具有圖樣之結晶化玻璃物品的製造方法 的另一個實施形式的側面圖’（B)是(A)的概略平面圖。 圖3 (A)是在實施例4中得到之具有圖樣之結晶化玻璃物品的 照片’（B)是習知之結晶化玻璃物品的照片。 元件符號說明： 10、20耐火物模具 12、22 結晶性玻璃小體 14A、14B 結晶性玻璃板 24A ^ 24B 結晶性玻璃板
28 、公
Claims (1)
1332488 99年8月20曰修正替換頁 95127471 (無劃線）、 十、申請專利範圍： 一 1. 一種具有圖樣之結晶化玻璃物品，包含： -第-結晶化玻璃層，其是由—片或多片第—結晶性玻璃板 '、、至加熱軟化及/或融著並析出結晶而形成，其巾該第—結晶性 板經由加工而具有預定形狀或圖形；以及 二結晶化玻璃層，層疊於該第一結晶化玻璃層之上或之 下，該第二結晶化玻璃層是由多個結晶性玻璃小體、及/或一片戋 多片第二結晶，玻璃板經加熱軟化及/或融著並析出結晶而形成； 其中，該第一結晶性玻璃板是由析出々_石夕灰石或透輝石為主 結晶之一結晶性玻璃材料所形成，該結晶性玻璃材料在高於軟、化 點的溫度被燒成時，結晶會從該結晶性玻璃材料表面 出，而該第一結晶性玻璃板產生軟化及/或融著並依據該第一結晶 性玻璃板之預定加工形狀或圖形及/或多片該第一結晶性 組合方式的變化而產生不同圖樣。 2. 如，請專利範圍第丨項所述之具有圖樣之結晶化玻璃物品，其 中該第二結晶化玻璃層是由一種以0 _矽灰石或透輝石為主結晶析 出而成之結晶化玻璃所形成。 3. 如申請專利範圍第1項所述之具有圖樣之結晶化玻璃物品，其 中該第一結晶性玻璃板、該結晶性玻璃小體以及該第二結晶性玻 璃板於熱處理後之熱膨脹係數的差值介於OdOxiO-YC。 29
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005248768 | 2005-08-30 | ||
| JP2006146549A JP4451860B2 (ja) | 2005-08-30 | 2006-05-26 | 模様付き結晶化ガラス物品及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200708492A TW200708492A (en) | 2007-03-01 |
| TWI332488B true TWI332488B (en) | 2010-11-01 |
Family
ID=37428619
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095127471A TWI332488B (en) | 2005-08-30 | 2006-07-27 | Crystallized glass article having patterns and method of producing the same |
| TW099127915A TWI399348B (zh) | 2005-08-30 | 2006-07-27 | 具有圖樣之結晶化玻璃物品之製造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW099127915A TWI399348B (zh) | 2005-08-30 | 2006-07-27 | 具有圖樣之結晶化玻璃物品之製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7615284B2 (zh) |
| EP (1) | EP1760050B1 (zh) |
| JP (1) | JP4451860B2 (zh) |
| CN (1) | CN1923736B (zh) |
| AT (1) | ATE528266T1 (zh) |
| ES (1) | ES2372505T3 (zh) |
| PT (1) | PT1760050E (zh) |
| TW (2) | TWI332488B (zh) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4523021B2 (ja) * | 2007-07-18 | 2010-08-11 | 建權玻璃開発股▲はん▼有限公司 | 模様付き結晶化ガラス物品及びその製造方法 |
| JP2009023865A (ja) * | 2007-07-18 | 2009-02-05 | Jian Quan Glass Development Co Ltd | 模様付き結晶化ガラス物品及びその製造方法 |
| DE102007062979B4 (de) * | 2007-12-21 | 2013-03-07 | Schott Ag | Verfahren zur Herstellung eines Glasgegenstands in Form einer Gargeräte-Innenscheibe, Glasscheibenpaket und Haushalts-Gargerätetür |
| CN102134156B (zh) * | 2010-01-21 | 2012-10-10 | 江苏拜富科技有限公司 | 深色微晶玻璃熔块及深色微晶玻璃陶瓷复合板制备方法 |
| JP5652742B2 (ja) * | 2010-02-12 | 2015-01-14 | 日本電気硝子株式会社 | 強化板ガラス及びその製造方法 |
| JP5644129B2 (ja) * | 2010-02-12 | 2014-12-24 | 日本電気硝子株式会社 | 強化板ガラス及びその製造方法 |
| JP2010270003A (ja) * | 2010-08-24 | 2010-12-02 | Jian Quan Glass Development Co Ltd | 模様付き結晶化ガラス物品及びその製造方法 |
| JP5603207B2 (ja) * | 2010-11-08 | 2014-10-08 | 湖州大享玻璃制品有限公司 | 結晶化ガラスの連続成形方法および結晶化ガラスの連続成形装置 |
| JP5661479B2 (ja) * | 2011-01-11 | 2015-01-28 | 建權玻璃開発股▲はん▼有限公司 | 模様付き結晶化ガラス物品 |
| CN102180658A (zh) * | 2011-03-09 | 2011-09-14 | 李训竹 | 低熔点高韧性陶瓷材料及其制备方法和使用 |
| CN102417303A (zh) * | 2011-08-06 | 2012-04-18 | 蚌埠玻璃工业设计研究院 | 一种含有合成透辉石的玻璃配合料 |
| CN102674695A (zh) * | 2012-05-25 | 2012-09-19 | 南昌航空大学 | 废灯管玻璃快速烧结制备钙铝硅微晶玻璃的方法 |
| CA2787584A1 (en) | 2012-08-22 | 2014-02-22 | Hy-Power Nano Inc. | Method for continuous preparation of indium-tin coprecipitates and indium-tin-oxide nanopowders with substantially homogeneous indium/tin composition, controllable shape and particle size |
| CN104058581A (zh) * | 2014-06-30 | 2014-09-24 | 四川一名微晶科技股份有限公司 | 微晶玻璃厚板及其加工方法 |
| KR101695950B1 (ko) * | 2014-10-27 | 2017-01-12 | 주식회사 엘지화학 | 결정화 유리 및 그 제조 방법 |
| CN105667050B (zh) * | 2016-01-20 | 2017-09-12 | 广西柳州中嘉知识产权服务有限公司 | 多层色彩微晶石瓷砖的加工方法 |
| CN105669037B (zh) * | 2016-01-20 | 2017-09-12 | 广西柳州中嘉知识产权服务有限公司 | 分层微晶石瓷砖的加工方法 |
| CN113003939A (zh) * | 2019-12-19 | 2021-06-22 | 湖州大享玻璃制品有限公司 | SiO2-CaO系结晶化玻璃及其制造方法 |
| CN114230183B (zh) * | 2021-12-24 | 2024-01-12 | 晋城市光机电产业协调服务中心(晋城市光机电产业研究院) | 陶瓷玻璃、曲面陶瓷玻璃及其制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3847582A (en) | 1971-06-01 | 1974-11-12 | M Kozmin | Method of continuous fabrication of glass-crystalline materials with rib configuration |
| CA1007051A (en) * | 1972-01-22 | 1977-03-22 | Shigeharu Nakamura | Crystallized glass article having a pattern and method for producing the same |
| BE794258A (en) | 1972-01-22 | 1973-05-16 | Nippon Electric Glass Co | Crystallised glass - exhibiting granite,marble etc effects for high strength decorative articles eg wall panels |
| CN1066834A (zh) * | 1991-05-20 | 1992-12-09 | 中国科学院上海硅酸盐研究所 | 白色系列微晶玻璃高级建材的制造方法 |
| JPH0624768A (ja) | 1992-07-01 | 1994-02-01 | Nippon Electric Glass Co Ltd | 天然大理石様結晶化ガラス物品及びその製造方法 |
| TW349933B (en) * | 1996-02-28 | 1999-01-11 | Nippon Electric Glass Co | Process for preparing crystalline glasses using these for an architectural material having a marble effect |
-
2006
- 2006-05-26 JP JP2006146549A patent/JP4451860B2/ja not_active Expired - Fee Related
- 2006-07-27 TW TW095127471A patent/TWI332488B/zh not_active IP Right Cessation
- 2006-07-27 TW TW099127915A patent/TWI399348B/zh active
- 2006-08-02 US US11/498,463 patent/US7615284B2/en active Active
- 2006-08-03 AT AT06016246T patent/ATE528266T1/de not_active IP Right Cessation
- 2006-08-03 EP EP06016246A patent/EP1760050B1/en not_active Not-in-force
- 2006-08-03 PT PT06016246T patent/PT1760050E/pt unknown
- 2006-08-03 ES ES06016246T patent/ES2372505T3/es active Active
- 2006-08-24 CN CN200610126247.3A patent/CN1923736B/zh not_active Expired - Fee Related
-
2009
- 2009-09-21 US US12/564,021 patent/US7913516B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007091575A (ja) | 2007-04-12 |
| CN1923736A (zh) | 2007-03-07 |
| US7615284B2 (en) | 2009-11-10 |
| EP1760050A1 (en) | 2007-03-07 |
| ATE528266T1 (de) | 2011-10-15 |
| TW200708492A (en) | 2007-03-01 |
| EP1760050B1 (en) | 2011-10-12 |
| JP4451860B2 (ja) | 2010-04-14 |
| TW201100339A (en) | 2011-01-01 |
| CN1923736B (zh) | 2011-07-20 |
| ES2372505T3 (es) | 2012-01-20 |
| TWI399348B (zh) | 2013-06-21 |
| US20100018253A1 (en) | 2010-01-28 |
| US7913516B2 (en) | 2011-03-29 |
| US20070048529A1 (en) | 2007-03-01 |
| PT1760050E (pt) | 2011-12-16 |
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