TWI377183B - Crystallized glass article having patterns and method of producing the same - Google Patents

Crystallized glass article having patterns and method of producing the same Download PDF

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TWI377183B
TWI377183B TW97126614A TW97126614A TWI377183B TW I377183 B TWI377183 B TW I377183B TW 97126614 A TW97126614 A TW 97126614A TW 97126614 A TW97126614 A TW 97126614A TW I377183 B TWI377183 B TW I377183B
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layer
crystallized
glass
crystalline
glass plate
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TW200904769A (en
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Jian Quan Glass Dev Company Ltd
Hsu Kuo Chuan
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Description

1377183 九、發明說明: 【相關申請案之交互參照】 本申請案係基於並且主張曰本專利申請案第2007-187654號 的優先權’此優先權案申請於2007年7月18曰,其整體内容藉 由參考文獻方式合併於此。 【發明所屬之技術領域】 本發明係關於一種具有圖樣之結晶化玻璃物品及其製造方 法,其應用於建築物外裝材、内裝材或家具面板材以及辦公桌面 板材等。1377183 IX. INSTRUCTIONS: [Reciprocal References in Related Applications] This application is based on and claims the priority of the present patent application No. 2007-187654. This priority application was filed on July 18, 2007, the entire The content is incorporated herein by reference. BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a crystallized glass article having a pattern and a method of manufacturing the same, which is applied to a building exterior material, an interior material or a furniture surface board, and a desk top board.

【先前技術】 近年來,隨著時代的變遷,人們不斷地對例如作為建築物外[Prior Art] In recent years, with the changes of the times, people are constantly on, for example, outside the building.

裝材、内裝材或家具面板材以及辦公桌面板材的各種結晶化玻璃 物品提出要求。 作為使用於這些用途的結晶化玻璃,為人們所熟知的結晶化 玻璃包含:以沒-石夕灰石(石1〇11於切11^’/5-(^〇.以〇2)為主結 晶析出而成的結晶化玻璃,或以透輝石(diopside,ca〇. Mg〇. 為主結晶析出而成的結晶化玻璃。 此外,習知含有上述結晶之結晶化玻璃物品的製造方法包 ,:(1)藉由將板狀的結晶性玻璃加以熱處理而使結晶從表面向内 部析出、成長的製造方法(專利文獻1);以及(2)所謂「^積^ ,製造方法,即,熔融玻璃經由水冷等急冷處理作成結晶性玻▲ 小體’將這種結晶性玻璃小體集積於耐火性模型内,藉由熱 使結晶性玻璃小體互相融著成為一體而同時進行結晶^ g、生 法(專利文獻2〜8)。 万 圖樣製造方法所製成的結晶化玻璃物品具有天然大理石 [專利文獻1]日本特公昭51-23966號公報 1377183 [專利文獻2]曰本特公昭53_39884號公報 [專利文獻3]日本特公昭55_29〇18號公報 [專利文獻4]曰本特開昭63_2〇1〇37號公報 [專利文獻5]曰本特開平3—164446號公報 [專利文獻6]日本特開平3_2〇5323號公報 [專利文獻7]曰本特開平5—163〇33號公報 [專利文獻8]日本特開平6_24768號公報Various crystallized glass items for packaging, interior or furniture panels and office panels are required. As a crystallized glass used for these purposes, a crystallized glass which is well known includes: a stone-free stone (stone 1〇11 in a cut 11^'/5-(^〇.〇〇2) Crystallized glass obtained by crystallization, or crystallized glass which is precipitated by diopside (ca〇. Mg〇. as a main crystal). Further, a method for producing a crystallized glass article containing the above crystal is known. (1) A production method in which crystals are precipitated and grown from the surface to the inside by heat treatment of a plate-shaped crystallized glass (Patent Document 1); and (2) "Means, a manufacturing method, that is, melting" The glass is crystallized by water cooling or the like to form a crystallized glass ▲ small body 'This crystallized glass body is accumulated in a fire resistance mold, and the crystallized glass bodies are integrated with each other by heat to simultaneously crystallize, The crystallization method of the crystallization of the glazed glass article is a natural marble. [Patent Document 1] Japanese Patent Publication No. Sho 51-23966 No. 1377183 [Patent Document 2] 曰本特公昭53_39884 Bulletin [Patent Document 3] Japan Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 7] Japanese Patent Laid-Open Publication No. Hei 5-163-33

然而’當使用上述⑴所揭露之方法將板狀破璃進行熱處理而 製造結晶化玻璃物品時,由於板狀玻璃中不含核形成劑,所以, 結晶會從板狀玻璃的表面、背面及端面向内部析出並且成長。因 此例如尽度大約1〇馳的板狀結晶化玻璃物品,其中心部分沒 有被結晶化,並且殘留厚度大約4mm的玻璃母體,而這些玻璃母 體部分會發生龜裂的情形。 一 以下,這種狀態可藉由圖式作進一步的說明,圖3係顯示上 述板,玻璃經由熱處理所得到之結晶化玻璃物品的斷面圖。‘在圖3 中,符號100表示結晶化玻璃物品,11〇表示結晶化玻璃體, 表示未結晶化的結晶性玻璃母體,130表示龜裂。如圖3所示,結 晶從板狀玻璃的表面、背面以及端面向内部成長,在已結晶化之 結晶化玻璃體110所包圍的區域(板狀玻璃物品的中心部)内存 在有未結晶化之結晶性玻璃母體12〇,而在這些結晶性玻璃母體 120内會發生龜裂13〇。 因此’對於經由上述(1)所揭露之製造方法而得到的結晶化玻 ,物品100而言’雖然從外觀上觀察不出龜裂13〇,但由於内部確 貫存在有龜裂130,所以會導致強度的不足。 另一方面,當使用上述(2)所揭露之集積法製造結晶化玻璃物 品,將結晶性破璃小體集積於耐火性模型内時,空氣會被密封在 結晶性玻璃小體間的空隙内。因此,所製造之結晶化玻璃物品的 内部容易產生氣泡。為了對結晶化玻璃物品的表面進行精細處理 而加以研磨時,這些氣泡容易在表面產生半圓形狀的氣孔缺陷。However, when the crystallized glass article is produced by heat-treating the plate-shaped glass by the method disclosed in the above (1), since the plate-like glass does not contain a core forming agent, the crystallizes from the surface, the back surface and the end of the plate glass. Develop and grow internally. Therefore, for example, a plate-like crystallized glass article having a fullness of about 1 pacing has no central portion to be crystallized, and a glass matrix having a thickness of about 4 mm remains, and the glass matrix portion is cracked. Hereinafter, this state can be further illustrated by the drawings, and Fig. 3 is a cross-sectional view showing the crystallized glass article obtained by heat treatment of the above-mentioned plate. In Fig. 3, reference numeral 100 denotes a crystallized glass article, 11A denotes a crystallized glass body, and a crystallized glass precursor which is not crystallized, and 130 denotes a crack. As shown in Fig. 3, the crystal grows from the front surface, the back surface, and the end surface of the sheet glass, and there is uncrystallized in the region surrounded by the crystallized crystallized glass body 110 (the center portion of the sheet glass article). The crystallized glass precursor 12 〇, and cracks 13 会 occur in the crystallized glass precursor 120. Therefore, in the case of the crystallized glass obtained by the production method disclosed in the above (1), the article 100 does not have cracks 13 外观 from the appearance, but since there is a crack 130 in the interior, Lead to insufficient strength. On the other hand, when the crystallized glass article is produced by the accumulation method disclosed in the above (2), when the crystallized glass body is accumulated in the fire resistance model, the air is sealed in the space between the crystallized glass bodies. . Therefore, bubbles are easily generated inside the crystallized glass article to be produced. In order to polish the surface of the crystallized glass article by grinding, these bubbles easily cause a semicircular pore defect on the surface.

Claims (1)

I377183 101年5月22日修正替換頁 97126614(無劃線) 十、申請專利範圍: -- 1·種具有圖樣之結晶化玻璃物品,包含: 一結晶化玻璃層A,藉由使複數個結晶性玻璃小體互相融 並且同時結晶化而形成圖樣; 一結晶化玻璃層B,藉由在該結晶化玻璃層a之至少一表面 處於融著狀態時,於該至少-表面上配置一結晶性玻璃板B,並使 該結晶性玻璃板B從其表面朝向内部到達中心部進行結晶化而 成半透明狀態;及 一結晶化玻璃層C,融著於該結晶化玻璃層A之端面部分或 ί的該結晶化玻璃層A與該結晶化玻璃層B之端面部分,該結晶化玻 璃層C係使結晶性玻璃板c從其表面朝向内部到達中心部進行結 晶化而形成,且含有万-矽灰石以及透輝石至少其中一種結晶以作 為主結晶,其中該結晶化玻璃層C之厚度為6麵以下, 其中该結晶化玻璃層A的主結晶為点-石夕灰石(0 -wollastonite,/9-CaO . Si〇2)以及透輝石(diopside,CaO . MgO . 2Si〇2)至少其中一種,而該結晶化玻璃層B的主結晶為召一矽灰石 以及透輝石至少其中一種’且該結晶化玻璃層B具有〇.丨麵至6刪 的厚度。 鲁2.如申請專利範圍第1項之具有圖樣之結晶化玻璃物品,其中該 結晶化玻璃層A具有〇. lmm至3〇mm的厚度。 3. 如申請專利範圍第1項之具有圖樣之結晶化玻璃物品,其中該 結晶化玻璃物品具有8mm至30mm的厚度。 4. 如申請專利範圍第1項之具有圖樣之結晶化玻璃物品,其中在 該結晶化玻璃層A的上下兩表面處於融著狀態時,於該上下兩表 面分別配置該結晶化玻璃層B。 42 1377183 101年5月22曰修正替換頁 97126614(無劃線) 5.如申請專利範圍第1項之具有圖樣之結晶化玻璃物品,其中該 結晶化玻璃層A與該結晶化玻璃層B在30〜38(TC範圍内之熱膨脹 係數差的絕對值為〇〜10 X 1〇-7 /。〇範圍内。 6· —種具有圖樣之結晶化玻璃物品的製造方法,包含用以對下列 至少其中一種積層體進行熱處理的熱處理步驟: (1) 由複數個結晶性玻璃小體集積成層狀的一結晶性玻璃小 體層、層®配置於該結晶性玻璃小體層表面的一結晶性玻璃板B、 以及配置在該結晶性玻璃小體層的端面部分或該結晶性玻璃小體 V, 層與該結晶性玻璃板B的端面部分的一結晶性玻璃板c所構成的 一積層體; (2) 由結晶性玻璃板b、位於該結晶性玻璃板B表面上之複數 個結aa性玻璃小體集積成層狀的該結晶性玻璃小體層、以及配置 f該結晶性玻璃小體層的端面部分或該結晶性玻璃小體層與該結 晶性玻璃板B的端面部分的一結晶性玻璃板c所構成的一積層 體;及 、I377183 May 22, 2011 Amendment Replacement Page 97126614 (without line) X. Patent Application Range: -- 1. A crystallized glass article with a pattern comprising: a crystallized glass layer A, by making a plurality of crystals The glass bodies are mutually fused and simultaneously crystallized to form a pattern; a crystallized glass layer B is disposed on the at least one surface when at least one surface of the crystallized glass layer a is in a fused state The glass plate B is formed into a translucent state by crystallizing the crystalline glass plate B from the surface toward the center thereof; and a crystallized glass layer C is fused to the end face portion of the crystallized glass layer A or ί of the crystallized glass layer A and the end face portion of the crystallized glass layer B, the crystallized glass plate C is formed by crystallizing the crystalline glass plate c from the surface toward the center portion, and contains 10,000- At least one of the ash and the diopside is crystallized as a main crystal, wherein the thickness of the crystallized glass layer C is 6 or less, wherein the main crystal of the crystallized glass layer A is a point-stone-stone (0-woll Astonite, /9-CaO. Si〇2) and at least one of diopside (CaO.Mg.2Si〇2), and the main crystal of the crystallized glass layer B is at least one of a limestone and a diopside. A kind of the crystallized glass layer B has a thickness of from 丨. A crystallized glass article having a pattern as claimed in claim 1, wherein the crystallized glass layer A has a thickness of from 0.1 mm to 3 mm. 3. The crystallized glass article having a pattern as claimed in claim 1, wherein the crystallized glass article has a thickness of from 8 mm to 30 mm. 4. The crystallized glass article having the pattern of the first aspect of the invention, wherein the crystallized glass layer B is disposed on the upper and lower surfaces when the upper and lower surfaces of the crystallized glass layer A are in a molten state. </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; 30~38 (the absolute value of the difference in thermal expansion coefficient in the range of TC is 〇~10 X 1〇-7 /. 〇. 6) - A method for manufacturing a crystallized glass article having a pattern, including at least A heat treatment step of heat treatment of one of the laminates: (1) a crystalline glass body layer formed by laminating a plurality of crystalline glass bodies, and a layer of crystalline glass plate disposed on the surface of the crystallized glass body layer And a laminate comprising a crystallized glass plate c disposed on an end face portion of the crystalline glass body layer or the crystalline glass body V, and an end face portion of the crystalline glass plate B; a crystalline glass plate b, a plurality of aa-containing glass bodies located on the surface of the crystallized glass plate B, and a layered portion of the crystalline glass body layer, and an end portion of the crystal glass body layer The crystallinity of a glass laminate layer and the junction bodies crystalline glass plate to the end portion B of a crystalline glass plate composed of c; and, (3i由一第一結晶性玻璃板B、位於該第一結晶性玻璃板B表 面上之,數個結晶性玻璃小體集積成層狀的該結晶性玻璃小體 ,、層®配置於該結晶性玻璃小體層表面的一第二結晶性玻璃板 以及配,在讓結晶性玻璃小體層的端面部分或該結晶性玻璃小 ,層與該第-或該第二結晶性玻璃板Β的端面部分的—結晶性玻 璃板C所構成的一積層體, 其中該等熱處理步驟包含: # · ^吏該結晶性玻璃小體層中的該複數個結晶性玻璃小體相互融 =結晶性玻璃小體層與該結晶性玻璃板Β、該結晶性玻璃 ㈣奴’、該第一及該第二結晶性玻璃板Β相互融著,並且同時使 盘=^生^1 小體與該結晶性玻璃板β、該結晶性玻璃板 s 弟及该第二結晶性玻璃板β結晶化,並且使該結晶性 43 1377183 101年5月22曰修正替換頁 97126614(無劃線) ‘ 體層形成結晶化玻璃層A、使該結晶性玻璃板B形成結晶化 ·==、使料—結晶性玻璃板B與該第二結·玻璃板B形成 2,二結晶化玻璃層β、以及使該結晶性玻璃板C形成結晶化 Μ —其中,該結晶化玻璃層Α形成圖樣,而該結晶化玻璃層 B以及該第一與該第二結晶化玻璃層B呈現半透明狀態, 、甘ί中在該結晶性玻璃小體層中,析出石_矽灰石以及透輝石至 少種結晶,以作為主結晶’而在該結晶性玻璃板Β、或該第 及—結晶性玻璃板Β中,從該結晶性玻璃板β、或從該第一 及該第二結晶性玻璃板Β的表面朝向内部到達中心部析出沒一矽灰 ^ 石以及透輝石至少其中一種結晶,以作為主結晶, 八中該結晶性玻璃板Β具有〇.丨咖至6刪的厚度,該第一結 璃板Β以及該第二結晶性玻璃板Β分別具有Q. i職至二 • 、旱又,以及該結晶化玻璃層C的厚度為6刪以下,該結晶化玻. ,璃層C含有点-矽灰石以及透輝石至少其中一種結晶’以作為主结 7.如申請專利範圍第6項之具有圖樣之結晶化玻璃物品的製 法,其中該結晶性玻璃小體層具有^刪至昶瞧的厚度。、。 十一、圖式: 44(3i consists of a first crystalline glass plate B, the crystallized glass body in which a plurality of crystalline glass bodies are layered on the surface of the first crystalline glass plate B, and the layer® is disposed in the layer a second crystalline glass plate on the surface of the crystalline glass body layer and the end face of the crystalline glass body layer or the crystallized glass is small, and the end face of the layer and the second or the second crystalline glass plate a layered body composed of a part of the crystalline glass plate C, wherein the heat treatment step comprises: # · ^吏 the plurality of crystalline glass bodies in the crystalline glass body layer are fused to each other = crystalline glass body layer And the crystalline glass plate Β, the crystalline glass (four) slaves, the first and the second crystalline glass plate Β are mutually fused, and at the same time, the disk is made of the crystalline glass plate β The crystalline glass plate s and the second crystalline glass plate β are crystallized, and the crystallinity is changed. 43 1377183 May 22, 2011 Revision Replacement page 97126614 (without scribe line) ' Body layer forms crystallized glass layer A And forming the crystalline glass plate B Crystallization·==, the material-crystallized glass plate B and the second layer/glass plate B are formed 2, the second crystallized glass layer β, and the crystallized glass plate C are crystallized, wherein the crystal The glass layer is formed into a pattern, and the crystallized glass layer B and the first and second crystallized glass layers B are in a translucent state, and in the crystalline glass body layer, precipitated stone The stone and the diopside are at least crystallized, and the crystallized glass plate Β or the first crystalline glass plate , is used as the main crystal ′, from the crystalline glass plate β, or from the first and the first The surface of the two crystallized glass plate is directed toward the center to form a crystallization of at least one of the ash and the diopside as the main crystal, and the crystalline glass plate has a 〇. The thickness, the first glass plate Β and the second crystalline glass plate 具有 have a Q. i job to two, a dry, and the thickness of the crystallized glass layer C is 6 or less, the crystallized glass. , the glass layer C contains at least one of a point - a limestone and a diopside A method for producing a crystallized glass article having a pattern as in the sixth aspect of the invention, wherein the crystalline glass body layer has a thickness of 昶瞧 to 昶瞧. 十一. 44
TW97126614A 2007-07-18 2008-07-14 Crystallized glass article having patterns and method of producing the same TWI377183B (en)

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JP2006199538A (en) * 2005-01-20 2006-08-03 Huzhou Daikyo Hari Seihin Yugenkoshi Li2O-Al2O3-SiO2 CRYSTALLINE GLASS AND CRYSTALLIZED GLASS AND MANUFACTURING METHOD OF Li2O-Al2O3-SiO2 CRYSTALLIZED GLASS
JP4451860B2 (en) * 2005-08-30 2010-04-14 建權玻璃開発股▲はん▼有限公司 Crystallized glass article with pattern and manufacturing method thereof
JP2007154648A (en) * 2005-11-08 2007-06-21 Nippon Electric Glass Co Ltd Glass brick, glass brick construction body and its execution method

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