TWI325431B - Multifunctional monomers and their use in making cross-linked polymers and porous films - Google Patents

Multifunctional monomers and their use in making cross-linked polymers and porous films Download PDF

Info

Publication number
TWI325431B
TWI325431B TW092103132A TW92103132A TWI325431B TW I325431 B TWI325431 B TW I325431B TW 092103132 A TW092103132 A TW 092103132A TW 92103132 A TW92103132 A TW 92103132A TW I325431 B TWI325431 B TW I325431B
Authority
TW
Taiwan
Prior art keywords
page
monomer
product
reactor
bis
Prior art date
Application number
TW092103132A
Other languages
English (en)
Chinese (zh)
Other versions
TW200415157A (en
Inventor
Shan J Niu Qing
E Hefner Robert Jr
P Godschalx James
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of TW200415157A publication Critical patent/TW200415157A/zh
Application granted granted Critical
Publication of TWI325431B publication Critical patent/TWI325431B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/48—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation involving decarboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/34—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D309/36—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
    • C07D309/38—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms one oxygen atom in position 2 or 4, e.g. pyrones
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00—Interconnections in chips, wafers or substrates
    • H10W20/40—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
    • H10W20/45—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their insulating parts
    • H10W20/48—Insulating materials thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Pyrane Compounds (AREA)
TW092103132A 2002-02-15 2003-02-14 Multifunctional monomers and their use in making cross-linked polymers and porous films TWI325431B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7820502A 2002-02-15 2002-02-15

Publications (2)

Publication Number Publication Date
TW200415157A TW200415157A (en) 2004-08-16
TWI325431B true TWI325431B (en) 2010-06-01

Family

ID=31990029

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092103132A TWI325431B (en) 2002-02-15 2003-02-14 Multifunctional monomers and their use in making cross-linked polymers and porous films

Country Status (7)

Country Link
EP (1) EP1476416B1 (enExample)
JP (1) JP4447923B2 (enExample)
KR (1) KR100965394B1 (enExample)
CN (1) CN100480226C (enExample)
AU (1) AU2003215182A1 (enExample)
TW (1) TWI325431B (enExample)
WO (1) WO2003068825A2 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4765076B2 (ja) * 2003-02-20 2011-09-07 ダウ グローバル テクノロジーズ エルエルシー ポリアリーレンの合成方法及びその方法により製造されたポリアリーレン
WO2004090018A1 (en) * 2003-04-02 2004-10-21 Dow Global Technologies Inc. Multifunctional substituted monomers and polyarylene compositions therefrom
US7381850B2 (en) 2003-04-02 2008-06-03 Dow Global Technologies Inc. Multifunctional unsymmetrically substituted monomers and polyarylene compositions therefrom
JP2007515501A (ja) * 2003-09-19 2007-06-14 ダウ グローバル テクノロジーズ インコーポレイティド 多官能性モノマー及びそれからのポリアリーレン組成物
JP2007505976A (ja) * 2003-09-19 2007-03-15 ダウ グローバル テクノロジーズ インコーポレイティド 結合ポラゲン含有多官能性モノマー及びそれからのポリアリーレン組成物
WO2005037761A2 (en) * 2003-10-21 2005-04-28 Dow Global Technologies Inc. Multifunctional ethynyl substituted monomers and polyarylene compositions therefrom
JP4885724B2 (ja) * 2003-10-21 2012-02-29 ダウ グローバル テクノロジーズ エルエルシー 結合メソゲン性ポラゲン形成性部分を含有する多官能性モノマー及びそれからのポリアリーレン組成物
ATE526359T1 (de) * 2004-06-10 2011-10-15 Dow Global Technologies Llc Verfahren zur herstellung eines nanoporösen dielektrischen films
US8399349B2 (en) * 2006-04-18 2013-03-19 Air Products And Chemicals, Inc. Materials and methods of forming controlled void
KR101045669B1 (ko) 2009-12-04 2011-07-01 광주과학기술원 다공성 유기물 박막의 제조방법 및 이에 의해 제조된 다공성 유기물 박막
US9868820B2 (en) * 2014-08-29 2018-01-16 Rohm And Haas Electronic Materials Llc Polyarylene materials
US11746254B2 (en) * 2019-11-19 2023-09-05 Rohm And Haas Electronic Materials Llc Tunable refractive index polymers
CN118562127B (zh) * 2024-08-02 2024-10-11 中国科学技术大学 一种具有高Tg、低介电、本征阻燃型生物基苯并噁嗪树脂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4400540A (en) * 1982-04-08 1983-08-23 The United States Of America As Represented By The Secretary Of The Air Force Oxy and thioaryl-phenylated aromatic biscyclopentadienones
US5965679A (en) 1996-09-10 1999-10-12 The Dow Chemical Company Polyphenylene oligomers and polymers
WO2000031183A1 (en) * 1998-11-24 2000-06-02 The Dow Chemical Company A composition containing a cross-linkable matrix precursor and a poragen, and a porous matrix prepared therefrom
US6156812A (en) 1999-04-09 2000-12-05 Honeywell International Inc. Nanoporous material fabricated using polymeric template strands
US6172128B1 (en) 1999-04-09 2001-01-09 Honeywell International Inc. Nanoporous polymers crosslinked via cyclic structures
US6359091B1 (en) 1999-11-22 2002-03-19 The Dow Chemical Company Polyarylene compositions with enhanced modulus profiles

Also Published As

Publication number Publication date
WO2003068825A8 (en) 2003-12-04
JP4447923B2 (ja) 2010-04-07
AU2003215182A1 (en) 2003-09-04
WO2003068825A3 (en) 2004-04-29
KR20040086381A (ko) 2004-10-08
AU2003215182A8 (en) 2003-09-04
EP1476416A2 (en) 2004-11-17
EP1476416B1 (en) 2015-12-30
CN1646463A (zh) 2005-07-27
KR100965394B1 (ko) 2010-06-24
TW200415157A (en) 2004-08-16
WO2003068825A2 (en) 2003-08-21
JP2005517745A (ja) 2005-06-16
CN100480226C (zh) 2009-04-22

Similar Documents

Publication Publication Date Title
US7635741B2 (en) Multifunctional monomers and their use in making cross-linked polymers and porous films
US5489623A (en) Photodefinable polymers containing perfluorocyclobutane groups
TW384295B (en) 2,7-substituted fluorene compounds, compositions comprising fluorene oligomers or polymers
TW200925175A (en) Directly photodefinable polymer compositions and methods thereof
TW200415156A (en) Composition for forming porous organic film
TW200415157A (en) Multifunctional monomers and their use in making cross-linked polymers and porous films
TW200918573A (en) Process for the synthesis of oligo/polythiophenes by a "one-pot" synthesis route
CN106750257A (zh) 一种高含氟量耐热聚芳醚树脂及其制备方法
TWI402282B (zh) 聚合物、包括該聚合物之薄膜形成組成物、用該組成物形成之絕緣膜及電子裝置
JP4694473B2 (ja) 多官能性の、非対称的に置換されたモノマー類、および、そのポリアリーレン組成物。
US7276188B2 (en) Organic dye molecules and nonlinear optical polymeric compounds containing chromophores
JP4637830B2 (ja) 多官能性の、置換モノマー類、および、そのポリアリーレン組成物
TWI286147B (en) Composition for film formation and insulating film
US7626059B2 (en) Multifunctional ethynyl substituted monomers and polyarylene compositions therefrom
US20070037894A1 (en) Multifunctional menomers and polyarylene compsotions therefrom
JP4688371B2 (ja) 含フッ素アリールエーテルケトン重合体
TWI248449B (en) Radially multi branched polymer and porous film using the same
TW492981B (en) Oligomer, uncured polymer or cured polymer, a process for forming an uncured polymer or a cured polymer, and an integrated circuit article
WO2006126415A1 (ja) 含硫黄環状オレフィン樹脂およびその製造方法
JP4885724B2 (ja) 結合メソゲン性ポラゲン形成性部分を含有する多官能性モノマー及びそれからのポリアリーレン組成物
JP2004263021A (ja) ポリエーテル樹脂および絶縁膜形成用塗布液
KR20010106181A (ko) 폴리에테르 공중합체
TW200304455A (en) Polyether and its production method
Schwegler et al. Synthesis of polyethylene oxide graft polysilylenes and networks based on poly (di‐n‐pentylsilylene/n‐pentyloct‐7‐enyl) copolymers
JP2002293890A (ja) デンドロン側鎖含有ポリフェニレンエチニレン

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees