TWI306081B - Hydrogen generating apparatus and hydrogen generating method using the hydrogen generating apparatus - Google Patents
Hydrogen generating apparatus and hydrogen generating method using the hydrogen generating apparatus Download PDFInfo
- Publication number
- TWI306081B TWI306081B TW095111879A TW95111879A TWI306081B TW I306081 B TWI306081 B TW I306081B TW 095111879 A TW095111879 A TW 095111879A TW 95111879 A TW95111879 A TW 95111879A TW I306081 B TWI306081 B TW I306081B
- Authority
- TW
- Taiwan
- Prior art keywords
- unit
- combustion
- group
- reaction
- reaction device
- Prior art date
Links
- 239000001257 hydrogen Substances 0.000 title claims description 129
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 129
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 121
- 238000000034 method Methods 0.000 title claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 429
- 238000002485 combustion reaction Methods 0.000 claims description 205
- 238000005215 recombination Methods 0.000 claims description 153
- 230000006798 recombination Effects 0.000 claims description 153
- 239000000446 fuel Substances 0.000 claims description 111
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 95
- 239000003054 catalyst Substances 0.000 claims description 72
- 239000002994 raw material Substances 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 35
- 239000007789 gas Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 33
- 238000002309 gasification Methods 0.000 claims description 19
- 238000007254 oxidation reaction Methods 0.000 claims description 17
- 239000007800 oxidant agent Substances 0.000 claims description 16
- 230000001590 oxidative effect Effects 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 230000003647 oxidation Effects 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 13
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000005304 joining Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000011364 vaporized material Substances 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 3
- 239000012071 phase Substances 0.000 claims 3
- 238000003786 synthesis reaction Methods 0.000 claims 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims 2
- 229910000431 copper oxide Inorganic materials 0.000 claims 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 1
- 239000005751 Copper oxide Substances 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims 1
- 238000000975 co-precipitation Methods 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000006104 solid solution Substances 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 18
- 229910002091 carbon monoxide Inorganic materials 0.000 description 18
- 229930182558 Sterol Natural products 0.000 description 12
- 150000003432 sterols Chemical class 0.000 description 12
- 235000003702 sterols Nutrition 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 150000002431 hydrogen Chemical class 0.000 description 8
- 230000008016 vaporization Effects 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- 239000002918 waste heat Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011112 process operation Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001651 catalytic steam reforming of methanol Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H3/00—Dolls
- A63H3/36—Details; Accessories
- A63H3/46—Connections for limbs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H3/00—Dolls
- A63H3/04—Dolls with deformable framework
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H3/00—Dolls
- A63H3/16—Dolls made of parts that can be put together
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H9/00—Special methods or compositions for the manufacture of dolls, toy animals, toy figures, or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00801—Means to assemble
- B01J2219/00804—Plurality of plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00822—Metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00835—Comprising catalytically active material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00851—Additional features
- B01J2219/00858—Aspects relating to the size of the reactor
- B01J2219/0086—Dimensions of the flow channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00851—Additional features
- B01J2219/00858—Aspects relating to the size of the reactor
- B01J2219/00862—Dimensions of the reaction cavity itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00873—Heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1223—Methanol
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20050027570 | 2005-04-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200711989A TW200711989A (en) | 2007-04-01 |
| TWI306081B true TWI306081B (en) | 2009-02-11 |
Family
ID=37087201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095111879A TWI306081B (en) | 2005-04-01 | 2006-04-03 | Hydrogen generating apparatus and hydrogen generating method using the hydrogen generating apparatus |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5252927B2 (ko) |
| KR (1) | KR100733582B1 (ko) |
| TW (1) | TWI306081B (ko) |
| WO (1) | WO2006109949A1 (ko) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100746344B1 (ko) * | 2006-05-19 | 2007-08-03 | 한국과학기술원 | 연소 촉매층을 함유하는 마이크로 채널 반응기 |
| TW201209225A (en) * | 2010-08-31 | 2012-03-01 | Li-Shui Tang | Hydrogen generation apparatus |
| US9333477B2 (en) * | 2011-04-15 | 2016-05-10 | Korea Institute Of Energy Research | Hydrocarbon reforming device using micro channel heater |
| KR101271398B1 (ko) * | 2011-05-09 | 2013-06-11 | 한국에너지기술연구원 | 미세유로 가열기를 이용한 적층형 탄화수소 개질장치 |
| US9819044B2 (en) * | 2013-11-04 | 2017-11-14 | Bosal Emission Control Systems Nv | Apparatus comprising a fuel cell unit and a component, and a stack component for use in such an apparatus |
| FR3015308B1 (fr) * | 2013-12-19 | 2017-10-13 | Air Liquide | Geometrie d'un reacteur catalytique alliant bonne tenue mecanique et bonne distribution des fluides |
| JP7257019B2 (ja) * | 2018-05-01 | 2023-04-13 | 東京都公立大学法人 | 水素製造触媒 |
| KR102579656B1 (ko) | 2018-05-30 | 2023-09-15 | 한화오션 주식회사 | 금속 롤을 이용한 연속 수소생산설비 |
| KR102324146B1 (ko) * | 2019-12-17 | 2021-11-08 | 전남대학교산학협력단 | 탄화수소계 연료를 이용한 수소 제조 장치 및 그 방법 |
| CN111302305B (zh) * | 2020-03-25 | 2021-09-28 | 哈尔滨工业大学 | 一种利用甲醇水蒸气重整的低一氧化碳微型氢气产生装置 |
| CN114162782B (zh) * | 2021-11-24 | 2022-12-02 | 德州新动能铁塔发电有限公司 | 一种制氢设备及方法 |
| CN114955994B (zh) * | 2022-06-14 | 2023-07-18 | 中南大学 | 一种醇类燃料裂解制氢装置以及系统 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05105404A (ja) * | 1991-10-21 | 1993-04-27 | Ishikawajima Harima Heavy Ind Co Ltd | プレート型リフオーマ |
| JPH06111838A (ja) * | 1992-09-30 | 1994-04-22 | Toshiba Corp | 改質器、改質システム、及び燃料電池システム |
| US5733347A (en) * | 1995-12-27 | 1998-03-31 | International Fuel Cells Corp. | Compact fuel gas reformer assemblage |
| DE19743673C2 (de) * | 1997-10-02 | 2002-05-08 | Xcellsis Gmbh | Vorrichtung zur Wasserstofferzeugung aus Kohlenwasserstoffen und Verfahren zur Herstellung eines Katalysators |
| JP4186329B2 (ja) | 1999-04-01 | 2008-11-26 | 三菱電機株式会社 | 燃料改質装置 |
| JP2001226104A (ja) | 2000-02-21 | 2001-08-21 | Suzuki Motor Corp | メタノール改質装置 |
| JP2002107073A (ja) * | 2000-09-28 | 2002-04-10 | Hitachi Ltd | 積層型熱交換器 |
| US6652830B2 (en) * | 2001-02-16 | 2003-11-25 | Battelle Memorial Institute | Catalysts reactors and methods of producing hydrogen via the water-gas shift reaction |
| JP4682476B2 (ja) * | 2001-08-01 | 2011-05-11 | カシオ計算機株式会社 | 加熱装置、改質装置及び燃料電池システム |
| JP2003089502A (ja) * | 2001-09-12 | 2003-03-28 | Suzuki Motor Corp | メタノール改質装置 |
| US7883670B2 (en) * | 2002-02-14 | 2011-02-08 | Battelle Memorial Institute | Methods of making devices by stacking sheets and processes of conducting unit operations using such devices |
| US6713032B2 (en) * | 2002-04-12 | 2004-03-30 | Matsushita Electric Works, Ltd. | Catalyst for removing carbon monoxide in hydrogen rich gas and production method therefor |
| JP3831688B2 (ja) * | 2002-06-21 | 2006-10-11 | 三菱重工業株式会社 | 改質器システム |
| JP3774445B2 (ja) * | 2003-03-27 | 2006-05-17 | 京セラ株式会社 | 燃料電池用容器および燃料電池 |
| JP4423847B2 (ja) * | 2002-10-25 | 2010-03-03 | カシオ計算機株式会社 | 小型化学反応装置 |
| JP4495419B2 (ja) * | 2002-11-11 | 2010-07-07 | パナソニック電工株式会社 | 燃焼装置および熱電発電装置 |
| JP2004261911A (ja) * | 2003-02-28 | 2004-09-24 | Mitsubishi Heavy Ind Ltd | チャンネル構造体及びその製造方法 |
| DE10317451A1 (de) * | 2003-04-16 | 2004-11-18 | Degussa Ag | Reaktor für heterogen katalysierte Reaktionen |
| JP4587016B2 (ja) * | 2003-05-30 | 2010-11-24 | ソニー株式会社 | 反応装置とその製造方法、改質装置、電源供給システム |
| JP4486429B2 (ja) * | 2003-07-14 | 2010-06-23 | 大日本印刷株式会社 | 水素製造用のマイクロリアクターおよびその製造方法 |
| KR100551062B1 (ko) * | 2004-06-29 | 2006-02-13 | 삼성에스디아이 주식회사 | 연료 전지 시스템, 이에 사용되는 개질기 및 그 제조 방법 |
-
2006
- 2006-04-03 KR KR1020060030253A patent/KR100733582B1/ko active IP Right Grant
- 2006-04-03 TW TW095111879A patent/TWI306081B/zh active
- 2006-04-03 WO PCT/KR2006/001219 patent/WO2006109949A1/en active Application Filing
- 2006-04-03 JP JP2007556092A patent/JP5252927B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP5252927B2 (ja) | 2013-07-31 |
| TW200711989A (en) | 2007-04-01 |
| WO2006109949A1 (en) | 2006-10-19 |
| KR20060106778A (ko) | 2006-10-12 |
| KR100733582B1 (ko) | 2007-06-28 |
| JP2008529953A (ja) | 2008-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI306081B (en) | Hydrogen generating apparatus and hydrogen generating method using the hydrogen generating apparatus | |
| US9493350B2 (en) | Method and system for the production of hydrogen | |
| JP6002249B2 (ja) | 水素生成のための触媒燃焼式熱統合型改質器 | |
| CN104603402B (zh) | 太阳能热化学处理系统和利用其的方法 | |
| AU2010253491B2 (en) | Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas | |
| Siriwardane et al. | Production of pure hydrogen and synthesis gas with Cu–Fe oxygen carriers using combined processes of chemical looping combustion and methane decomposition/reforming | |
| US20010018140A1 (en) | Catalytic burner element inside a fuel cell with structured catalytic coated surfaces | |
| US20030172589A1 (en) | Steam-reforming catalytic structure and pure hydrogen generator comprising the same and method of operation of same | |
| WO2003067698A1 (fr) | Systeme de pile a combustible a oxyde solide | |
| Giaconia et al. | Multi-fuelled solar steam reforming for pure hydrogen production using solar salts as heat transfer fluid | |
| JP2007238341A (ja) | 水素発生装置および水素添加反応装置 | |
| CA2428548C (en) | Methanol-steam reformer | |
| TW200937721A (en) | System and process for generating electrical power | |
| JP2007128716A (ja) | 燃料電池 | |
| US20060137246A1 (en) | System and method for hydrogen production | |
| JP2004502623A (ja) | 熱交換膜反応装置による発電 | |
| Yadav et al. | Advancements in microreactor technology for hydrogen production via steam reforming: A comprehensive review of experimental studies | |
| WO2001019727A1 (fr) | Appareil de production de gaz hydrogene et dispositif de pile a combustible | |
| US20070056247A1 (en) | Combustion of gaseous fuel | |
| JP6974402B2 (ja) | 改質ガスを消費するプラント及び原料ガスを改質する方法 | |
| US20070033873A1 (en) | Hydrogen gas generator | |
| JPH06325783A (ja) | 内部改質型溶融炭酸塩型燃料電池システム | |
| JPH0450246B2 (ko) | ||
| JP5301265B2 (ja) | 酸素生成装置と水素生成装置とを備える燃料電池システム | |
| Zhang et al. | Development of Methane Steam Reformer for Domestic Fuel Cell by Using Electro-Thermal Alumite Catalyst |