TWI256340B - Aqueous urethane resin composition for forming pores, process for producing fiber sheet-shape composite - Google Patents
Aqueous urethane resin composition for forming pores, process for producing fiber sheet-shape compositeInfo
- Publication number
- TWI256340B TWI256340B TW089101621A TW89101621A TWI256340B TW I256340 B TWI256340 B TW I256340B TW 089101621 A TW089101621 A TW 089101621A TW 89101621 A TW89101621 A TW 89101621A TW I256340 B TWI256340 B TW I256340B
- Authority
- TW
- Taiwan
- Prior art keywords
- urethane resin
- aqueous urethane
- resin composition
- heat
- fiber sheet
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6644—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2435199 | 1999-02-01 | ||
JP3065999 | 1999-02-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
TWI256340B true TWI256340B (en) | 2006-06-11 |
Family
ID=26361851
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW089101621A TWI256340B (en) | 1999-02-01 | 2000-01-31 | Aqueous urethane resin composition for forming pores, process for producing fiber sheet-shape composite |
Country Status (7)
Country | Link |
---|---|
US (1) | US6794446B1 (zh) |
EP (1) | EP1164169B1 (zh) |
KR (1) | KR100501660B1 (zh) |
AT (1) | ATE293716T1 (zh) |
DE (1) | DE60019569T2 (zh) |
TW (1) | TWI256340B (zh) |
WO (1) | WO2000046301A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102803602A (zh) * | 2010-03-16 | 2012-11-28 | 东丽株式会社 | 片状物及其制造方法 |
TWI642724B (zh) * | 2013-09-06 | 2018-12-01 | 日商迪愛生股份有限公司 | 胺基甲酸酯樹脂組成物、皮革樣片及皮革樣片之製造方法 |
TWI688618B (zh) * | 2015-03-03 | 2020-03-21 | 日商迪愛生股份有限公司 | 皮革樣片之製造方法 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7071241B2 (en) * | 2000-02-28 | 2006-07-04 | Matsumoto Yushi-Seiyaku Co., Ltd. | Process for producing porous object |
JP3796573B2 (ja) | 2001-06-12 | 2006-07-12 | 帝人コードレ株式会社 | 多孔性シート、繊維複合シートおよびそれらの製造方法 |
ATE437264T1 (de) | 2002-04-10 | 2009-08-15 | Alcantara Spa | Verfahren zur herstellung eines mikrofasrigen, wildlederähnlichen vliesstoffes |
JP4570964B2 (ja) * | 2002-12-20 | 2010-10-27 | ダウ グローバル テクノロジーズ インコーポレイティド | 合成皮革を製造するための方法及びそれから製造した合成皮革 |
US20040249106A1 (en) * | 2003-06-03 | 2004-12-09 | Gindin Lyubov K. | Modified polyurethanes |
TWI275679B (en) * | 2004-09-16 | 2007-03-11 | San Fang Chemical Industry Co | Artificial leather materials having elongational elasticity |
US20060116454A1 (en) * | 2004-12-01 | 2006-06-01 | Bedri Erdem | Stable thermally coaguable polyurethane dispersions |
TWI301166B (en) * | 2005-03-30 | 2008-09-21 | San Fang Chemical Industry Co | Manufacturing method for environment friendly artificial leather made from ultramicro fiber without solvent treatment |
TWI297049B (en) * | 2005-05-17 | 2008-05-21 | San Fang Chemical Industry Co | Artificial leather having ultramicro fiber in conjugate fiber of substrate |
JP4788551B2 (ja) * | 2005-11-30 | 2011-10-05 | 東レ株式会社 | 皮革様シート状物、その製造方法、並びにそれを用いてなる内装材、衣料用資材及び工業用資材 |
TW200825244A (en) | 2006-12-13 | 2008-06-16 | San Fang Chemical Industry Co | Flexible artificial leather and its manufacturing method |
ES2378504T3 (es) * | 2008-06-10 | 2012-04-13 | Dow Global Technologies Inc. | Procedimiento para preparar una espuma rígida de poliuretano a partir de polioles iniciados con metilenbis(ciclohexilamina) |
CN102083618B (zh) * | 2009-06-01 | 2015-04-08 | 东洋纺高机能制品贸易株式会社 | 透湿防水性布料及其制备方法 |
IT1397868B1 (it) * | 2010-02-11 | 2013-02-04 | Same S R L | Procedimento per la produzione di tessuti spalmati con poliuretano coagulato. |
EP2361939B1 (de) | 2010-02-25 | 2012-08-22 | Cognis IP Management GmbH | Verdickungsmittel auf Polyurethanbasis |
US20110244746A1 (en) * | 2010-04-02 | 2011-10-06 | Valley Forge Fabrics, Inc. | Synthetic leather fabric with lyocell backing and method of producing the same |
JP5706897B2 (ja) * | 2010-07-12 | 2015-04-22 | 株式会社クラレ | 皮膜形成方法、及び皮膜 |
WO2015129602A1 (ja) * | 2014-02-27 | 2015-09-03 | 東レ株式会社 | シート状物およびその製造方法 |
TWI629298B (zh) * | 2014-09-30 | 2018-07-11 | 東麗股份有限公司 | Sheet material manufacturing method |
WO2017169244A1 (ja) * | 2016-04-01 | 2017-10-05 | Dic株式会社 | 一液型水性樹脂組成物、及び、繊維積層体 |
EP3444286B1 (en) * | 2016-04-14 | 2023-01-11 | DIC Corporation | Water-based urethane resin composition and synthetic leather |
JP6323620B1 (ja) * | 2016-06-01 | 2018-05-16 | Dic株式会社 | 凝固物の製造方法 |
EP3910024A4 (en) * | 2019-02-25 | 2022-03-23 | DIC Corporation | AQUEOUS URETHANE RESIN DISPERSION, LEATHER SHEET AND LEATHER SHEET PRODUCTION METHOD |
KR20200114340A (ko) | 2019-03-28 | 2020-10-07 | 코오롱인더스트리 주식회사 | 인공피혁의 제조방법 |
US20240109999A1 (en) * | 2019-10-28 | 2024-04-04 | Dic Corporation | Fiber base material and artificial leather |
IT202200003428A1 (it) | 2022-02-24 | 2023-08-24 | Lamberti Spa | Metodo di produzione di un materiale similpelle |
CN114908571B (zh) * | 2022-05-17 | 2023-10-17 | 陕西科技大学 | 一种蒸汽凝聚复合制备水性聚氨酯超纤革的方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4079028A (en) * | 1975-10-03 | 1978-03-14 | Rohm And Haas Company | Polyurethane thickeners in latex compositions |
JPS5480349A (en) | 1977-12-06 | 1979-06-27 | Rohm & Haas | Polyurethane thickener for latex composition |
US4496624A (en) * | 1982-07-14 | 1985-01-29 | Norwood Industries, Inc. | Fibrous web impregnated with coagulated polyurethane and polyolefin admixture |
US4707400A (en) * | 1986-09-03 | 1987-11-17 | Burlington Industries, Inc. | Thickening of water-coagulable solvent coating solutions |
DE3633874A1 (de) * | 1986-10-04 | 1988-04-14 | Stockhausen Chem Fab Gmbh | Verfahren zur herstellung mit polyurethan beschichteter textiler flaechengebilde, mit polyurethan beschichtete textile flaechengebilde und ihre verwendung zur herstellung atmungsaktiver und wasserabweisender ausruestungen |
JPH0635712B2 (ja) * | 1989-09-06 | 1994-05-11 | 鐘紡株式会社 | 透湿性、柔軟性および機械的強度に優れた人工皮革およびその製造方法 |
US5574083A (en) * | 1993-06-11 | 1996-11-12 | Rohm And Haas Company | Aromatic polycarbodiimide crosslinkers |
EP0674039A3 (de) * | 1994-03-22 | 1999-11-24 | Bayer Ag | Verfahren zur Textilbeschichtung |
US5741828A (en) * | 1995-05-01 | 1998-04-21 | S.K.Y. Polymers, Inc. | Flexible hydrophilic composite coatings |
US5733967A (en) * | 1996-08-20 | 1998-03-31 | Bayer Corporation | Aqueous polyurethane dispersions and their use for preparing coatings with excellent hydrolytic and thermal stability |
JPH1192653A (ja) * | 1997-09-22 | 1999-04-06 | Asahi Denka Kogyo Kk | 水系ポリウレタン樹脂組成物 |
US5916636A (en) * | 1998-03-17 | 1999-06-29 | Milliken & Company | Method of making a polyurethane suede-like fabric/elastomer composite |
DE19847791A1 (de) * | 1998-10-16 | 2000-04-20 | Bayer Ag | Wäßrige Polyurethandispersionen |
BR9914833B1 (pt) * | 1998-10-26 | 2008-11-18 | composiÇço aquosa de revestimento. |
-
2000
- 2000-01-31 TW TW089101621A patent/TWI256340B/zh not_active IP Right Cessation
- 2000-02-01 DE DE60019569T patent/DE60019569T2/de not_active Expired - Lifetime
- 2000-02-01 KR KR10-2001-7009724A patent/KR100501660B1/ko active IP Right Grant
- 2000-02-01 WO PCT/JP2000/000536 patent/WO2000046301A1/ja active IP Right Grant
- 2000-02-01 EP EP00902036A patent/EP1164169B1/en not_active Expired - Lifetime
- 2000-02-01 AT AT00902036T patent/ATE293716T1/de active
-
2001
- 2001-02-01 US US09/889,570 patent/US6794446B1/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102803602A (zh) * | 2010-03-16 | 2012-11-28 | 东丽株式会社 | 片状物及其制造方法 |
TWI642724B (zh) * | 2013-09-06 | 2018-12-01 | 日商迪愛生股份有限公司 | 胺基甲酸酯樹脂組成物、皮革樣片及皮革樣片之製造方法 |
TWI688618B (zh) * | 2015-03-03 | 2020-03-21 | 日商迪愛生股份有限公司 | 皮革樣片之製造方法 |
Also Published As
Publication number | Publication date |
---|---|
KR20010112255A (ko) | 2001-12-20 |
EP1164169A4 (en) | 2002-12-04 |
KR100501660B1 (ko) | 2005-07-18 |
US6794446B1 (en) | 2004-09-21 |
ATE293716T1 (de) | 2005-05-15 |
EP1164169A1 (en) | 2001-12-19 |
DE60019569T2 (de) | 2006-02-23 |
WO2000046301A1 (fr) | 2000-08-10 |
EP1164169B1 (en) | 2005-04-20 |
DE60019569D1 (de) | 2005-05-25 |
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