TWI243708B - Hydrothermally synthesized Mo-V-M-X oxide catalysts for the selective oxidation of hydrocarbons - Google Patents
Hydrothermally synthesized Mo-V-M-X oxide catalysts for the selective oxidation of hydrocarbons Download PDFInfo
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- TWI243708B TWI243708B TW091112636A TW91112636A TWI243708B TW I243708 B TWI243708 B TW I243708B TW 091112636 A TW091112636 A TW 091112636A TW 91112636 A TW91112636 A TW 91112636A TW I243708 B TWI243708 B TW I243708B
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- 239000003054 catalyst Substances 0.000 title claims abstract description 159
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 51
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 6
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- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
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- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
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- 229960004889 salicylic acid Drugs 0.000 description 1
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- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940096017 silver fluoride Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
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- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 description 1
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- CLDWGXZGFUNWKB-UHFFFAOYSA-M silver;benzoate Chemical compound [Ag+].[O-]C(=O)C1=CC=CC=C1 CLDWGXZGFUNWKB-UHFFFAOYSA-M 0.000 description 1
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- 241000894007 species Species 0.000 description 1
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- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
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- 230000035900 sweating Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
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- 239000000057 synthetic resin Substances 0.000 description 1
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- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 1
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- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
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- OMDXFCRSKHYDTM-UHFFFAOYSA-J thorium(4+);tetrabromide Chemical compound Br[Th](Br)(Br)Br OMDXFCRSKHYDTM-UHFFFAOYSA-J 0.000 description 1
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- KBXXFKPVKJZGJG-UHFFFAOYSA-K tribromoiridium;hydrate Chemical compound O.Br[Ir](Br)Br KBXXFKPVKJZGJG-UHFFFAOYSA-K 0.000 description 1
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 1
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- UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 1
- 229940041260 vanadyl sulfate Drugs 0.000 description 1
- 229910000352 vanadyl sulfate Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003746 yttrium Chemical class 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
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- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| US6919472B2 (en) * | 2001-12-21 | 2005-07-19 | Saudi Basic Industries Corporation | Catalyst compositions for the selective conversion of alkanes to unsaturated carboxylic acids, methods of making and methods of using thereof |
| DE10247784A1 (de) * | 2002-10-14 | 2004-04-22 | Bayer Ag | Ein Katalysator für die Oxidation von Kohlenwasserstoffen zu Epoxiden |
| JP4155034B2 (ja) * | 2003-01-21 | 2008-09-24 | 東亞合成株式会社 | 金属酸化物触媒の製造方法 |
| US8383158B2 (en) * | 2003-04-15 | 2013-02-26 | Abbott Cardiovascular Systems Inc. | Methods and compositions to treat myocardial conditions |
| US20050054869A1 (en) * | 2003-06-06 | 2005-03-10 | Lugmair Claus G. | Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same |
| US7642214B2 (en) * | 2003-06-10 | 2010-01-05 | Nippon Kayaku Kabushiki Kaisha | Catalyst for oxidation of alkane, process for preparing thereof and process for producing unsaturated oxygen-containing compound |
| DE102004009985A1 (de) | 2004-03-01 | 2005-09-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Magnetische Manipulation von biologischen Proben |
| BRPI0500615B1 (pt) * | 2004-03-10 | 2015-07-14 | Rohm And Haas Company | Catalisador modificado, e, sistema de catalisador modificado |
| US7009075B2 (en) * | 2004-06-30 | 2006-03-07 | Saudi Basic Industries Corporation | Process for the selective conversion of alkanes to unsaturated carboxylic acids |
| US20060122055A1 (en) * | 2004-12-06 | 2006-06-08 | Gaffney Anne M | (Amm)oxidation catalyst and catalytic (amm)oxidation process for conversion of lower alkanes |
| EP1693107A1 (en) | 2005-02-11 | 2006-08-23 | Rohm And Haas Company | Method for preparing mixed-metal oxide catalysts and the catalysts produced thereby |
| US20060183626A1 (en) * | 2005-02-11 | 2006-08-17 | Cavalcanti Fernando Antonio Pe | Process for preparing catalysts and catalysts produced therefrom |
| DE102006018886A1 (de) * | 2006-04-18 | 2007-10-31 | Leibnitz-Institut für Katalyse e.V. an der Universität Rostock | Vanadiumhaltige Mischoxide des Cs(WNb)5O14 - Strukturtyps |
| US7875571B2 (en) * | 2006-09-07 | 2011-01-25 | Rohm And Haas Company | Activated mixed metal oxide oxidation catalysts |
| KR100962082B1 (ko) * | 2008-07-31 | 2010-06-09 | 희성촉매 주식회사 | 수소를 이용한 질소산화물의 환원제거용 촉매 및 이를이용한 질소산화물의 환원제거 방법 |
| TR201900712T4 (tr) * | 2009-01-30 | 2019-02-21 | Asahi Chemical Ind | Silika destekli katalizörün üretilmesine yönelik yöntem. |
| CA3005637A1 (en) | 2015-11-16 | 2017-05-26 | HHeLI, LLC | Synthesized, surface-functionalized, acidified metal oxide materials for energy storage, catalytic, photovoltaic, and sensor applications |
| WO2020252389A1 (en) | 2019-06-12 | 2020-12-17 | HHeLI, LLC | Blended active materials for battery cells |
| WO2018093945A1 (en) | 2016-11-15 | 2018-05-24 | Hheli, Llc. | A surface-functionalized, acidified metal oxide material in an acidified electrolyte system or an acidified electrode system |
| KR20200015476A (ko) | 2017-04-10 | 2020-02-12 | 에이치헬리, 엘엘씨 | 신규 성분을 가진 배터리 |
| KR102721312B1 (ko) | 2017-05-17 | 2024-10-24 | 에이치헬리, 엘엘씨 | 산성화 캐소드와 리튬 애노드를 가진 배터리 |
| KR20200008587A (ko) | 2017-05-17 | 2020-01-28 | 에이치헬리, 엘엘씨 | 신규 구성을 가진 배터리 셀 |
| US10978731B2 (en) | 2017-06-21 | 2021-04-13 | HHeLI, LLC | Ultra high capacity performance battery cell |
| US11165090B2 (en) | 2017-09-22 | 2021-11-02 | HHeLI, LLC | Construction of ultra high capacity performance battery cells |
| US11283267B2 (en) | 2018-09-10 | 2022-03-22 | HHeLI, LLC | Methods of use of ultra high capacity performance battery cell |
| CN113661002A (zh) | 2019-05-02 | 2021-11-16 | 陶氏环球技术有限责任公司 | 使用高活性和选择性催化剂在丙烯酸生产中减少醛副产物的方法 |
| US12278342B2 (en) | 2019-06-12 | 2025-04-15 | HHeLI, LLC | Alkaline and acidified metal oxide blended active materials |
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| CN111569924B (zh) * | 2020-04-22 | 2023-08-22 | 中南民族大学 | 氨氧化法制备2,6-二氯苯腈的专用催化剂及其制备方法和用途 |
| CN119776892B (zh) * | 2024-12-31 | 2025-11-21 | 广东工业大学 | 一种碳包覆二氧化铱电解水制氢催化剂及其制备方法和应用 |
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|---|---|---|---|---|
| TW218008B (enExample) * | 1991-05-09 | 1993-12-21 | Mitsubishi Chemicals Co Ltd | |
| KR930004254A (ko) * | 1991-08-08 | 1993-03-22 | 에또 다께또시 | 니트릴의 제조방법 |
| EP0608838B1 (en) * | 1993-01-28 | 1997-04-16 | Mitsubishi Chemical Corporation | Method for producing an unsaturated carboxylic acid |
| JP3500663B2 (ja) | 1993-08-18 | 2004-02-23 | 三菱化学株式会社 | アクリル酸の製造方法 |
| JP2000143244A (ja) | 1998-07-24 | 2000-05-23 | Mitsubishi Chemicals Corp | 複合金属酸化物の製造方法 |
| AU5445599A (en) * | 1998-08-28 | 2000-03-21 | Asahi Kasei Kabushiki Kaisha | Method for producing oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane |
| US6043185A (en) * | 1999-04-02 | 2000-03-28 | The Standard Oil Company | Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
-
2002
- 2002-06-07 DE DE60210709T patent/DE60210709T2/de not_active Expired - Lifetime
- 2002-06-07 EP EP02253989A patent/EP1270068B1/en not_active Expired - Lifetime
- 2002-06-10 US US10/165,892 patent/US6746983B2/en not_active Expired - Fee Related
- 2002-06-11 TW TW091112636A patent/TWI243708B/zh active
- 2002-06-13 MX MXPA02005875A patent/MXPA02005875A/es unknown
- 2002-06-17 BR BR0202283-4A patent/BR0202283A/pt active Search and Examination
- 2002-06-18 KR KR1020020034031A patent/KR100905958B1/ko not_active Expired - Fee Related
- 2002-06-18 JP JP2002176924A patent/JP2003088758A/ja not_active Ceased
- 2002-06-18 CN CNB02122658XA patent/CN1275694C/zh not_active Expired - Fee Related
-
2004
- 2004-03-23 US US10/806,582 patent/US7074956B2/en not_active Expired - Fee Related
-
2006
- 2006-01-04 US US11/324,909 patent/US20060106244A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003088758A (ja) | 2003-03-25 |
| BR0202283A (pt) | 2003-04-22 |
| CN1275694C (zh) | 2006-09-20 |
| EP1270068A1 (en) | 2003-01-02 |
| US7074956B2 (en) | 2006-07-11 |
| US20030004379A1 (en) | 2003-01-02 |
| US20060106244A1 (en) | 2006-05-18 |
| CN1395997A (zh) | 2003-02-12 |
| US6746983B2 (en) | 2004-06-08 |
| KR20020096982A (ko) | 2002-12-31 |
| US20040181084A1 (en) | 2004-09-16 |
| MXPA02005875A (es) | 2005-09-08 |
| KR100905958B1 (ko) | 2009-07-06 |
| EP1270068B1 (en) | 2006-04-19 |
| DE60210709T2 (de) | 2007-01-11 |
| DE60210709D1 (de) | 2006-05-24 |
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