TW594058B - Reflective sheet treated with fluorosilane - Google Patents
Reflective sheet treated with fluorosilane Download PDFInfo
- Publication number
- TW594058B TW594058B TW091111562A TW91111562A TW594058B TW 594058 B TW594058 B TW 594058B TW 091111562 A TW091111562 A TW 091111562A TW 91111562 A TW91111562 A TW 91111562A TW 594058 B TW594058 B TW 594058B
- Authority
- TW
- Taiwan
- Prior art keywords
- reflective
- fluorinated
- group
- reflective sheet
- microspheres
- Prior art date
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- XPBBUZJBQWWFFJ-UHFFFAOYSA-N fluorosilane Chemical compound [SiH3]F XPBBUZJBQWWFFJ-UHFFFAOYSA-N 0.000 title description 5
- 239000004005 microsphere Substances 0.000 claims abstract description 89
- -1 fluorinated silane compound Chemical class 0.000 claims abstract description 30
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000010410 layer Substances 0.000 claims description 78
- 239000012790 adhesive layer Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 15
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 11
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 125000005647 linker group Chemical group 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 125000006162 fluoroaliphatic group Chemical group 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims 2
- 206010029412 Nightmare Diseases 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 238000006884 silylation reaction Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 31
- 229920000642 polymer Polymers 0.000 description 25
- 238000005406 washing Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 150000004756 silanes Chemical class 0.000 description 13
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- 238000005259 measurement Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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- 229920000728 polyester Polymers 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 4
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- 125000005842 heteroatom Chemical group 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 125000004429 atom Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
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- 241000282376 Panthera tigris Species 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
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- 239000013039 cover film Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
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- AVXLXFZNRNUCRP-UHFFFAOYSA-N trichloro(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)silane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[Si](Cl)(Cl)Cl AVXLXFZNRNUCRP-UHFFFAOYSA-N 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 1
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 1
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- 239000003981 vehicle Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01202053A EP1262802B1 (en) | 2001-05-31 | 2001-05-31 | Reflective sheet treated with fluorosilane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW594058B true TW594058B (en) | 2004-06-21 |
Family
ID=8180394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091111562A TW594058B (en) | 2001-05-31 | 2002-05-30 | Reflective sheet treated with fluorosilane |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1262802B1 (enExample) |
| JP (1) | JP2004533013A (enExample) |
| KR (1) | KR20040004634A (enExample) |
| CN (1) | CN1273844C (enExample) |
| AR (1) | AR034050A1 (enExample) |
| AT (1) | ATE302958T1 (enExample) |
| AU (1) | AU2002305312B9 (enExample) |
| BR (1) | BR0210035A (enExample) |
| CA (1) | CA2446850A1 (enExample) |
| DE (1) | DE60112901T2 (enExample) |
| MX (1) | MXPA03010571A (enExample) |
| TW (1) | TW594058B (enExample) |
| WO (1) | WO2002099476A2 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7247386B2 (en) * | 2003-12-23 | 2007-07-24 | 3M Innovative Properties Company | Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet |
| US7195360B2 (en) | 2004-12-28 | 2007-03-27 | 3M Innovative Properties Company | Prismatic retroreflective article and method |
| KR20130008643A (ko) | 2004-12-28 | 2013-01-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 불소- 또는 규소-함유 프리즘을 갖는 프리즘 역반사 물품 |
| US20120148848A1 (en) * | 2010-12-10 | 2012-06-14 | Martin David C | Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods |
| KR101657568B1 (ko) | 2015-04-22 | 2016-09-19 | (주) 숲으로벽지 | 내오염성과 내마모성이 향상된 천연소재를 이용한 수성발포 벽지 |
| KR102563668B1 (ko) * | 2020-12-18 | 2023-08-04 | 홍익대학교 산학협력단 | 재귀반사 특성이 우수한 경계석 부착용 커버 및 그 제조방법 |
| JP2023117031A (ja) * | 2022-02-10 | 2023-08-23 | Ｍｉｐｏｘ株式会社 | 再帰性反射布および衣類 |
| CN116061352B (zh) * | 2022-12-30 | 2025-11-14 | 中国电信股份有限公司 | 一种微流控光导开关制备方法、开关和开关模具 |
| DE102024112160A1 (de) * | 2024-04-30 | 2025-10-30 | Valkental Gmbh | Reflektierendes Textilmaterial |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3646085A (en) * | 1970-09-24 | 1972-02-29 | Du Pont | Perfluoroalkyletheramidoalkyltrialkoxysilanes |
| EP0497189B1 (en) * | 1991-01-23 | 1997-04-09 | Matsushita Electric Industrial Co., Ltd. | Water- and oil-repelling absorbed film and method of manufacturing the same |
| JP2774743B2 (ja) * | 1992-09-14 | 1998-07-09 | 松下電器産業株式会社 | 撥水部材及びその製造方法 |
| JPH08309929A (ja) * | 1995-05-19 | 1996-11-26 | Unitika Ltd | 再帰性反射布帛 |
| GB2347366A (en) * | 1999-03-05 | 2000-09-06 | Reflective Technology Ind Ltd | Reflective tape |
| US6548164B1 (en) * | 1999-06-30 | 2003-04-15 | 3M Innovative Properties Company | Removable sheeting |
-
2001
- 2001-05-31 EP EP01202053A patent/EP1262802B1/en not_active Expired - Lifetime
- 2001-05-31 DE DE60112901T patent/DE60112901T2/de not_active Expired - Fee Related
- 2001-05-31 AT AT01202053T patent/ATE302958T1/de not_active IP Right Cessation
-
2002
- 2002-04-30 WO PCT/US2002/013791 patent/WO2002099476A2/en not_active Ceased
- 2002-04-30 JP JP2003502537A patent/JP2004533013A/ja active Pending
- 2002-04-30 CA CA002446850A patent/CA2446850A1/en not_active Abandoned
- 2002-04-30 KR KR10-2003-7015100A patent/KR20040004634A/ko not_active Ceased
- 2002-04-30 BR BR0210035-5A patent/BR0210035A/pt not_active IP Right Cessation
- 2002-04-30 CN CNB028111478A patent/CN1273844C/zh not_active Expired - Fee Related
- 2002-04-30 AU AU2002305312A patent/AU2002305312B9/en not_active Expired - Fee Related
- 2002-04-30 MX MXPA03010571A patent/MXPA03010571A/es active IP Right Grant
- 2002-05-29 AR ARP020101997A patent/AR034050A1/es not_active Application Discontinuation
- 2002-05-30 TW TW091111562A patent/TW594058B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1537243A (zh) | 2004-10-13 |
| MXPA03010571A (es) | 2004-07-01 |
| AU2002305312B2 (en) | 2008-04-03 |
| BR0210035A (pt) | 2004-08-10 |
| CA2446850A1 (en) | 2002-12-12 |
| DE60112901D1 (de) | 2005-09-29 |
| DE60112901T2 (de) | 2006-06-14 |
| KR20040004634A (ko) | 2004-01-13 |
| ATE302958T1 (de) | 2005-09-15 |
| JP2004533013A (ja) | 2004-10-28 |
| AU2002305312B9 (en) | 2008-05-29 |
| AR034050A1 (es) | 2004-01-21 |
| WO2002099476A2 (en) | 2002-12-12 |
| EP1262802B1 (en) | 2005-08-24 |
| CN1273844C (zh) | 2006-09-06 |
| EP1262802A1 (en) | 2002-12-04 |
| WO2002099476A3 (en) | 2003-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |