TW574070B - Halogen promoted multi-metal oxide catalyst - Google Patents
Halogen promoted multi-metal oxide catalyst Download PDFInfo
- Publication number
- TW574070B TW574070B TW090123927A TW90123927A TW574070B TW 574070 B TW574070 B TW 574070B TW 090123927 A TW090123927 A TW 090123927A TW 90123927 A TW90123927 A TW 90123927A TW 574070 B TW574070 B TW 574070B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- mixture
- element selected
- gas
- alkanes
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 104
- 229910052736 halogen Inorganic materials 0.000 title claims description 8
- 150000002367 halogens Chemical class 0.000 title claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 87
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 73
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 55
- 150000001336 alkenes Chemical class 0.000 claims abstract description 40
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims abstract description 28
- 230000003647 oxidation Effects 0.000 claims abstract description 26
- 150000002825 nitriles Chemical class 0.000 claims abstract description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 45
- 239000012018 catalyst precursor Substances 0.000 claims description 37
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 31
- 238000001354 calcination Methods 0.000 claims description 31
- 230000003197 catalytic effect Effects 0.000 claims description 26
- 229910052750 molybdenum Inorganic materials 0.000 claims description 26
- 229910052697 platinum Inorganic materials 0.000 claims description 25
- 229910052792 caesium Inorganic materials 0.000 claims description 24
- 229910052759 nickel Inorganic materials 0.000 claims description 24
- 229910052738 indium Inorganic materials 0.000 claims description 23
- 229910052749 magnesium Inorganic materials 0.000 claims description 23
- 229910052758 niobium Inorganic materials 0.000 claims description 23
- 229910052718 tin Inorganic materials 0.000 claims description 23
- 229910052720 vanadium Inorganic materials 0.000 claims description 23
- 229910052790 beryllium Inorganic materials 0.000 claims description 22
- 229910052742 iron Inorganic materials 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 229910052701 rubidium Inorganic materials 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 22
- 229910052791 calcium Inorganic materials 0.000 claims description 21
- 229910052804 chromium Inorganic materials 0.000 claims description 21
- 229910052730 francium Inorganic materials 0.000 claims description 21
- 229910052732 germanium Inorganic materials 0.000 claims description 21
- 229910052744 lithium Inorganic materials 0.000 claims description 21
- 229910052748 manganese Inorganic materials 0.000 claims description 21
- 229910052700 potassium Inorganic materials 0.000 claims description 21
- 229910052703 rhodium Inorganic materials 0.000 claims description 21
- 229910052707 ruthenium Inorganic materials 0.000 claims description 21
- 229910052708 sodium Inorganic materials 0.000 claims description 21
- 229910052785 arsenic Inorganic materials 0.000 claims description 20
- 229910052735 hafnium Inorganic materials 0.000 claims description 20
- 229910052712 strontium Inorganic materials 0.000 claims description 20
- 229910052715 tantalum Inorganic materials 0.000 claims description 20
- 229910052719 titanium Inorganic materials 0.000 claims description 20
- 229910052721 tungsten Inorganic materials 0.000 claims description 20
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 19
- 229910052693 Europium Inorganic materials 0.000 claims description 19
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 19
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 19
- 229910052731 fluorine Inorganic materials 0.000 claims description 19
- 229910052745 lead Inorganic materials 0.000 claims description 19
- 229910052698 phosphorus Inorganic materials 0.000 claims description 18
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- 229910021529 ammonia Inorganic materials 0.000 claims description 15
- -1 C Wang Inorganic materials 0.000 claims description 14
- 229910052691 Erbium Inorganic materials 0.000 claims description 14
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- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims 1
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- 229910052786 argon Inorganic materials 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000000126 substance Substances 0.000 description 18
- 239000011651 chromium Substances 0.000 description 17
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
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- 150000003842 bromide salts Chemical class 0.000 description 1
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- 238000002485 combustion reaction Methods 0.000 description 1
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- 239000008367 deionised water Substances 0.000 description 1
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- DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- DCSRPHQBFSYJNN-UHFFFAOYSA-L disodium 4-[(2-arsonophenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Oc1c(N=Nc2ccccc2[As](O)(O)=O)c2ccc(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O DCSRPHQBFSYJNN-UHFFFAOYSA-L 0.000 description 1
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- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
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- LNDHQUDDOUZKQV-UHFFFAOYSA-J molybdenum tetrafluoride Chemical compound F[Mo](F)(F)F LNDHQUDDOUZKQV-UHFFFAOYSA-J 0.000 description 1
- QKKCMWPOASMDQR-UHFFFAOYSA-J molybdenum(4+);tetraiodide Chemical compound I[Mo](I)(I)I QKKCMWPOASMDQR-UHFFFAOYSA-J 0.000 description 1
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- 231100000252 nontoxic Toxicity 0.000 description 1
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- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
- NFVUDQKTAWONMJ-UHFFFAOYSA-I pentafluorovanadium Chemical compound [F-].[F-].[F-].[F-].[F-].[V+5] NFVUDQKTAWONMJ-UHFFFAOYSA-I 0.000 description 1
- FWIYBTVHGYLSAZ-UHFFFAOYSA-I pentaiodoniobium Chemical compound I[Nb](I)(I)(I)I FWIYBTVHGYLSAZ-UHFFFAOYSA-I 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
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- 235000019699 ravioli Nutrition 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
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- 241000894007 species Species 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- SWLJJEFSPJCUBD-UHFFFAOYSA-N tellurium tetrachloride Chemical compound Cl[Te](Cl)(Cl)Cl SWLJJEFSPJCUBD-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- MPVSPHKBQDMOHE-UHFFFAOYSA-J tetrabromoosmium Chemical compound Br[Os](Br)(Br)Br MPVSPHKBQDMOHE-UHFFFAOYSA-J 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Chemical group 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
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- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
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- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23626300P | 2000-09-28 | 2000-09-28 | |
| US23597700P | 2000-09-28 | 2000-09-28 | |
| US23626100P | 2000-09-28 | 2000-09-28 | |
| US23626200P | 2000-09-28 | 2000-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW574070B true TW574070B (en) | 2004-02-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW090123927A TW574070B (en) | 2000-09-28 | 2001-09-27 | Halogen promoted multi-metal oxide catalyst |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US6461996B2 (enExample) |
| EP (1) | EP1192984B1 (enExample) |
| JP (1) | JP3971148B2 (enExample) |
| KR (1) | KR100809462B1 (enExample) |
| CN (1) | CN1188214C (enExample) |
| BR (1) | BR0104319A (enExample) |
| DE (1) | DE60121696T2 (enExample) |
| MX (1) | MXPA01009749A (enExample) |
| TW (1) | TW574070B (enExample) |
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| TW548133B (en) * | 2001-04-12 | 2003-08-21 | Rohm & Haas | NOx treated mixed metal oxide catalyst |
| US6740620B2 (en) * | 2001-04-25 | 2004-05-25 | Rohn And Haas Company | Single crystalline phase catalyst |
| US6642173B2 (en) * | 2001-04-25 | 2003-11-04 | Rohm And Haas Company | Catalyst |
| EP1266688A3 (en) * | 2001-06-14 | 2003-07-09 | Rohm And Haas Company | Mixed metal oxide catalyst doped by vapor depositing a metal and mixed metal oxide catalyst prepared by depositing a plurality of films of different elements using physical vapor deposition |
| ZA200208247B (en) * | 2001-10-26 | 2003-05-14 | Rohm & Haas | Treatment of mixed metal oxide catalyst. |
| CN100354042C (zh) * | 2001-11-08 | 2007-12-12 | 三菱化学株式会社 | 复合氧化物催化剂及其制备方法 |
| US6919295B2 (en) * | 2002-05-01 | 2005-07-19 | Rohm And Haas Company | Supported mixed metal oxide catalyst |
| TW200400851A (en) * | 2002-06-25 | 2004-01-16 | Rohm & Haas | PVD supported mixed metal oxide catalyst |
| US6946422B2 (en) * | 2002-12-12 | 2005-09-20 | Saudi Basic Industries Corporation | Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes |
| JP4155034B2 (ja) * | 2003-01-21 | 2008-09-24 | 東亞合成株式会社 | 金属酸化物触媒の製造方法 |
| US20050054869A1 (en) * | 2003-06-06 | 2005-03-10 | Lugmair Claus G. | Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same |
| US20050107252A1 (en) * | 2003-11-17 | 2005-05-19 | Gaffney Anne M. | Process for preparing mixed metal oxide catalyst |
| US7553986B2 (en) * | 2003-12-23 | 2009-06-30 | Rohm And Haas Company | Process for the selective (amm)oxidation of lower molecular weight alkanes and alkenes |
| BRPI0500615B1 (pt) * | 2004-03-10 | 2015-07-14 | Rohm And Haas Company | Catalisador modificado, e, sistema de catalisador modificado |
| TWI303584B (en) * | 2004-04-08 | 2008-12-01 | Rohm & Haas | Improved catalytic (amm)oxidation process for conversion of lower alkanes |
| EP1598110A1 (en) * | 2004-04-22 | 2005-11-23 | Rohm and Haas Company | Structured oxidation catalysts |
| EP1593663A1 (en) * | 2004-05-05 | 2005-11-09 | Haldor Topsoe A/S | Process for the preparation of acrolein and/or acrylic acid |
| US20060020142A1 (en) | 2004-07-23 | 2006-01-26 | Pessoa Cavalcanti Fernando A | Catalytic (AMM)oxidation process for conversion of lower alkanes to carboxylic acids and nitriles |
| US20060122055A1 (en) * | 2004-12-06 | 2006-06-08 | Gaffney Anne M | (Amm)oxidation catalyst and catalytic (amm)oxidation process for conversion of lower alkanes |
| US20060183626A1 (en) * | 2005-02-11 | 2006-08-17 | Cavalcanti Fernando Antonio Pe | Process for preparing catalysts and catalysts produced therefrom |
| EP1693107A1 (en) | 2005-02-11 | 2006-08-23 | Rohm And Haas Company | Method for preparing mixed-metal oxide catalysts and the catalysts produced thereby |
| US7795469B2 (en) | 2006-12-21 | 2010-09-14 | Rohm And Haas Company | Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes |
| JP5091715B2 (ja) | 2007-03-01 | 2012-12-05 | ローム アンド ハース カンパニー | 管から固形物を取り外し、抜き出すための装置および方法 |
| WO2013048646A1 (en) | 2011-09-29 | 2013-04-04 | Rohm And Haas Company | Process for the (amm)oxidation of lower molecular weight alkanes and alkenes |
| EP2768794B1 (en) | 2011-10-18 | 2017-08-23 | Rohm and Haas Company | Method for preparing acrylic acid from propane and propylene |
| US8945418B2 (en) * | 2011-11-16 | 2015-02-03 | The United States Of America, As Represented By The Secretary Of The Navy | Melt stabilization and vapor-phase synthesis of cesium germanium halides |
| CN105312067B (zh) * | 2014-07-11 | 2018-01-09 | 中国石油化工股份有限公司 | 低碳烷烃氨氧化催化剂 |
| CN107223127B (zh) | 2015-02-06 | 2020-09-11 | 美国陶氏有机硅公司 | 制备有机卤代硅烷的方法 |
| EP3253771B1 (en) | 2015-02-06 | 2020-08-12 | Dow Silicones Corporation | Method of producing organohalosilanes |
| CN106745647B (zh) * | 2015-11-25 | 2020-03-17 | 重庆三峡学院 | 四水合碘酸氢铈的应用 |
| KR20220004141A (ko) | 2019-05-02 | 2022-01-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 아크릴산 제조에서 고활성 및 고선택성 촉매를 사용한 알데히드 부산물의 저감 공정 |
| CN110176606A (zh) * | 2019-05-21 | 2019-08-27 | 大连理工大学 | 一种Co@NC高分散核壳结构催化剂、制备方法及其应用 |
| CN112675848B (zh) * | 2021-01-12 | 2022-07-12 | 万华化学集团股份有限公司 | 一种用于生产间苯二甲腈的催化剂、制备方法和用其制备间苯二甲腈的方法 |
| FR3156249B1 (fr) * | 2023-12-05 | 2025-10-31 | Accumulateurs Fixes | Matière active pour élément électrochimique lithium-ion |
| CN118477663B (zh) * | 2024-06-03 | 2025-09-23 | 山东玉皇化工有限公司 | 一种MoVTeNbOx系金属氧化物成型催化剂、其成型方法及应用 |
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| US4010188A (en) * | 1968-06-24 | 1977-03-01 | Standard Oil Company | Catalytic conversion of saturated hydrocarbons to unsaturated products by oxidation in the presence of a halogen |
| IN146520B (enExample) | 1976-06-30 | 1979-06-23 | Standard Oil Co Ohio | |
| JPS63122642A (ja) | 1986-11-11 | 1988-05-26 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
| EP0529853B1 (en) | 1991-08-08 | 1996-02-28 | Mitsubishi Chemical Corporation | Catalyst and process for producing nitriles |
| EP0608838B1 (en) | 1993-01-28 | 1997-04-16 | Mitsubishi Chemical Corporation | Method for producing an unsaturated carboxylic acid |
| KR100277241B1 (ko) | 1993-06-25 | 2001-02-01 | 고오사이 아끼오 | 불포화 알데하이드 및 불포화 카복실산의 제조방법 |
| JP3500663B2 (ja) | 1993-08-18 | 2004-02-23 | 三菱化学株式会社 | アクリル酸の製造方法 |
| US5534650A (en) * | 1994-01-12 | 1996-07-09 | Mitsubishi Chemical Corporation | Method for producing a nitrile |
| UA51701C2 (uk) * | 1997-10-15 | 2002-12-16 | Асахі Касеі Когіо Кабусікі Кайся | Каталізатор амоксидування та спосіб одержання акрилонітрилу або метакрилонітрилу |
| JP4166334B2 (ja) | 1998-07-24 | 2008-10-15 | 旭化成ケミカルズ株式会社 | 酸化用触媒の調製方法 |
| US6143928A (en) | 1998-08-10 | 2000-11-07 | Saudi Basic Industries Corporation | Catalysts for low temperature selective oxidation of propylene, methods of making and using the same |
| US6114278A (en) | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
| US6043185A (en) | 1999-04-02 | 2000-03-28 | The Standard Oil Company | Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
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2001
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- 2001-09-21 KR KR1020010058665A patent/KR100809462B1/ko not_active Expired - Fee Related
- 2001-09-25 DE DE60121696T patent/DE60121696T2/de not_active Expired - Fee Related
- 2001-09-25 EP EP01308121A patent/EP1192984B1/en not_active Expired - Lifetime
- 2001-09-27 MX MXPA01009749A patent/MXPA01009749A/es unknown
- 2001-09-27 TW TW090123927A patent/TW574070B/zh not_active IP Right Cessation
- 2001-09-27 BR BR0104319-6A patent/BR0104319A/pt not_active IP Right Cessation
- 2001-09-27 CN CNB011409304A patent/CN1188214C/zh not_active Expired - Fee Related
- 2001-10-12 JP JP2001315888A patent/JP3971148B2/ja not_active Expired - Fee Related
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2002
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| Publication number | Publication date |
|---|---|
| US20020058835A1 (en) | 2002-05-16 |
| US6747168B2 (en) | 2004-06-08 |
| CN1188214C (zh) | 2005-02-09 |
| EP1192984A1 (en) | 2002-04-03 |
| DE60121696D1 (de) | 2006-09-07 |
| US20030018208A1 (en) | 2003-01-23 |
| JP2003053190A (ja) | 2003-02-25 |
| DE60121696T2 (de) | 2007-08-02 |
| CN1346699A (zh) | 2002-05-01 |
| KR20020030012A (ko) | 2002-04-22 |
| US6461996B2 (en) | 2002-10-08 |
| EP1192984B1 (en) | 2006-07-26 |
| US20030176734A1 (en) | 2003-09-18 |
| KR100809462B1 (ko) | 2008-03-03 |
| US6624111B2 (en) | 2003-09-23 |
| JP3971148B2 (ja) | 2007-09-05 |
| BR0104319A (pt) | 2002-06-04 |
| MXPA01009749A (es) | 2004-08-12 |
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